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Ram Prasad · Manoj Kumar Vivek Kumar Editors Nanotechnology An Agricultural Paradigm Nanotechnology Ram Prasad • Manoj Kumar • Vivek Kumar Editors Nanotechnology An Agricultural Paradigm Editors Ram Prasad Manoj Kumar Amity Institute of Microbial Technology Amity Institute of Microbial Technology Amity University Amity University Noida, Uttar Pradesh, India Noida, Uttar Pradesh, India Vivek Kumar Amity Institute of Microbial Technology Amity University Noida, Uttar Pradesh, India ISBN 978-981-10-4572-1 ISBN 978-981-10-4573-8 (eBook) DOI 10.1007/978-981-10-4573-8 Library of Congress Control Number: 2017943328 © Springer Nature Singapore Pte Ltd. 2017 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. Printed on acid-free paper This Springer imprint is published by Springer Nature The registered company is Springer Nature Singapore Pte Ltd. The registered company address is: 152 Beach Road, #21-01/04 Gateway East, Singapore 189721, Singapore Contents 1 Agricultural Nanotechnology: Concepts, Benefits, and Risks . . . . . . 1 Jeyabalan Sangeetha, Devarajan Thangadurai, Ravichandra Hospet, Prathima Purushotham, Gururaja Karekalammanavar, Abhishek Channayya Mundaragi, Muniswamy David, Megha Ramachandra Shinge, Shivasharana Chandrabanda Thimmappa, Ram Prasad, and Etigemane Ramappa Harish 2 Nanotechnology in Life Science: Its Application and Risk . . . . . . . . . 19 Gero Benckiser 3 Production of Bionanomaterials from Agricultural Wastes . . . . . . . . 33 Jeyabalan Sangeetha, Devarajan Thangadurai, Ravichandra Hospet, Prathima Purushotham, Kartheek Rajendra Manowade, Mohammed Abdul Mujeeb, Abhishek Channayya Mundaragi, Sudisha Jogaiah, Muniswamy David, Shivasharana Chandrabanda Thimmappa, Ram Prasad, and Etigemane Ramappa Harish 4 Nanomaterials: Implications on Agroecosystem . . . . . . . . . . . . . . . . . 59 M.R. Davari, S. Bayat Kazazi, and O. Akbarzadeh Pivehzhani 5 N anoagrotechnology for Soil Quality, Crop Performance and Environmental Management . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73 Jeyabalan Sangeetha, Devarajan Thangadurai, Ravichandra Hospet, Etigemane Ramappa Harish, Prathima Purushotham, Mohammed Abdul Mujeeb, Jadhav Shrinivas, Muniswamy David, Abhishek Channayya Mundaragi, Shivasharana Chandrabanda Thimmappa, Suresh Basavaraj Arakera, and Ram Prasad 6 Nanoengineering Superabsorbent Materials: Agricultural Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99 Majid Peyravi, Peyman Pouresmaeel Selakjani, and Soodabeh Khalili 7 Nanotechnology in Agriculture, Food Process Product, and Food Packaging . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117 A. Allwyn Sundarraj v vi Contents 8 Green Nanotechnology: Biomimetic Synthesis of Metal Nanoparticles Using Plants and Their Application in Agriculture and Forestry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133 Mohammadhassan Gholami-Shabani, Zeynab Gholami- Shabani, Masoomeh Shams-Ghahfarokhi, Fatemehsadat Jamzivar, and Mehdi Razzaghi-Abyaneh 9 Nanomaterials for Delivery of Nutrients and Growth-Promoting Compounds to Plants . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 177 Josef Jampílek and Katarína Kráľová 10 Synthesis, Characterization, and Application of Chitosan Nanomaterials Loaded with Zinc and Copper for Plant Growth and Protection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 227 Ram Chandra Choudhary, R.V. Kumaraswamy, Sarita Kumari, Ajay Pal, Ramesh Raliya, Pratim Biswas, and Vinod Saharan 11 Nanotechnology for Enhancing Crop Productivity . . . . . . . . . . . . . . . 249 Suresh Kaushik and Setyowati Retno Djiwanti 12 Nanomaterial-Based Biosensors in Agriculture Application and Accessibility in Rural Smallholding Farms: Food Security . . . . . 263 M.S. Mufamadi and P.R. Sekhejane 13 N anosensors: Frontiers in Precision Agriculture . . . . . . . . . . . . . . . . . 279 Manoj Kaushal and Suhas P. Wani 14 A pplication of Nanomaterials Toward Development of Nanobiosensors and Their Utility in Agriculture. . . . . . . . . . . . . . . 293 Ravindra Pratap Singh 15 Modern Prospects of Nanotechnology in Plant Pathology . . . . . . . . . 305 Massalimov Ismail, Ram Prasad, Amr I.M. Ibrahim, and Ahmed I.S. Ahmed 16 Nanocomposites: Future Trends and Perspectives Towards Affinity Biosensor . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 319 Ajay Kumar Gupta and Murthy Chavali Yadav 17 Application of Nanotechnology in Enhancement of Crop Productivity and Integrated Pest Management . . . . . . . . . . . 361 Manish Kumar, Tooba Naz Shamsi, Romana Parveen, and Sadaf Fatima About the Editors Dr. Ram Prasad, Ph.D. is assistant professor at the Amity Institute of Microbial Technology, Amity University, Uttar Pradesh, India. His research interest includes plant-microbe interactions, sustainable agri- culture, and microbial nanobiotechnology. Dr. Prasad has more than a hundred publications to his credit, including research papers and book chapters and five patents issued or pending, and edited or authored sev- eral books. Dr. Prasad has 11 years of teaching experi- ence, and he has been awarded the Young Scientist Award (2007) and Prof. J.S. Datta Munshi Gold Medal (2009) by the International Society for Ecological Communications, a fellowship (2010) by the Society for Applied Biotechnology, the Outstanding Scientist Award (2015) in the field of microbiology by Venus International Foundation, and the American Cancer Society UICC International Fellowship for Beginning Investigators (USA, 2014). In 2014–2015, Dr. Prasad served as visiting assistant professor in the Department of Mechanical Engineering at Johns Hopkins University, USA. Dr. Manoj Kumar, Ph.D. is a scientist with sanguine behavior who is adoring about research and develop- ment, with a commitment to lifelong learning. He is determined on high-quality science that contributes broadly to both increasing intellectual knowledge of plant development and increasing the ecological niche. He has a high level of professional desire and intellec- tual hunt and the potential to fulfill the dream of his high-impact publications and the future recognition of these by academic peers. Dr. Kumar has pursued his Ph.D. in plant biotechnology from prestigious Jawaharlal Nehru University and then was awarded two postdoctoral fellowships consecutively: (i) DBT-PDF from IISc Bangalore in 2005 and then NRF-PDF from the University of Pretoria. Dr. Manoj Kumar is a researcher of plant biotechnology in the Amity Institute of Microbial Technology at Amity vii viii About the Editors University, Uttar Pradesh, India. Dr. Kumar’s research is the integration of micro- bial genetics with a breadth of plant physiological approaches to enable novel gene discovery and conferring metabolites. Dr. Vivek Kumar, Ph.D. is a scientist involved in teaching, research, and guidance, with a pledge to endur- ing knowledge. Dr. Kumar is working in the Amity Institute of Microbial Technology at Amity University, Noida, Uttar Pradesh, India. He obtained his master’s and doctoral degree from CCS Haryana Agricultural University, Hisar, Haryana, India. He is serving in the editorial board of reputed international journals, viz., EnvironmentAsia, the International Journal of Biological and Chemical Sciences, the Journal of Advanced Botany and Zoology, and the Journal of Ecobiotechnology. He has published 61 research papers, 19 book chapters, 6 review articles, and 2 books. Dr. Kumar has also served as microbiologist for 8 years in the Department of Soil and Water Research, Public Authority of Agricultural Affairs and Fish Resources, Kuwait. Dr. Kumar has orga- nized a number of conferences/workshops as a convener/organizing secretary. Agricultural Nanotechnology: Concepts, 1 Benefits, and Risks Jeyabalan Sangeetha, Devarajan Thangadurai, Ravichandra Hospet, Prathima Purushotham, Gururaja Karekalammanavar, Abhishek Channayya Mundaragi, Muniswamy David, Megha Ramachandra Shinge, Shivasharana Chandrabanda Thimmappa, Ram Prasad, and Etigemane Ramappa Harish Abstract Nanotechnology is one of the utmost significant tools in modern agriculture is predicted to become a driving cost-effective force in the near future. Nanotechnology in agriculture has gained drive in the last decade with an abun- dance of public funding, but the step of development is uncertain, even though many disciplines come under the agriculture system. This could be attributed to a unique nature of farm production whereby energy and matter are exchanged freely, the scale of demand of input materials constantly being enormous in con- trast with industrial nanoproducts. The nanotechnologic intervention in farming has prospects for improving the efficiency of nutrient use through nanoformula- tions of fertilizers, surveillance and control of pests and diseases, improvement of new-generation pesticides, biosensors (which are exclusively used in remote J. Sangeetha Department of Environmental Science, Central University of Kerala, Kasaragod, Kerala 671316, India D. Thangadurai (*) • R. Hospet • P. Purushotham • A.C. Mundaragi Department of Botany, Karnatak University, Dharwad, Karnataka 580003, India e-mail: [email protected] G. Karekalammanavar • M. David • E.R. Harish Department of Zoology, Karnatak University, Dharwad, Karnataka 580003, India M.R. Shinge • S.C. Thimmappa Department of Microbiology and Biotechnology, Karnatak University, Dharwad, Karnataka 580003, India R. Prasad Amity Institute of Microbial Technology, Amity University, Noida, Uttar Pradesh 201313, India © Springer Nature Singapore Pte Ltd. 2017 1 R. Prasad et al. (eds.), Nanotechnology, DOI 10.1007/978-981-10-4573-8_1 2 J. Sangeetha et al. sensing devices for precision farming), clay-based nanoresources for precision water management, and reclamation of salt-affected lands. Keywords Conventional farming • Nanotools • Nanoprocesses • Nanomaterials • Nanofertilizers • Nanopesticides 1.1 Introduction Nanotechnology refers to the engineering and restructuring of functional systems on the scale of molecules and atoms. It is an interdisciplinary field which has the potentiality for the drastic changes in the fields of medicine, food, pharmacology, and agriculture since the eighteenth and nineteenth centuries. Inadequate supply of food is the current major problem in developing countries, due to increasing popula- tion as a result of an impact on agricultural practices and productivity. The agricul- tural field broadly gets benefited by the nanotech-based devices to inspect diseases in a rapid manner, to enhance the capacity of the crop plants for the possible intake of minerals, and to lead molecular treatment of diseases (Huang et al. 2007). Nanotechnology for agricultural applications predominantly shows growth from theoretical possibilities to applicable realms. An appreciation of the experimental tool is designed to operate at nanometric levels to boost research in molecular and cellular biology. The current global population is nearly about 7 billion, with 50% living in Asia. Due to increase in proportion, those living in developing countries face extreme food scarcity as a result of environmental impacts on agriculture, including storms, droughts, and flood. In a similar way, the agricultural production is constrained by a certain number of biotic and abiotic factors, and, the insect pests, diseases, and weeds cause the high loss for the potential production of agricultural crops (Dhaliwal et al. 2010). Nanomaterial-based pesticides and insecticides were manufactured exclusively for the management of insect pests using bioconjugated nanoparticles (encapsulation), agricultural productivity was enhanced for slow release of nutrients and water molecules, nanoparticle-mediated gene or DNA was incorporated in the plants for developing insect pest-resistant varieties, and also nanomaterials were used for preparing different kind of biosensors, which are exclusively used in remote sensing devices for precision farming (Prasad 2014, 2016; Prasad et al. 2014). The use of traditional methods of integrated pest manage- ment in agriculture has some major limits, and also applying chemical pesticides like DDT imposed major effects on soil fertility and major drawbacks – its adverse effects on animals and human beings. Thus, it has been concluded that nanotechnol- ogy provides an efficient and eco-friendly approach for insect pest’s management of plant crops without harming the environment (Rai and Ingle 2012). Insects were found in all the types of environment, and it occupies more than two-thirds of known species of animals in the world. Insects infest to injure the plants and stored prod- ucts directly or indirectly; the damage that causes less than 5% is not considered (Dhaliwal et al. 2010). Pimentel (2009) estimated that throughout the world

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This book highlights the implications of nanotechnology and the effects of nanoparticles on agricultural systems, their interactions with plants as well as their potential applications as fertilizers and pesticides. It also discusses how innovative, eco-friendly approaches to improve food and agricu
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