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NMR Crystallography PDF

472 Pages·2009·11.769 MB·English
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EMR Handbooks Based on the Encyclopedia of Magnetic Resonance (EMR), this monograph series focuses on hot topics and major developments in modern magnetic resonance and its many applications. Each volume in the series will have a specific focusineithergeneralNMRorMRI,withcoverageofapplicationsinthekeyscientificdisciplinesofphysics,chemistry, biologyormedicine.Allthematerialpublishedinthisseries,plusadditionalcontent,willbeavailableintheonlineversion ofEMR,althoughinaslightlydifferentformat. Previous EMR Handbooks NMRCrystallography EditedbyRobinK.Harris,RoderickE.Wasylishen,MelindaJ.Duer ISBN978-0-470-69961-4 MultidimensionalNMRMethodsfortheSolutionState EditedbyGarethA.Morris,JamesW.Emsley ISBN978-0-470-77075-7 Solid-StateNMRStudiesofBiopolymers EditedbyAnnE.McDermott,TatyanaPolenova ISBN978-0-470-72122-3 NMRofQuadrupolarNucleiinSolidMaterials EditedbyRoderickE.Wasylishen,SharonE.Ashbrook,StephenWimperis ISBN978-0-470-97398-1 Forthcoming EMR Handbooks MRIofTissueswithShortT andT ∗ 2 2 EditedbyIanR.Young,GaryFullertonandGraemeM.Bydder ISBN978-0-470-68835-9 Encyclopedia of Magnetic Resonance EditedbyRobinK.Harris,RoderickE.Wasylishen,EdwinD.Becker,JohnR.Griffiths,VivianS.Lee,IanR.Young,Ann E.McDermott,TatyanaPolenova,JamesW.Emsley,GeorgeA.Gray,GarethA.Morris,MelindaJ.DuerandBernardC. Gerstein. The Encyclopedia of Magnetic Resonance (EMR) is based on the original printed Encyclopedia of Nuclear Magnetic Resonance, which was first published in 1996 with an update volume added in 2000. EMR was launched online in 2007 withallthematerialthathadpreviouslyappearedinprint.Newupdateshavesincebeenandwillbeaddedonaregularbasis throughouttheyeartokeepthecontentuptodatewithcurrentdevelopments.Nuclearwasdroppedfromthetitletoreflect theincreasingprominenceofMRIandothermedicalapplications.Thisallowstheeditorstoexpandbeyondthetraditional bordersofNMRtoMRIandMRS,aswellastoEPRandothermodalities.EMRcoversallaspectsofmagneticresonance, witharticlesonthefundamentalprinciples,thetechniquesandtheirapplicationsinallareasofphysics,chemistry,biology andmedicineforbothgeneralNMRandMRI.Additionally,articlesonthehistoryofthesubjectareincluded. Formoreinformationsee:www.wileyonlinelibrary.com/ref/emr RF Coils for MRI Editors J. Thomas Vaughan University of Minnesota, Minneapolis, Minnesota, USA John R. Griffiths Cancer Research UK, Cambridge Research Institute, Cambridge, UK A John Wiley and Sons, Ltd., Publication Thiseditionfirstpublished2012 ©2012JohnWiley&SonsLtd Registeredoffice JohnWiley&SonsLtd,TheAtrium,SouthernGate,Chichester,WestSussex, PO198SQ,UnitedKingdom Fordetailsofourglobaleditorialoffices,forcustomerservicesandforinformationabout howtoapplyforpermissiontoreusethecopyrightmaterialinthisbookpleaseseeour websiteatwww.wiley.com. Therightoftheauthorstobeidentifiedastheauthorsofthisworkhasbeenassertedin accordancewiththeCopyright,DesignsandPatentsAct1988. Allrightsreserved.Nopartofthispublicationmaybereproduced,storedina retrievalsystem,ortransmitted,inanyformorbyanymeans,electronic,mechanical, photocopying,recordingorotherwise,exceptaspermittedbytheUKCopyright,Designs andPatentsAct1988,withoutthepriorpermissionofthepublisher. Wileyalsopublishesitsbooksinavarietyofelectronicformats.Somecontentthat appearsinprintmaynotbeavailableinelectronicbooks. Designationsusedbycompaniestodistinguishtheirproductsareoftenclaimedas trademarks.Allbrandnamesandproductnamesusedinthisbookaretradenames, servicemarks,trademarksorregisteredtrademarksoftheirrespectiveowners.The publisherisnotassociatedwithanyproductorvendormentionedinthisbook.This publicationisdesignedtoprovideaccurateandauthoritativeinformationinregardtothe subjectmattercovered.Itissoldontheunderstandingthatthepublisherisnotengaged inrenderingprofessionalservices.Ifprofessionaladviceorotherexpertassistanceis required,theservicesofacompetentprofessionalshouldbesought. Frontcoverimagecredit: CoverimageswerekindlysuppliedbyBrandonTrammandJinfengTian. LibraryofCongressCataloging-in-PublicationData RFcoilsforMRI/editors,J.ThomasVaughan,JohnR.Griffiths. p.;cm. Includesbibliographicalreferencesandindex. ISBN978-0-470-77076-4(cloth) I.Vaughan,J.Thomas(JohnThomas),1957-II.Griffiths,JohnR.,1945- III.Encyclopediaofmagneticresonance. [DNLM:1. MagneticResonanceImaging–methods.2. ElectromagneticFields. 3. MagneticResonanceSpectroscopy–instrumentation.4. RadioWaves. 5. Transducers. WN185] 616.07’548–dc23 2012015267 AcataloguerecordforthisbookisavailablefromtheBritishLibrary. ISBN-13:978-0-470-77076-4 Setin9.5/11.5ptTimesbyLaserwords(Private)Limited,Chennai,India PrintedandboundinSingaporebyMarkonoPrintMediaPteLtd Encyclopedia of Magnetic Resonance Editorial Board Editors-in-Chief RobinK.Harris RoderickE.Wasylishen UniversityofDurham UniversityofAlberta Durham Edmonton,Alberta UK Canada Section Editors SOLID-STATE NMR & PHYSICS MelindaJ.Duer BernardC.Gerstein UniversityofCambridge Ames,IA Cambridge USA UK SOLUTION-STATE NMR & CHEMISTRY JamesW.Emsley GeorgeA.Gray GarethA.Morris UniversityofSouthampton VarianInc. UniversityofManchester Southampton PaloAlto,CA Manchester UK USA UK BIOCHEMICAL NMR AnnE.McDermott TatyanaPolenova ColumbiaUniversity UniversityofDelaware NewYork,NY Newark,DE USA USA MRI & MRS JohnR.Griffiths IanR.Young CancerResearchUK ImperialCollege CambridgeResearch London Institute UK Cambridge UK HISTORICAL PERSPECTIVES EdwinD.Becker NationalInstitutesofHealth Bethesda,MD USA vi Encyclopedia of Magnetic Resonance International Advisory Board David M. Grant(Chairman) University of Utah Salt Lake City, UT USA Isao Ando Adriaan Bax Chris Boesch Tokyo Institute National Institutes of Health University of Bern of Technology Bethesda, MD Bern Tokyo USA Switzerland Japan Paul A. Bottomley William G. Bradley Graeme M. Bydder Johns Hopkins University UCSD Medical Center UCSD Medical Center Baltimore, MD San Diego, CA San Diego, CA USA USA USA Paul T. Callaghan Richard R. Ernst Ray Freeman (deceased) Eidgeno¨ssische Technische University of Cambridge Victoria University Hochschule (ETH) Cambridge of Wellington Zu¨rich UK Wellington Switzerland New Zealand Lucio Frydman Maurice Goldman Harald Gu¨nther Weizmann Institute Villebon sur Yvette Universita¨t Siegen of Science France Siegen Rehovot Germany Israel Herbert Y. Kressel C. Leon Partain Alexander Pines Harvard Medical School Vanderbilt University Medical University of California Boston, MA Center at Berkeley USA Nashville, TN Berkeley, CA USA USA George K. Radda Hans Wolfgang Spiess Charles P. Slichter University of Oxford Max-Planck Institute University of Illinois Oxford of Polymer Research at Urbana-Champaign UK Mainz Urbana, IL Germany USA John S. Waugh Bernd Wrackmeyer Kurt Wu¨thrich Massachusetts Institute Universita¨t Bayreuth The Scripps Research of Technology (MIT) Bayreuth Institute Cambridge, MA Germany La Jolla, CA USA USA and ETH Zu¨rich Zu¨rich Switzerland Contents Contributors ix Series Preface xiii Volume Preface xv PartA:SurfaceCoils 1 1 AnHistoricalIntroductiontoSurfaceCoils:TheEarlyDays JosephJ.H.Ackerman 3 2 RadiofrequencyCoilsforNMR:APeripateticHistoryofTheirTwistsandTurns EiichiFukushima 9 3 QuadratureSurfaceCoils ChristopherM.Collins,AndrewG.Webb 17 4 Double-TunedSurfaceCoils BarbaraL.Beck 27 5 NestedSurfaceCoilsforMultinuclearNMR ArthurW.Magill,RolfGruetter 39 6 QuadratureTransverseElectromagnetic(TEM)SurfaceCoils NikolaiI.Avdievich 51 PartB:LoopArrays 63 7 ReceiverLoopArrays StevenM.Wright 65 8 CoilArrayDesignforParallelImaging:TheoryandApplications DanielK.Sodickson,MichaelA.Ohliger,RiccardoLattanzi,GrahamC.Wiggins 81 9 TransceiverLoopArrays RandyDuensing 101 10 CharacterizationofMultichannelCoilArraysontheBenchtop MarkA.Griswold 111 PartC:VolumeCoils 121 11 BirdcageVolumeCoilDesign NicolaDeZanche 123 12 Double-TunedBirdcageCoils:ConstructionandTuning JosephMurphy-Boesch 137 13 TEMBodyCoils J.ThomasVaughan 147 viii Contents 14 TEMArrays,DesignandImplementation CarlSnyder 169 15 TEMTransceiverHeadArrayCoilsforUltraHighMagneticFields GregorAdriany 175 16 TransverseElectromagnetic(TEM)CoilsforExtremities NikolaiI.Avdievich 185 17 AntennasasSurfaceArrayElementsforBodyImagingatUltra-highFieldStrengths A.J.E.Raaijmakers,C.A.T.vandenBerg 197 PartD:SpecialPurposeCoils 209 18 CatheterCoils ErginAtalar 211 19 Microcoils AndrewG.Webb 225 20 CryogenicandSuperconductingCoilsforMRI SvenJunge 233 21 LitzCoilsforHighResolutionandAnimalProbes,EspeciallyforDoubleResonance F.DavidDoty,GeorgeEntzmingerJr 245 22 MillipedeCoils ErnestW.H.Wong 259 PartE:CoilInterfaceCircuits 269 23 ReceiverDesignforMR DavidI.Hoult 271 24 RadiofrequencyPowerAmplifiersforNMRandMRI DanielP.Myer 299 25 ImpedanceMatchingandBaluns DavidM.Peterson 315 PartF:CoilModelingandEvaluation 325 26 RadiofrequencyMRICoilAnalysis:AStandardProcedure RostislavA.Lemdiasov,ReinholdLudwig 327 27 PracticalElectromagneticModelingMethods Jian-MingJin 339 28 RadiofrequencyFieldsandSARforBirdCages TamerS.Ibrahim 363 29 RFFieldModelingforDouble-TunedVolumeCoils WanzhanLiu 377 30 RadiofrequencyFieldsandSARforTransverseElectromagnetic(TEM)SurfaceCoils CanEyupAkgun 387 31 TEMCoilFieldsandSAR JinfengTian 397 PartG:RFSafety 407 32 RFDeviceSafetyandCompatibility JohnNyenhuis 409 33 RadiofrequencyHeatingModelsandMeasurements DevashishShrivastava,J.ThomasVaughan 425 Index 437 Contributors Joseph J. H. Ackerman Department of Chemistry, Campus Box 1134, Washington University, SaintLouis,MO63130,USA Chapter 1: An Historical Introduction to Surface Coils: The Early Days Gregor Adriany Department of Radiology, Center for Magnetic Resonance Research, UniversityofMinnesota,Minneapolis,MN55455,USA Chapter 15: TEM Transceiver Head Array Coils for Ultra High Magnetic Fields Can Eyup Akgun Center for Magnetic Resonance Research, University of Minnesota, Minneapolis,MN55455,USA Chapter 30: Radiofrequency Fields and SAR for Transverse Electromagnetic (TEM) Surface Coils Ergin Atalar Electrical & Electronics Engineering Department, Bilkent University, Ankara,TR-06800,Turkey Chapter 18: Catheter Coils Nikolai I. Avdievich Department of Neurosurgery, Yale University, New Haven, CT 06520, USA Chapter 6: Quadrature Transverse Electromagnetic (TEM) Surface Coils Chapter 16: Transverse Electromagnetic (TEM) Coils for Extremities Barbara L. Beck McKnight Brain Institute, University of Florida, Gainesville, FL 32610, USA Chapter 4: Double-Tuned Surface Coils C. A. T. van den Berg DepartmentofRadiotherapy,UniversityMedicalCenterUtrecht,Utrecht 3508GA,TheNetherlands Chapter 17: Antennas as Surface Array Elements for Body Imaging at Ultra-high Field Strengths Christopher M. Collins DepartmentofRadiology,ThePennsylvaniaStateUniversity,Collegeof Medicine,Hershey,PA17033,USA Chapter 3: Quadrature Surface Coils F. David Doty DotyScientificInc.,Columbia,SC29229,USA Chapter 21: Litz Coils for High Resolution and Animal Probes, Especially for Double Resonance x Contributors Randy Duensing InvivoCorporation,Gainesville,FL32608,USA Chapter 9: Transceiver Loop Arrays George Entzminger Jr DotyScientificInc.,Columbia,SC29229,USA Chapter 21: Litz Coils for High Resolution and Animal Probes, Especially for Double Resonance Eiichi Fukushima ABQMR,Albuquerque,NM87106,USA Chapter 2: Radiofrequency Coils for NMR: A Peripatetic History of Their Twists and Turns Mark A. Griswold Department of Radiology, Case Western Reserve University, Cleveland, OH44106,USA Chapter 10: Characterization of Multichannel Coil Arrays on the Benchtop Rolf Gruetter Laboratory of Functional and Metabolic Imaging, Ecole Polytechnique FederaledeLausanne,CH-1015Lausanne,Switzerland Department of Radiology, University of Lausanne, CH-1015 Lausanne, Switzerland Department of Radiology, University of Geneva, CH-1211 Geneva, Switzerland Chapter 5: Nested Surface Coils for Multinuclear NMR David I. Hoult Institute for Biodiagnostics, National Research Council Canada, Winnipeg,Manitoba,MBR3B1Y6,Canada Chapter 23: Receiver Design for MR Tamer S. Ibrahim Departments of Bioengineering and Radiology, University of Pittsburgh, Pittsburgh,PA15213,USA Chapter 28: Radiofrequency Fields and SAR for Bird Cages Jian-Ming Jin DepartmentofElectricalandComputerEngineering,Universityof Illinois,1406WestGreenStreet,Urbana,IL61801,USA Chapter 27: Practical Electromagnetic Modeling Methods Sven Junge BrukerBiospinMRIGmbH,Ettlingen76275,Germany Chapter 20: Cryogenic and Superconducting Coils for MRI Riccardo Lattanzi NewYorkUniversitySchoolofMedicine,NewYork,NY10016,USA Chapter 8: Coil Array Design for Parallel Imaging: Theory and Applications Rostislav A. Lemdiasov InsightNeuroimagingSystems,11CanterburySt.,Worcester,MA01610, USA Chapter 26: Radiofrequency MRI Coil Analysis: A Standard Procedure Wanzhan Liu MedtronicInc.,Minneapolis,MN55126,USA Chapter 29: RF Field Modeling for Double-Tuned Volume Coils

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