Nonequilibrium Phonon Dynamics NATO ASI Series Advanced Science Institutes Series A series presenting the results of activities sponsored by the NA TO Science Committee, which aims at the dissemination of advanced scientific and technological knowledge, with a view to strengthening links between scientific communities. The series is published by an international board of publishers in conjunction with the NATO Scientific Affairs Division A Life Sciences Plenum Publishing Corporation B Physics New York and London C Mathematical D. Reidel Publishing Company and Physical Sciences Dordrecht, Boston, and Lancaster o Behavioral and Social Sciences Martinus Nijhoff Publishers E Engineering and The Hague, Boston, and Lancaster Materials Sciences F Computer and Systems Sciences Springer-Verlag G Ecological Sciences Berlin, Heidelberg, New York, and Tokyo Recent Volumes in this Series Volume 118-Regular and Chaotic Motions in Dynamic Systems edited by G. Velo and A. S. Wightman Volume 119-Analytical Laser Spectroscopy edited by S. Martellucci and A. N. Chester Volume 120-Chaotic Behavior in Quantum Systems: Theory and Applications edited by Giulio Casati Volume 121-Electronic Structure, Dynamics, and Quantum Structural Properties of Condensed Matter edited by Jozef T. Devreese and Piet Van Camp Volume 122-Quarks, Leptons, and Beyond edited by H. Fritzsch, R. D. Peccei, H. Saller, and F. Wagner Volume 123-Density Functional Methods in Physics edited by Reiner M. Dreizler and Joao da Providencia Volume 124-Nonequilibrium Phonon Dynamics edited by Walter E. Bron Series B: Physics Nonequilibrium Phonon Dynamics Edited by Walter E. Bran Indiana University Bloomington, Indiana Plenum Press New York and London Published in cooperation with NATO Scientific Affairs Division Proceedings of a NATO Advanced Study Institute on Nonequilibrium Phonon Dynamics, held August 27-September 7, 1984, in Les Arcs, France Library of Congress Cataloging in Publication Data NATO Advanced Study Institute on Nonequilibrium Phonon Dynamics (1984: Les Arcs, France) Nonequilibrium phonon dynamics, (NATO ASI series. Series B, Physics; v. 124) "Proceedings of a NATO Advanced Study Institute on Nonequilibrium Phonon Dynamics, held August 27-September 7, 1984, in Les Arcs, France" - T.p. verso. "Published in cooperation with NATO Scientific Affairs Division." Bibliography: p. Includes index. 1. Phonons-Congresses. 2. Lattice dynamics-congresses. I. Bron, Walter E. II. North Atlantic Treaty Organization. Scientific Affairs Divi sion. III. Title. IV. Title: Phonon dynamics. V. Series. QC176.8.P5N38 1984 530.4'1 85-6449 ISBN-13: 978-1-4612-9513-6 e-ISBN-13: 978-1-4613-2501-7 001: 10.1007/978-1-4613-2501-7 © 1985 Plenum Press, New York Softcover reprint of the hardcover 1s t edition 1985 A Division of Plenum Publishing Corporation 233 Spring Street, New York, N.Y. 10013 All rights reserved No part of this book may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, microfilming, recording, or otherwise, without written permission from the Publisher PREFACE Phonons are always present in the solid state even at an absolute temperature of 0 K where zero point vibrations still abound. Moreover, phonons interact with all other excitations of the solid state and, thereby, influence most of its properties. Historically experimental information on phonon transport came from measurements of thermal conductivity. Over the past two decades much more, and much more detailed, information on phonon transport and on many of the inherent phonon interaction processes have come to light from experiments which use nonequilibrium phonons to study their dynamics. The resultant research field has most recently blossomed with the development of ever more sophisticated experimental and theoretical methods which can be applied to it. In fact, the field is moving so rapidly that new members of the research community have difficulties in keeping up to date. This NATO Advanced Study Institute (ASI) was organized with the objective of overcoming the information barrier between those expert in the field and those who are new to it. Thus it was decided to (i) organize a set of tutorially based lectures covering most of the important facets in the field, and (ii) to produce an Institute proceedings which would serve both as the first general textbook, as well as a valuable reference book, for this field of knowledge. The set of lectures and this text are organized into two main subjects. These are Nonequilibrium Phonon Dynamics in the Bulk, and Phonons and Phonon Dynamics at (and near) Solid Surfaces. This also represents, for the most part, the order in which the material was presented during the ASI. Each lecturer presented essentially all of his material during a single 3 1/4 hour period. Although such a lecture period is quite an imposition on the lecturer, it results in a more coherent form of presentation than when the material is presented over fragmented periods of time. After each three lecture periods, a full period of 3 1/4 hours was dedicated to a general and completely open discussion period. The discussion periods were under the leadership of a chairman and the three v PREFACE previous lecturers. These periods were designed to offer to the participants ample time to ask detailed questions on the previous lectures (in a format useful to all the participants) and to make comments and contributions of their own. All of the discussion periods took up all their allotted time and would have taken more if time had been available. It became obvious as the ASI progressed that although much new knowledge in the field of nonequilibrium phonon dynamics has come to light in the past decade, much remains to be done before the field can be considered to be fully mature. Perhaps the most obvious missing links are theoretical formulations which are readily reducible to comparison with experimental results. We expect progress in this area in the future. Some comments about the manuscripts. Modern word processors have become an obvious tool for speeding up the typing of camera-ready manuscripts. However, they lead to a wide spread of typing fonts and in the general appearance of manuscripts, as compared to the past when the IBM selectric typewriter, or its equivalent, were the norm. I have, however, decided to accept this spread in manuscript appearance so as not to undergo both the expense and the consequent delay in retyping a number of the manuscripts. Content is more important than form. I also regretfully take note that the manuscripts by Professor Bilz on the Dynamical Aspects of Nonlinear Oscillators and that by Professor Maneval on the Thermal Response of Thin Metal Films were not available at the time of publication. The ASI was held in the Hotel du Golf, Les Arcs (Savoy), France from August 27 through September 7, 1984 .. Situated some 1800 meters above sea level, and overlooking Mont Blanc and other exceptionally beautiful scenery, the Hotel and its surroundings became a welcomed relief from the ASI's full and, at times, hectic program. It goes almost without saying that an Institute of this scope and size can not occur without the financial and organizational help from a variety of sources. Most important, of course, was the funding and organizational advice from the Scientific Affairs Office of NATO. We are all grateful for their help. I would also wish to thank the Max Planck Institut fuer Festkoerperforschung, Stuttgart which helped to produce and mail the ASI's poster, and the Physics Department at Indiana University who provided the personnel for the second and subsequent mailings. The U.S. National Science Foundation provided travel funding for three young U.S. participants. The same is so for the science foundations and universities of the countries of many of the other lecturers and participants. We thank them all for their help and PREFACE trust that their aid to future ASIs will continue to assist scientific communication. I have also to thank many individuals whose aid helped to make the ASI the success it turned out to be. Among these persons, I would particularly like to acknowledge the help and advice of the members of the Organizing Committee; namely, Professors L. Challis and K. Renk, and of Professor J.-P. Maneval who undertook to be the local coordinator and who made the original contact with the hotel and, most importantly, battled with the vagaries of the international banking system to balance the hotel phase of the budget. Many thanks go to Kathryn Crouch, my excellent secretary at Indiana University. By far the greatest graditude goes to my wife, Ann, who took on the secretarial and treasurers job during our prolonged stay in Stuttgart during the summer of 1984, plus during and after the ASI. Her help and organizational skills have been acknowledged by lecturers and participants alike. Finally, my thanks go to Mrs. J. Challis and Mrs. A.-M. Maneval who helped my wife to staff the secretariat at Les Arcs, and to Mr. T. Gazaud and Mr. P. Fabing of the staff of the Hotel du Golf for making our stay there so pleasant. Walter E. Bron Institute Director and Professor of Physics Department of Physics Indiana University Bloomington, IN 47405 USA CONTENTS BULK NONEQUILIBRIUM PHONONS Studies of Nonequilibrium Dynamics in the time Domain . • . • . . • . . • 1 W.E. Bron Studies on Nonequilibrium Phonons by Optical Techniques. • • • • 59 K.F. Renk Generation, Propagation and Detection of Terahertz Phonons in Gallium Arsenide 101 R.G. Ulbrich Monochromatic Phonon Generation by Super conducting Tunnel Junctions • • • . 129 H. Kinder Phonon Imaging: Theory and Applications 165 G.A. Northrop and J.P. Wolfe An Introduction to Crossing Effects in Phonon Scattering •.•• 243 L.J. Challis Phonon Echoes, Polarization Echoes, and Acoustic Phase Conjugation in Solids. 277 K. Fossheim Introduction to Phonon Hydrodynamics. . . . • • • • • • • •• 313 R. Klein Electron-Phonon Interaction, Screening and Phonon-Generation • • . • • • • • . • 357 J.T. Devreese ix x CONTENTS SURFACE NONEQUILIBRIUM PHONONS Surface Acoustic Waves. 395 A.A. Maradudin Vibrational Energy Exchange Between Gases and Solids. . • • • • • • • . • . 601 G. Benedek The Gas/Phonon Interface: Desorption and Other Phenomena •.•••••. 623 D.L. Goodstein Photograph. 662 Index • . • 663
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