Loughborough University Institutional Repository Phase equilibria in mixtures containing alkanes and alcohols ThisitemwassubmittedtoLoughboroughUniversity’sInstitutionalRepository by the/an author. Additional Information: • A Doctoral Thesis. Submitted in partial ful(cid:28)llment of the requirements for the award of Doctor of Philosophy of Loughborough University. Metadata Record: https://dspace.lboro.ac.uk/2134/10419 Publisher: (cid:13)c A.H.D. El Nikheli Please cite the published version. This item was submitted to Loughborough’s Institutional Repository (https://dspace.lboro.ac.uk/) by the author and is made available under the following Creative Commons Licence conditions. For the full text of this licence, please go to: http://creativecommons.org/licenses/by-nc-nd/2.5/ " ox BkOSC n.o:- ~3?.4-7 " LOUGHBOROUGH UNIVERSITY OF TECHNOLOGY LIBRARY AUTHOR/FILING TITlE H..u A- ~L "'11(~.rL.1 '-----------------------~-------------------- _. -- -- - -----------------------------------.------ . -~ ACCESSION/COPY NO, , ~2t)907 /02' , ._---------------- -------_____L ________ ------"---- ~ , .... VOl. NO. CLASS MARK I . ~ .' PHASE EQUILIBRIA IN MIXTURES CONTAINING ALKANES AND ALCOHOLS BY ALl HASSAN DARWISH EL NIKHELI B,Sc, AND M,Sc, A THESIS DOCTORA~ SUBMITTED IN PARTIAL FULFILMENT OF THE REQUIREMENTS FOR THE AWARD OF DOCTOR OF PHILOSOPHY OF THE LOUGHBOROUGH UNIVERSITY OF TECHNOLOGY DECEMBER 1987 SUPERVISORS: DR. A.S. TEJA DR. P. RICE DR. A.O. FARAG CS) A. H. D. El. NIKHELI 1987 LeughWOO{1!t IJnlv.,..tty of T::Jd':r;,-: ''i'" :".!br&ry ~~,'~,:1Sii~ .. '_-1 Cl:. .. !i.~i~q~7) 01.- I -H- DECLARATION I declare that the following thesis is a record of research work carried out by me, and that the thesis is of my own composition. I also certify that neither this thesis nor the original work contained therein has been submitted to this or to any other institution for a higher degree. . . "'iii- ACKNOWLEDGEMENTS I have known Dr. Amyn S. Teja for several years during which deep friendship has developed between us. It started after I joined the University of Riyadh (later King Saud University) to teach in its chemical engineer- ing department. I decided to drop my graduate studies at New York Polytech, N.Y., U.S.A. to work with him for my Ph.D. degree at Loughborough University of Technology the first time I met him and I continued to work with him when he moved to Tech., Atlanta, U. S. A. , till Georg~a this thesis was completed this year. He is agreat man. I owe to him my deep attraction to the subject of this research. My gratitude and appreciation to him are unlimited. His continuous guidance and inspiration through all phases of this work make me for ever grateful to him. I would like to express my sincere appreciation also to Dr. P. Rice for his supervision, patience and guid ance. His help in resolving many difficulties which occured during this work and his valuable discussions and remarks are highly acknowledged. My special thanks are to Dr. Ahmad Omar Farag for his continuous encouragement and support to me during my undergraduate and graduate studies and along my life. To me he is like a father, and I owe him a lot. -iv- I wish to thank also Dr. S. Madani and Dr. M. Soliman for their fruitful discussions and help. Special thanks are also extended to Dr. G. Georgeton for the many fruitful discussions during my work on this thesis at GeorgA.a Institute of Technology, U.S.A., and also to other graduate members of Dr. Teja's thermo- w. dynamic school. My deepest thanks are due to Dr. Tawfik and his wife Marybeth for making my work and my stay in Georgea Tech quite comfortable. I learned a lot about VLE measurement at' the Institute of Thermodynamics, University of Berlin, .West Germany. Thanks to Dr. H. Knapp for giving me this good opportunity for learning from him. I thank also the Research Cent er of the College of Engineering at KSU for encouraging research work on VLE measurements. I also thank Dr. A. Sharaf and M. Abul Kasim for their continuous help in my computer work. I wish to thank M. Jamil for the effort and patience spent in typing my thesis and M. Al Sodsi for doing the draw ings in this thesis. My mother and my family with their sincere love have always encouraged me to complete this work. I am grate ful to all of them. My wife stood beside me with kind ness and love during all aspects of this thesis and -v- during hard times of my illness which extended along this work, for her I will always be indebted and grateful. Finally I would like to apologize to and at the same time thank my son Omar and my daughter Ghada for the time I should have spent with them and for the vacations I spent far from them doing this work. It is for them, my parents, and my wife that this thesis is dedicated.
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