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NASA Technical Reports Server (NTRS) 20160010278: Fused Silica and Other Transparent Window Materials PDF

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National Aeronautics and Space Administration Fused Silica and Other Transparent Window Materials Jon Salem NASA Glenn Research Center Cleveland, Ohio ICACC, Daytona Beach, January 27th, 2016 Advanced Ceramics Laboratory Life Prediction Branch 1 www.nasa.gov National Aeronautics and Space Administration Outline  Window Applications and Requirements  Historical Material  New Materials and Mechanical Properties  ISS Windows and Damage  Anomalous Behavior of Silica  Comparison to Published Literature  Conclusions Advanced Ceramics Laboratory www.nasa.gov 2 National Aeronautics and Space Administration Some NASA Window Applications www.nasa.gov 3 National Aeronautics and Space Administration Fused Silica – Workhorse Material • Fused silica has been the historical material of choice: – Apollo – SkyLab (73-74) , Mir… – ISS (98-xxxx) – Shuttle – Orion • Only one unexpected failure during an Apollo window proof test. www.nasa.gov 4 National Aeronautics and Space Administration Window Requirements • Thermal shock • Mechanical (crack growth) • Optical (haze, transmittance…..imagery, piloting) • Chemical (atomic oxygen, radiation..) • Impact residual strength (handling, hyper) • Big advantages are optical and thermal. • But why windows at all?! Psychological. www.nasa.gov 5 National Aeronautics and Space Administration Windows in Use - ISS Most famous are the Cupola windows, which are shuttered:  More typical widow (10”):  HITF White Sands STS-84 Atlantis 1 mm Some windows are not shuttered and can be damaged by MMOD….  www.nasa.gov 6 National Aeronautics and Space Administration New, Impact Resistant Materials • A variety of “new” materials have been developed or re-developed: - AlON 19” - Spinel - MgO, Alumina, glass-ceramics 24” • One driving force has been military armor: Fused Silica - 35 lbs/ft2 ALON - 17 lbs/ft2 Comparable Performance • Might these materials work for spacecraft windows? www.nasa.gov 7 National Aeronautics and Space Administration Property Comparison   1 v  • Thermals shock related: R''  c EC p Material Young's Fracture CTE x Thermal Heat R R’’ Modulus Strength 10-6/oC Conductivity Capacity (K) (Wcm2 GPa (MPa)  (W/mK) λ (J/gK) /gK) Silica 72 80 0.5 14 0.77 1733 143 Spinel 270 80 6 15 0.88 73 3.5 (coarse grain) Spinel 270 160 6 15 0.88 73 3.5 (fine grain) AlON 314 210 5 13 0.92 99 3.8 • Positive: similar thermal conductivity. • Negative: new materials have higher CTE.  Poor thermal shock. www.nasa.gov 8 National Aeronautics and Space Administration Mechanical Property Comparison • Crack growth related: Material Density Young's Fracture Crack Fracture (g/cc) Modulus Toughness Growth Strength (GPa) (MPam) Exponent, n MPa Silica 2.2 72 0.75 24 80 Spinel 3.6 270 1.5 22 80 (coarse grain) Spinel 3.6 270 2.0 50 160 (fine grain) AlON 3.7 314 2.2 35 - 50 210 • Positive: New materials are tougher and SCG resistant. • Negative: New materials are denser and stiffer. www.nasa.gov 9 National Aeronautics and Space Administration Slow Crack Growth Curve • The SCG curve captures much of the mechanicals: Material Density (g/cc) Silica 2.2 Spinel 3.6 Spinel 3.6 AlON 3.7 • Does not account for weight……. www.nasa.gov 10

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