Organic Mass Spectrometry in Art and Archaeology Organic Mass Spectrometry in Art and Archaeology Edited by MARIA PERLA COLOMBINI AND FRANCESCA MODUGNO University of Pisa, Pisa, Italy A John Wiley and Sons, Ltd., Publication Thiseditionfirstpublished2009 (cid:2)2009JohnWiley&Sons,Ltd Registeredoffice JohnWiley&SonsLtd,TheAtrium,SouthernGate,Chichester,WestSussex,PO198SQ,UnitedKingdom Fordetailsofourglobaleditorialoffices,forcustomerservicesandforinformationabouthowtoapplyfor permissiontoreusethecopyrightmaterialinthisbookpleaseseeourwebsiteatwww.wiley.com. Therightoftheauthortobeidentifiedastheauthorofthisworkhasbeenassertedinaccordancewiththe Copyright,DesignsandPatentsAct1988. Allrightsreserved.Nopartofthispublicationmaybereproduced,storedinaretrievalsystem,ortransmitted,in anyformorbyanymeans,electronic,mechanical,photocopying,recordingorotherwise,exceptaspermitted bytheUKCopyright,DesignsandPatentsAct1988,withoutthepriorpermissionofthepublisher. 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LibraryofCongressCataloging-in-PublicationData Colombini,MariaPerla. Organicmassspectrometryinartandarchaeology/MariaPerlaColombini,FrancescaModugno. p. cm. Includesbibliographicalreferencesandindex. ISBN978-0-470-51703-1 1. Massspectrometry. 2. Organiccompounds—Analysis. I. Modugno,Francesca. II. Title. QD272.S6C632009 702.808—dc22 2009009694 AcataloguerecordforthisbookisavailablefromtheBritishLibrary. 978-0-470-51703-1 Setin10/12ptTimesbyIntegraSoftwareServicesPvt.Ltd,Pondicherry,India PrintedandboundinItalybyPrinterTrento CoverImage Onthecover:upperpartofaclaylamp,fromAntinoupolis,Egypt(inv.718,unpublished,(cid:2)CentroStudi IstitutoPapirologicoG.Vitelli,Universita`degliStudidiFirenze). Contents ListofContributors vii Acknowledgements ix Preface xi PARTI INTRODUCTION 1 1 OrganicMaterialsinArtandArchaeology 3 MariaPerlaColombiniandFrancescaModugno 2 OverviewofMassSpectrometricBasedTechniquesApplied intheCulturalHeritageField 37 GianlucaGiorgi PARTII DIRECTMASSSPECTROMETRICANALYSIS 75 3 DirectMassSpectrometricTechniques:VersatileToolstoCharacterise ResinousMaterials 77 ErikaRibechini 4 DirectMassSpectrometrytoCharacteriseWaxandLipid Materials 97 MartineRegert 5 GALDI-MSAppliedtoCharacteriseNaturalVarnishesandBinders 131 PatrickDietemannandChristophHerm 6 MALDI-MSAppliedtotheAnalysisofProteinPaintBinders 165 StepankaKuckova,RadovanHynekandMilanKodicek vi Contents PARTIII GASCHROMATOGRAPHY/MASSSPECTROMETRY 189 7 GC/MSintheCharacterizationofLipids 191 MariaPerlaColombini,FrancescaModugnoandErikaRibechini 8 GC/MSintheCharacterisationofResinousMaterials 215 FrancescaModugnoandErikaRibechini 9 GC/MSintheCharacterisationofProteinPaintBinders 237 MariaPerlaColombiniandGwe´nae¨lleGautier 10 SPME/GC-MSintheCharacterisationofTerpenicResins 261 JeanBletonandAlainTchapla 11 Py-GC/MSofOrganicPaintBinders 303 IlariaBonaduceandAlessiaAndreotti 12 Py-GC/MSofNaturalandSyntheticResins 327 DominiqueScalaroneandOscarChiantore PARTIV LIQUIDCHROMATOGRAPHY/MASSSPECTROMETRY 363 13 CharacterizationofOrganicNaturalDyesbyElectrospray MassSpectrometryCoupledwithHPLCand/orCapillary Electrophoresis 365 KatarzynaLech,KatarzynaPołec´-PawlakandMaciejJarosz PARTV OTHERMS-BASEDTECHNIQUES 389 14 Compound-specificStableIsotopesinOrganicResidue AnalysisinArchaeology 391 RichardP.Evershed 15 ToF-SIMSStudyofOrganicMaterialsinCulturalHeritage: IdentificationandChemicalImaging 433 VincentMazelandPascaleRichardin 16 AcceleratorMassSpectrometryfor14CDating 459 MariaelenaFedi Index 483 List of Contributors AlessiaAndreotti,DepartmentofChemistryandIndustrialChemistry,UniversityofPisa, ViaRisorgimento35,56126Pisa,Italy JeanBleton,GroupedeChimieAnalytiquedeParis-Sud11(LETIAM)EA4041,Institut UniversitairedeTechnologied’Orsay,PlateaudeMoulon,91400Orsay,France IlariaBonaduce,DepartmentofChemistryandIndustrialChemistry,UniversityofPisa, ViaRisorgimento35,56126Pisa,Italy Oscar Chiantore, Department of IPM Chemistry and Centre of Excellence NIS, UniversityofTorino,ViaGiuria7,10125Torino,Italy MariaPerlaColombini,DepartmentofChemistryandIndustrialChemistry,University ofPisa,ViaRisorgimento35,56126Pisa,Italy PatrickDietemann,DoernerInstitut,BayerischeStaatsgema¨ldesammlungen,BarerStr. 29,D-80799Mu¨nchen,Germany RichardP.Evershed,OrganicGeochemistryUnit,BristolBiogeochemistryResearch Centre, School of Chemistry, University of Bristol, Cantock’s Close, Bristol BS8 1TS,UK MariaelenaFedi,INFNSezionediFirenze,ViaBrunoRossi1,50019SestoFiorentino, Italy Gwe´nae¨lleGautier,TheArtInstituteofChicago,111SouthMichiganAvenue,Chicago, IL60603-6404,USA GianlucaGiorgi,DepartmentofChemistry,UniversityofSiena,ViaAldoMoro,53100 Siena,Italy ChristophHerm,StudiengangRestaurierung,Hochschulefu¨rBildendeKu¨nsteDresden, Gu¨ntzstr.34,D-01307Dresden,Germany Radovan Hynek, Institute of Chemical Technology, Department of Biochemistry and Microbiology,Technicka´ 3,16628Prague6,CzechRepublic viii List of Contributors MaciejJarosz,FacultyofChemistry,WarsawUniversityofTechnology,Noakowskiego 3,00-664Warsaw,Poland Milan Kodicek, Institute of Chemical Technology, Department of Biochemistry and Microbiology,Technicka´ 3,16628Prague6,CzechRepublic Stepanka Kuckova, Charles University, Department of Chemistry and Chemical Education, M.D. Rettigove´ 4, 11639 Prague 1, Czech Republic and Institute of Chemical Technology, Department of Biochemistry and Microbiology, Technicka´ 3, 16628Prague6,CzechRepublic Katarzyna Lech, Faculty of Chemistry, Warsaw University of Technology, Noakowskiego3,00-664Warsaw,Poland VincentMazel,LaboratoireMate´riauxetSante´,UFRdePharmacie,Universite´Paris-sud XI,92296ChatenayMalabryCedex,France FrancescaModugno,DepartmentofChemistryandIndustrialChemistry,Universityof Pisa,ViaRisorgimento35,56126Pisa,Italy Katarzyna Połec´-Pawlak, Faculty of Chemistry, Warsaw University of Technology, Noakowskiego3,00-664Warsaw,Poland Martine Regert, CEPAM (Centre d’Etudes Pre´histoire, Antiquite´, Moyen Aˆge), UMR 6130,Universite´NiceSophiaAntipolis–CNRS,Baˆt.1;250,rueAlbertEinstein,F-06560 Valbonne,France ErikaRibechini,DepartmentofChemistryandIndustrialChemistry,UniversityofPisa, ViaRisorgimento35,56126Pisa,Italy PascaleRichardin, C2RMF–CNRS UMR 171, Centre de Recherche et de Restauration desMuse´esdeFrance,PalaisduLouvre,PortedesLions,14,QuaiFranc¸oisMitterrand, 75001Paris,France Dominique Scalarone, Department of IPM Chemistry and Centre of Excellence NIS, UniversityofTorino,ViaGiuria7,10125Torino,Italy Alain Tchapla, Groupe de Chimie Analytique de Paris-Sud 11 (LETIAM) EA 4041, InstitutUniversitairedeTechnologied’Orsay,PlateaudeMoulon,91400Orsay,France
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