Polymer Surface Modification

499 Pages·2004·8 MB·English

by  Kash L Mittal

Polymer Surface Modification: Relevance to Adhesion
Volume 3
TThhiiss ppaaggee iinntteennttiioonnaallllyy lleefftt bbllaannkk
POLYMER SURFACE
M O D I F I C A T I O N:
RELEVANCE TO ADHESION
VOLUME 3
Editor:
K.L. Mittal
///VSP///
UTRECHT • BOSTON 2004
CRC Press
Taylor & Francis Group
6000 Broken Sound Parkway NW, Suite 300
Boca Raton, FL 33487-2742
© 2004 by Taylor & Francis Group, LLC
CRC Press is an imprint of Taylor & Francis Group, an Informa business
No claim to original U.S. Government works
Version Date: 20120727
International Standard Book Number-13: 978-9-04-741416-2 (eBook - PDF)
This book contains information obtained from authentic and highly regarded sources. Reasonable
efforts have been made to publish reliable data and information, but the author and publisher cannot
assume responsibility for the validity of all materials or the consequences of their use. The authors and
publishers have attempted to trace the copyright holders of all material reproduced in this publication
and apologize to copyright holders if permission to publish in this form has not been obtained. If any
copyright material has not been acknowledged please write and let us know so we may rectify in any
future reprint.
Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced,
transmitted, or utilized in any form by any electronic, mechanical, or other means, now known or
hereafter invented, including photocopying, microfilming, and recording, or in any information stor-
age or retrieval system, without written permission from the publishers.
For permission to photocopy or use material electronically from this work, please access www.copy-
right.com (http://www.copyright.com/) or contact the Copyright Clearance Center, Inc. (CCC), 222
Rosewood Drive, Danvers, MA 01923, 978-750-8400. CCC is a not-for-profit organization that pro-
vides licenses and registration for a variety of users. For organizations that have been granted a pho-
tocopy license by the CCC, a separate system of payment has been arranged.
Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and are
used only for identification and explanation without intent to infringe.
Visit the Taylor & Francis Web site at
http://www.taylorandfrancis.com
and the CRC Press Web site at
http://www.crcpress.com
Contents
Preface ix
Part 1. Plasma Surface Modification Techniques
The effects of atmospheric pressure plasma treatments on adhesion
and mechanical properties of high-performance fibers for
composites
Y. Qiu, X. Shao, C. Jensen, Y.J. Hwang, C. Zhang and
M.G. McCord 3
Modification of electrostatic properties of polymer powders by
atmospheric pressure plasma treatment
R. Sharma, S. Trigwell, M.K. Mazumder and R.A. Sims 25
Improved stain-release properties of PET fabric by plasma-surface
modifications
K.S. Johansson and P.A.K. Vesa 39
Surface characterization and properties of keratin fibers treated
with low-temperature plasmas
R. Molina, P. Jovancic, L. Julia, E. Bertran, D. Jocic and P. Erra 51
Surface modification of PET films by plasma source ion
implantation
T. Tanaka, M. Yoshida, M. Shinohara, S. Watanabe and T. Takagi 69
Functionalised plasma polymer coatings for promoting
the adhesion of high-performance polymer fibres
H. Sugihara, T. Kitagawa and F.R. Jones 83
Part 2. Other/Miscellaneous Surface Modification Techniques
Photon-based processes for surface modification of synthetic
fibers
T. Bahners, T. Textor and E. Schollmeyer 97
Contents
Wettability and surface free energies of polymeric materials
exposed to excimer ultraviolet light and particle deposition onto
their surfaces in water
K. Gotoh 125
Adhesion of copper to poly(tetrafluoroethylene) surfaces modified
with vacuum UV radiation downstream from He and Ar
microwave plasmas
H. Desai, L. Xiaolu, A. Entenberg, B. Kahn, F.D. Egitto,
L.J. Matienzo, T. Debies and G.A. Takacs 139
KrF excimer laser surface modification of ultrahigh molecular
weight polyethylene fibers for improved adhesion to epoxy resins
J. Zeng and A.N. Netravali 159
The effects of excimer laser irradiation on the surface morphology
and self-adhesion properties of some engineering polymers as
evaluated by ultrasonic welding
E. Sancaktar and HLu 183
Structural and chemical surface modification of polymers by
low-energy ions and influence on nucleation, growth and adhesion
of noble metals
J. Zekonyte, V. Zaporojtchenko, S. Wille, U. Schuermann and
F. Faupel 243
Surface modification of natural fibers by photo-grafting and
photo-curing
M.A. Khan and MM. Hassan 263
Surface modification of polypropylene for improved adhesion
E. Sancaktar and N. Sunthonpagasit 285
Surface modification of polymer-based materials to enhance their
resistance to highly aggressive oxidative environments
Y. Gudimenko, R. Ng> J J. Kleiman, Z.A. Iskanderova,
R. C. Tennyson and P. C. Hughes 325
Fixation strategies for macrocyclic ligands such as cyclodextrins
or cucurbit[6]uril on polymeric surfaces
E. Schollmeyer, H.-J. Buschmann, K. Jansen and A. We go 341
Functionalization of synthetic polymers by supramolecular
compounds: Immobilization of calix[n]arenes on polyester
E. Schollmeyer, K. Jansen, H.-J. Buschmann and K. Schmeide 353
Contents vn
Part 3. General Papers
Quantitative depth profiles from polymer surfaces by
angle-resolved X-ray photoelectron spectroscopy
R.W. Paynter 369
Adhesion failure of paints on thermoplastic polyolefin substrates
A. Bilyk, S. Li, W.S. Gutowski, M. Espiritu andl. Bur gar 379
Adhesion between hydroxyl graft-modified polypropylene and
polycarbonate films
S. Sdnchez-Valdes, S. Vazquez-Rodriguez, Y. del Angel-Vargas,
L.F. Ramos-de Valle O. Manero-Brito and CA. Valdes-Ponce 391
f
A novel process for formation of polymer release surfaces
Y, Gudimenko, R. Ng and 7. Kleiman 407
A novel approach based on scanning probe microscopy for
nanolithography in polymer films
S.F. Lyuksyutov, E. Sancaktar, G. Sigalov, P.B. Paramonov and
J. Kim 417
Controlled grafting of well-defined functional polymers on
hydrogen-terminated silicon substrates: Relevance to adhesion
of electrolessly-deposited copper
W.H. Yu E.T. Kang andK.G. Neoh 435
t
Gas barrier properties of transparent ceramic thin layers deposited
on PET substrate film by reactive sputtering
5. Iwamori 457
The modification of interphase layer and adhesion: Tuning and
predictability
A. Sharif, N. Mohammadi and N. Taheri Qazvini All
TThhiiss ppaaggee iinntteennttiioonnaallllyy lleefftt bbllaannkk
Polymer Surface Modification: Relevance to Adhesion, Vol. 3, pp. ix-x
Ed.K.L. Mittal
© VSP 2004
Preface
This book documents the proceedings of the Fourth International Symposium on
Polymer Surface Modification: Relevance to Adhesion held under the aegis of
MST Conferences, LLC in Orlando, FL, June 9-11, 2003. The premier sympo
sium on this topic was held in Las Vegas, Nevada, November 3-5, 1993, the pro
ceedings of which were properly chronicled [1]. The second symposium in this
series was held under the auspices of MST Conferences, LLC in Newark, NJ,
May 24-26, 1999, which was also documented in a proceedings book [2]. Apro
pos, it should be recorded that the third symposium in this vein was organized
also by MST Conferences, LLC in Newark, NJ, May 21-23, 2001 but, for a vari
ety of reasons, the proceedings of this event were not documented in the form of a
hard-bound book.
Polymers are used for a variety of purposes in a host of technological applica
tions and even a cursory look at the literature will evince that currently there is
tremendous interest and R&D activity in the area of polymer surface modification
to attain their desired surface characteristics, particularly to enhance their adhe
sion. This arises from the fact that polymers are innately not very adhesionable
and this necessitates their surface treatment to enhance their adhesion to other ma
terials. It should be underscored here that there exists a legion of polymer surface
treatment methods which can be broadly classified into wet and dry processes.
The technical program for this symposium was comprised of 28 papers reflect
ing both overviews and original research contributions. These presentations dis
cussed many different surface treatment methods, polymer surface analysis, and
the life and durability of treatment methods.
Now turning to this volume, it contains a total of 25 papers which were prop
erly peer reviewed, revised and edited. So this book is not a mere collection of
papers, rather represents the highest standard of publication. The book is divided
into three parts: Part 1. Plasma Surface Modification Techniques; Part 2.
Other/Miscellaneous Surface Modification Techniques; and Part 3. General Pa
pers. The topics covered include: low pressure plasma surface modification of a
variety of polymers using various gases; atmospheric pressure plasma treatment;
improvement of stain release properties of fabrics; modification of electrostatic
properties of polymers; photon-based processes for surface modification of fibers;
excimer UV light treatment; excimer laser surface treatment; low-energy ion
treatment; photo-grafting and photo-curing; metallization of treated polymers;
chemical (wet) functionalization of polymers; adhesion of paints to thermoplastic
substrates; polymer release surfaces; nanolithography in polymer films; gas bar-