Nitrification and Denitrification in the Activated Sludge Process Michael H. Gerardi A John Wiley & Sons, Inc., Publication Nitrification and Denitrification in the Activated Sludge Process Nitrification and Denitrification in the Activated Sludge Process Michael H. Gerardi A John Wiley & Sons, Inc., Publication Thisbookisprintedonacid-freepaper.zy Copyright(2002byJohnWileyandSons,Inc.,NewYork.Allrightsreserved. PublishedsimultaneouslyinCanada. Nopartofthispublicationmaybereproduced,storedinaretrievalsystemor transmittedinanyformorbyanymeans,electronic,mechanical,photocopying, recording,scanningorotherwise,exceptaspermittedunderSections107or108of the1976UnitedStatesCopyrightAct,withouteitherthepriorwrittenpermissionof thePublisher,orauthorizationthroughpaymentoftheappropriateper-copyfeeto theCopyrightClearanceCenter,222RosewoodDrive,Danvers,MA01923, (978)750-8400,fax(978)750-4744.RequeststothePublisherforpermissionshould beaddressedtothePermissionsDepartment,JohnWiley&Sons,Inc.,605Third Avenue,NewYork,NY10158-0012,(212)850-6011,fax(212)850-6008,E-Mail: [email protected]. Fororderingandcustomerservice,call1-800-CALL-WILEY. LibraryofCongressCataloging-in-PublicationData: Gerardi,MichaelH. Wastewatermicrobiology:nitrification/denitrificationintheactivatedsludge process/MichaelH.Gerardi. p. cm. Includesbibliographicalreferences. ISBN0-471-06508-0(cloth:alk.paper) 1.Sewage—Purification—Nitrogenremoval. 2. Nitrification. 3. Sewage— Purification—Activatedsludgeprocess. I. Title. TD758.3.N58G472002 2001046765 PrintedintheUnitedStatesofAmerica. 10 9 8 7 6 5 4 3 2 1 To L. Vernon Frye and the men and women of the Williamsport Sanitary Authority and Williamsport Municipal Water Authority The author extends his sincere appreciation to joVanna Gerardi for computer support and Cristopher Noviello for artwork used in this text. Contents Preface xi PART I OVERVIEW 1 1 Nitrogen: Environmental and Wastewater Concerns 3 2 The Oxidation States of Nitrogen 11 3 Nitrogenous Compounds 17 4 Bacteria 21 5 The Activated Sludge Process 31 PART II NITRIFICATION 35 6 Introduction to Nitrification 37 7 Nitrifying Bacteria 43 8 Organotrophs 55 9 The Wastewater Nitrogen Cycle 63 vii
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