FOOD AND BEVERAGE CONSUMPTION AND HEALTH P EPPERS H M , ARVESTING ETHODS A P NTIOXIDANT ROPERTIES AND HEALTH EFFECTS F B C OOD AND EVERAGE ONSUMPTION H AND EALTH Additional books in this series can be found on Nova’s website under the Series tab. Additional e-books in this series can be found on Nova’s website under the e-book tab. FOOD AND BEVERAGE CONSUMPTION AND HEALTH P EPPERS H M , ARVESTING ETHODS A P NTIOXIDANT ROPERTIES H E AND EALTH FFECTS BEATRICE DAWSON EDITOR New York Copyright © 2016 by Nova Science Publishers, Inc. All rights reserved. No part of this book may be reproduced, stored in a retrieval system or transmitted in any form or by any means: electronic, electrostatic, magnetic, tape, mechanical photocopying, recording or otherwise without the written permission of the Publisher. We have partnered with Copyright Clearance Center to make it easy for you to obtain permissions to reuse content from this publication. 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Additional color graphics may be available in the e-book version of this book. Library of Congress Cataloging-in-Publication Data ISBN:(cid:3)(cid:28)(cid:26)(cid:27)(cid:16)(cid:20)(cid:16)(cid:25)(cid:22)(cid:23)(cid:27)(cid:23)(cid:16)(cid:27)(cid:24)(cid:26)(cid:16)(cid:21)(cid:3)(cid:11)(cid:72)(cid:37)(cid:82)(cid:82)(cid:78)(cid:12) Library of Congress Control Number: 2016933382 Published by Nova Science Publishers, Inc. † New York CONTENTS Preface vii Chapter 1 Pre and Postharvest Treatments Affecting Bell Pepper Antioxidant Activity 1 Zoran S. Ilić and Elazar Fallik Chapter 2 EPR and 9 GHz EPR Imaging of Paramagnetic Species in Pepper Seeds 41 Kouichi Nakagawa, Boris Epel and Hideyuki Hara Chapter 3 Drying Peppers: Technology and Properties 55 Raquel de Pinho Ferreira Guiné Chapter 4 Antioxidant Properties and Healthy Effects of Peppers 97 S. F. Zanini, M. C. Pina-Pérez, M. Sanz-Puig, D. Rodrigo and A. Martínez Chapter 5 Phytochemicals-Rich Food, Human Health and Food Processing: The Case of Pepper (Capsicum Species) 125 Monica Rosa Loizzo, Seyed Mohammad Nabavi, Marco Bonesi, Francesco Menichini and Rosa Tundis Index 145 PREFACE The pepper fruit is commonly consumed as fresh fruit. In addition, the fruit is used in food industry and in manufacture processing, either fermented or concentrated. The pepper fruit is a rich source of bioactive compounds with antioxidant properties to which highly desirable medicinal properties and health benefits have been attributed. The stability and concentration of these bioactive compounds are affected by preharvest factors such as cultivar, cultivation methods and fertilisation, grafting, shading, stage of maturity, and postharvest factors such as prestorage treatments, temperature management and packaging. Chapter One of this book discusses in detail the preharvest and postharvest factors influencing the functional properties of pepper fruit. Chapter Two reviews electron paramagnetic resonance imaging of paramagnetic species in pepper seeds. Chapter Three studies the technology and properties of drying peppers after harvesting. Chapter Four presents the potential use of peppers for therapeutic management besides its use as a food additive in various spicy cuisines. Chapter Five provides an overview of recent research on the chemical profile, health properties, and processing of peppers. Chapter 1 - The pepper fruit is commonly consumed as fresh fruit. In addition, the fruit is used in food industry and in manufacture processing, either fermented or concentrated. The pepper fruit is a rich source of bioactive compounds with antioxidant properties to which highly desirable medicinal properties and health benefits have been attributed. The stability and concentration of these bioactive compounds are affected by preharvest factors such as cultivar, cultivation methods and fertilisation, grafting, shading, stage of maturity, and postharvest factors such as prestorage treatments (short hot water rinsing and brushing treatments applied either individually or in combination with other means), temperature management and packaging. This viii Beatrice Dawson review discusses in detail the preharvest and postharvest factors influencing the functional properties of pepper fruit. Chapter 2 - Noninvasive 9 GHz electron paramagnetic resonance (EPR) imaging and continuous wave (CW) EPR were used to investigate the locations of paramagnetic species in black pepper seeds without irradiation. Commercially available black pepper seeds were measured. The authors observed signatures from three different radical species, which were assigned to stable organic radicals, Fe3+, and Mn2+ complexes. In addition, no EPR spectral change in the seed was observed after it was submerged in distilled H O for 1 h. The EPR and EPR imaging results suggested that the 2 paramagnetic species were mostly located at the seed surface. Fewer radicals were found inside the seed. Thus, pepper seeds contain persistent radicals as well as paramagnetic species. The persistent radicals were located on the surface region of the pepper seed. CW EPR and 9 GHz EPR imaging were useful for the determination of the spatial distribution of paramagnetic species in various seeds. Chapter 3 - The peppers can be very diverse, from sweet to hot peppers, varying in shape, in colour, in properties and usages. While some are eaten in the fresh state, many of them undergo a drying process to be preserved for a longer time and to increase availability and convenience. Hence, after harvesting, in many cases a drying operation is involved, and the present chapter aims to address this operation, of pivotal importance. In ancient times, the drying of foods in general and peppers in particular was done by exposure to the solar radiation. However, despite its cheapness and easiness, this process involved many drawbacks, like long drying times, probability of adverse atmospheric conditions and contaminations of the product. Hence, nowadays its usage is reduced. The most popular industrial drying method is the hot air convective drying. However, the high temperatures to which the product is exposed can cause changes in the composition and nutritional value as well as in the physical properties or organoleptic quality of the products. Other alternative methods can be used, but sometimes they are more expensive or more time consuming, such as is the case of freeze drying. Still, this last also has visible advantages from the quality point of view, minimizing the changes in texture, colour, flavour or nutrients. The knowledge of adequate drying operating conditions allows the optimization of the product characteristics, and hence to know the drying kinetics or the isotherms is fundamental to properly design the most adequate Preface ix drying processes, and therefore preserve the organoleptic characteristics as well as the bioactive compounds present. Chapter 4 - The peppers are used to spice up dishes and make it more appealing to the eye and to the palate by get more flavor, aroma, taste, color and spiciness, and can also act as food preservation, to treat health disorders and to prevent diseases. From the time of Hippocrates peppers has been used as a medicine and condiment. Frequently used in culinary, Brazilian pepper has therapeutic properties. The mature red berries of Brazilian pepper resemble the red berries of black pepper (Piper nigrum), but is not a true pepper. Therefore, there is wide spectrum of peppers varieties, rich in phytochemicals, with recognized source of pharmaceutical agents and as a food additive in various spicy cuisines. The most popular genus of peppers is Piper and Capsicum. Currently, there are more than 150 varieties of Capsicum, derived from domesticated species and about 40 wild species, which are used at crossings to make them more resistant cash crops to pests and diseases. Among the wild varieties, only five have been domesticated as Capsicum spp. L. are Capsicum annuum, Capsicum baccatum, Capsicum chinense, Capsicum frutescens, and Capsicum pubescens where the first three are the ones that have gained economic importance. The health benefits of the Capsicum genus include relief from cancer, menopausal problems, low risk of cardiovascular disease and diabetes. Further, it has anti-inflammatory, antimicrobial, immunomodulatory, anti-carcinogenic, analgesic properties and may also provide relief in pain related to rheumatoid arthritis. It has been described that the bioactive compounds implicated in the potential of peppers are polyphenols, vitamin C, carotenoids, and capsaicinoids. Concerning nutritional value is a source of vitamins, especially A and C and to have even more minerals which are essential for the perfect functioning of the body. In conclusion, the aim of this chapter was to present the potential use of peppers for therapeutic management besides its use as a food additive in various spicy cuisines. Chapter 5 - Epidemiological studies and associated meta-analyses suggest that long term consumption of diets rich in spice offers protection against development of cancers, cardiovascular diseases, diabetes, osteoporosis, and neurodegenerative diseases. The genus Capsicum (pepper fruits) includes a large number of wild and cultivated species. Peppers, one of the most consumed spices worldwide, are an excellent source of health-related compounds including carotenoids, capsaicinoids, phenols, tocopherols, and vitamin C. Pepper fruits are used fresh and/or cooked and also for medicinal purposes. An overview of recent research on the chemical profile, health