Nanotechnology for Bioenergy and Biofuel Production PDF
Preview Nanotechnology for Bioenergy and Biofuel Production
Green Chemistry and Sustainable Technology Mahendra Rai Silvio Silvério da Silva Editors Nanotechnology for Bioenergy and Biofuel Production Green Chemistry and Sustainable Technology Serieseditors Prof.Liang-NianHe StateKeyLaboratoryofElemento-OrganicChemistry,NankaiUniversity,Tianjin, China Prof.RobinD.Rogers DepartmentofChemistry,McGillUniversity,Montreal,Canada Prof.DangshengSu ShenyangNationalLaboratoryforMaterialsScience,InstituteofMetalResearch, ChineseAcademyofSciences,Shenyang,China and Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society,Berlin,Germany Prof.PietroTundo Department of Environmental Sciences, Informatics and Statistics, Ca’ Foscari UniversityofVenice,Venice,Italy Prof.Z.ConradZhang DalianInstituteofChemicalPhysics,ChineseAcademyofSciences,Dalian,China AimsandScope The series Green Chemistry and Sustainable Technology aims to present cutting-edge research and important advances in green chemistry, green chemical engineeringandsustainableindustrialtechnology.Thescopeofcoverageincludes (butisnotlimitedto): – Environmentally benign chemical synthesis and processes (green catalysis, greensolventsandreagents,atom-economysyntheticmethodsetc.) – Green chemicals and energy produced from renewable resources (biomass, carbondioxideetc.) – Novelmaterialsandtechnologiesforenergyproductionandstorage(bio-fuels andbioenergies,hydrogen,fuelcells,solarcells,lithium-ionbatteriesetc.) – Greenchemicalengineeringprocesses(processintegration,materialsdiversity, energysaving,wasteminimization,efficientseparationprocessesetc.) – Green technologies for environmental sustainability (carbon dioxide capture, waste and harmful chemicals treatment, pollution prevention, environmental redemptionetc.) TheseriesGreenChemistryandSustainableTechnologyisintendedtoprovidean accessible reference resource for postgraduate students, academic researchers and industrialprofessionalswhoareinterestedingreenchemistryandtechnologiesfor sustainabledevelopment. Moreinformationaboutthisseriesathttp://www.springer.com/series/11661 Mahendra Rai (cid:129) Silvio Silve´rio da Silva Editors Nanotechnology for Bioenergy and Biofuel Production Editors MahendraRai SilvioSilve´riodaSilva DepartmentofBiotechnology DepartmentofBiotechnology SantGadgeBabaAmravatiUniversity UniversityofS~aoPaulo Amravati,India Lorena/SP S~aoPaulo,Brazil ISSN2196-6982 ISSN2196-6990 (electronic) GreenChemistryandSustainableTechnology ISBN978-3-319-45458-0 ISBN978-3-319-45459-7 (eBook) DOI10.1007/978-3-319-45459-7 LibraryofCongressControlNumber:2016959554 ©SpringerInternationalPublishingAG2017 Thisworkissubjecttocopyright.AllrightsarereservedbythePublisher,whetherthewholeorpartof the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilarmethodologynowknownorhereafterdeveloped. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publicationdoesnotimply,evenintheabsenceofaspecificstatement,thatsuchnamesareexempt fromtherelevantprotectivelawsandregulationsandthereforefreeforgeneraluse. Thepublisher,theauthorsandtheeditorsaresafetoassumethattheadviceandinformationinthis book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained hereinorforanyerrorsoromissionsthatmayhavebeenmade. Printedonacid-freepaper ThisSpringerimprintispublishedbySpringerNature TheregisteredcompanyisSpringerInternationalPublishingAG Theregisteredcompanyaddressis:Gewerbestrasse11,6330Cham,Switzerland Preface Thereisagreaterneedtosearchforalternativesourcesofenergyduetothelimited availabilityoffossilfuels.Theuseofbiofuelsisthecommonalternativeinfrontof thewholeworld,anditsuseissignificantlyincreasedinmanycountries.Generally, biodieselisusedasafuelfordieselenginesduetoitstechnical,environmental,and strategic advantages. Apart from these, biodiesel is technically competitive with conventional,petroleum-deriveddieselfuelandrequiresvirtuallynochangesinthe fueldistributioninfrastructure.Otheradvantagesofbiodieselascomparedtopetro- diesel include reduction of most exhaust emissions, biodegradability, higher flash point, inherence, and the fact that it is of domestic origin. However, ethanol is mostlyusedforOttocycleenginesasanalternativetogasoline. Nanotechnology is one of the most important research areas in the twenty-first century. The potential applications of nanobiotechnology in the production of sustainable bioenergy and biosensorshave encouraged researchers in recent years to investigate new novel nanoscaffolds to build robust nanobiocatalytic systems. Differentkindsofnanomaterialshavebeendevelopedaspertheneedforapplica- tionpurpose. Variousmetal nanomaterialsare found to have direct or indirect applicationin theproductionofbiofuels.Amongthese,nanoparticle-mediatedenzymehydrolysis oflignocellulosicresiduesfortheproductionofethanolisinpractice.Magneticand metal oxide nanoparticles such as TiO , ZnO, SnO , etc. are commonly used 2 2 matrices for enzyme immobilization. Magnetic nanoparticles are found to have potential uses in the field of biofuel and bioenergy, i.e., in the production of bioethanol from lignocellulosic materials by immobilization of enzymes like cel- lulasesandhemicellulasesbyphysicaladsorption,covalentbinding,cross-linking, orspecificligandspacers.Suchnanomaterialsaregenerallycalledasnanocatalysts, which are fabricated by immobilizing enzymes with functional nanomaterials as enzymecarriers. v vi Preface The book would be immensely useful for a diverse group of readers including physicists,chemists,microbiologists,biotechnologists,foodtechnologists,agricul- tureengineers,nanotechnologists,andthosewho areinterestedinclean technolo- gies.Thestudentsshouldfindthisbookuseful. Amravati,Maharashtra,India MahendraRai Lorena,SP,Brazil SilvioSilve´riodaSilva Contents PartI NanotechnologicalApplicationsinBioenergyandBiofuel 1 BioenergyandBiofuels:NanotechnologicalSolutionsfor SustainableProduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 FelipeAntonioFernandesAntunes,SwapnilGaikwad,AvinashP.Ingle, RakshaPandit,Ju´lioCe´sardosSantos,MahendraRai, andSilvioSilve´riodaSilva 2 NanotechnologyApplicationsonLignocellulosicBiomass Pretreatment. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 JohnattAllanRochadeOliveira,LuizaHelenadaSilvaMartins, AndreaKomesu,andJo~aoMoreiraNeto 3 ApplicationsofCarbon-BasedNanomaterialsinBiofuelCell. . . . . 39 Ming-GuoMa,BoLiu,andLing-YanMeng 4 MultifunctionalNanoparticleApplicationstoMicroalgal Biorefinery. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 JungYoonSeo,MinjeongG.Kim,KyubockLee,Young-ChulLee, Jeong-GeolNa,SangGooJeon,SeungBinPark,andYou-KwanOh PartII NanotechnologyinBiomassConversion 5 PotentialApplicationsofNanotechnologyinThermochemical ConversionofMicroalgalBiomass. . . . . . . . . . . . . . . . . . . . . . . . . 91 AbdulRaheem,LiaquatAliMemon,SikandarAliAbbasi, Y.H.TaufiqYap,MichaelK.Danquah,andRazifHarun 6 HierarchyNano-andUltrastructureofLignocelluloseand ItsImpactontheBioconversionofCellulose. . . . . . . . . . . . . . . . . 117 XuebingZhao,FengQi,andDehuaLiu vii viii Contents 7 RoleofNanoparticlesinEnzymaticHydrolysisofLignocellulosein Ethanol. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153 MahendraRai,AvinashP.Ingle,SwapnilGaikwad,KellyJ.Dussa´n, andSilvioSilve´riodaSilva 8 PhysicochemicalCharacterizationsofNanoparticlesUsed forBioenergyandBiofuelProduction. . . . . . . . . . . . . . . . . . . . . . . 173 RafaellaO.doNascimento,LucianaM.Rebelo,andEdwardSacher PartIII Nano-characterizationandRoleofCatalysts 9 FromBiomasstoFuels:Nano-catalyticProcesses. . . . . . . . . . . . . . 195 MohammadBarati 10 CatalyticConversiononLignocellulosetoBiodieselProduct. . . . . 207 SamiraBagheri,NurhidayatullailiMuhdJulkapli, andRabi’atulAdawiyahZolkepeli 11 HeterogeneousCatalystsforAdvancedBiofuel Production. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231 VorranutchItthibenchapong,AtthaponSrifa, andKajornsakFaungnawakij 12 AnOverviewoftheRecentAdvancesintheApplicationofMetal OxideNanocatalystsforBiofuelProduction. . . . . . . . . . . . . . . . . . 255 MandanaAkia,EsmailKhalife,andMeisamTabatabaei 13 NanocatalysisfortheConversionofNonedibleBiomass toBiogasolineviaDeoxygenationReaction. . . . . . . . . . . . . . . . . . . 301 HweiVoonLeeandJoonChingJuan 14 ImpactofNanoadditiveBlendedBiodieselFuels inDieselEngines. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 325 J.SadhikBasha PartIV RiskManagement 15 NanotechnologiesandtheRiskManagement ofBiofuelProduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 343 MariadeLourdesOshiro,EdgarOshiro,T^aniaEliasMagnodaSilva, WilliamWaissmann,andWilsonEngelmann Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 365 Contributors Abdul Raheem Department of Chemical and Environmental Engineering, UniversitiPutraMalaysia,Serdang,Malaysia Andrea Komesu Faculdade de Engenharia Qu´ımica, UNICAMP, Campinas, Brazil AtthaponSrifa NationalNanotechnologyCenter(NANOTEC),NationalScience and Technology Development Agency (NSTDA), Khlong Luang, Pathumthani, Thailand Avinash P.Ingle NanobiotechnologyLaboratory,Department ofBiotechnology, SantGadgeBabaAmravatiUniversity,Amravati,Maharashtra,India Bo Liu Engineering Research Center of Forestry Biomass Materials and Bioenergy, Beijing Key Laboratory of Lignocellulosic Chemistry, College of MaterialsScienceandTechnology,BeijingForestryUniversity,Beijing,PRChina DehuaLiu DepartmentofChemicalEngineering,InstituteofAppliedChemistry, TsinghuaUniversity,Beijing,China EdgarOshiro Dr.JorgeDavidNasserPublicHealthSchool,MatoGrossodoSul StateHealthSecretariat,CampoGrande,MatoGrossodoSul,Brazil EdwardSacher De´partementdeGe´niePhysique,Montre´al,QC,Canada EsmailKhalife BiofuelResearchTeam(BRTeam),Karaj,Iran Department of Agricultural Machinery, College of Agricultural Technology and NaturalResources,UniversityofMohagheghArdabili,Ardabil,Iran Feng Qi College of Life Sciences/Engineering Research Center of Industrial Microbiology,FujianNormalUniversity,Fuzhou,China Hwei Voon Lee Nanotechnology & Catalysis Research Centre (NANOCAT), InstituteofPostgraduateStudies,UniversityofMalaya,KualaLumpur,Malaysia ix
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