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NASA Technical Reports Server (NTRS) 19930007711: Glass and ceramics. [lunar resources] PDF

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Preview NASA Technical Reports Server (NTRS) 19930007711: Glass and ceramics. [lunar resources]

u98-1G900 S.¢ Glass and Ceramics /-Y Larry A. Haskin A variety of glasses and ceramics lunar material or close simulants, can be produced from bulk lunar so properties are not known in materials or from separated detail; however, common glass components. Many glassy technologies such as molding and materials have been described in spinning seem feasible (fig. 7). previous studies (Mackenzie and Uses of glass include structural Claridge 1979, Criswell 1980). applications (bricks, slabs, beams, They include sintered (heated and windows) and specialty applications pressed) regolith, quenched molten (fiber strengtheners, insulation, basalt, and transparent glass heat shields, cables, light pipes). formed from fused plagioclase. No See figures 8 and 9. research has been carried out on Finished Empty mold Loaded mold Glass pressed piece (a) Block mold Figure 7 Finishe_d Glass Forming Empty mold Loaded mold Glass pressed piece The materia/ on the lunar surface has a high sificate content. Some of (b) Split mold these silicate materials could be the constituents of transparent glasses, which could have a variety of uses at a lunar base. Various processes are available for fabricating objects from glass. Here, molds are usecl for glass Dressing. The fiquid glass is poured into the mold, which is compressed. When the glass has cooled, the object is extracted from Untrimmed Finished the mold. Empty mold Loaded mold Glass presseo piece piece From Shand 1958, p. 164. (c) Font mold 291 Continuous filaments Figure 8 Sapizpinliegd Glass Drawing Strand When silicate glasses are me/ted, they are viscous and thus can readily be drawn by special machines into fibers Winding or rods or tubes. Glass fiber textiles tube and mats, which are commonly used terrestrially as thermal and electrical insulators, could be used as construction materials in a space facili_/. From Shand 1958, p. 385. arbles :: :2e221:Ee?us'2:o Figure 9 Fiberglass / __High-pressuresteamjetsattenuate Another product that could be formed '_/1:_ _ molten streams into fine fibers from lunar soil is fiberglass, which _/I/_}_,_k I Mat Bonded in drying oven might find use as a structural material, perhaps combined with organic or metallic materials. On Earth, fiberglass tanks are commonly used for storage of fluids, such as in standard water Fibers laidin thin _, heaters. web-like mat on Binder From Shand 1958, p. 384. conveyor belt applied 292 Among the high-leverage uses and microwave heating. Direct use of fused silicate materials in of waste heat from nuclear the proposed utilization of reactors used in space or on the nonterrestrial resources are the Moon may also be practical but fabrication of heat shields for might require complex heat orbital transfer vehicles traveling exchangers, heat pipes, and other from the Moon to Earth and the devices for thermal control. The use of sintered or melted and microwave heating concept is sand-cast soil for structural support described in more detail in the first in unpressurized lunar shelters. appendix to this part. It offers an The work of Blacic (1985) indicates efficient means of converting that lunar glasses made under electrical energy into heat, the anhydrous, hard-vacuum delivered locally and in a controlled conditions on the Moon could have manner to the target to be heated. very high strengths and thus be Additional work is necessary to quite applicable to structures in define optimum thermal processing space. Prestressed beams made systems for glass and ceramic with sintered bricks, using products and the properties of the fiberglass or iron bars as tendons, heated lunar material. It will be may find early application as desirable to have access to good structural members. simulants of lunar regolith or increased quantities of real lunar Ceramics like those used on Earth soil to further such necessary could be produced by chemical research. processing of raw lunar material; for example, fractional volatilization The production of more complex of plagioclase could lead to melts ceramics, composites, and even for ceramic applications. The semiconductors may prove recombination of plagioclase desirable at some point during the with the residue of the ilmenite development of a lunar base. reduction process (metallic iron Although perhaps not within the and titanium dioxide) could yield scope of most easily obtainable cermets with interesting properties. materfals, semiconductors Ceramics might find uses similar to produced from lunar materials those of glasses. could have a major effect on the means of producing electricity Alternative means of preparing on the Moon. Silicon-based glasses and ceramics appear to photovoltaic devices could be be direct heating using solar constructed using silicon reduced concentrators (Ho and Sobon from silicate minerals, covered with 1979), electrical resistive heating, thin glass layers made from silicon 293 dioxide, supported by iron, aluminum, or glass structures, and supplied with iron wires to conduct currents. Lunar ilmenite has interesting semiconductor properties (see fig. 10) and might be usable in converting sunlight to electricity. The preparation of photovoltaic devices is now well known on Earth; however, adapting these processes to alunar environment would be quite challenging. Figure 10 Semiconductors Lunarilmenite is a natural semiconductor. Here, a "boule" of ilmenite of lunar composition has been fabricated in a furnace as a single crystal. Cut into thinwafers, provided withelectrical leads, and exposed tothe Sun, this semiconductor would cause an electrical current toflow. A/though rather low in its efficiency of converting light to electricity, ilmenite is so abundant on the Moon that itmay be anattractive alternative to photovoltaic devices brought from Earth. Courtesy of R. K.Pandey, Electronic Materials Laboratory, Texas A&M University, College Station, TX O,r__IL__I,_1./,-_I,. PA_,_,_ EtLACK AND WHJTE PHOTOGRAPH 294

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