Nomenclature of Inorganic Chemistry II Recommendations 2000

146 Pages·2001·1.576 MB·English

by  Jon A McCleverty

NOMENCLATURE OF INORGANIC CHEMISTRY II
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International Union of Pure and Applied Chemistry
Nomenclature of
Inorganic Chemistry II
RECOMMENDATIONS 2000
Issued by the Commission on the
Nomenclature of Inorganic Chemistry
and edited by J.A. McCleverty and N.G. Connelly
ISBN 0–85404–487–6
A catalogue record for this book is available from the British Library.
© 2001 International Union of Pure and Applied Chemistry
All rights reserved.
Apart from any fair dealing for the purposes of research or private study, or criticism or
review as permitted under the terms of the UK Copyright, Designs and Patents Act, 1988,
this publication may not be reproduced, stored or transmitted, in any form or by any
means, without the prior permission in writing of the International Union of Pure and
Applied Chemistry, in the case of reprographic reproduction only in accordance with the
terms of the licences issued by the Copyright Licensing Agency in the UK, or in
accordance with the terms of the licences issued by the appropriate Reproduction Rights
Organisation outside the UK. Enquiries concerning reproduction outside the terms stated
here should be sent to the International Union of Pure and Applied Chemistry.
Published for the International Union of Pure and Applied Chemistry by the Royal
Society of Chemistry,
Thomas Graham House, Science Park, Milton Road, Cambridge CB4 0WF, UK
Registered Charity Number 207890
For further information see the RSC web site at www.rsc.org and the IUPAC site at
www.iupac.chemsoc.org
Typeset by RefineCatch Limited, Bungay, Suffolk
Printed by Bookcraft Ltd
Contents
Principal authors of this Edition vii
Preface viii
II-1 POLYANIONS 1
II-1.1 Introduction 1
II-1.2 Numbering of condensed polyanions 3
II-1.3 Polyanions with six central atoms 6
II-1.4 Polyanions with the Anderson structure 10
II-1.5 Polyanions with twelve central atoms 11
II-1.6 Polyanions with eighteen central atoms 20
II-1.7 Conclusion 22
II-2 ISOTOPICALLY MODIFIED INORGANIC
COMPOUNDS 23
II-2.1 Introduction 24
II-2.2 Classification and symbolism 24
II-2.3 Isotopically substituted compounds 26
II-2.4 Isotopically labelled compounds 27
II-2.5 Locants and numbering of isotopically modified compounds 34
II-2.6 Summary of types of isotopically modified compounds 35
II-3 METAL COMPLEXES OF TETRAPYRROLES 36
II-3.1 Introduction 36
II-3.2 The construction of systematic names 37
II-3.3 Trivial names 42
II-3.4 Less common structural types 43
II-3.5 Trivial names of porphyrins, chlorins, chlorophylls, bilanes, fundamental rings
and related species 46
v
CONTENTS
II-4 HYDRIDES OF NITROGEN AND DERIVED CATIONS,
ANIONS AND LIGANDS 54
II-4.1 Introduction 54
II-4.2 Parent hydrides 54
II-4.3 Cations 55
II-4.4 Anions 56
II-4.5 Ligands 56
II-4.6 Organic derivatives of the nitrogen hydride ligands 61
II-5 INORGANIC CHAIN AND RING COMPOUNDS 62
II-5.1 Introduction 63
II-5.2 Unbranched chain and monocyclic compounds 63
II-5.3 Branched chain and polycyclic compounds 75
II-5.4 Conclusion 94
II-6 GRAPHITE INTERCALATION COMPOUNDS 95
II-6.1 General considerations 95
II-6.2 Vocabulary 96
II-6.3 Classification of graphite intercalation compounds 98
II-6.4 Non-formula-based description of graphite intercalation compounds 99
II-6.5 Formulation of graphite intercalation compounds 100
II-6.6 Structural notation 101
II-7 REGULAR SINGLE-STRAND AND QUASI SINGLE-
STRAND INORGANIC AND COORDINATION
POLYMERS 104
II-7.1 Introduction 105
II-7.2 Fundamental principles 106
II-7.3 Recommendations 110
INDEX 126
vi
Principal Authors of this Edition
Chapter II-1
Y. Jeannin, M. Fournier, France
Chapter II-2
W.C. Fernelius, USA
T.D. Coyle, USA
W.H. Powell, USA
P. Fodor-Csányi, Hungary
Chapter II-3
R.S. Laitinen, Finland
J.E. Merritt, USA
K.L. Loening, USA
Chapter II-4
J. Chatt, UK
R.S. Laitinen, Finland
Chapter II-5
R.S. Laitinen, Finland
E. Fluck, Germany
Chapter II-6
H.P. Boehm, Germany
R. Setton, France
E. Stumpp, Germany
Chapter II-7
L.G. Donaruma, USA
B.P. Block, USA
K.L. Loening, USA
N. Platé, Russia
T. Tsuruta, Japan
K.Ch. Buschbeck, Germany
W.H. Powell, USA
J. Reedijk, Netherlands
Preface
This book is intended to be an adjunct to the first volume which appeared in 1990 and which
contains aims, grammar, basic tenets and main classes of nomenclature. For these basic
aspects the reader is referred to the primary volume. The current volume is intended to deal
with the nomenclature of systems which have specific difficulties with condensed phases such
as solids or polymers and where various local nomenclatures have grown up to confuse the
practitioners or those entering the fields of research. It addresses such diverse chemistry as
polyanions, isotopic modification, tetrapyrroles, nitrogen hydrides, inorganic ring, chain,
polymer, and graphite intercalation compounds. It is aimed at bringing order into the nomen-
clature of these specialized systems based on the more fundamental nomenclature described
in the primary volume and in the organic nomenclature publications. The volume is timely in
relation to the growth of inorganic polymers especially and it is hoped that the practitioners
will accept the orderly recommendations proposed and use it to simplify the literature espe-
cially for the students who now begin to study such systems.
The various chapters have been subject to extensive review not only by Commission
members but also by practising chemists in the various areas over several years. The evolved
chapters should therefore represent a consensus view of appropriate nomenclature for now
and some years to come. The Commission is grateful to the external reviewers for their careful
and critical comments and support to bring order into the nomenclature of such complex
systems. Also, since the topics are largely unrelated and each has an Introduction or Pre-
amble, no overall introduction is required and the reader is referred to the first volume for
such general comments on nomenclature.
1st July, 2000 A S
H D. K
Chairmen, IUPAC Commission of the Nomenclature of Inorganic Chemistry