Organometallic Chemistry Vol. 1

258 Pages·1971·4.681 MB·English

by  I Fairlamb, Jason M LyNAm

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Organometallic chemistry is an interdisciplinary science which list Specialist Periodical Reports
continues to grow at a rapid pace. Although there is continued P
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interest in synthetic and structural studies, the last decade rio
has seen a growing interest in the potential of organometallic d Edited by Ian Fairlamb and Jason Lynam
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chemistry to provide answers to problems in catalysis, synthetic a
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organic chemistry and also in the development of new materials. e Organometallic Chemistry
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This Specialist Periodical Report aims to refl ect these current o
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Specialist Periodical Reports
Specialist Periodical Reports provide systematic and detailed ISBN 978-0-85404-358-3
review coverage in major areas of chemical research. Compiled
by teams of leading experts in their specialist fi elds, this series
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the latest developments in their fi eld. Each volume in the series is lam
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Organometallic Chemistry
Volume 35
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A Specialist Periodical Report View Online
Organometallic Chemistry
Volume 35
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1 A Review of the Literature Published between
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1210. Editors
gust 20g | doi: I. Fairlamb and J. Lynam, University of York, UK
on 11 Auubs.rsc.or AL.uAt.hAordsrio, Imperial College London, UK
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A. Sella, University College London, UK
A.E.H. Wheatley, University of Cambridge, UK
D.S. Wright, University of Cambridge, UK
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Ifyoubuythistitleonstandingorder,youwillbegivenFREEaccess
to the chapters online. Please contact [email protected] with proof of
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n 11 Aubs.rsc.or r The Royal Society of Chemistry 2009
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The Royal Society of Chemistry at the address printed on this page.
Published by The Royal Society of Chemistry,
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Preface
Ian Fairlamb and Jason Lynam
DOI: 10.1039/b819427k
The format for this Volume follows on from the modifications made to
thestructureofthisjournalseries,whichwereintroducedinVolume34.The
Volumeissplitintotwosections:Comprehensivereviewsandcriticalreviews.
Comprehensive reviews of the organometallic chemistry of a wide range
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7 of elements from across the periodic table are included in this Volume.
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94 These articles cover the literature from 2006 and 2007. Contributions are
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B8 madebyJohnG.BrennanandAndreaSella,JoannaHaywoodandAndrew
39/ E.H.Wheatley,FelipeGarcı´aandDominicS.Wright,MarkG.Humphrey
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20.1 and Marie P. Cifuentes. One important highlight is the review of the
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DepartmentofChemistry,UniversityofYork,Heslington,York,UKYO105DD
Organomet. Chem., 2009, 35, 7–8 | 7
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CONTENTS
Cover
Ballandstickrepresentationof
GrubbsgenerationIIcatalyst.
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by pte Ligand electronic effects in homogeneous catalysis using transition 19
ded 0 Se metal complexes of phosphine ligands
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Dohe Introduction 19
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Electronic effects on Rh-catalysed hydroformylation 33
Hydroaminomethylation 40
AbnormalNHCs:coordination,reactionchemistryandcatalyticapplications 47
Martin Albrecht and Kingsley J. Cavell
Introduction 47
The redox behaviour of the imidazolium salt/NHC couple and the 48
impactonthereactionchemistryofabnormalNHCcomplexes
Catalysis with complexes of abnormal, C4-bound carbenes 51
Donor properties of C4-bound imidazolylidenes 56
Conclusions 59
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Application of phosphine ligands in organic synthesis 62
Luis A. Adrio and King Kuok (Mimi) Hii
Introduction 62
Asymmetric hydrogenation 62
Cross-coupling and related reactions (C–C bond formation) 75
CouplingreactionswithpronucleophilesNuc–H 80
(Nuc=C,N,O,S)
Other catalytic methodologies enabled by phosphine ligands 87
2F Summary 88
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Dalhomber Aryl–aryl bond formation via coupling of two C–H bonds 119
by pte Conclusion and outlook 125
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The coinage metals 140
Group 2 (Be–Ba) and Group 12 (Zn–Hg) 162
Felipe Garcı´a and Dominic S. Wright
Scope and organisation of the reviews for 2006 and 2007 162
Review of 2006 162
Review of 2007 169
Scandium, yttrium and the lanthanides 183
John G. Brennan and Andrea Sella
Introduction 183
Hydrocarbyls 183
Allylic chemistry 184
Cyclopentadienyl and related ligands 185
10 | Organomet. Chem., 2009, 35, 9–18
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Boron ligands V1i9ew1 Online
Arene complexes 192
Chemistry in new or ambiguous oxidation states 193
S and P ligands 197
Amides 199
Alkoxides 203
Chemistry with alkyl-aluminium compounds 205
Organolanthanides in organic synthesis 208
Materials synthesis 209
F Polymerization chemistry 209
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Dalhomber Introduction 234
by pte Spectroscopic studies 234
ded 0 Se Theory 234
nloaon 3 Structural studies 235
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Group 8 238
Group 9 245
Group 10 246
Group 11 247
Mixed-metal clusters 248
Clusters containing three different metals 254
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