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Post-quench dynamics and pre-thermalization in a resonant Bose gas Xiao Yin∗ and Leo Radzihovsky† Department of Physics, University of Colorado, Boulder, CO 80309 (Dated: January 8, 2016) We explore the dynamics of a resonant Bose gas following its quench to a strongly interacting regimenearaFeshbachresonance. Forsuchdeepquenches,weutilizeaself-consistentdynamicfield approximationandfindthatafteraninitialregimeofmany-bodyRabi-likeoscillationsbetweenthe condensateandfinite-momentumquasiparticlepairs,atlongtimes,thegasreachesapre-thermalized nonequilibriumsteadystate. Weexploretheresultingstatethroughitsbroadstationarymomentum distribution function, that exhibits a power-law high momentum tail. We study the dynamics and 6 steady-state form of the associated enhanced depletion, quench-rate dependent excitation energy, 1 Tan’scontact,structurefunctionandradiofrequencyspectroscopy. Wefindthesepredictionstobe 0 in a qualitative agreement with recent experiments. 2 n PACSnumbers: 67.85.De,67.85.Jk a J 7 I. INTRODUCTION time evolution |ψˆ(t)(cid:105) = eiHˆft|ψˆi(0)(cid:105) of a closed quan- tum system vis-´a-vis eigenstate thermalization hypoth- ] esis [24, 25], role of conservation laws and obstruction s A. Background and motivation a to full equilibration of integrable models argued to in- g stead be characterized by a generalized Gibb’s ensemble Degenerate atomic gases have radically expanded the - (GGE),emergenceofstatisticalmechanicsunderunitary t scope of quantum many-body physics beyond the tradi- n time evolution for equilibrated and nonequilibrium sta- a tional solid-state counter part, offering opportunity to tionary states [26, 27]. These questions of post-quench u study highly coherent, strongly interacting, and well- dynamicshavebeenextensivelyexploredinalargenum- q characterized, defects-free systems. Atomic field-tuned ber of systems [28–43] t. Feshbach resonances (FRs) [1–4] have become a pow- a Early studies of a Feshbach-resonant Fermi gas pre- erful experimental tool that has been extensively uti- m dicted persistent coherent post-quench oscillations [30, lizedtoexplorestrongresonantinteractionsinthesesys- - tems. Feshbach resonances have thus led to a seminal 44] and, more recently found topological nonequilibrium d steady states and phase transitions [45, 46]. n realization of paired s-wave fermionic superfluidity, with o the associated BCS-to-Bose-Einstein condensate (BEC) Resonant Bose gas quenched dynamics studies date c crossover [3–6] through a universal unitary regime [7–9], back to seminal experiments on 85Rb [47, 48], that [ andphasetransitionsdrivenbyspeciesimbalance[10,11] demonstrated coherent Rabi-like oscillations between 1 and by Mott-insulating physics in an optical lattice [12– atomic and molecular condensates [49], enabling a mea- v 16]. Numerous other promising many-body states and surement of the molecular binding energy. More re- 7 phase transitions, such a p-wave fermionic superfluidity cently, oscillations in the dynamic structure function 9 [17–19] and Stoner ferromagnetism [20] have been pro- have also been observed in quasi-2D bosonic 133Cs [38] 3 posed and continue to be explored. andstudiedtheoretically[37,50]forshallowquenchesbe- 1 tweenweakly-repulsiveinteractions(smallgasparameter Unmatched by their extreme coherence and high tun- 0 na3 (cid:28)1 where a is the s-wave scattering length). . abilityofsystemparameters,suchasFRinteractionsand s s 1 single-particle (trap and lattice) potentials, atomic gases Such resonant bosonic gases were also predicted to ex- 0 have also enabled numerous experimental realizations of hibit distinct atomic and molecular superfluid phases, 6 highly nonequilibrium, strongly-interacting many-body separated by a quantum Ising phase transition (rather 1 : states and associated phase transitions [2, 6, 12]. than just a fermionic smooth BCS-BEC crossover) and v otherrichphenomenology[51–55], therebyprovidingad- This has motivated extensive theoretical studies [21– i X 23], with a particular focus on nonequilibrium dynamics ditional motivation for their studies. r followingaquenchofHamiltonianparameters,Hˆi →Hˆf. Important recent developments are experiments by a Makotyn, et al, [56], that explored dynamics of 85Rb fol- In addition to studies of specific physical systems, ex- lowingadeepquenchtothevacinityoftheunitarypoint periments on these closed and highly coherent systems onthemolecular(positivescatteringlength,a >0)side have driven theory to address fundamental questions in s of the Feshbach resonance. It was discovered that even quantum statistical mechanics. These include the con- neartheunitarypoint,whereaBosegasisexpectedtobe ditions for and nature of thermalization under unitary unstable[57], thethree-bodydecayrateγ (ontheorder 3 of an inverse milli-second) appears to be more than an order of magnitude slower than the two-body equilibra- ∗[email protected] tion rate γ2 (both measured to be proportional to Fermi †[email protected] energy, as expected [58, 59]. This thereby opened a win- 2 dow of time scales from a microsecond (a scale of the C. Summary of results quench)toamilli-secondforobservationofametastable strongly-interacting nonequilibrium dynamics. Before turning to the derivation and analysis, we Stimulated by these fascinating experimental develop- brieflysummarizethekeypredictionsofourwork. Work- mentsandmotivatedbytheaforementionedearlierwork, ing within the upper-branch of a single-channel model of in a recent brief publication [39] we reported on results a resonantly interacting Bose gas we studied an array for the upper-branch repulsive dynamics of a resonant ofnonequilibriumobservablesfollowingitsFeshbachres- Bose gas following a deep-detuning quench close to the onance quench toward the unitary point. One central unitary point on the molecular side (a > 0) of the FR quantityextensivelystudiedinrecenttimeofflightmea- s [56]. Taking the aforementioned slowness of γ (cid:28) γ as surements [38, 56] is the momentum distribution func- 3 2 an empirical fact, consistent with experimental observa- tion,n (t)=(cid:104)gs |a†(t)a (t)|gs (cid:105)attimetafteraquench k i k k i tions we predicted a fast evolution to a pre-thermalized from a ground state |gs (cid:105) of an initial Hamiltonian Hˆ to i i strongly-interacting stationary state, characterized by a a final Hamiltonian Hˆ . Motivated by experiments we f broad, power-law steady-state momentum distribution take|gs (cid:105)tobeasuperfluidBECgroundstateintheup- function, nss, with a time scale τ = (cid:126)/E for the pre- i k k k per branch of the repulsive Bose gas [61]. For a shallow thermalization of momenta k set by the inverse of the quench in the scattering length a → a , away from the i f excitation spectrum, E . The associated condensate de- k immediatevicinityoftheunitarypoint,thecalculationis pletion was found to exhibit a monotonic growth to a controlled by an expansion in a small interaction param- nonequilibrium value exceeding that of the correspond- eter, na3 (cid:28)1. Within the lowest, Bogoluibov approxi- ing ground state. In the current manuscript we present i,f mation the momentum distribution function is given by thedetailsoftheanalysesthatledtotheseresultsaswell (choosingunitswhere(cid:126)=1andk =1throughout)[37] B as a large number of other predictions. (cid:113) n (tˆ)= kˆ2+σ+ 2kˆ(12−+σ2)sin2(tˆ kˆ2(kˆ2+2)) − 1, (1.1) kˆ 2(cid:113)kˆ2(kˆ2+2σ) 2 B. Outline whereσ ≡a /a characterizesthe“depth”ofthequench, i f and we have rescaled the momentum k and time t The rest of the paper is organized as follows. We con- (cid:112) with the coherence length ξ ≡ 1/ 2mng and pre- f clude the Introduction with a summary of our key re- thermalization timescale t = 1/ng , as kˆ = kξ and sults. In Section II, starting with a one-channel model 0 f tˆ= t/t , respectively. We start the system in a weakly of a Feshbach-resonant Bose gas, we develop its approxi- 0 interacting state, characterized by a short positive scat- mateBogoluibovandself-consistentdynamicfieldforms. tering length a and quench it to a > a (σ ≤ 1). In Section III, as a warmup we analyze the equilibrium i f i Following coherent oscillations, the gas then exhibits self-consistentmodelforthestronglyinteractingcaseand pre-thermalization dynamics, where after a dephasing compare its predictions to that of the Bogoluibov ap- time τ , set by the inverse of the excitation spectrum proximation. In Section IV we utilize the Bogoluibov k (cid:113) model to study the nonequilibrium dynamics following a 1/E =1/ kˆ2(kˆ2+2)consistentwithexperiments[56], k shallow-quench, computing the momentum distribution the initial narrow Bogoluibov momentum distribution function nk(t) probed in the time-of-flight, the radio- evolves to a stationary state, characterized by a broad- frequency (RF) spectroscopy signal, I(ω,t), and the ened distribution function structure function S (t) probed via Bragg spectroscopy. k   Then in Section V we generalize the quench to a more 1 (kˆ2+σ)(kˆ2+2)+1−σ estxupdeyrimtheenteafflelyctroefalriastmicpcraastee.ofInaSfiecntiitoen-raVtIewraememppalnody nskˆs = 2 (kˆ2+2)(cid:113)kˆ2(kˆ2+2σ) −1, (1.2a) the self-consistent dynamic field theory to study these  Css/k4, for kξ (cid:29)1, and a number of other observables for deep quenches in  ∼ 1/k2, for σ (cid:28)kξ (cid:28)1, (1.2b) a strongly interacting regime relevant to JILA experi- 1/k, for kξ (cid:28)σ, ments[56]. InSectionVIIwestudyexcitationenergy,an important measure of long time nonequilibrium station- where we defined Css as the nonequilibrium analog of ary state, for both sudden quench and finite ramp-rate Tan’s contact for the nonequilibrium steady state, given cases, and discuss its dependence on quench depth and by ramp rate. We generalize Tan’s Contact to nonequilib- rium process and study its long time behavior in Section Css =(4πa n)2[1+(1−σ)2]. (1.3) f VIII.FinallyinSectionIXweconcludewithadiscussion of our predictions for experiments and of the future di- Within above approximation the quasi-particles do not rections for this work. We relegate the details of most scatter, precluding full thermalization, and the above fi- calculations to Appendices. nalstateremainsnonequilibrium,completelydetermined 3 bythedepth-quenchparameterσ,withtheassociateddi- 1.0 agonal density matrix ensemble. t=0.1 The associated condensate depletion nd(t) = 0.8 t=0.5 1 (cid:80) n (t) is then straightforwardly computed and t=1.0 N k(cid:54)=0 k t=6.0 monotonically pre-thermalizes to 0.6 t=10 t=∞ nss(σ)= √8 (cid:0)na3(cid:1)1/2(cid:20)σ3/2+ 3√1−σarccos(√σ)(cid:21), d 3 π f 2 0.4 (1.4) 0.2 a value exceeding that for the ground state of the final scattering length a and greater than the initial ground f state depletion ni =nss(σ =1)= √8 (cid:0)na3(cid:1)1/2 at scat- 0.2 0.4 0.6 0.8 1.0 1.2 1.4 d d 3 π i tering length ai. FIG.1: (Coloronline)Timeevolutionofthe(column-density) With the goal of understanding deep quenches of a momentum distribution function, n˜ (t) ≡ (cid:82) dk n (t) fol- k⊥ z k strongly interacting Bose gas [39, 56, 62] near a Fesh- lowing a deep scattering length quench k a = 0.01 → n i bach resonance, we developed a self-consistent dynamic knaf = 1 in a resonant Bose gas (where kn ≡ n1/3), com- field theory of coupled Gross-Petaevskii equation for the puted within a self-consistent dynamic field approximation. Here momentum is rescaled by the coherence length ξ as condensate n (t) and a Heisenberg equation for atoms √ c kˆ = kξ ≡ k/ 2mng . Lowest curve corresponds to earlier aˆ (t) excited out of the condensate. It accounts for f k(cid:54)=0 timeattˆ≡t/t =0.1inunitsofpre-thermalizationtimescale strong time-dependent depletion of the condensate, with 0 t = 1/ng = m/(4πa n) while the dashed-thick black one feedbackondynamicsofexcitations. Withinthisnonper- 0 f f represents the asymptotic steady-state distribution. The fig- tubative (but uncontrolled) approximation this amounts ureillustratestheinitialnarrowmomentumdistribution(low- to solving for a Heisenberg evolution of aˆk(t) with a estcurve)evolvingtoamuchbroadermomentumdistribution time-dependent Bogoluibov-like Hamiltonian, parame- (highest curve), corresponding to a pre-thermalized steady terized by a condensate density n (t). The latter is self- state. The grey region indicates a range of momenta not re- c consistently determined by the atom-number constraint solvedinJILAexperiments,duetoinitialinhomogeneousreal equation, n (t) = n − (cid:80) n (t,[n (t)]) [30, 39]. Our space density profile and finite trap size. c k k c treatment here is closely related to the analysis of post- quench quantum coarsenning dynamics of the O(N) [36] n /n c and Ising [35] models. The resulting momentum distri- 1.0 bution function, n˜ (t) (projected column density mea- k⊥ sured in experiments [56]) and the corresponding deple- 0.8 tion n (t) are illustrated in Figs. 1,3. d We also studied the excitation energy after a constant 0.6 ramp rate γ between a and a scattering lengths. As i f √ illustrated in Fig. 4, wefound thatit displays a γ form self-consistent 0.4 E (γ) 4(σ−1)2n2a 0.2 Bogoluibov exc = fa Λf(γ/E ), (1.5a) V m f Λ k a ∝ (1−σ)3/2√γ, for γ (cid:28)E , 0.00.0 0.5 1.0 1.5 2.0 2.5 3.0 n s Λ ∝ (1−σ)2a Λ , for γ (cid:29)E , f Λ FIG. 2: (Color online) Ground state condensate fraction as (1.5b) a function of a dimensionless measure of atom density and interaction, k a (with k ≡ n1/3), computed within a self- n s n foraramp-ratebelowthemicroscopicenergycutoffE = Λ consistent dynamic field approximation (solid red curve), as Λ2/2m. compared to Bogoluibov approximation result (dashed blue To further characterize the post-quench evolution curve). and the resulting pre-thermalized steady-state we have also computed a time dependent structure function S(q,t)=(cid:104)gs |n(−q,t)n(q,t)|gs (cid:105), a Fourier transform of first computed and measured in Ref. [38], and after pre- i i the density-density connected correlation function. For thermalization reduces to a time-independent form [39], the weakly interacting, shallow-quench regime, at tem- (cid:32) (cid:33) perature 1/β it is given by n (cid:15) E2 Sss = 0 q coth(βE /2) 1+ qi . (1.7) (cid:34) (cid:35) q 2E2 qi E2 n (cid:15) E2 −E2 qf qf S(q,t)= 0 q coth(βE /2) 1+ qi qf sin2(E t) , Eq2f qi Eq2f qf Utilizing our self-consistent dynamic field theory we (1.6) extendedabovecalculationofS(q,t)todeepquenchesof 4 n /n S (t) d q 1.0 100 t=0 1.0 t=1 0.8 80 t=50 0.7 t=∞ 0.6 60 0.5 0.4 0.3 40 0.2 20 knaf=0.1 0.00.0 0.5 1.0 1.5 2.0t/t0 0.5 1.0 1.5 2.0 2.5 qξ FIG. 3: (Color online) Time evolution of the condensate de- FIG. 5: (Color online) Time evolution of the structure func- pletion fraction nd(t)/n (treated within a self-consistent dy- tion Sq(t) defined in the text following a scattering length namic field analysis), following a scattering length quench quench from 0.1af →af with knaf =0.7 (where kn ≡n1/3), fromk a =0.01tovariousk a inaresonantBosegas. Here referringtoEq.(6.17)usingquasi-adiabaticself-consistentap- n i n f we normalize the time with the pre-thermalization timescale proximation (see Sec. VIA). It illustrates the initial ground t = 1/ng = m/(4πa n) associated with k a = 1 (where state structure function (blue curve), that following the 0 f f n f k ≡n1/3). quench develops oscillations and after a pre-thermalization n time approaches a steady-state distribution (dashed black curve), which within-quasi-adiabatic approximation almost ε /ε exc 0 collapseswiththeinitialgroundstatecurve. Heremomentum √ ● andtimearerescaledwithξ≡1/ 2mngf andt0 ≡1/(ngf), respectively. ● 3 ● tional to Tan’s contact, that in the simplest Bogoluibov 2 approximation is given by C =(4πnaf)2. ● We next turn to a single-channel Feshbach resonant ● model, followedbyitsdetailedanalysisthatledtoabove 1 ● and other results. ● ● ● ● γ 50 100 150 200 II. MODEL OF A RESONANT SUPERFLUID FIG. 4: (Color online) Excitation energy (scaled by LHY A resonant gas of bosonic atoms can be modeled by correction to the ground state energy) following a scatter- a single-channel grand-canonical Hamiltonian, (defining inglengthrampasafunctionoframprateγ (asa“zoom-in” (cid:82) ≡(cid:82) d3r) for Fig. 22, see Sec. VII). The red data points are obtained r fmoromeaecnhtucmhocseuntoγffaΛˆt=ai/Λaξf==110/02,(ξwi≡th1s/c√al2emdndgimeisnstihoenlceoss- Hˆ =(cid:90) [ψˆ†((cid:15)ˆ−µ)ψˆ+ gψˆ†ψˆ†ψˆψˆ], (2.1) f 2 herencelength);thebluecurverepresentsthefittingfunction r √ y=0.26 x. whereψˆ(r)isabosonicatomfieldoperator,(cid:15)ˆ=−∇2 isa 2m single-particle Hamiltonian, µ is the chemical potential, andthepseudo-potentialg characterizestheatomictwo- strongly interacting resonant condensates. The resulting bodyinteractiononthescalelongerthanitsmicroscopic time-dependent structure function and its steady-state range r =1/Λ, typically on the order of ten angstroms. form are illustrated in Fig. 5. 0 For simplicy, we have set (cid:126)=1. We also computed the RF spectroscopy signal I(ω ) RF AsdiscussedindetailinRef.[4]andreferencestherein, [63, 64], that measures the transition rate of atoms from near a Feshbach resonance the magnetic field-dependent two resonantly interacting hyperfine states into a third coupling g(B) controls the s-wave scattering length a weakly interacting hyperfine state, for the quench pro- s through the renormalized coupling (T-matrix) g˜−1 = cess. WithintheBogoluibovapproximationtheresponse g−1+(cid:82) 1 =g−1+mΛ/(2π2), is given by k 2(cid:15)k √ g 2τVI2(4πna )2 g˜= , (2.2) I(ωRF)= 4√πm0 ω3/2f , (1.8) 1+g/gc RF related to the scattering length via g˜ = 4πa /m. As s as measured experimentally, with the amplitude propor- illustrated in Fig. 6, for a sufficiently strong attractive 5 g (cid:90) interaction, in a vacuum, the two-atom scattering length Hˆ = aˆ†aˆ†aˆaˆ. (2.6d) diverges at g =2π2/(mΛ)=2π2r /m, as the two-body 4 2 r c 0 bound state forms for g < −g and a turns positive on are the operator components organized by respective or- c s the so-called “BEC” side of the Feshbach resonance. r ders in the excitation aˆ. 0 is the range of the potential and Λ is the corresponding momentum cutoff. It is this scattering-length tunabil- ity that enables studies of phase transitions in resonant A. Bogoluibov approximation for weakly Bose [51–55] (and BCS-BEC crossover in Fermi [1–3, 3– interacting bosons 6]) gases and quenched dynamics [38, 39, 56, 62] that is our focus here. We set the stage for the study of dynamics following a shallowquench[38]andofaself-consistentdynamicfield a treatment [39] of a deep quench [56] by first briefly sum- s marizing the results for the ground state and excitations in the Bogoluibov approximation [65, 66]. In the weakly interacting limit the atomic gas is char- acterized by a small gas parameter na3 (cid:28) 1, well- s approximatedbytheBogoluibovquadraticHamiltonian, neglecting the nonlinear Hˆ components of Hˆ. Focus- 3,4 πr0/2 ingontheuniform(bulk)condensateandeliminatingthe chemical potential in favor the condensate density by re- g quiring the vanishing of the Hˆ1 component (equivalent -gc 0 to a minimization of Hˆ over Ψ ), µ = g|Ψ |2 ≈ gn, 0 0 0 neglectingthedifferencebetweenthecondensatedensity, |Ψ |2 ≡n andtotalatomdensity,n,thegrand-canonical 0 c Hamiltonian reduces to Hˆ ≈−1Vgn2+Hˆ , 2 B FIG. 6: (Color online) A plot of the s-wave scattering length (cid:18) (cid:19)(cid:18) (cid:19) ainsa(reFneoshrmbaaclhizerdescoonuapnlcine.gg˜H)earesagcfu=nc2tπio2nr0o/fmbairsetchoeucprliitnigcagl HˆB = −21k(cid:88)(cid:54)=0εk+ 21k(cid:88)(cid:54)=0(cid:0)aˆ†k aˆ−k(cid:1) gεnkc gεnkc aˆaˆ†−kk , coupling strength at which a diverges. s = −1 (cid:88)ε + 1 (cid:88)Φˆ† h Φˆ , 2 k 2 k,i k,ij k,j To allow for dynamics within a Bose-condensed state k(cid:54)=0 k(cid:54)=0 explored experimentally [38, 56], we decompose the = −1 (cid:88)ε + 1 (cid:88)E Ψˆ† Ψˆ , atomic field operator ψˆ(r) = √1V (cid:80)kaˆkeik·r, into a c- 2k(cid:54)=0 k 2k(cid:54)=0 k k,s k,s field condensate Ψ and a fluctuation field aˆ(r), 0 1 (cid:88) (cid:88) = − (ε −E )+ E αˆ†αˆ , (2.7) ψˆ=Ψ0+aˆ. (2.3) 2k(cid:54)=0 k k k(cid:54)=0 k k k where the quadratic Hamiltonian was straightforwardly Expressing the Hamiltonian, (2.1) in terms of the opera- diagonalized in terms of the Bogoluibov quasi-particles tor aˆ, it decomposes into Ψˆ = (αˆ ,αˆ† ), related to the atomic Nambu spinor k k −k Hˆ =Hˆ0+Hˆ1+Hˆ2+Hˆ3+Hˆ4, (2.4) Φˆk =(aˆk,aˆ†−k) by a pseudo-unitary transformation, Uk (cid:18) (cid:19) (cid:18) (cid:19)(cid:18) (cid:19) where aˆk = uk vk αˆk, (2.8a) aˆ† v∗ u∗ αˆ† , (cid:90) g −k k k −k Hˆ0 = [Ψ∗0((cid:15)ˆ−µ)Ψ0+ 2|Ψ0|4], (2.5) Φˆk = UkΨˆk. (2.8b) r U satisfies a pseudo eigenvalue equation h U = is the lowest order mean-field ground-state energy, and k k k E σzU and preserves the canonical commutation re- k k (cid:90) lation, [a ,a† ] = δ , corresponding to [Φˆ ,Φˆ† ] = Hˆ1 = [aˆ†((cid:15)ˆ+g|Ψ0|2−µ)Ψ0]+h.c., (2.6a) σzδ , dkefinke(cid:48)d by k,k(cid:48) ik jk(cid:48) ij k,k(cid:48) r Uσ U† =σ , (2.9) z z Hˆ2 =(cid:90)r(cid:104)aˆ†(cid:0)(cid:15)ˆ+2g|Ψ0|2−µ(cid:1)aˆ+ g2(cid:16)Ψ∗02aˆaˆ+Ψ20aˆ†aˆ†(cid:17)(cid:105), wiWthi|tuhkε|2k−=|vkk2|/22=m1+agnndiσnz(2th.7e),ththiredBPoaguolilumibaotvrixsp.ec- (2.6b) trum is given by a well-known gapless form, (cid:113) (cid:113) (cid:112) (cid:90) Ek = ε2k−g2n2 = (cid:15)2k+2gn(cid:15)k =ck 1+ξ2k2/2, Hˆ =g [Ψ aˆ†aˆ†aˆ+Ψ∗aˆ†aˆaˆ], (2.6c) 3 0 0 (2.10) r 6 that interpolates between the low-momentum zeroth- Wick’s theorem, we have (cid:112) sound with velocity c = gn/m (a Goldstone mode of the U(1) symmetry breaking) and the high-momentum aˆ†aˆ†aˆaˆ → 4(cid:104)aˆ†aˆ(cid:105)aˆ†aˆ+(cid:104)aˆ†aˆ†(cid:105)aˆaˆ+(cid:104)aˆaˆ(cid:105)aˆ†aˆ† quadratic dispersion, w√ith crossover scale set by the cor- −2(cid:104)aˆ†aˆ(cid:105)(cid:104)aˆ†aˆ(cid:105)−(cid:104)aˆ†aˆ†(cid:105)(cid:104)aˆaˆ(cid:105), relationlengthξ =1/ 2mgn. Thecorrespondingcoher- ≈ 4n aˆ†aˆ−2n2, (2.16a) ence factors defining U are given by d d k aˆ†aˆaˆ → 2(cid:104)aˆ†aˆ(cid:105)aˆ≈2n aˆ, (2.16b) d 1(cid:18)ε (cid:19) 1(cid:18)ε (cid:19) aˆ†aˆ†aˆ → 2aˆ†(cid:104)aˆ†aˆ(cid:105)≈2n aˆ†, (2.16c) u2 = k +1 , v2 = k −1 . (2.11) d k 2 E k 2 E k k where we kept the depletion density n = (cid:104)aˆ†aˆ(cid:105) and ne- d The ground state is a vacuum of Bogoluibov quasi- glected “anomalous” averages (e.g., (cid:104)aˆaˆ(cid:105) = 0) and high particles, αˆ |gs(cid:105) = 0, with the energy density E = order correlators (e.g., (cid:104)aˆ†aˆaˆ(cid:105)=0) that we expect to be k gs V−1(cid:104)gs|Hˆ|gs(cid:105) given by subdominant. WiththeseweapproximateHˆ andHˆ byalinearand 3 4 1 1 (cid:88) quadratic forms E = gn2− E n , (2.12a) gs 2 V k k (cid:90) k(cid:54)=0 Hˆ = g [Ψ aˆ†aˆ†aˆ+Ψ∗aˆ†aˆaˆ]→δHˆ , (2.17) 2πa (cid:20) 128 (cid:21) 3 0 0 1 = sn2 1+ √ (na3)1/2 , (2.12b) r m 15 π s where where the T =0 momentum distribution function (cid:90) δHˆ = g (2Ψ n aˆ†+h.c.), (2.18) 1 0 d n = (cid:104)gs|aˆ†aˆ |gs(cid:105)=|v |2 ≈ C/k4, (2.13) r k k k k k→∞ and with Tan’s contact C = ∂E /∂a−1 = 16π2n2a2[(1 + gs s s 36√4π(na3s)1/2] and Hˆ = g (cid:90) aˆ†aˆ†aˆaˆ→δHˆ +δHˆ , (2.19) 4 2 0 2 r (cid:20) (cid:21) 4πan 32 µ = 1+ √ (na3)1/2 . (2.14) where m 3 π s δHˆ = −gVn2, (2.20a) Theinteraction-drivencondensatedepletion,n ≡n− 0 d d (cid:90) nc is given by δHˆ = 2g n aˆ†aˆ. (2.20b) 2 d r n = 1 (cid:88)n ≈ √8 (cid:0)na3(cid:1)1/2n, (2.15) d V k 3 π s The grand-canonical Hamiltonians now take the follow- k(cid:54)=0 ing forms: Hˆ ≈Hˆ(cid:48) +Hˆ(cid:48) +Hˆ(cid:48), where 0 1 2 and provides an important measure of the validity of the Hˆ(cid:48) =Hˆ +δHˆ , Bogoluibov approximation that neglects the difference 0 0 0 (cid:90) (cid:104) g (cid:105) (2.21a) between n and nc. = Ψ∗((cid:15)ˆ−µ)Ψ + n2−gn2 , Clearly, for a large gas parameter, na3 (cid:29)1 the deple- 0 0 2 c d s r tion is substantial and must be accounted for. Although there is no currently available systematic analysis in this Hˆ(cid:48) =Hˆ +δHˆ , nonperturbativelimit,aswewillshowinsubsequentsec- 1 1 1 tions, an uncontrolled self-consistent method, akin to a =(cid:90) (cid:2)aˆ†((cid:15)ˆ+gn +2gn −µ)Ψ (cid:3)+h.c., (2.21b) spherical, large-N model[35,36,59,67,68]capturesim- c d 0 r portant qualitative physics in this resonantly interacting regime. Hˆ(cid:48) =Hˆ +δHˆ , 2 2 2 (cid:90) (cid:104) gn (cid:105) B. Generalization for large scattering length = aˆ†((cid:15)ˆ+2g(nc+nd)−µ)aˆ+ 2c(aˆaˆ+aˆ†aˆ†) . r (2.21c) To extend the analysis to a large na3 we need to ac- s count (even if approximately) for the nonlinear compo- Above, for simplicity, we have defined n ≡ |Ψ |2 and c 0 nents of the Hamiltonian, Hˆ neglected in the Bogolui- n ≡ (cid:104)aˆ†aˆ(cid:105) and in Eqs. (2.21a),(2.21b),(2.21c) have dis- 3,4 d bovmodel. Tothisend,inthespiritofvariationaltheory cardedthe”anomalousaverage”termm˜ ≡(cid:104)aˆaˆ(cid:105)tosatisfy or a spherical model [68], we replace these nonlinear op- the constraint of Goldstone theorem, which requires a erators by their “best” approximation in terms of opera- gaplessexcitationspectrum. Thisamountstothewidely tors up to a quadratic order in fluctuation field aˆ. Using used Popov approximation [69]. 7 Following what was done in the last subsection, we fix The solution to Eq. (3.2) is illustrated in Fig. 2. We the chemical potential µ by requiring Hˆ(cid:48) =0 find that the self-consistency constraint suppresses con- 1 densate depletion, leading to a higher condensate frac- ((cid:15)ˆ+g|Ψ0|2+2gnd)Ψ0 =µΨ0. (2.22) tion nc than the Bogoluibov approximation for the same strength of the interaction parameter k a . We also ob- n s For a uniform system, this gives servethat,asexpectedthecorrectiontoBogoluibovthe- oryfromtheself-consistencyconditiongrows(fromzero) µ=gn +2gn . (2.23) c d withincreasinggasparameterk a ,therebyavoidingthe n s spurious transition to a vanishing condensate state ap- Thus we obtain the grand-canonical Hamiltonian pearing in the Bogoluibov theory. (cid:90) (cid:104) g (cid:105) Hˆ = aˆ†((cid:15)ˆ+gn )aˆ+ n (aˆaˆ+aˆ†aˆ†) −E c 2 c 0 r (cid:20) (cid:21) IV. DYNAMICS FOR SHALLOW QUENCH (cid:88) 1 = ((cid:15) +gn )aˆ†aˆ + gn (aˆ†aˆ† +aˆ aˆ ) −E , k c k k 2 c k −k k −k 0 k(cid:54)=0 We now turn to nonequilibrium dynamics following a (2.24) changeinthescatteringlengtha fromitsinitialvaluea s i tothefinalvaluea ,ascanberealizedexperimentallyin where E0/V = g2n2c+2gncnd+gn2d. It exhibits the stan- aFeshbachresonanftBosegasbyachangeintheexternal dard Bogoluibov form with gapless spectrum, but also magneticfield[56]. Hereweassumethechangeisinstan- approximately accounts for a potentially strong deple- taneous(suddenquench),allowinganalyticalanalysis. In tionthroughthecondensatedensitync replacingthefull this section, we focus on shallow quenches characterized density n as the self-consistently determined parameter by both na3 (cid:28) 1 and na3 (cid:28) 1, so that the Bogoluibov i f of the Hamiltonian. approximation remains rigorously valid. Forshallowquenches,thesystemiswellapproximated by Hamiltonian (2.7) with g and g for the initial and i f III. SELF-CONSISTENT ANALYSIS FOR final Hamiltonians, respectively, with corresponding Bo- STRONGLY INTERACTING GROUND STATE goluibovquasi-particlebases(αˆ ,αˆ†)priortothequench k k and (βˆ ,βˆ†) post the quench. Focussing on a sudden Before turning to our main focus of nonequilibrium k k quench, the two sets of bases are related to the atomic post-quench dynamics, we examine the ground state basis (aˆ ,aˆ†) via a pseudo-unitary transformations properties of a strongly interacting resonant Bose gas, k k crahmareatcetrernizae3d(cid:29)by1.aTlahrigseresgciamtteerliinesgbleenyognthd athnedsgcaospepao-f (cid:18) aˆk (cid:19) = (cid:18)u(cid:48)k vk(cid:48)(cid:19)(cid:18) αˆk (cid:19), (4.1a) s aˆ† v(cid:48) u(cid:48) αˆ† the standard Bogoluibov theory. Nevertheless we expect −k k k −k tobeabletotreatitqualitativelycorrectly(evenifquan- Φˆ (0) = U (0−)Ψˆ (0−), (4.1b) k k k titatively uncontrolled) by taking into account the large depletionn−n >0throughtheHamiltonian(2.24)and and c tchonesseerlvf-actoionnsistency condition through the atom number (cid:18) aˆk (cid:19) = (cid:18)uk vk(cid:19)(cid:18) βˆk (cid:19), (4.2a) aˆ†−k vk uk βˆ−†k 1 (cid:88) n = nc+ V (cid:104)aˆ†kaˆk(cid:105), (3.1a) Φˆk(0) = Uk(0+)Ψˆk(0+), (4.2b) k(cid:54)=0 where = n + √8 (cid:0)n a3(cid:1)1/2n , (3.1b) c 3 π c s c (cid:115) (cid:18) (cid:19) (cid:115) (cid:18) (cid:19) 1 (cid:15) +ng 1 (cid:15) +ng u(cid:48) = k i +1 , v(cid:48) =− k i −1 , where in the second line we calculated the depletion by k 2 E k 2 E ki ki diagonalizing(2.24)asinSec.IIAoftheconventionalBo- (4.3a) goluibovtheory,butwithn replacingn. Suchtreatment c (cid:115) (cid:115) (cid:18) (cid:19) (cid:18) (cid:19) is quite close in spirit to the self-consistent Hartree-Fock 1 (cid:15) +ng 1 (cid:15) +ng u = k f +1 , v =− k f −1 , approximations, and the BCS and other mean-field gap k 2 E k 2 E kf kf equations. (4.3b) In the dimensionless form for nˆ = n /n, the self- c c consistency equation reduces to define Bogoluibov transformations for Hamiltonians Hˆ i (with interaction g ≡g(0−)) before and Hˆ (with inter- 1−nˆ −λnˆ3/2 =0, (3.2) i f c c action g ≡ g(0+)) after the quench, respectively. The f √ √ where λ = 8(na3)1/2/(3 π) ≡ 8(k a )3/2/(3 π), with corresponding excitation spectra are s n s kn ≡ n1/3 the mometum scale set by the boson density (cid:112) (cid:113) n. Eki = (cid:15)k2+2ngi(cid:15)k, Ekf = (cid:15)k2+2ngf(cid:15)k, (4.4) 8 and the two quasi-particle bases are related by Having derived the evolution of the atomic fields Φˆ (t) = (aˆ (t),aˆ†(t)), we can now compute the basic (cid:18) βˆ (cid:19) (cid:18) αˆ (cid:19) k k k k = U−1(0+)U (0−) k , atomic bilinear correlator (supressing the momentum k βˆ−†k k k αˆ−†k argument on the right hand-side): (cid:18) (cid:19)(cid:18) (cid:19) = csoinshh∆∆θθkk csoinshh∆∆θθkk αˆαˆ−†kk , (4.5) Ckij(t,t(cid:48)) = (cid:104)Φˆ†i(t)Φˆj(t(cid:48))(cid:105), = (cid:104)Ψˆ† (0−)U† (t)U (t(cid:48))Ψˆ (0−)(cid:105), m mi jn n with = U† (t)N U (t(cid:48)), (4.12) (cid:20) (cid:18) (cid:19)(cid:21) mi mn jn 1 1 E E ∆θ = cosh−1 kf + ki . (4.6) k 2 2 E E in terms of the pre-quench (t = 0−) quasi-particle occu- ki kf pation matrix Wetaketheinitialstate|0−(cid:105)tobethegroundstateof the pre-quenched Hamiltonian Hˆi [61], and thus a vac- Nmn = (cid:104)Ψˆ†m(0−)Ψˆn(0−)(cid:105), (4.13a) uum of αˆ quasi-particles, αˆk|0−(cid:105) = 0. At finite temper- (cid:32) (cid:104)αˆ†αˆ (cid:105) (cid:104)αˆ†αˆ† (cid:105) (cid:33) ature this generalizes to Bose-Einstein distribution of αˆ = k k k −k , (4.13b) (cid:104)αˆ αˆ (cid:105) (cid:104)αˆ αˆ† (cid:105) quasi-particle occupation, −k k −k −k mn (cid:18)n (0−) 0 (cid:19) 1 = k , (4.13c) (cid:104)αˆ†αˆ (cid:105) = . (4.7) 0 n (0−)+1 k k 0− eEki/T −1 −k mn (cid:18) (cid:19) 0 0 Because experiments probe physical observables ex- = , for T =0, (4.13d) 0 1 pressed in terms of atomic operators, we need to com- mn pute time evolution of Φˆk(t)=(aˆk(t),aˆ†k(t)). Using free from which physical observables, such as the momen- post-quench evolution of βˆ quasi-particles tum distribution function, structure function, RF spec- troscopy signal, and many others can be obtained. We (cid:18) βˆk(t) (cid:19)=(cid:18)e−iEkft 0 (cid:19)(cid:18) βˆk(0) (cid:19)≡T (t)Ψˆ (0+), turn to their computation in the following subsections. βˆ† (t) 0 eiEkft βˆ† (0) k k −k −k (4.8) the relation (4.5), together with the simplicity of matrix A. Time of flight: momentum distribution function elements of αˆ quasi-particles in the pre-quench ground state (vacuum of αˆ ), we find Time of flight measurements, where a gas is released k from its trap and its density profile is measured at long (cid:18) aˆk(t) (cid:19) = U (0+)(cid:18) βˆk(t) (cid:19), (4.9a) times, is one of the central experimental probes dating aˆ† (t) k βˆ† (t) back to the realization of BEC in dilute alkali gases [70, −k −k (cid:18) βˆ (0) (cid:19) 71]. A straightforward analysis demonstrates [11], that = U (0+)T (t) k , (4.9b) at long times the density profile is proportional to the k k βˆ† (0) −k momentum distribution function. At T = 0, that is our (cid:18) (cid:19) αˆ (0) main focus here, we obtain = U (0+)T (t)U−1(0+)U (0−) k , k k k k αˆ† (0) −k n (t) = (cid:104)0−|aˆ†(t)aˆ (t)|0−(cid:105)=C11(t,t), (4.9c) k k k k Φˆ (t) = U (t)Ψˆ (0−)=R (t)U (0−)Ψˆ (0−), = |(uke−iEkftsinh∆θk+vkeiEkftcosh∆θk)|2, k k k k k k (4.9d) = (cid:15)k+gin+ 2gf(cid:15)k(g+f2−ggfin)n2 sin2(Ekft) − 1, (4.14) (cid:112) 2 (cid:15) ((cid:15) +2g n) 2 where the matrix k k i at t=0 reducing to the ground-state momentum distri- R (t) = U T (t)U−1, (4.10a) ij il lm mn butionEq.(2.13),asexpectedbycontinuityofevolution. (cid:18) (cid:19) = (cosEkft)Iij +isinEEkfkft (cid:15)k−+gfgnfn −(cid:15)kg−fngfn , aRsetˆsc=alitn/gt m≡omtnegnt,uwmeoabstkˆai=ntkhξe≡mokm/(cid:112)en2tummngdfisatrnidbuttiimone 0 f (4.10b) in terms of dimensionless variables as evolves the initial Bogoluibov spinor (u (0−),v (0−))→ (cid:113) (uk(t),vk(t)), and k k n (tˆ)= [kˆ2+σ+ 2kˆ(12−+σ2)sin2(tˆ kˆ2(kˆ2+2))] − 1, U (t) = U (0+)T (t)U−1(0+)U (0−), (4.11a) kˆ 2(cid:113)kˆ2(kˆ2+2σ) 2 k k k k k = (cid:18)uke−iEkft vkeiEkft(cid:19)(cid:18)cosh∆θk sinh∆θk(cid:19). (4.15) vke−iEkft ukeiEkft sinh∆θk cosh∆θk where the initial-to-final scattering length ratio, σ ≡ (4.11b) a /a characterizes the “depth” of the quench. i f 9 The column momentum distribution n˜ (tˆ) ≡ n kˆ k (cid:82) dkˆznkˆ(tˆ) is a more experimentally relevant quantity 10 that we plot at different times in Fig. 7. We observe 8 thermalstate 3.0 t=0.1 quenched t=0.3 t=0.5 6 state 2.5 t=1.0 t=10 2.0 t=∞ 4 1.5 2 1.0 adiabaticstate 0 kξ 0.0 0.2 0.4 0.6 0.8 1.0 0.5 FIG.8: (Coloronline)Quenchedsteady-statemomentumdis- 0.2 0.4 0.6 0.8 1.0 1.2 1.4 tribution function nsks following a scattering length quench a = 0.1a → a (thick black curve), as compared to the i f f FIG.7: (Coloronline)Timeevolutionofthecolumnmomen- groundstatemomentumdistributionataf (dash-dottedred) tum distribution defined in the text following a scattering and the corresponding Bogoluibov thermalized distribution length quench from 0.1af →af, referring to Eq. (4.15) using (dotted blue) at temperature T =0.45ngf. Bogoluibov approximation. It illustrates the initial narrow momentum distribution (lowest curve) evolving to a much broadermomentumdistribution(highestcurve), correspond- A simpler measure of the post-quench dynamics is the ing to a pre-thermalized steady state. Here momentum and evolution of the condensate depletion, obtained from the √ time are rescaled with ξ ≡1/ 2mng and t ≡1/(ng ), re- momentum distribution function, n (t), (4.14), f 0 f k spectively. Thegreyregionindicatesarangeofmomentanot resolved in JILA experiments, due to initial inhomogeneous (cid:88) (cid:90) d3k n (t) = n (t)=V n (t), real space density profile and finite trap size. d k (2π)3 k k that starting with a narrow BEC peak, the column mo- = n0dFd(σ,t), (4.17) mentum distribution function quickly broadens and de- √ where n0 = 8/(3 π)(na3)1/2 is the ground-state deple- velops a large momentum tail. The momentum distribu- d f tion for a =a . tion approaches a pre-thermalized steady-state n˜ss from s f k high momenta, with momenta k > kpth(t) taking time F (σ,t) = (σ)3/2+ 3√1−σArccos(√σ) tpth(k)≈1/Ekf to pre-thermalize [61]. Thus we obtain d 2 √ (cid:113) 3 2(cid:90) (1−σ)cos(2ty(cid:112)y2+2) t (kˆ)=1/ kˆ2(kˆ2+2), (4.16) − ydy (4.18) pth 2 (y2+2)(y2+2σ)1/2 consistent with experiments [56] scaling as 1/k and 1/k2 is the nonequilibrium depletion enhancement factor at small and large momenta, respectively. above the corresponding ground state, that interpolates The steady-state momentum distribution, nss for a k between σ3/2 (giving the initial depletion at t = 0− for a = 0.1a → a is plotted in Fig. 8 and compared i f f a =a ) and the asymptotic depletion to the ground state n for the same a as well as s i k f thermal state nk at finite temperature. We observe Fss(σ)≡F (σ,t→∞)=σ3/2+ 3√1−σArccos(√σ) that this steady-state momentum distribution lies above d d 2 the ground state one, indicating that even in the long (4.19) time limit the post-quench system remains in the ex- cited states, as required by energy conservation. How- of the pre-thermalized state, plotted in Fig. 10. ever, it also differs significantly from the correspond- As is clear from the asymptotics of Fd(σ,t) defined by ing finite-temperature thermal-equilibrium distribution, (4.19) and illustrated in F√ig. 9, the depletion fraction nTk = (u2k + vk2)(cid:104)αˆk†αˆk(cid:105)0− + vk2 = 1/(eEkf/T − 1) + monotonically increases as t over a characteristic time vk2coth(Ekf/2T), demonstrating that even in the long 1 time, stationary state limit the system is only pre- tpth ≈ ng , (4.20) thermalized. This is expected because of the quadratic, f fullyintegrableformoftheBogoluibovHamiltonian. The approaching its asymptotic pre-thermalized value, that latterguaranteestheabsenceofscatteringoftheBogolui- is always higher than that of the ground state with the bov quasi-particles βˆ , with a conserved momentum dis- same scattering length a = a . The quenched steady- k s f tribution function, that is directly related to the initial state depletion enhancement, Fss(σ) monotonically in- d distribution by (4.5). creasing with decreasing σ (deeper quench), reaching a 10 n /n B. Bragg spectroscopy: structure function d 0.15 A two-time structure function S (t,t(cid:48)) = q (cid:104)δnˆ(−q,t)δnˆ(q,t(cid:48))(cid:105) is another central probe of the quenchedstate nonequilibrium dynamics of degenerate atomic gases. 0.10 It can be measured via Bragg spectroscopy through a stimulated two-photon transitions [72], and via a correlation function of a measured density excitation, 0.05 δnˆ(q,t) at momentum q and time t [38]. The former thus allowed measurements of the excitation spectrum adiabaticstate of a strongly interacting (85Rb) BEC, near unitarity t/t (na3 (cid:29) 1), demonstrating a large deviation from the 0 s 1 2 3 4 5 Bogoluibov and Lee-Huang-Yang (LHY) prediction of Sec. (IIA).Thelattertechniquewasusedtocharacterize FIG. 9: (Color online) Post quench dynamics of the conden- dynamics of a Feshbach-resonant Cesium gas, following sate depletion fraction as a function of rescaled time in units a shallow quench in its scattering length [38]. of pre-thermalization timescale t = (cid:126)/(ng ) = m/(4πa n(cid:126)) 0 f f With current experiments in mind, for simplicity we (solidblackcurve),followingascatteringlengthquenchfrom 0.1a →a with k a =0.1 (where k ≡n1/3), as compared focus on the equal-time t = t(cid:48) structure function (non- f f n f n trivial for nonequilibrium dynamics), tothegroundstatedepletionatk a (dashedredline). Fora n f typical85Rbexperimentwithn=5×1012cm−3,a =1100a f 0 (here a0 =5.29×10−11m is the Bohr radius), t0 ≈360µs. Sq(t) = (cid:104)δnˆ(−q,t)δnˆ(q,t)(cid:105), 1 (cid:90) = eiq·(r−r(cid:48))(cid:104)ψˆ†(r,t)ψˆ(r,t)ψˆ†(r(cid:48),t)ψˆ(r(cid:48),t)(cid:105) , V c r,r(cid:48) ≈ S0(t)+δSB(t), (4.21) q q minimum at σ = 1 (no quench), and exhibiting a maxi- where mum at σ = 0, corresponding to initially noninteracting gasoraquenchdeepintounitaryregime,wherea →∞. (cid:104) f S0(t) = n (cid:104)aˆ†(t)aˆ (t)(cid:105)+(cid:104)aˆ (t)aˆ† (t)(cid:105) We note, however, that the latter strongly-interacting q c q q −q −q resonant regime, clearly lies outside of the perturbative (cid:105) +(cid:104)aˆ (t)aˆ (t)(cid:105)+(cid:104)aˆ†(t)aˆ† (t)(cid:105) , (4.22a) Bogoluibov theory. We will treat this k a (cid:29) 1 non- −q q q −q n f perturbative regime in a subsequent section, using an = n (cid:2)C11(t)+C22(t)+C21(t)+C12(t)(cid:3), c q q q q approximate self-consistent treatment. (4.22b) and Fdss(σ) δSqB(t) = V1 (cid:88)(cid:104)(cid:104)aˆ†k(t)aˆk(t)(cid:105)(cid:104)aˆk−q(t)aˆ†k−q(t)(cid:105) k(cid:54)=0 2.5 (cid:105) +(cid:104)aˆ†(t)aˆ† (t)(cid:105)(cid:104)aˆ (t)aˆ (t)(cid:105) , k −k k−q −k+q 2.0 = 1 (cid:88)(cid:104)C11(t)C22 (t)+C(12)(t)C(21) (t)(cid:105), V k −k+q k −k+q k(cid:54)=0 (4.23) 1.5 are, respectively the quadratic and quartic contribution to S (t), both computed within the Bogoluibov approx- q σ imation. 0.2 0.4 0.6 0.8 1.0 Utilizing the Bogoluibov analysis of the nonequilib- rium quenched dynamics from the previous subsection, FIG. 10: (Color online) Quenched steady-state depletion en- (Eqs.(4.9), (4.10b), (4.11), (4.12), (4.13)) the leading hancement factor Fdss(σ) above the corresponding ground quadratic contribution to SB(t) is given by [38] state value as a function of σ = a /a following a quench q i f fernohmanaciem→enatf.FdsTs(h0e)tw=o3dπo/t4s c(oqpurernecshpionngdatontohne-inmtearxaimctuinmg S0(t) = S0(cid:34)1+ Eq2i−Eq2f sin2(E t)(cid:35), (4.24) gas or quenching to unitarity) and minimum enhancement q q E2 qf qf Fss(1)=1 (no quench), respectively. d where as a check, at initial time S0(t = 0) and/or for q no-quench g = g above expression reduces to the pre- i f

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