principles of modern physics principles of modelrn physics N E I L A S H B Y S T A N L E Y C . M I L L E R University of Colorado H O L D E N - D A Y , I N C . San Francisco Cambridge London Amsterdam o Copyright 1970 by Holden-Day, Inc., 500 Sansome Street San Francisco, California All rights reserved. No part of this book may be reproduced in any form, by mimeograph or any other means, without permission in writing from the publisher. library of Congress Catalog Card Number: 71-l 13182 Manufactured in the United States of America HOLDEN-DAY SERIES IN PHYSICS McAllister Hull and David S. Saxon, Editors preface This book is intended as a general introduction to modern physics for science and engineering students. It is written at a level which presurnes a prior tull year’s course in classical physics, and a knowledge of elementary differential and integral calculus. The material discussed here includes probability, relativity, quantum me- chanics, atomic physics, statistical mechanics, nuclear physics and elementary particles. Some of these top&, such as statistical mechanics and probability, are ordinarily not included in textbooks at this level. However, we have felt that for proper understanding of many topics in modern physics--such as quaIlturn me- chanics and its applications--this material is essential. It is our opilnion that present-day science and engineering students should be able to worlk quanti- tatively with the concepts of modern physics. Therefore, we have attempted to present these ideas in a manner which is logical and fairly rigorous. A number of topics, especially in quantum1 mechanics, are presented in greater depth than is customary. In many cases, unique ways of presentation are given which greatly simplify the discussion of there topics. However, few of the developments require more mathematics than elementary calculus and the algebra of complex nurn- bers; in a few places, familiarity with partial differentiation will be necessary. Unifying concepts which halve important applications throughout modern physics, such as relativity, probability and the laws of conservation, have been stressed. Almost all theoretical developments are linked to examples and data taken from experiment. Summaries are included at the end of each chapter, as well as problems with wide variations in difficulty. This book was written for use in a one-semester course at the sophlomore or iunior level. The course could be shortened by omitting some topics; for example, Chapter 7, Chapter 12, Chapters 13 through 15, and Chapter 16 contain blocks of material which are somewhat independent of each other. The system of units primarily used throughout is the meter-kilogram-second system. A table of factors for conversion to other useful units is given in Appen- dix 4. Atomic mass units are #defined with the C” atom as tihe standard. We are grateful for the helpful comments of a large number of students, who used the book in preliminary term for a number of years. We also thank our colleagues and reviewers for their constructive criticism. Finally, we wish to ex- press our thanks to Mrs. Ruth Wilson for her careful typing of the manuscript. vii contents 1 INTRODUCTION 1 .l HISTORICAL SURVEY 1.2 NOTATION AND UNITS 1.3 UNITS OF ENERGY AND MOMENTUM 1.4 ATOMIC MASS UNIT 1.5 PROPAGATION OF WAVES; PHASE AND GROUP SPEEDS 1.6 COMPLEX NUMBERS 2 PROBABILITY 2.1 DEFINITION OF PROBABILITY 2.2 SUMS OF PROBABILITIES 2.3 CALCULATION OF PROBABILITIES BY COUN’TING 2.4 PROBABILITY OF SEVERAL EVENTS OC:CUF!RING TOGETHER 2.5 SUMMARY OF RULES FOR CALCULATINIG PROBABILITIES 2.6 DISTRYBUTION FUNCTIONS FOR COIN FLIPPING 2.7 DISTRIBUTION FUNCTIONS FOR MORE THAN TWO POSSIBLE OUTCOMES 2.8 EXPECTATION VALUES 2.9 NORMALIZATION 2.10 EXPECTATION VALUE OF THE NUMBER OF HEADS 2.1 1 EXPERIWIENTAL DETERMINATION OF PROBABILITY 2.12 EXPERIMENTAL ERROR 2.13 RMS DEVIATION FROM THE MEAN 2.114 RMS DEVIATION FOR COIN FLIPPING 2.15 ERRORS IN A COIN-FLIPPING EXPERIMENT 2.16 ERRORS IN AVERAGES OF REPEATED EXPERIMENTS 2.17 PROBABILITY DENSITIES 2.18 EXPECTATION VALUES FROM PROBABILITY DENSITIES 2.19 GAUSS1A.N DISTRIBUTION 2.20 EXPECTATION VALUES USING A GAUSS1A.N DISTRIBUTION SUMh\ARY PROBLEMS 3 SPECIAL THEORY OF RELATIVITY 3.1 CONFLICT BETWEEN ULTIMATE SPEED AND NEWTON’S LAWS 1 1 3 .4 .5 (6 :3 II 1 :2 1 :3 14 14 1:s 16 19 20 2 ‘I 2 ‘I 22 24 24 25 27 28 30 3:! 34 35 37 3Ei 421 42 ix 3.2 CLASSICAL MOMENTUM AND EINERGY CONSERVATION- COINFLICT WITH EXPERIMENT 3.3 CONSERVATION OF MASS-COlNFLICT WITH EXPERIMENT 3.4 CORRESPONDENCE PRINCIPLE 3.5 INERTIAL SYSTEMS 3.6 NON-INERTIAL SYSTEMS 3.7 AXES RELATIVE TO FIXED STARS 3.8 GALILEAN TRANSFORMATIONS 3.9 GALILEAN VELOCITY TRANSFORMATIONS 3.10 SECGND LAW OF MOTION UNDER GALILEAN TRANSFORMATIONS 3.11 THIRD LAW UNDER GALILEAN TRANSFORMATIONS :3.12 MICHELSON-MORLEY EXPERIMENT 3.13 POSTULATES OF RELATIVITY 3.14 EXPERIMENTAL EVIDENCE FOR THE SECOND POSTULATE 3.15 GALILEAN TRANSFORMATIONS AND THE PRINCIPLE OF RELATIVITY 3.16 TRANSFORMATION OF LENGTHS PERPENDICULAR TO THE RELATIVE VELOCITY 3.17 TIME DILATION 3.18 LENGTH CONTRACTION 3.19 LORENTZ TRANSFORMATIONS 3.20 SIMULTANEITY 3.21 TRANSFORMATION OF VELOCITIES SUMMARY PROBLEMS 4 RELATIVISTIC MECHANICS AND DYNAMICS 4.1 LORENTZ TRANSFORMATIONS 4.2 DISCREPANCY BETWEEN EXPERIMENT AND NEWTONIAN MOMENTUM 4.3 MOMENTUM FROM A THOUGHT EXPERIMENT 4.4 EXPERIMENTAL VERIFICATION OF MASS FORMULA 4.5 RELATIVISTIC SECOND LAW OF MOTION 4.6 THIRD LAW OF MOTION AND CONSERVATION OF MOMENTUM 4.7 RELATIVISTIC ENERGY 4.8 KINETIC ENERGY 4.9 POTENTIAL ENERGY AND CONSERVATION OF ENERGY 4.10 EXPERIMENTAL ‘VERIFICATION OF EQUIVALENCE OF MASS AND ENERGY 4.11 RELATIONSHIP BETWEEN ENERGY AND MOMENTUM 4:12 REST MASS (OF ilo FROM EXPERIMENT 4.13 TRANSFORMATION PROPERTIES OF ENERGY AND MOMENTUM 43 44 47 47 49 50 51 52 53 54 54 55 57 59 59 60 64 65 67 71 74 76 79 79 80 81 83 85 85 86 87 88 89 89 90 96 Contents xi 4.14 TRANSFORMATIONS FOR FREQUENCY AND WAVELENGTH 4.15 TRANSVERSE DijPPLER EFFECT 4.16 LONGITUDINAL DOPPLER EFFECT SUMMARY PROBLIfMS 5 QUANTUM PROPERTIES OF LIGHT 5.1 ENERGY TRANSFORMATION FOR PARTICLES OF ZERO REST MASS 5.2 FORM-INVARIANCE OF E = hv 5.3 THE DUANE-HUNT L.AW 5.4 PHOTOELECTRIC EFFECT 5 . 5 COMPTON E F F E C T 5.6 PAIR PRODUCTION AND ANNIHILATION 5.7 UNCERTAINTY PRINCIPLE FOR LIGHT WAVES 5.8 MOMENTUM, POSITION UNCERTAINTY 5.9 PROBABILITY INTERPRETATION OF AMPLITUIDES SUMMARY PROBLEMS 6 MATTER WAVES 6.1 PHASE OF .4 PLANE WAVE 6.2 INVARIANCE OF THE PHASE OF .A PLANE WAVE 6.3 TRANSFORMATION EQUATIONS FOR WAVEVECTOR A,ND FREQUENCY 6.4 PHASE SPEED OF DE BROGLIE WAVES 6.5 PARTICLE INCIDENT ON INTERFACE SEPARATING DIFFERENT POTENTIAL ENERGIES 6.6 WAVE RELATION AT INTERFACE 6.7 DE BROGLIE RELATIONS 6.8 EXPERIMENTAL DETERMINATION OF A 6 . 9 BRA.GG EQUATION 6.10 DIFFRACTION OF ELECTRONS 6.11 UNCERTAINTY PRINCIPLE FOR PARTICLES 6.12 UNCERTAINTY AND SINGLE SLIT DIFFRACTION 6.13 UNCERTAINTY IN BALANCING AN OBJECT 6.14 ENERGY-TIME UNCERTAINTY 6.15 PROBABILITY INTERPRETATION OF VVAVEFUNCTllON 6.16 EIGENFUNCTIONS OF ENERGY AND MOMENTUM OPERATORS 6.17 EXPECTATION VALUES FOR MOMENTUM IN A PARTICLE BEAM 6.18 OPERATOR FORMALISM FOR CALCULATION OF MOMENTUM EXPECTATION VALLJES 6.19 ENERGY OPERATOR AND EXPECTATION VALUES 6 . 2 0 SCHRODINGER EQUATllON 99 101 102 104 105 110 111 112 113 115 1119 123 126 128 129 131 13i 136 136 138 139 141 143 144 145 146 147 148 152 152 155 155 156 158 160 162 164 165 xii Contents 6.21 SCHRijDlNGER EQUATION FOR VARIABLE POTENTIAL 6.22 SOLUTION OF THE SCHRijDlNGER EQUATION FOR A CONSTANT POTENTIAL 6.23’ BOUNDARY CONDITIONS SUMMARY PROBLEMS 167 7 EXAMPLES OF THE USE OF SCHRiiDINGER’S EQUATION 7.1 FREE PARTICLE GAUSSIAN WAVE PACKET 7.2 PACKET AT t = 0 7.3 PACKET FOR t > 0 7.4 STEP POTENTIAL; HIGH ENERGY E > V, 7.5 BEAM OF INCIDENT PARTICLES 7.6 TRANSMISSION AND REFLECTION COEFFICIENTS 7.7 ENERGY LESS THAN THE STEP HEIGHT 7.8 TUNNELING FOR A SQUARE POTENTIAL BARRIER 7.9 PARTICLE IN A BOX 7.10 BOUNDARY CONDITION WHEN POTENTIAL GOES TO INFINITY 169 170 172 175 178 178 180 181 183 185 186 187 188 190 7.11 STANDING WAVES AND DISCRETE ENERGIES 7.12 MOMENTUM AND UNCERTAINTY FOR A PARTICLE IN A BOX 192 192 7.‘13 LINEAR MOLECULES APPROXIMATED BY PARTICLE IN A BOX 7.14 HARMONIC OSCILLATOR 7.15 GENERAL WAVEFUNCTION AND ENERGY FOR THE HARMONIC OSCILLATOR 7.16 COMPARISON OF QIJANTUM AND NEWTONIAN MECHANICS FOR THE HARMONIC OSCILLATOR 7.17 CORRESPONDENCE PRINCIPLE IN QUANTUM THEORY SUMMARY PROBLEMS 194 195 196 198 8 HYDROGEN ATOM AND ANGULAR MOMENTUM 8.1 PARTICLE IN A BOX 8.2 BALMER’S EXPERIMENTAL FORMULA FOR THE HYDROGEN SPECTRUM 204 207 208 209 213 213 8.3 SPECTRAL SERIES FOR HYDROGEN 8.4 BOHR MODEL FOR HYDROGEN 8.5 QUANTIZATION IN THE BOHR MODEL 8.6 REDUCED MASS 8.7 SCHRoDlNGER EQUATION FOR HYDROGEN 8.8 PHYSICAL INTERPRETATION OF DERIVATIVES WITH RESPECT T O r 215 216 217 218 220 221 8.9 SOLUTIONS OF THIE SCHRijDlNGER EQUATION 8.10 BINDING ENERGY AND IONIZATION ENERGY 8.11 ANGULAR MOMENTUM IN QUANTUM MECHANICS 8.12 ANGlJLAR MOMENTUM COMPONENTS IN SPHERICAL 223 225 230 230 COORDINATES 231 C o n f e n t s *‘* XIII 8.13 EIGENFUNCTIONS OF L,; AZIMUTHAL QUANTU,M NUMBER 8.14 SQUARE OF THE TOTAL ANGULAR MOMENTUM 8.15 LEGENDRE POILYNOMIALS 8.16 SlJMMARY OF QUANTUM NUMBERS FOR THE HYDROGEN ATOM 8.17 ZEEMAN EFFECT 8.18 SPLITTING OF LEVELS IN A MAGNETIC FIELD 8.19 SELECTION RULES 8.20 NORMAL ZEEMAN SPLITTING 8.21 ELECTRON SPIN 8.22 SPIN-ORBIT INTERACTION 8.23 HALF-INTEGRAL SPINS 8.24 STERN-GERLACH EXPERIMENT 8.25 SUMS OF ANGULAR ,MOMENTA 8.26 ANOMALOUS ZEEMAN EFFECT 8.27 RIGID DIATOMIC ROTATOR SUMMARY PROBLEMS 9 PAW EXCLUSION PRINCIPLE AND THE PERIODIC TABLE 9.1 DESIGNATION OF ATOMIC STATES 9.2 NUMBER OF STATES IN AN n SHELL 9.3 INDISTINGUISHABILITY OF PARTICLES 9.4 PAULI EXCLUSION PRINCIPLE 9.5 EXCLUSION PRINCIPLE AND ATOMIC ELECTRON STATES 9.6 ELECTRON CONFIGURATIONS 9.7 INERT GASES 9.8 HALOGENS 9 . 9 ALKAILI METALS 9.10 PERIODIC TABLE OF THE ELEMENTS 9.1 11 X-RAYS 9.12 ORTHO- AND PARA-H’YDROGEN !jUMMARY PROBLEMS 1 0 C L A S S I C A L S T A T I S T I C A L M E C H A N I C S 10.1 PROBABILITY DISTIPIBUTION IN ENERGY FOR SYSTEMS IN THERMAL EQ~UILIBRIUM 10.2 BOLTZMANN DISTRIBUTION 10.3 PROOF THAT P(E) IS OF EXPONENTIAL FORM 10.4 PHA!jE SPACE 10.5 PHASE SPACE DISTRIBUTION FUNCTIONS 10.6 MAXWELL-BOLTZMANN DISTRIBUTION 10.7 EVALUATION OF /I 10.8 EVALUATION OIF NP(O)p lo..9 MAXWELL-BOLTZMANN DISTRIBUTION INCLUDING POTENTIAL ENERGY 10.10 GAS IN A GRAVITATIONAL FIELD 232 233 234 235 236 237 238 239 240 240 241 242 242 243 244 246 249 254 255 256 256 258 260 262 263 265 265 266 270 273 273 275 279 280 281 282 283 285 287 288 291 292 293 xiv Contenfs 10.11 DISCRETE ENERGIES 10.12 DISTRIBUTION OF THE MAGNITUDE OF MOMENTUM 10.13 EXPERIMENTAL VERIFICATION OF MAXWELL DISTRIBUTION 10.14 DISTRIBUTION OF ONE COMPONENT OF MOMENTUM 10.15 SIMPLE HARMONIC OSCILLATORS 10.16 DETAILED BALANCE 10.17 TIME REVERSIBILITY SUMMARY PROBLEMS 11 QUANTUM STATISTICAL MECHANICS 11.1 EFFECTS OF THE EXCLUSION PRINCIPLE ON STATISTICS OF PARTICLES 11.2 DETAILED BALANCE AND FERMI-DIRAC PARTICLES 11.3 FERMI ENERGY AND FERMI-DIRAC DISTRIBUTION 11.4 ONE DIMENSIONAL DENSITY OF STATES FOR PERIODIC BOUNDARY CONDITIONS 11.5 DENSITY OF STATES IN THREE DIMENSIONS 11.6 COMPARISON BETWEEN THE CLASSICAL AND QUANTUM DENSITIES OF STATES 11.7 EFFECT OF SPIN ON THE DENSITY OF STATES 11.8 NUMBER OF STATES PIER UNIT ENERGY INTERVAL 11.9 FREE PARTICLE FERMI ENERGY-NONDEGENERATE CASE 11.10 FREE ELECTRONS IN METALS-DEGENERATE CASE 11.11 HEAT CAPACIITY OF AN ELECTRON GAS 11.12 WORK FUNCTION 11 .lm 3 PHOTON DISTRIBUTION 11.14 PLA.NCK RADIATION FORMULA 11 .15 SPONTANEOUS EMISSION 11.16 RELATIONSHIP BETWEEN SPONTANEOUS AND STIMULATED EMISSION 11.17 ORIGIN OF THE FACTOR 1 + II, IN BOSON TRANSITIONS 1 I .18 BOSE-EINSTEIN DISTRIBUTION FUNCTION SUMMARY PROBLEMS 112 SOLID STATE PHYSICS 12.1 CLASSIFICATION OF CRYSTALS 12.2 REFLECTION AIND ROTATION SYMMETRIES 12.3 CRYSTAL BINDING FORCES 12.4 SOUND WAVES IN A CONTINUOUS MEDIUM 12.5 WAVE EQUATION FOR SOUND WAVES IN A DISCRETE MEDIUM 12.6 SOLUTIONS OF THE WAVE EQUATION FOR THE DISCRETE MEDIUM 12.7 NUMBER OF SOLUTIONS 12.8 LINEAR CHAIN WITH TWO MASSES PER UNIT CELL 294 295 296 298 300 303 305 306 308 312 313 313 315 316 318 319 320 320 321 323 324 325 326 328 331 332 333 335 336 338 341 341 342 346 347 349 351 352 354 contents xv 12.9 ACOUSTIC AND ‘OPTICAL BRANCHES 12.10 ENERGY OF LATTICE VIBRATIONS 12.11 ENERGY FOR A SUPERPOSITION OF MODES 12.12 QUANTUM THIEORY OF HARMONIC OSCILLATORS AND LATTICE VIBRATIONS 12.13 PHONONS; AVEl?AGE ENERGY PER MODE AS A FUNCTION O F TEMPERATIJRE 12.14 LATTICE SPECIFIC HEAT OF A SOLID 12.15 ENERGY BANDS OF ELECTRONS IN CRYSTALS 12.16 BLOCH’S THEOREM 12.17 NUMBER OF BLOCH FUNCTIONS PER BAND 12.18 TYPES OF BANDS 12.19 EFFECTIVE MASS IN A BAND 12.20 CONDIJCTORS, INSULATORS, SEMICONDUCTORS 1 2 . 2 1 H O L E S 12.2;! n-TYPE AND p-TYPE SEMICONDUCTORS ‘12.23 H.ALL EFFECT SUMMARY PROBLEMS 13 PROBING THE NUCLEUS 13.1 A NUCLEAR MODEL 13.2 LIMITATIONS ON NUCLEAR SIZE FROM ATOMIC CONSIDERATIONS 13.3 SCATTERING EXPERIMENTS 13.4 CROSS-SECTIONS 13.5 DIFFERENTIAL CROSS-SECTIONS 13.6 NUMBER OF SCATTERERS PER UNIT AREA 13.7 BARN AS A UNIT OF CROSS-SECTION 13.8 a AND @ PARTICLES 13.9 RUTHERFORD MODEL OF THE ATOM 13.10 RUTHERFORD THEORY; EQUATION OF ORBIT 113.11 RUTHERFORD SCATTERING ANGLE 13.12 RUTHERFORD DIFFERENTIAL CROSS-SECTION 13.13 MEASUREMENT OF THE DIFFERENTIAL CROSS-SECTION 13.14 EXPERIMENTAL VERIFICATION OF THE RLJTHERFORD SCATTERING FORMlJLA 13.15 PARTICLE ACCELERATORS SUMMARY PROBLEMS 14 NUCLEAR STRUCTURE 14.1 NUCLEC\R M A S S E S 14.2 NEUTRONS IN THE NUCLEUS 14.3 PROPERTIES OF THE NEUTRON AND PROTON 1 4 . 4 T H E DEUTERON (,H’) 14.5 NUCLEAR FORCES 14.6 YUKAWA F O R C E S 356 357 359 360 361 362 364 365 366 367 368 369 371 372 373 374 377 381 381 383 385 386 387 390 390 391 393 394 395 397 398 400 402 404 405 408 408 410 411 414 416 418