Opportunities for Fluoropolymers: Synthesis, Characterization, Processing, Simulation and Recycling (Progress in Fluorine Science) PDF
Preview Opportunities for Fluoropolymers: Synthesis, Characterization, Processing, Simulation and Recycling (Progress in Fluorine Science)
Progress in Fluorine Science Series OPPORTUNITIES FOR FLUOROPOLYMERS Synthesis, Characterization, Processing, Simulation and Recycling Edited by BRUNO AMEDURI Institut Charles Gerhardt; University Montpellier, CNRS, ENSCM, Montpellier, France SERGEY FOMIN Institute of Chemistry and Ecology, Vyatka State University, Kirov, Russian Federation Series Editors Bruno Ameduri and Olga Boltalina Elsevier Radarweg 29, PO Box 211, 1000 AE Amsterdam, Netherlands The Boulevard, Langford Lane, Kidlington, Oxford OX5 1GB, United Kingdom 50 Hampshire Street, 5th Floor, Cambridge, MA 02139, United States Copyright © 2020 Elsevier Inc. All rights reserved. No part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopying, recording, or any information storage and retrieval system, without permission in writing from the publisher. Details on how to seek permission, further infor- mation about the Publisher’s permissions policies and our arrangements with organizations such as the Copyright Clearance Center and the Copyright Licensing Agency, can be found at our website: www.elsevier.com/permissions. This book and the individual contributions contained in it are protected under copyright by the Pub- lisher (other than as may be noted herein). Notices Knowledge and best practice in this field are constantly changing. As new research and experience broaden our understanding, changes in research methods, professional practices, or medical treat- ment may become necessary. Practitioners and researchers must always rely on their own experience and knowledge in evaluating and using any information, methods, compounds, or experiments described herein. In using such information or methods they should be mindful of their own safety and the safety of others, includ- ing parties for whom they have a professional responsibility. To the fullest extent of the law, neither the Publisher nor the authors, contributors, or editors, as- sume any liability for any injury and/or damage to persons or property as a matter of products liabil- ity, negligence or otherwise, or from any use or operation of any methods, products, instructions, or ideas contained in the material herein. Library of Congress Cataloging-in-Publication Data A catalog record for this book is available from the Library of Congress British Library Cataloguing-in-Publication Data A catalogue record for this book is available from the British Library ISBN: 978-0-12-821966-9 For information on all Elsevier publications visit our website at https://www.elsevier.com/books-and-journals Publisher: Susan Dennis Acquisitions Editor: Emily M. McCloskey Editorial Project Manager: Lindsay Lawrence Production Project Manager: R.Vijay Bharath Designer: Mark Rodgers Typeset by Thomson Digital Contributors Gozde Aktas Eken Macromolecular Engineering Research Group (MERG), Chemistry Department, Istanbul Technical University, Istanbul, Turkey Alexandru D. Asandei Institute of Materials Science, Polymer Program and Department of Chemistry, University of Connecticut, CT, United States Sabine Beuermann Clausthal University of Technology, Institute of Technical Chemistry, Clausthal-Zellerfeld, Germany Roberta Bongiovanni Politecnico di Torino, Department of Applied Science and Technology, Torino, Italy Florian Brandl Clausthal University of Technology, Institute of Technical Chemistry, Clausthal-Zellerfeld, Germany Vyacheslav M. Buznik Russian Academy of Sciences, Federal State Unitary Enterprise All-Russian Scientific Research Institute of Aviation Materials State Research Center of the Russian Federation, Moscow, Russian Federation Marco Drache Clausthal University of Technology, Institute of Technical Chemistry, Clausthal-Zellerfeld, Germany Abhirup Dutta Institute of Materials Science, Polymer Program and Department of Chemistry, University of Connecticut, CT, United States Mariya Edeleva N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RAS, Novosibirsk, Russian Federation; National Research University – Novosibirsk State University, Novosibirsk, Russian Federation Behzad Farajidizaji Department of Chemistry and the Marvin B. Dow Advanced Composites Institute, Starkville, MS, United States Karen K. Gleason Department of Chemical Engineering, MIT, Cambridge, MA, United States Metin Hayri Acar Macromolecular Engineering Research Group (MERG), Chemistry Department, Istanbul Technical University, Istanbul, Turkey xi xii Contributors Ryo Honma Department of Chemistry, Faculty of Science, Kanagawa University, Hiratsuka, Japan Hisao Hori Department of Chemistry, Faculty of Science, Kanagawa University, Hiratsuka, Japan Polina Kaletina N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RAS, Novosibirsk, Russian Federation; National Research University – Novosibirsk State University, Novosibirsk, Russian Federation Sergey A. Khatipov Leading Researcher, Doctor of Physical and Mathematical Sciences, Federal State Budgetary Educational Institution of Higher Education “Vyatka State University”, Kirov, Russian Federation Joon-Sung Kim Institute of Materials Science, Polymer Program and Department of Chemistry, University of Connecticut,CT, United States Jena M. McCollum Department of Mechanical and Aerospace Engineering, University of Colorado Colorado Springs, CO, United States Ganesh Narayanan Department of Chemistry and the Marvin B. Dow Advanced Composites Institute, Starkville, MS, United States Emanuele Nettis Politecnico di Torino, Department of Applied Science and Technology, Torino, Italy Hideo Sawada Department of Frontier Materials Chemistry, Graduate School of Science and Technology, Hirosaki University, Hirosaki, Japan Jan Schwaderer Clausthal University of Technology, Institute of Technical Chemistry, Clausthal-Zellerfeld, Germany Sergey A. Serov Senior Researcher, Limited Liability Company “Research and production enterprise “Arflon”, Moscow, Russian Federation Irene Serrano Delgado Department of Mechanical and Aerospace Engineering, University of Colorado Colorado Springs, CO, United States Dennis W. Smith Department of Chemistry and the Marvin B. Dow Advanced Composites Institute, Starkville, MS, United States Contributors xiii Armand Soldera Laboratory of Physical-Chemistry of Matter, Department of chemistry, Faculty of science, Université de Sherbrooke, Sherbooke, QC, Canada Vignesh Vasu Institute of Materials Science, Polymer Program and Department of Chemistry, University of Connecticut, CT, United States Alessandra Vitale Politecnico di Torino, Department of Applied Science and Technology, Corso Duca degli Abruzzi, Torino, Italy About the editors Dr. Bruno Ameduri (DR CNRS Senior Researcher) leads the “Fluorine” Group at the “Engineering and Macromolecular Architectures” Team of Institute Charles Gerhardt in Montpellier, France. His main interests focus on the synthesis and the characterization of fluorinated monomers (including cure site monomers, telechelics, and polyfunctional ones), telomers, and copoly- mers for various applications such as F-surfactants, F-elastomers, F-coatings, and F-polymers related to energy (fuel cell membranes-protonic, alka- line and quasianhydrous ones-, polymer gel electrolytes and separators for Li-ions batteries, piezo-, ferro- or electroactive films), and nanocomposites. Coauthor of three books, ca. 50 reviews or book chapters, >370 peer review publications and coinventor of more than 80 patents, he is also a member of the American and French Chemical Societies and is a member of the Editorial Boards of the Journal of Fluorine Chemistry, European Polymer Journal, Polymer Bulletin. Outside of research, Bruno enjoys cycling, soccer, tennis, and jogging and is also an active member of the “Rire” Association and visits, dressed as a clown, sick children in hospitals of Montpellier. Sergey Fomin is the Director of the Institute of Chemistry and Ecology of Vyatka State University (Russian Federation, Kirov). His main research interests are in the field of adhesion of polymer materials, development of new ingredients for polymer compositions, modeling, and calculations of polymer products. The main research objects are elastomers of various purposes, including fluoro-rubber, but also a great deal of attention is paid to thermoplastic fluoropolymer materials. He led more than ten research and design projects for industry (including for improving the frost resis- tance of rubber, the development of production technology of self-healing pneumatic tires, the development of methods for assessing the content of polyaromatic hydrocarbons in rubber, the creation of a new production of polymer monofilament, the creation of a new production of polymer materials resistant to aggressive media, etc.). He has co-authored more than 30 articles in peer-reviewed publications, 4 patents in 2019. He was the co-organizer of the the First Internation Conference on Fluoropolymers in Russsia with Dr. Ameduri. He is also a member of the Nanotechnology Society of Russia. Personal interests include music, playing electric guitar, snowboarding, and running. xv Preface New technologies are changing our daily lives. New green energy, means of communication, computers, modern medicine and prosthetics, automo- tive, and aerospace industries—all have been invented and created by man to ensure that as our lives undergo changes, we experience better outcomes. But, new products for a better life require novel materials in addition to further needing new design and technology solutions. The importance of the fact that materials fundamentally change the life of mankind is reflected in the names of the eras. After all, anyone remembers that the Stone Age, Bronze Age, Iron Age and so on, have been distinguished periods in history. What age is it now? Without doubt, we are ready to answer that now there is an era of polymers. It is difficult to imagine a modern world with- out plastics, rubber, and composites. After all, these materials have been used to make almost everything surrounding us. Among many classes of macromolecules, fluoropolymers play a particular and essential role. Such a class of specialty polymers is endowed with remark- able properties, such as a wide temperature range of service, biological and chemical inertnesses, excellent mechanical and optical properties, good ionic or proton conductivity, piezoelectric characteristics, and shape memory ef- fect. All this leads to the fact that fluoropolymers are indeed indispensable in many high-tech areas. They are used to make parts for aerospace and auto- motive industries, as well as membranes for fuel cells. They are involved in gas separation, water filtration, actuators and sensor devices, components of lithium-ion batteries, coatings for optical fibers, surfaces of household appli- ances and cookware, as well as clothing and fabrics, building structures, and many more applications. Years have long passed when only polytetrafluoroethylene, PTFE, has encompassed fluoropolymers. Now, in these polymer material classes, tens of species and thousands of brands of materials with their own specificity have been available. But at the same time, they all have a common feature—the presence of fluorine atoms in the molecule. These atoms and their strong and short covalent bonds to carbon have supplied these materials with all their unique characteristics. Two books from the “Fluoropolymers” series are offered to you: BOOK 1: Opportunities of Fluoropolymers: Synthesis, Characteriza- tions, Processing, Simulation, and Recycling BOOK 2: Fascinating Fluoropolymers and their Applications xvii xviii Preface The first book is devoted to processes and key strategies to obtain and study various characteristics of fluoropolymers and simulation, as well as highlighting their processing and recycling. The chapters of this book deal with the synthesis and determination of properties of various classes of fluoropolymers, such as PTFE, fluori- nated aromatic perfluorocyclobutanes, polyvinylidene fluoride, and others, including composites. Tackling the kinetics of radical polymerization and controlling the molar masses and dispersities of synthesized polymers are also considered. A chapter reports the success of the use of fluoro-substituted compounds as initiators and controlling agents in various types of con- trolled radical polymerization (RDRP). In addition, other chapters inform about special polymerization processes such as a photoinitiated one and chemical vapor deposition polymerization in a vacuum chamber. Attention is paid to the modification of fluoropolymers (especially PTFE) by radiation whereas the use of fluoroalkanoyl peroxides to control the structure of ter- minal groups is also considered to induce lipophilic and superhydrophobic properties of fluoropolymers. The production and processes of fluoropoly- mers for membrane separation of water/oil suspensions and fluoropolymers with shape memory, as well as the modeling of the molecular structure of fluoropolymers (especially PVDF) for efficient production of their char- acteristics, are also discussed. One of the chapters is devoted to a detailed overview of technological approaches for processing fluoropolymers into specific items by various methods which are also industrially developped. The crucial issues of depolymerization and mineralization of different fluo- ropolymers as well as their recycling, which can be used to reduce negative impact on the environment, are also considered. The second book focuses on the most important and advanced appli- cations of these remarkable materials. Much attention is paid to the elec- troactive (relaxor, multiferroic ferro- and piezoelectric) characteristics of polymers, which allow them to be used as sensors and actuators. Several sections are also devoted to membrane applications, either for ionic and proton conductions for fuel cells or for purification or separation of various substances. Another section reviews the optical properties of fluoropoly- mers and methods to improve optical fibers and waveguides. In addition, a chapter deals with the medical use of fluoropolymers, particularly in artifi- cial blood circulation systems while two other ones report the development of new organic electronics using fluoropolymers and their redox properties. The use of fluoropolymer-based textiles in architecture is also discussed Preface xix whereas a chapter summarizes the production of frost-resistant rubber con- taining fine particles of PTFE. These two books were initiated from the First International Con- ference on Fluoropolymers in Kirov (Russia) in October 2019, entitled “Fluoropolymers: Research, Production Problems, New Applications” and we would like to thank all contributors who kindly extended their talks into such book chapters, as well as authors who could not attend that meeting but accepted to contribute in such books. We are confident that these two books, written by internationally rec- ognized scientists involved in cutting-edge research projects, will be highly informative for researchers, engineers, and practitioners from industry or academia working in materials science, chemistry, polymer physics, engi- neering and energy, developing or facing synthesis or applications of fluo- ropolymers in various aspects. They will also serve as excellent reference sources of information for graduate students and scientists at all levels. Bruno Ameduri Sergey Fomin
The list of books you might like
