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Nanotechnology: Synthesis to Applications PDF

351 Pages·2018·16.52 MB·English
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Nanotechnology Synthesis to Applications Nanotechnology Synthesis to Applications Edited by Sunipa Roy, Chandan Kumar Ghosh, and Chandan Kumar Sarkar CRC Press Taylor & Francis Group 6000 Broken Sound Parkway NW, Suite 300 Boca Raton, FL 33487-2742 © 2018 by Taylor & Francis Group, LLC CRC Press is an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works Printed on acid-free paper International Standard Book Number-13: 978-1-138-03273-6 (Hardback) This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmitted, or utilized in any form by any electronic, mechanical, or other means, now known or hereafter invented, including photocopying, microfilming, and recording, or in any information storage or retrieval system, without written permission from the publishers. For permission to photocopy or use material electronically from this work, please access www. copyright.com (http://www.copyright.com/) or contact the Copyright Clearance Center, Inc. (CCC), 222 Rosewood Drive, Danvers, MA 01923, 978-750-8400. CCC is a not-for-profit organization that provides licenses and registration for a variety of users. For organizations that have been granted a photocopy license by the CCC, a separate system of payment has been arranged. Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and are used only for identification and explanation without intent to infringe. Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the CRC Press Web site at http://www.crcpress.com Dedicated to our families for their love and support Contents Preface ......................................................................................................................ix Editors .....................................................................................................................xv Authors ................................................................................................................xvii Contributors ..........................................................................................................xxi 1. Introduction: Motivation for Nanotechnology .........................................1 Sunipa Roy, Chandan Kumar Ghosh, and Chandan Kumar Sarkar 2. Introductory Quantum Mechanics for Nanoscience ................................5 Chandan Kumar Ghosh 3. Crystallography, Band Structure, and Density of States at Nanoscale .....33 Swapnadip De 4. Growth Techniques and Characterization Tools of Nanomaterials ....51 Chandan Kumar Ghosh and Arka Dutta 5. Electrical Transport in Nanostructures .....................................................87 Angsuman Sarkar 6. Synthesis of Noble Metal Nanoparticles: Chemical and Physical Routes ...................................................................................107 Chandan Kumar Ghosh 7. Biological Synthesis of Metallic Nanoparticles: A Green Alternative ....................................................................................................131 Kaushik Roy and Chandan Kumar Ghosh 8. Environmental and Biological Applications of Nanoparticles ..........147 Kaushik Roy and Chandan Kumar Ghosh 9. Nanogenerator: A Self-Powered Nanodevice........................................171 Sunipa Roy and Amrita Banerjee 10. Solar Photovoltaic: From Materials to System ......................................197 Sunipa Roy and Swapan Das 11. Volatile Organic Compound–Sensing with Different Nanostructures ............................................................................................219 Sunipa Roy and Swapan Das vii viii Contents 12. Nanoscience with Graphene .....................................................................241 Angsuman Sarkar 13. Nanoscale Silicon MOS Transistors ........................................................259 Soumya Pandit 14. Nanotechnology Applications in Electron Devices .............................285 Sarosij Adak, Arghyadeep Sarkar, and Sanjit Kumar Swain 15. Micro/Nanoelectromechanical Systems .................................................297 Atanu Kundu Index .....................................................................................................................319 Preface Nano is a Greek word meaning “dwarf.” One nanometer is 10−9 meter. In modern-day technology, the term “nano” has assumed great significance because physical and chemical properties of materials change significantly when their sizes are reduced to dimensions of 100 nm or less. Thus nanosci- ence and nanotechnology refer to the science and technology of materials and systems having dimensions in the range of 1–100 nm. In the field of electronics, there are immense possibilities of nanostructured semiconductor devices, some of which are demonstrated by different authors in this book. This technological advancement also demanded understanding of the new device physics as the properties of materials changed significantly at such reduced dimensions. These dimensions are comparable to the electron wavelength of motion, and hence the device characteristics are governed by the confinement of the electron wave function, commonly referred to as quantum confinement effect. Quantum confinement effect due to changes in the size and shape of nanoparticles (NPs) can modify the energy bands of semiconductors and insulators. A brief description on electrical transport of nanostructure is given in this book. Nano particles have attracted much interest in recent years by virtue of their unusual mechanical, electrical, optical, and magnetic properties. Due to their special properties, NPs are finding wide applications in all fields of engineering. Several synthetic approaches have been developed to control their morphology and synthesis. Metal NPs are of particular interest in medical diagnostics because of their antibacterial activity and low toxicity to human cells. This antibacterial effect is further enhanced with the reduction in particle size. Biomedical devices must be biocompatible, which indicates nontoxicity of the reactants used in nanoparticle synthesis. The so-called “green synthesis” method suits well for this purpose. A novel green synthesis of NPs makes use of environmental- friendly, nontoxic, and safe reagents, which is discussed in Chapter 7. Nanocomposites for energy harvesting are a latest area of research and contain many unexpected benefits in the field of technology. Keeping this in mind, a chapter has been written to present the matter from an experimental point of view. Nanotechnology is a completely new science that came on the market a few years ago, though many are not fully conscious of its presence in daily life. The application of nanotechnology can be found in many everyday items. Thousands of commercial products incorporate nanomaterials. Though it is a relatively new science, its applications range from consumer goods to medicine to improving the environment. ix

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Nano particles have created a high interest in recent years by virtue of their unusual mechanical, electrical, optical and magnetic properties and find wide applications in all fields of engineering. This edited volume aims to present the latest trends and updates in nanogenerators, thin film solar
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