Problems and Solutions to Accompany McQuarrie and Simon, Physical Chemistry: A Molecular Approach PDF
Preview Problems and Solutions to Accompany McQuarrie and Simon, Physical Chemistry: A Molecular Approach
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Coprrght 81997 by Coberiy Science Bovks TUN OPS Reproeson ge wemfaion any pat of Ei work been teal erate by Seen] a 108 ul the 1976 United Stes (Copycat tet witout tte praia of vpyeight vam Ss anlawo. Reyusis for pcasion Tne :ofomaion ‘onl be kre fe Peas Dpsninen, Uivenaty Save Books int in Vai Sates ul Arceien mye Tes Contents Preface vi Acknowledgments. ii Chauk 1 the Daven of the Quantum theory 1 MAINCHAPTTR A / Complex Numbers 1 Chavnae 2 The Classical Wave Cyalion 27 MAINCHAPITR H /Prolabisty and Stalls 47 ‘Craven 4 Ihe Schrédirgor Equation and a Panicle in 3 Box 51 MAIHCHAPRER © Vectors. 77 (Chapien 4 Some Postlates and General Principles af Quantum Mechanies i) MaTHCHArER J Spherical Coordinates 17 COhAPTER 5 The Harmonie Oscillator andthe Rigid Roar: tw Speewascopic Models 121 1 APTER 6 fThe LIydragen Atora 255 MATHCEAPTER E j Determinants 197 1 APTEK 7? f Acproximation Methads 293 1 APTER 8 ¢ Mule wutren Atoms 273 Cli#pTee 9 The Chemical Bon: Disternic Molectles 277 ‘cruapreR 10 Bo-ding in Polyauernis Molecules 301 CLinpTER TT / Computational Quanrn Chemistry 339 MATIICLIPTER = / Mawices 359 (CHAPTER 12/ Group Theory: The Bxplilalion of Symmetry 369 GUNPTER 13) Molecu ar Spectroscopy 35 Canter 14 J Nuclear Magnet Recrance Speciroscapyy 429 Craeme 15 Lasers, Loser Specoscopy, and Pholochemisiny 45% MAIHCLIPTTR CJ Numerical Methods. 475 Cavite 14 / Ihe Propecies af Gases. 481 MainChaptre H {Partial Ditirentiasion $17 CCrastue 17 J The Boltzmann Factor and Partition Functions 2 MacHCHAPTER L! Series are Limits 549 (Corie 11s Farttion kanctions ancl Kfeal Gases 53: Cuuarrre 19 J"The Kisst aw of thermody amnics. 585 MATICLIITTR |; The Binomial Distribut on and Stirling's Approximation 645 Chusptre 20 Fatropy and the Second Law of The-madynamics 621 Chuptrr 21 J Entropy and the Third Lave of Ihemagdynarycs. 647 CuiaPTER 22 Helmholtz and Cilbhs Frerpies 679 Cupersr 23 / Phase Equilibda, 721 CupeTaR 24 / Solutions I Liquid-Liquid Solutions 755 (CHAPTER 25 / Solutions I Solid-tiquid Solutions 793 1 APTER 76 Chemical Fey lineiurs 823 GuupTUR 22 / The Kinerc theory of Cases 869 CUTER 28 / Chemical Kinetics Is Rate Laws 83 CLIETER 29 { Chernical Kinetics II Reaction Mechanisms 925 CHAPTER 3017 Gas Phase Reaction Dynamics 963 CHINPTER 31 /Sotids and Surface Chemisey 989 Preface This tumual contains complete solutions 16 eseiy ume Uke mone shan £400 problems in Physieul Chemistry: A Molecular Approactt hy Donald A. MeQuarie aid Juhn D. Simon, Moy of the problems in this text invelve the mauipalation of experimental data oF cupirivally derived equations. In most casse, a geaphing piogra (euch as Kaleidagraph) is th ssl apprepriate too! to use, and most students of pysical deity already have experiences sit hese programs TFor some problen:s, however, that are unnovesearily Welious ve Gime-consuening axing 2 siuple pruphing program, J recarnmend using» progtata like Mathematica ox MathCad for related calculations and graphs. The pots of staudavd mola cManies ayia dempesatue using. cempmcet equations, tor which a function mst be defined aver varying leraperatuse range, a> sampler and podagogically move usefol with @ piogtans ht allows such definisims, Als, because the pragrsm is stved, the sock is easily checked and easily corrected, and che salenations f standard! plas quanities using re sane enupsial equations? fullos: nasal Althengh moleentar saristeal theumedgoarsic problems cau. be dune using paper and penctn thoy ac also mone Use (9 the seudoat whew peinmaed will x program suck a» Mathematica, toy alleting the student t spend mote fime opting with the eqpavons aud less Gane win na cantants fo be aniplied topsthoe Unforanatly, de learing ceeve on a program Tike Mashen of beiiy 8 Gine-saving too), ican easily become a source. of feostadan stile vue suugsles ts leaim bow le define Iuactions or how 10 fou a data set. Thave posted several siple Mathematica Ces wu Ure web sive fr this buok al lngvsewuseleks cum i vodes to eid ‘a prictical and ueful detnonstraion of le applications ith segard Ww souve probleme in peal chemistry, This ill provide the student ur professor with auune eqpusure to the available problem-solving methods, and enable thee wilh unly a basic knuwledge uf Mason id in ways dal ray eve been diel without eile have tempted to muce thie muna) as socurate as poesible, and would wppreciae boing informed ul amy eurs that are present si is pather steep nl instead Heather Cox "he 1,5, 2-7, 2115, 528, 22-25 and 12.46, 2 een 3118 2:6, 2118 ea 2-2) ho Stolen 3-49 caoegh 21-29, 28-3 ene cent Acknowledgments Jotm Simon and Dumald MeQuaris devoted much time and encrey to making sur that these solusions were both clear seul corect and Tar Snebled us them bot Cor thee substantial help. ‘sould 330 tke to Thank Bruce and Kathy Aerbrster Jur giving ne the oppurtedty 19 wock on is muual sd proving thei supeur. axl Dux. Cale, sud Bo McQuacts, wi encouraged tne every step uf Uke way, and withoul whose generous stsistamee, hospittiy, sa general arch. I woul not hve bee able w each om Let aou complete this past Problems and Solut ce accompary ear Simon CPAVSICAT GHPUISTIOY: A MOLECULAR APPROACH
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