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388 Pages·1975·16.779 MB·English
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PERGAMON MATERIALS ADVISORY COMMITTEE SIR MONTAGUE FINNISTON, F.R.S., Chairman DR. G. ARTHUR PROFESSOR J. W. CHRISTIAN, M.A., D.PHIL., F.R.S. PROFESSOR R. W. DOUGLAS, D.SC. PROFESSOR MATS HILLERT, SC.D. D. W. HOPKINS, M.SC. PROFESSOR H. G. HOPKINS, D.SC. PROFESSOR W. S. OWEN, D.ENG., PH.D. PROFESSOR G. V. RAYNOR, F.R.S. LT.-COL. CHARLES GUILLAN, Executive Member OTHER TITLES IN THE INTERNATIONAL SERIES ON MATERIALS SCIENCE AND TECHNOLOGY KUBASCHEWSKI, EVANS & ALCOCK Metallurgical Thermochemistry RAYNOR The Physical Metallurgy of Magnesium and its Alloys WEISS Solid State Physics for Metallurgists PEARSON A Handbook of Lattice Spacings and Structures of Metals and Alloys—Volume 2 MOORE The Friction and Lubrication of Elastomers WATERHOUSE Fretting Corrosion REID Deformation Geometry for Materials Scientists BLAKELY Introduction to the Properties of Crystal Surfaces GRAY & MULLER Engineering Calculations in Radiative Heat Transfer MOORE Principles and Applications of Tribology CHRISTIAN The Theory of Transformations in Metals and Alloys Part 1, 2nd Edition HULL Introduction to Dislocations, 2nd Edition OTHER TITLES OF INTEREST IN THE PERGAMON INTERNATIONAL LIBRARY GABE Principles of Metal Surface Treatment and Protection GILCHRIST Extraction Metallurgy SARKAR Mould and Core Material for the Steel Foundry SMALLMAN & ASHBEE Modern Metallography A complete catalogue of all books in the Pergamon International Library is available on request. The terms of our inspection copy service apply to all the above books. A complete catalogue of all books in the Pergamon International Library is available on request. The Publisher will be pleased to receive suggestions for revised editions and new titles. PRINCIPLES A ND A P P L I C A T I O NS OF T R I B O L O GY DESMOND F. MOORE B.E., M.S., Ph.D., C.Eng., F.I.E.I., M.I.Mech.E., M.A.S.M.E. Lecturer in Mechanical Engineering, University College, Dublin, Ireland Director, International Mechanical Consultants Ltd. P E R G A M ON PRESS Oxford · New York • Toronto · Sydney · Paris · Braunschweig U.K. Pergamon Press Ltd., Headington Hill Hall, Oxford OX3 OBW, England U.S.A. Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, New York 10523, U.S.A. CANADA Pergamon of Canada, Ltd., 207 Queen's Quay West, Toronto 1, Canada AUSTRALIA Pergamon Press (Aust.) Pty. Ltd., 19a Boundary Street, Rushcutters Bay, N.S.W. 2011, Australia FRANCE Pergamon Press SARL, 24 rue des Ecoles, 75240 Paris, Cedex 05, France WEST GERMANY Pergamon Press G MbH D-3300 Braunschweig, Postfach 2923, Burgplatz 1, West Germany Copyright © 1975 Desmond F. Moore All Rights Reserved. No part of this publication may be reproduced, stored in a retrieval system or transmitted in any form or by any means: electronic, electrostatic, magnetic tape, mechanical, photocopying, recording or otherwise, without permission in writing from the publishers First edition 1975 Library of Congress Cataloging in Publication Data Moore, Desmond F. Principles and applications of tribology. (International series in materials science and technology, v. 14) Includes bibliographical references. 1. Tribology. I. Title. TJ1075. M59 1975 621.8 9 74-4261 ISBN 0-08-017902-9 ISBN 0-08-019007-3 (Flexi) Printed in Great Britain by A. Wheaton & Co., Exeter. PREFACE TRIBOLOGY is defined as the science and practice of friction, lubrication and wear applied to engineering surfaces in relative motion. In recent years it has become widely recognized as a truly diverse and interdisciplinary field of study. Physics, chemistry, metallurgy, mate- rials science, rheology, lubrication, elasticity, viscoelasticity, elastohydrodynamics, thermo- dynamics and heat transfer play complex and interactive roles in determining the general condition of surface friction. It has been estimated that approximately one third to one-half of the world's energy resources in present use appears ultimately as friction in one form or another. The importance of friction and wear in our modern world cannot therefore be over-emphasized. This book attempts to deal with the whole field of tribology in a single volume. While some may consider this an impossible task, there are those, including the author, who feel that today's engineering student deserves a relatively simple and unified treatment of the subject area. In pursuing this objective, the contents of the book have been divided into two sections dealing broadly with principles and applications respectively. The text is written from the point of view of the mechanical engineer, and the section on principles emphasizes a fundamental understanding of the subject matter before proceeding to a diversity of practical applications. Although the complete text is presented in systematic order, the chapters are to a large extent independent and self-sufficient and may therefore be selected in a diffιrent order suitable to a particular course of instruction. Chapter 1 deals with the immense scope of tribology and range of applications in the modern world of technology. Chapter 2 is devoted entirely to the evaluation and measurement of surface texture. Chapters 3, 4 and 5 present the fundamental concepts underlying the friction of metals, elastomers and other materials respectively. The principles of hydrodynamic lubrication are dealt with briefly in Chapter 6, and the mechanisms of boundary and elastohydrodynamic lubrication receive a more comprehensive treatment in Chapters 7 and 8 respectively. Chapter 9 is a generalized treatise on wear and abrasion phenomena in metals and elastomers. Whereas surface inter- actions are dealt with exclusively throughout Chapters 2 to 8, internal friction in solids, liquids and gases is identified and explained in Chapter 10. Chapter 11 is an abbreviated yet thorough treatment of experimental methods used in tribological studies. The remaining five chapters in the book are devoted to specific applications, including manufacturing processes, automotive applications, transportation, locomotion, bearing design and miscel- laneous. Because of the immense scope of the subject matter, omissions must inevitably occur in a xi χίί Preface limited text on tribology, but it is hoped that the number of these has been kept to a mini- mum. Above all, it is hoped to impress upon the student the relevance of tribology to his entire mechanized society, and to stimulate his interest in this important new field of engineering science. In attempting to achieve these objectives, a basic understanding of tribological principles is combined with as many practical examples as possible in a text of reasonable size. The author expresses his sincere appreciation to Professor W. E. Meyer from the Penn- sylvania State University, Professor H. C. A. van Eldik Thieme from the Technische Hoge- school in Delft and Professor Dr.-Ing. A. W. Hussmann from the Technische Universitδt in Munich who stimulated and promoted in different ways the author's continuing interest in this subject. Particular acknowledgement is due my colleague and close friend Dr.-Ing. W Geyer, formerly from the Technische Universitδt in Munich, whose enthusiasm and support have proved invaluable during the past three years. Mr. D. W. Hopkins from the University College of Swansea as series editor for the book deserves special thanks for reviewing the manuscript and offering helpful suggestions. Finally, a word of appreciation to Miss Gιraldine Warren for her excellent typing skills, and to my wife Miriam for her patience and understanding during the preparation of the manuscript. Dublin D. F. MOORE C H A P T ER 1 INTRODUCTION 1.1 Definition and Scope of Tribology Tribology is defined as the science and technology of interacting surfaces in relative motion, having its origin in the Greek word tribos meaning rubbing. It is a study of the friction, lubrication, and wear of engineering surfaces with a view to understanding surface interactions in detail and then prescribing improvements in given applications. The scope of tribology is, in fact, much broader than this definition implies. According to Dr. Salomon, former editor of the international journal Wear, "Tribology means a state of mind and an art: the intellectual approach to a flexible cooperation between people of widely differing background. It is the art of applying operational analysis to problems of great economic significance, namely : reliability, maintenance and wear of technical equipment, ranging from spacecraft to household appliances." The work of the tribologist is truly interdisciplin- ary, embodying physics, chemistry, mechanics, thermodynamics, and materials science, and encompassing a large, complex, and intertwined area of machine design, reliability, and performance where relative motion between surfaces is involved. It is estimated that approximately one-third of the world's energy resources in present use appear as friction in one form or another. This represents a staggering loss of potential power for today's mechanized society. The purpose of research in tribology is understand- ably the minimization and elimination of unnecessary waste at all levels of technology where the rubbing of surfaces is involved. Indeed, sliding and rolling surfaces represent the key to much of the effectiveness of our technological society. We may ask : What do rubbing surfaces cost the economy of our Western world? No one has yet offered a precise figure, but an estimate may be obtained from British figures. According to a report by the Committee on Tribology in Great Britain in 1965, approxi- mately £500 million is lost annually in worn parts within the United Kingdom alone because of the failure of industry to understand what happens to surfaces which must move across one another. The problem is of such gigantic proportions that tribological programmes have been established by industry and government in the United Kingdom, the Soviet Union, and several western European countries, and by individual corporations in the United States. Since World War II, the rapid rate of technological advancement has required great expansion in research on what to do about surfaces that rub. The obvious approach has 3 4 Principles and Applications of Tribology focused on learning how to oil, grease, or otherwise lubricate them. Thus conventional lubrication has been concerned with : (a) evaluating lubricants in the light of standard specifications; (b) compounding lubricants to meet new conditions, or (c) determining how lubricants respond to cold, heat, nuclear radiation, and other en- vironments and to the materials to be lubricated. Much of the technology associated with rubbing surfaces still involves conventional lubrication following the above procedure. Indeed, before the 1950s, most mechanical devices were lubricated primarily by mineral oils and soap-thickened mineral-oil greases, and the selection of lubricants for given uses was largely empirical. Now, however, synthetic materials have found increasing usage in lubrication, and extensive programmes of research and development make it possible to design lubricants to meet unusual or increasingly severe requirements. Complex systems such as nuclear submarines, supersonic aircraft or Apollo spacecraft demand the solution of critical lubrication problems. Thus advancing technology has brought us to the point where every aspect of the phenomena associated with rubbing surfaces must be investigated, and the new discipline—tribology—plays an increasing role in our mechanized environment. One of the important objectives in tribology is the regulation of the magnitude of frictional forces according to whether we require a minimum (as in machinery) or a maximum (as in the case of anti-skid surfaces). It must be emphasized, however, that this objective can be realized only after a fundamental understanding of the frictional process is obtained for all conditions of temperature, sliding velocity, lubrication, surface finish, and material pro- perties. This book is written to explain the fundamentals of tribology in the simplest terms and to illustrate the basic concepts with a variety of everyday applications. 1.2 Macroscopic and Microscopic Viewpoints The friction force generated between two bodies having relative tangential motion can be considered as a macroscopic or microscopic mechanism, depending on the interest and orientation of the reader. The microscopic or molecular mechanism can also be described as causative, since the molecular interaction of surface molecules of the sliding pair is treated in some detail and for a variety of experimental conditions to establish the true cause of the friction mechanism. This approach has obviously more appeal for the physicist or physical chemist. On the other hand, the macroscopic mechanism is often referred to as resultant, being based on a relatively crude simulation of frictional events and usually follow- ing a simple yet adequate model representation. Here, the simplistic treatment and emphasis on applications rather than underlying causes are of more interest to the engineer. It is not the purpose of this text to extol the virtues of either approach at the expense of the other. Indeed, both mechanisms should be treated in unison, each complementing the other where appropriate, so that a full comprehension of tribological principles emerges. This text is written with such an objective in mind. It is interesting to note that the most commonly Introduction 5 accepted welding-shearing-ploughing theory of metallic friction (1) can be classified as macroscopic since there is no mention of surface molecular activity. On the other hand, most of the current theories of elastomeric friction <2) describe adhesion as a thermally activated molecular-kinetic exchange mechanism, so that the microscopic viewpoint is adopted. The essential différence between the macroscopic and microscopic approaches, apart from the scale of events, is the distinction between a continuum and reality. In the vicinity of a frictional interface, each surface molecule pervades a volume greater than atomic dimen- sions and is continually vibrating and twisting with thermal energy. The interchange of these molecules as one surface captures and in turn loses some of its surface molecules to the mating surface is, of course, the reality which gives rise to adhesional friction. For a finite surface area, however, the number of degrees of freedom associated with such molecular activity is prohibitively large even for the modern computer to handle, and we therefore use either of two approaches : (a) we may apply statistical techniques to evaluate mean or averaged values of molecular motion and forces, or (b) we may neglect molecular activity entirely and treat both sliding materials as a con- tinuum having the same general properties as those observed from experiment. Thus the microscopic approach, while relatively precise in its representation of surface interactions, is severely limited in terms of applications, whereas the macroscopic approach has the opposite characteristics. The use of mechanical models (embodying springs and dashpots in different combinations) is widespread in the simulation of continuum behaviour, and it must be realized that they are merely a tool for predicting dynamic performance in viscoelastic bodies. We might generally conclude that a microscopic understanding of the frictional process is of inestimable value in establishing the validity of a macroscopic model for practical applications. 1.3 Internal and External Friction It is desirable at this stage to distinguish between internal and external friction in bodies. Surface interactions in general can be classified under the general term external friction for obvious reasons, whereas molecular-kinetic events and bulk energy dissipation occurring within the body of a material are the cause and result respectively of internal friction. The physicist will define a surface as a boundary having zero thickness, and of course, such do not exist in practice. We must therefore modify this definition and permit a surface to occupy an infinitesimal thickness layer perhaps measurable in Angstrom units. The origin of "surface" frictional forces is molecular-kinetic interchange as described previously, and this occurs within such layers which can be measured in both sliding members. This com- posite activity layer approaches zero dimensions in practical terms. Internal friction in solids is a direct consequence of the forced motion of bulk molecules which under equilibrium are closely spaced and exhibit a strong mutual attraction or 2 M: PAT: 2 6 Principles and Applications of Tribology repulsion for each other (see Chapter 10). Such motion causes internal shearing in the material of the body and results in internal heat generation. It is common to express internal friction as damping capacity, loss tangent, or tangent modulus. In the case of liquids and gases, internal friction is expressed as absolute or kinematic viscosity. Perhaps a pneumatic tyre offers the clearest example of both internal and external friction. During normal rolling, the body or carcass of the tyre increases in temperature as a result of con- tinual flexing and recovery of tread elements entering and leaving the contact patch. This is the internal friction generation mechanism. At the same time, the localized "squirming" of tread rubber over road asperities during rolling, braking, driving, and cornering gives rise to the external friction component which largely controls and steers the vehicle. The relative magnitude of the internal and external frictional mechanisms in this example depends to a large extent on the mode of operation of the vehicle and experimental con- ditions. 1.4 Dry and Lubricated Surfaces The most important criterion from a design viewpoint in a given application is whether dry or lubricated conditions are to prevail at the sliding interface. In many applications such as machinery, it is known that only one condition shall prevail (usually lubrication), al- though several régimes of lubrication may exist. There are a few cases, however, where it cannot be known in advance whether the interface is dry or wet, and it is obviously more difficult to proceed with any design. The commonest example of this phenomenon is again the pneumatic tyre. Under dry conditions it is desirable to maximize the adhesion 1" compo- nent of friction by ensuring a maximum contact area between tyre and road—and this is achieved by having a smooth tread and a smooth road surface. Such a combination, how- ever, would produce a disastrously low coefficient of friction under wet conditions. In the latter case, an adequate tread pattern and a suitably textured road surface offer the best conditions, although this combination gives a lower coefficient of friction in dry weather. The several lubrication régimes which exist may be classified as hydrodynamic, boundary, and elastohydrodynamic. The different types of bearing used today (journal, slider, thrust, and foil bearings) are the best examples of fully hydrodynamic behaviour, where the sliding surfaces are completely separated by an interfacial lubricant film. Boundary or mixed lubrication is a combination of hydrodynamic and solid contact between moving surfaces, and this régime is normally assumed to prevail when hydrodynamic lubrication fails in a given product design. For example, ajournai bearing is designed to operate at a given load and speed in the fully hydrodynamic region, but a fall in speed or an increase in load may cause part solid and part hydrodynamic lubrication conditions to occur between the journal and bearing surfaces. This boundary lubrication condition is unstable, and normally recovers to the fully hydrodynamic behaviour or degenerates into complete seizure of the surfaces. The pressures developed in thin lubricant films may reach proportions capable of t Friction comprises two principal components, adhesion and deformation, as shown in Chapter 3. Introduction 7 elastically deforming the boundary surfaces of the lubricant, and conditions at the sliding interface are then classified as elastohydrodynamic. It is now generally accepted that elasto- hydrodynamic contact conditions exist in a variety of applications hitherto considered loosely as belonging to the hydrodynamic or boundary lubrication régimes; for example, the contact of mating gear teeth, or that of ball-bearings in races, or lip seals on machined rotating shafts, etc. Solid lubricants exhibit a compromise between dry and lubricated conditions in the sense that although the contact interface is normally dry, the solid lubricant material behaves as though initially wetted. This is a consequence of a physico-chemical interaction occurring at the surface of a solid lubricant lining under particular loading and sliding conditions, and these produce the equivalent of a lubricating effect. 1.5 The Range of Applications One useful method of classifying tribology applications is to distinguish between rigid- rigid, rigid-flexible, and flexible-flexible surface pairings, as indicated in Table 1.1. The rigid-rigid pairing appears to be the most common type, the usual application being the friction of metal-on-metal. Table 1.1 illustrates the application of tribological principles to manufacturing technology, the central column indicating the particular manufacturing TABLE 1.1. TRIBOLOGICAL PROCESSES IN MANUFACTURING Tribological Manufacturing processes Related industry classification Metal-on-metal Forging Reaming Wire manufacture (rigid-rigid) Stamping Guillotining Iron and steel manufacturing surface pairing" Grinding Drawing Metal processing Milling Extrusion Tool design Lapping Forming Mechanical components Spinning Swaging Machine design Plastic6-on-metal Injection and blow moulding Tyre manufacture (flexible-rigid) Cold working Extrusion Plastics industry surface pairing" Thermo forming Drawing Building and construction Vacuum forming Coating Electrical insulation Laminating Shoe manufacture Flooring materials Solid lubricants Fibre-on-fibre Spinning Weaving, etc. Textile industry (flexible-flexible) Carding Plastics pairing Hosiery and knitwear Cable manufacture β Includes vertical or tangential motion. b Includes elastomers, solid lubricants, and rubbers. Note: All operations may or may not have a lubricant. 2*

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