Photoresponsive Polymers II PDF
Preview Photoresponsive Polymers II
214 Advances in Polymer Science EditorialBoard: A.Abe·A.-C.Albertsson·R.Duncan·K.Duˇsek·W.H.deJeu H.-H.Kausch·S.Kobayashi·K.-S.Lee·L.Leibler·T.E.Long I.Manners·M.Möller·O.Nuyken·E.M.Terentjev B.Voit·G.Wegner·U.Wiesner AdvancesinPolymerScience RecentlyPublishedandForthcoming Volumes Self-AssembledNanomaterialsII WaxCrystalControl·Nanocomposites VolumeEditor:Shimizu,T. Stimuli-ResponsivePolymers Vol.220,2008 Vol.210,2008 Self-AssembledNanomaterialsI FunctionalMaterialsandBiomaterials VolumeEditor:Shimizu,T. Vol.209,2007 Vol.219,2008 Phase-SeparatedInterpenetratingPolymer InterfacialProcessesandMolecularAggregation Networks ofSurfactants Authors:Lipatov,Y.S.,Alekseeva,T. VolumeEditor:Narayanan,R. Vol.208,2007 Vol.218,2008 HydrogenBondedPolymers NewFrontiersinPolymerSynthesis VolumeEditor:Binder,W. VolumeEditor:Kobayashi,S. Vol.207,2007 Vol.217,2008 Oligomers·PolymerComposites PolymersforFuelCellsII MolecularImprinting VolumeEditor:Scherer,G.G. Vol.206,2007 Vol.216,2008 PolysaccharidesII PolymersforFuelCellsI VolumeEditor:Klemm,D. VolumeEditor:Scherer,G.G. Vol.205,2006 Vol.215,2008 NeodymiumBasedZieglerCatalysts– PhotoresponsivePolymersII FundamentalChemistry VolumeEditors:Marder,S.R.,Lee,K.-S. VolumeEditor:Nuyken,O. Vol.214,2008 Vol.204,2006 PhotoresponsivePolymersI PolymersforRegenerativeMedicine VolumeEditors:Marder,S.R.,Lee,K.-S. VolumeEditor:Werner,C. Vol.213,2008 Vol.203,2006 PeptideHybridPolymers Polyfluorenes VolumeEditors:Klok,H.-A.,Schlaad,H. VolumeEditors:Scherf,U.,Neher,D. Vol.202,2006 Vol.212,2008 ChromatographyforSustainable SupramolecularPolymers PolymericMaterials PolymericBetains·Oligomers Renewable,DegradableandRecyclable Vol.201,2006 VolumeEditors:Albertsson,A.-C., Hakkarainen,M. OrderedPolymericNanostructuresatSurfaces Vol.211,2008 VolumeEditor:Vancso,G.J.,Reiter,G. Vol.200,2006 PhotoresponsivePolymers II Volume Editors: Seth R. Marder · Kwang-Sup Lee Withcontributionsby C.Andraud·P.L.Baldeck·C.Barsu·H.Chermette G.D.D’Ambruoso·R.Fortrie·H.Hoppe·D.V.McGrath N.S.Sariciftci·O.Stéphan 123 TheseriesAdvancesinPolymerSciencepresentscriticalreviewsofthepresentandfuturetrendsin polymerandbiopolymerscienceincludingchemistry,physicalchemistry,physicsandmaterialscience. Itisadressedtoallscientistsatuniversitiesandinindustrywhowishtokeepabreastofadvancesin thetopicscovered. Asarule,contributionsarespeciallycommissioned.Theeditorsandpublisherswill,however,always bepleasedtoreceivesuggestionsandsupplementaryinformation.PapersareacceptedforAdvancesin PolymerScienceinEnglish. InreferencesAdvancesinPolymerScienceisabbreviatedAdvPolymSciandiscitedasajournal. SpringerWWWhomepage:springer.com VisittheAPScontentatspringerlink.com ISBN978-3-540-69452-6 e-ISBN978-3-540-69454-0 DOI10.1007/978-3-540-69454-0 AdvancesinPolymerScienceISSN0065-3195 LibraryofCongressControlNumber:2008932858 (cid:1)c 2008Springer-VerlagBerlinHeidelberg Thisworkissubjecttocopyright.Allrightsarereserved,whetherthewholeorpartofthematerial isconcerned,specificallytherightsoftranslation,reprinting,reuseofillustrations,recitation,broad- casting,reproductiononmicrofilmorinanyotherway,andstorageindatabanks.Duplicationof thispublicationorpartsthereofispermittedonlyundertheprovisionsoftheGermanCopyrightLaw ofSeptember9,1965,initscurrentversion,andpermissionforusemustalwaysbeobtainedfrom Springer.ViolationsareliabletoprosecutionundertheGermanCopyrightLaw. Theuseofgeneraldescriptivenames,registerednames,trademarks,etc.inthispublicationdoesnot imply, even in the absence of a specific statement, thatsuchnamesareexempt fromthe relevant protectivelawsandregulationsandthereforefreeforgeneraluse. Coverdesign:WMXDesignGmbH,Heidelberg TypesettingandProduction:le-texpublishingservicesoHG,Leipzig Printedonacid-freepaper 9876543210 springer.com VolumeEditors Prof.SethR.Marder Prof.Dr.Kwang-SupLee GeorgiaInstituteofTechnology DepartmentofAdvancedMaterials SchoolofChemistry&Biochemistry HannamUniversity 770StateStreet 561-6Jeonmin-Dong AtlantaGA30332-0400 Yuseong-Gu305-811 USA Daejeon,SouthKorea [email protected] [email protected] EditorialBoard Prof.AkihiroAbe Prof.Dr.WimH.deJeu DepartmentofIndustrialChemistry PolymerScienceandEngineering TokyoInstituteofPolytechnics UniversityofMassachusetts 1583Iiyama,Atsugi-shi243-02,Japan 120GovernorsDrive [email protected] AmherstMA01003,USA [email protected] Prof.A.-C.Albertsson Prof.Hans-HenningKausch DepartmentofPolymerTechnology TheRoyalInstituteofTechnology EcolePolytechniqueFédéraledeLausanne 10044Stockholm,Sweden SciencedeBase [email protected] Station6 1015Lausanne,Switzerland Prof.RuthDuncan [email protected] WelshSchoolofPharmacy Prof.ShiroKobayashi CardiffUniversity RedwoodBuilding R&DCenterforBio-basedMaterials KingEdwardVIIAvenue KyotoInstituteofTechnology CardiffCF103XF,UK Matsugasaki,Sakyo-ku [email protected] Kyoto606-8585,Japan [email protected] Prof.KarelDuˇsek Prof.Kwang-SupLee InstituteofMacromolecularChemistry, Czech DepartmentofAdvancedMaterials AcademyofSciencesoftheCzechRepublic HannamUniversity HeyrovskýSq.2 561-6Jeonmin-Dong 16206Prague6,CzechRepublic Yuseong-Gu305-811 [email protected] Daejeon,SouthKorea [email protected] VI EditorialBoard Prof.L.Leibler Prof.OskarNuyken MatièreMolleetChimie LehrstuhlfürMakromolekulareStoffe EcoleSupérieuredePhysique TUMünchen etChimieIndustrielles(ESPCI) Lichtenbergstr.4 10rueVauquelin 85747Garching,Germany 75231ParisCedex05,France [email protected] [email protected] Prof.E.M.Terentjev Prof.TimothyE.Long CavendishLaboratory DepartmentofChemistry MadingleyRoad andResearchInstitute CambridgeCB3OHE,UK VirginiaTech [email protected] 2110HahnHall(0344) Blacksburg,VA24061,USA Prof.BrigitteVoit [email protected] InstitutfürPolymerforschungDresden HoheStraße6 Prof.IanManners 01069Dresden,Germany SchoolofChemistry [email protected] UniversityofBristol Cantock’sClose Prof.GerhardWegner BS81TSBristol,UK Max-Planck-Institut [email protected] fürPolymerforschung Ackermannweg10 Prof.MartinMöller 55128Mainz,Germany DeutschesWollforschungsinstitut [email protected] anderRWTHAachene.V. 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Preface Over the past 25 years or so there has been a revolution in the develop- mentoffunctionalpolymers.Whilemanypolymersascommoditiesrepresent huge markets, new materials with a high degree of functionality have been developed. Such specialty polymers play important roles in our day-to-day lives.Thecurrentvolumes213and214ofAdvancesinPolymerSciencefocus onphotoresponsivepolymers. Inparticular polymers thatcaneither change the properties of a beam of light that passes through them or who change their properties in response to light. Volume 213 starts with an introduc- tion to two-photon absorption by Rumi, Barlow, Wang, Perry, and Marder. In this chapter they develop the basic concepts of two-photon absorption, and describe structure–property relationships for a variety of symmetrical andunsymmetrical molecules.Theapplicationsofthesematerials in3Dmi- crofabrication of polymers, metals, and oxide materials are detailed in the chapterentitled“Two-PhotonAbsorberandTwo-PhotonInducedChemistry” contributed by the same group of authors. Then Belfield, Bondar, and Yao describethemolecules,dendrimers,oligomers,andpolymersthatcanbeex- citedbytwo-photonabsorptionandtheirapplicationinprocessingmaterials withthree-dimensional spatialcontrolintheirchapterentitled“Two-Photon AbsorbingPhotonicMaterials.”Specificallytheydescribethedevelopmentof symmetrical and polar conjugated materials for two-photonabsorption and theiruseasphoto-initiatorsfor3Dmicrofabrication.Juodkazis,Mizeikis,and Misawaalsoexploremultiphotonprocessingofmaterialsintheirchapter,and providemorefocusontheprocessing aspects ofthesematerials anddiscuss thestate-of-the-artinresolution. In Volume 214, Hoppe and Sariciftci describe how organic semiconduct- ing polymers can be used to produce electrical power when excited by light in the chapter entitled “Polymeric Photovoltaic Devices.” In particular the authors review approaches based upon blends of conjugated polymers with smallmoleculesthatareapproachingapointwheretheycanbeconsideredfor commercialization. Thisisfollowedby achapter by McGrathand D’Ambru- osoentitled“EnergyHarvestinginSyntheticDendriticMaterials”wherethey describedendritic materials thatcanabsorblightacrossvariouspartsofthe UV–visiblespectrumandfunnelenergydowntoalowenergyabsorber,which can be useful for a variety of applications including photovoltaics. Finally, X Preface BaldeckandAndraudprovideachapterentitled“ExitonicCoupledOligomers andDendrimers forTwo-PhotonAbsorption,”wherein the conceptsofexci- toniccouplingaredevelopedandtheirrelevancetomulti-photonabsorption processesaredescribed. Theeditorshopethatthesevolumeswillprovidethereaderwithanoverview ofvariousaspectsofphotoresponsivepolymers.Werecommendthatreaders alsoexamine othervolumesinthisseriestolearnmoreaboutrelated topics. In addition the editors thank the authors of the chapters in these volumes and the staff of Springer for their contribution to these volumes and accept responsibilityforanyerrorsorinaccuracies. Atlanta&Daejeon,May2008 S.R.MarderandK.-S.Lee Contents PolymerSolarCells H.Hoppe·N.S.Sariciftci . . . . . . . . . . . . . . . . . . . . . . . . . 1 EnergyHarvestinginSyntheticDendrimerMaterials G.D.D’Ambruoso·D.V.McGrath . . . . . . . . . . . . . . . . . . . . . 87 ExcitonicallyCoupledOligomersandDendrimers forTwo-PhotonAbsorption C.Andraud·R.Fortrie·C.Barsu·O.Stéphan H.Chermette·P.L.Baldeck . . . . . . . . . . . . . . . . . . . . . . . . 149 SubjectIndex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205
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