ink that contains the ingredients de- power density of 43 percent. At an ap- In accordance with Public Law 96-517, scribed for step 2, plus 0.035 g of plied current density of 100 mA/cm2, the contractor has elected to retain title to this poly(tetrafluoroethylene) particles. the cell voltage for the SOA cell and im- invention. Inquiries concerning rights for its 5. The membrane coated with catalyst proved cell are 0.43 and 0.49, respec- commercial use should be addressed to: layer is bonded to the gas-diffusion/ tively. The increase in cell voltage be- Innovative Technology Assets Management current-collecting carbon paper by tween the SOA and improved cell JPL use of heat and pressure. resulted in an increase in cell efficiency Mail Stop 202-233 The performance of membrane elec- of 8 percent when the effects of crossover 4800 Oak Grove Drive trode assemblies prepared by the new are included. Pasadena, CA 91109-8099 process is compared with those prepared This work was done by Thomas Valdez and (818) 354-2240 by the state-of-art (SOA) process in Fig- Sekharipuram Narayanan of Caltech for E-mail: [email protected] ure 2. The current density at 0.49 V has NASA’s Jet Propulsion Laboratory. Fur- Refer to NPO-30829, volume and number been raised from 70 mA/cm2 to 100 ther information is contained in a TSP (see of this NASA Tech Briefs issue, and the mA/cm2. This results in an increase in page 1). page number. X-Band, 17-Watt Solid-State Power Amplifier This is a smaller, lighter, less expensive alternative to prior X-band amplifiers. NASA’s Jet Propulsion Laboratory, Pasadena, California An advanced solid-state power ampli- wave-tube X-band amplifiers and to gain of the VGA is voltage-variable over a fier that can generate an output power prior solid-state X-band power ampli- range of 10 to 24 dB. To provide for tem- of as much as 17 W at a design operating fiers of equivalent output power. This perature compensation of the overall frequency of 8.4 GHz has been designed amplifier comprises a monolithic mi- amplifier gain, the gain-control voltage and constructed as a smaller, lighter, crowave integrated circuit (MMIC) am- is generated by an operational-amplifier less expensive alternative to traveling- plifier module and a power-converter circuit that includes a resistor/thermis- module integrated into a compact pack- tor temperature-sensing network. The age (see Figure 1). driver amplifier provides a gain of 14 dB The amplifier module contains an to an output power of 27 dBm to drive input variable-gain amplifier (VGA), an the four parallel output PHEMTs, each intermediate driver stage, a final power of which is nominally capable of putting stage, and input and output power mon- out as much as 5 W. The driver output is itors (see Figure 2). The VGA and the sent to the input terminals of the four driver amplifier are 0.5-µm GaAs-based parallel PHEMTs through microstrip metal semiconductor field-effect transis- power dividers; the outputs of these tors (MESFETs). The final power stage PHEMTs are combined by microstrip Figure 1. The Complete Amplifier Package has dimensions of 6.75 by 5.25 by 1.75 in. (about contains four parallel high-efficiency, power combiners (which are similar to 17.1 by 13.3 by 4.4 cm). GaAs-based pseudomorphic high-elec- the microstrip power dividers) to obtain tron-mobility transistors (PHEMTs). The the final output power of 17 W. Final Power Stage PD PC 8.4 GHz at 17 Watts VGA Driver Radio-Frequency Input: 1 dBm at 8.4 GHz PD PC Temperature Input-Power Compensator Monitor PD PC Output-Power Monitor Secondary Voltages PD: Microstrip Power Divider PC: Microstrip Power Combiner Temperature Monitor 28 VDC Input Power Converter Figure 2. This Block Diagramshows only major functional blocks of the amplifier and power-converter modules. 12 NASA Tech Briefs, January 2005 The power-converter module contains sation is provided by an error amplifier and stacked in a manner that provides a high-efficiency (nominally 90-percent and associated resistors and capacitors the best thermally conductive path for efficient) DC-to-DC power converter plus within the pulse-width modulator. To dissipating heat generated in the final analog signal-conditioning circuitry for maximize efficiency, the output voltages power stage. The amplifier can operate use in remote monitoring (e.g., teleme- are obtained via synchronous rectifiers over a temperature range from –40 to try) of temperature, and of radio-fre- connected to the secondary winding of +70 °C, from sea-level to Mars’ atmos- quency input and output power levels. the transformer. The ripple in the outputs phere and even to a vacuum. The power converter contains a trans- of the rectifiers is attenuated by use of in- This work was done by Anthony Mittskus former in a push-pull, pulse-width-modu- ductance-capacitance filters. and Ernest Stone of Caltech and William lated buck regulator circuit. Feedback for The output power of 17 W is obtained Boger, David Burgess, Richard Honda, and regulation of power-converter output volt- with a nominal input radio-frequency Carl Nuckolls of General Dynamics Decision ages is provided by a transformer winding power of 1 dBm (≈1.3 mW) and an input Systems for NASA’s Jet Propulsion Labora- that is in addition to the primary and sec- DC power of 59 W. The amplifier and tory. Further information is contained in a ondary winding. Feedback-loop compen- power-converter modules are configured TSP (see page 1). NPO-30663 Improved Anode for a Direct Methanol Fuel Cell Electrical resistance is decreased and utilization of catalyst is increased. NASA’s Jet Propulsion Laboratory, Pasadena, California A modified chemical composition has Some background information is help- ally deposited onto a polymer-electrolyte been devised to improve the perfor- ful for understanding the benefit afforded (proton-conducting) membrane and onto mance of the anode of a direct by the addition of hydrous ruthenium an anode gas-diffusion/current-collector methanol fuel cell. The main feature of oxide. The anode of a direct methanol fuel sheet that is subsequently bonded to the the modified composition is the incor- cell sustains the electro-oxidation of proton-conducting membrane by hot poration of hydrous ruthenium oxide methanol to carbon dioxide in the reac- pressing. into the anode structure. This modifica- tion CH3OH + H2O →CO2+ 6H++ 6e–. Heretofore, the areal density of tion can reduce the internal electrical An electrocatalyst is needed to enable this noble-metal catalyst typically needed resistance of the cell and increase the reaction to occur. The catalyst that offers for high performance has been about degree of utilization of the anode cata- the highest activity is an alloy of approxi- 8 mg/cm2. However, not all of the cata- lyst. As a result, a higher anode current mately equal numbers of atoms of the lyst has been utilized in the catalyzed density can be sustained with a smaller noble metals platinum and ruthenium. electro-oxidation reaction. Increasing amount of anode catalyst. These im- The anode is made of a composite mater- the degree of utilization of the catalyst provements can translate into a smaller ial that includes high-surface-area Pt/Ru- would make it possible to improve the fuel-cell system and higher efficiency of alloy particles and a proton-conducting performance of the cell for a given cata- conversion. ionomeric material. This composite is usu- lyst loading and/or reduce the catalyst loading (thereby reducing the cost of 0.6 the cell). The use of carbon and possibly other s Versu 0.5 4 mg/cm2 Pt:Ru + Hydrous RuO2 elalyeecrt rhoansi cb eceonn dpuroctpoorsse di nf otrh ien ccreaataslinysgt ed) 4 mg/cm2 Pt:Ru the utilization of the catalyst by increas- Correcte, Volts0.4 8 mg/cm2 Pt:Ru ilnysgt pelaerctitcrliecas.l Hcoonwneevcetri,v tihtye breetlwateievenl yc alotaw- esistance n Electrod0.3 dlmaeyenetrhsisat ytnh ooaflt ctioam rtbphoeend c era etthsauleyl ttmisc ia nssis tt ehtrsia.c nkAs lcpsaoot,ra ttl hyoseft Re electrical conductivity of carbon is less al (Internal mal Hydrog0.2 tmbhroaannre e1, m/t3ah0te0e rthipa loo ilfsy tmaycpeiidrc-iaecll eamcntedrt oamllyso.t seFt ummrtehetemarls-- entiNor are not chemically stable in contact with ot it. Finally, a material that conducts elec- P e 0.1 trons (but not protons) does not con- d no tribute to the needed transport of pro- A tons produced in the electro-oxidation 0 reaction. 10 100 1000 10,000 Hence, what is needed is an additive Current Density, mA/cm2 that is stable in contact with the polymer- electrolyte membrane and that conducts These Plots of Anode Overpotential Versus Current Densitywere obtained in tests of direct methanol fuel cells operated at a temperature of 90 °C and a methanol concentration of 1 M. both electrons and protons. Hydrous NASA Tech Briefs, January 2005 13