Issues in Environmental Science and Technology Vol 32 Edited by R E Hester and R M Harrison Nuclear Power and the Environment 32 N u c l e a r P o w e r a n d t h e E n v i r o n m e n t H e s t e r & H a r r is o n Nuclear Power and the Environment ISSUES IN ENVIRONMENTAL SCIENCE AND TECHNOLOGY EDITORS: R.E.Hester,UniversityofYork,UK R.M.Harrison,UniversityofBirmingham,UK EDITORIALADVISORYBOARD: P.Crutzen,Max-Planck-Institutfu¨rChemie,Germany,S.J.deMora,PlymouthMarineLabora- tory,UK,G.Eduljee,SITA,UK,L.Heathwaite,LancasterUniversity,UK,S.Holgate,University ofSouthampton,UK,P.K.Hopke,ClarksonUniversity,USA,SirJohnHoughton,Meteorological Office, UK, P. Leinster, Environment Agency, UK, J. Lester, Imperial College of Science, TechnologyandMedicine,UK,P.S.Liss,SchoolofEnvironmentalSciences,UniversityofEast Anglia, UK, D. Mackay, Trent University, Canada, A. Proctor, Food Science Department, UniversityofArkansas,USA,D.Taylor,AstraZenecaplc,UK. TITLESINTHESERIES: 1:MininganditsEnvironmentalImpact 17:GlobalEnvironmentalChange 2:WasteIncinerationandtheEnvironment 18:EnvironmentalandHealthImpactofSolid 3:WasteTreatmentandDisposal WasteManagementActivities 4:VolatileOrganicCompoundsinthe 19:SustainabilityandEnvironmentalImpactof Atmosphere RenewableEnergySources 5:AgriculturalChemicalsandthe 20:TransportandtheEnvironment Environment 21:SustainabilityinAgriculture 6:ChlorinatedOrganicMicropollutants 22:ChemicalsintheEnvironment:Assessing 7:ContaminatedLandanditsReclamation andManagingRisk 8:AirQualityManagement 23:AlternativestoAnimalTesting 9:RiskAssessmentandRiskManagement 24:Nanotechnology 10:AirPollutionandHealth 25:BiodiversityUnderThreat 11:EnvironmentalImpactofPower 26:EnvironmentalForensics Generation 27:ElectronicWasteManagement 12:EndocrineDisruptingChemicals 28:AirQualityinUrbanEnvironments 13:ChemistryintheMarineEnvironment 29:CarbonCapture 14:CausesandEnvironmentalImplicationsof 30:EcosystemServices IncreasedUV-BRadiation 31:SustainableWater 15:FoodSafetyandFoodQuality 32:NuclearPowerandtheEnvironment 16:AssessmentandReclamationof ContaminatedLand Howtoobtainfuturetitlesonpublication Asubscriptionisavailableforthisseries.Thiswillbringdeliveryofeachnewvolumeimmediately onpublicationandalsoprovideyouwithonlineaccesstoeachtitleviatheInternet.Forfurther informationvisithttp://www.rsc.org/issuesorwritetotheaddressbelow. Forfurtherinformationpleasecontact: Sales and Customer Care, Royal Society of Chemistry, Thomas Graham House, Science Park, MiltonRoad,Cambridge,CB40WF,UK Telephone:+44(0)1223432360,Fax:+44(0)1223426017,Email:[email protected] ISSUES IN ENVIRONMENTAL SCIENCE AND TECHNOLOGY EDITORS:R.E.HESTERANDR.M.HARRISON 32 Nuclear Power and the Environment ISBN: 978-1-84973-194-2 ISSN: 1350-7583 AcataloguerecordforthisbookisavailablefromtheBritishLibrary rRoyalSocietyofChemistry2011 Allrightsreserved Apartfromfairdealingforthepurposesofresearchfornon-commercialpurposesorfor privatestudy,criticismorreview,aspermittedundertheCopyright,DesignsandPatents Act1988andtheCopyrightandRelatedRightsRegulations2003,thispublicationmaynot bereproduced,storedortransmitted,inanyformorbyanymeans,withouttheprior permissioninwritingofTheRoyalSocietyofChemistryorthecopyrightowner,orinthe caseofreproductioninaccordancewiththetermsoflicencesissuedbytheCopyright LicensingAgencyintheUK,orinaccordancewiththetermsofthelicencesissuedbythe appropriateReproductionRightsOrganizationoutsidetheUK.Enquiriesconcerning reproductionoutsidethetermsstatedhereshouldbesenttoTheRoyalSocietyof Chemistryattheaddressprintedonthispage. TheRSCisnotresponsibleforindividualopinionsexpressedinthiswork. PublishedbyTheRoyalSocietyofChemistry, ThomasGrahamHouse,SciencePark,MiltonRoad, CambridgeCB40WF,UK RegisteredCharityNumber207890 Forfurtherinformationseeourwebsiteatwww.rsc.org Preface It is often forgotten that the human species has evolved in an environment surroundedbynaturalsourcesofradioactivity.Thesesourcesareasdiverseas cosmic ray particles from space, potassium-40 in igneous rocks and the radioactive decay products of radon, a gas emanating from the land beneath our feet. Indeed, for many people, the so-called ‘‘radon daughters’’ pose the largest health risk incurred by breathing air indoors. However, in the public mind, artificial radioactivity is far more important, and since the cessation of atmospheric nuclear weapon testing this is primarily the radiation associated withthenuclearfuelcycle.Thishasalreadycausedmajorpollutionissuesand continues to have the potential to do so, unless handled with great compe- tence. The early years of nuclear power saw great enthusiasm for building nuclear power stations stimulated by lavish but unfulfilled promises of cheap electricity for all. This was followed by a period of disillusionment as the true costsofbuildingnuclearpowerstations,generatingthepowerandsubsequent decommissioning became fully recognised, and the majority of investment went into fossil fuel sources of power. However, recent years have seen an increasing acceptance by politicians and the general public of the inevitability of damaging levels of climate change unless greenhouse gas emissions are curbed, and one of the few effective ways of doing so is through the adoption of nuclear power as a primary means of energy generation. This volume is designed to provide an overview of some of the most important aspects of this field of science. In the first chapter, John Walls maps the technical and societal context in which nuclear power has existed since the first construction of experimental reactors. This serves to highlight many of the important issues which are taken up in later chapters, including issues such as the availability of uranium as a nuclear fuel, the consequences of fuel reprocessing, the economics of power generation and the costs of decommissioning. Other issues not explored elsewhere in depth within the volume, such as public attitudes to nuclear power, are also touched upon. The issue of nuclear fuel cycles and their by-products and consequences IssuesinEnvironmentalScienceandTechnology,32 NuclearPowerandtheEnvironment EditedbyR.E.HesterandR.M.Harrison rRoyalSocietyofChemistry2011 PublishedbytheRoyalSocietyofChemistry,www.rsc.org v vi Preface for the environment are expanded upon in the second chapter by Francis Livens, Clint Sharrad and Laurence Harwood. In particular, this chapter highlights the limitations posed by the availability of uranium as a fuel, and the advantages and disadvantages of fuel reprocessing. The latter was developed originally largely to generate plutonium for military purposes but has gained a rather poor reputation because of discharges to the environment, and most countries now plan to store rather than reprocess spent fuel. One of the major drivers of public opinion on nuclear power is the occurrenceofnuclearaccidents.Some,such as Windscale,ThreeMile Island and Chernobyl, are well known to all but others occurring in the former Soviet Union were kept secret from the general public, yet have generated contamination which persists to this day. In the third chapter, Jim Smith describes the causes and implications of these accidents and puts the topic into context. Both major and minor accidents and planned releases of radioactive materials have led to land contamination and have generated low-level wastes which need to be stored safely. In the fourth chapter, Jon Lloyd, Francis Livens and Rick Kimber outline the issues raised by such contamination and describe some of the consequences and the available remediation techniques. Perhaps the greatest Achilles’ heal of nuclear power generation isthefact thatdecommissioning of nuclear sites is required at the end of their active life, although interim ‘‘storage’’ may be used to allow cooling of the radioactivity by decay of the shorter-lived radionuclides. In Chapter 5, Anthony Banford and Richard Jarvis describe the legacy of contaminated nuclear sites and the approaches taken towards decontami- nation, and their positive and negative attributes. The sixth chapter, by Katherine Morris, Gareth Law and Nick Bryan, deals with the geological disposal of higher activity wastes. This is currently a topical issue for many countries who have declared policies of con- structing deep geological repositories for high and intermediate level waste with a view to safe storage on a timescale of at least a million years. The many considerations which go into the siting and design of such a reposi- tory are considered in this chapter. In the seventh chapter, by Joanna Renshaw, Stephanie Handley-Sidhu and Diana Brookshaw, the pathways of radioactive substances in the environment are described. This highlights how the chemistry of the actinides and fission products determines their behaviour in the environment which, in turn, influences their mobility and ultimate potential to cause exposure of humans and other biota. Chapter 8, by Brenda Howard and Nick Beresford, describes how radioactive sub- stances translocate into biological organisms and the resultant dosimetry, and in Chapter 9, Richard (Jan) Pentreath describes the human con- sequences of exposure to environmental radioactivity. For many years, radiological protection was based upon the concept that measures adequate to protect human health would also be protective of the non-human biota. This paradigm has now shifted to one in which assessments are made of the Preface vii dose to representative animals and plants and the likely consequences of those doses. Overall, the volume provides a selective but broad overview of current issues in this long-standing but increasingly topical field, which we believe will be of immediate and lasting value, not only to practitioners in gov- ernment, consultancy and industry but also to environmentalists, policy- makers and students taking courses in environmental science, engineering and management. After the receipt of chapters from authors but before proof correction, the Japanese tsunami caused damage to the Fukushima nuclear plant which went into partial meltdown. At the time of production of this volume this situation was continuing with very little definitive information available. Where possible, authors have included this in their chapters but it is clear that a more complete view of the incident will only emerge well after the production of this book. Ronald E. Hester Roy M. Harrison Contents Nuclear Power Generation – Past, Present and Future 1 John Walls 1 Introduction 2 2 Origins of Nuclear Power: The Nuclear Weapons Programme 2 3 Expansion of Nuclear Power 7 4 A Period of Decline 12 5 A Nuclear Renaissance? Possibilities and Challenges 15 5.1 Uranium: A Sustainable Energy Source? 20 5.2 Nuclear Power Economics 22 5.3 Shortages in Skilled Labour and Materials 25 5.4 Nuclear Safety 26 5.5 Nuclear Waste Disposal and Decommissioning Nuclear Plants 28 5.6 Proliferation Risks 31 6 Conclusions 33 References 34 Nuclear Fuel Cycles: Interfaces with the Environment 40 Clint A. Sharrad, Laurence M. Harwood and Francis R. Livens 1 Nuclear Fission as an Energy Resource 40 2 Nuclear Fuel 41 2.1 Uranium Mining 41 2.2 Uranium Fuel Production and Use 42 2.3 Modern Civil Reactor Fuels 43 2.3.1 Plutonium 43 2.4 Irradiation of Nuclear Fuel 44 IssuesinEnvironmentalScienceandTechnology,32 NuclearPowerandtheEnvironment EditedbyR.E.HesterandR.M.Harrison rRoyalSocietyofChemistry2011 PublishedbytheRoyalSocietyofChemistry,www.rsc.org ix