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Nanostructure Physics and Fabrication. Proceedings of the International Symposium, College Station, Texas, March 13*b115, 1989. PDF

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N A N O S T R U C T U RE P H Y S I CS A ND F A B R I C A T I ON Proceedings of the International Symposium College Station, Texas March 75-75, 7989 Edited by Mark A. Reed Central Research Laboratories Texas Instruments Incorporated Dallas, Texas Wiley P. Kirk Department of Physics Texas A&M University College Station, Texas ACADEMIC PRESS, INC. Harcourt Brace Jovanovich, Publishers Boston San Diego New York Berkeley London Sydney Tokyo Toronto Copyright © 1989 by Academic Press, Inc. All rights reserved. No part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopy, recording, or any information storage and retrieval system, without permission in writing from the publisher. ACADEMIC PRESS, INC. 1250 Sixth Avenue, San Diego, CA 92101 United Kingdom Edition published by ACADEMIC PRESS, INC. (LONDON) LTD. 24-28 Oval Road, London NW1 7DX Library of Congress Cataloging-in-Publication Data Nanostructure physics and fabrication : proceedings of the international symposium, College Station, Texas, March 13-15, 1989 / edited by Mark A. Reed, Wiley Ρ Kirk, p. cm. "Contains contributions presented at the First International Symposium on Nanostructure Physics and Fabrication . . . [held] on the campus of Texas A&M University from March 13 to 15, 1989" — Pref. Includes bibliographies and index. ISBN 0-12-585000-X (alk. paper) 1. Electronic structure—Congresses. 2. Quantum electronics- -Congresses. 3. Superconducting quantum interference devices- -Congresses I. Reed, Mark Α. II. Kirk, Wiley Ρ III. International Symposium on Nanostructure Physics and Fabrication (1st : 1989 : Texas A&M University) QC176.8.E4N32 1990 530.4 'll-dc20 89-17516 CIP Printed in the United States of America 89 90 91 92 9 8 7 6 5 4 3 2 1 Preface This book contains contributions presented at the first In- ternational Symposium on Nanostructure Physics and Fabrica- tion. The symposium was attended by 160 researchers from around the world, who met in College Station, Texas, on the campus of Texas A&M University from March 13 to 15, 1989. The purpose of the symposium was to bring together an inter- disciplinary group of specialists in nanometer scale fabrication, physics of mesoscopic systems, electronic transport, and mate- rials scientists and technologists to discuss the current status of nanometer scale electronic structures. The symposium was organized into eleven sessions of 28 oral presentations that spanned three days, and was accompa- nied by two lively late afternoon poster sessions in which approx- imately forty technical posters w rere presented. These sessions addressed topics on conceptual origins of nanostructures, lateral periodicity and confinement, nanoconstruction and phase coher- ent effects, quantum devices and transistors, equilibrium and nonequilibrium response in nanoelectronic structures, quantum ballistic transport, quantum dots, ballistic transport at quan- tum point contacts, and quantum constriction and narrow wares. In order to convey the many important ideas and the most recent results of the symposium's contributors, we have orga- nized this book into seven chapters. The first chapter represents a condensed overview in which we attempt to unify and sum- marize briefly the various individual contributions that follow in the remaining six chapters. Because the field is very new, we have also provided in the first chapter some introductory com- ments and background material that has led to the formation of the field. The book, therefore, provides the most up-to-date view of a very active and growing subject that is gaining wide interest. The book's origin and contents are for the most part a re- sult of the symposium's success, which in turn was a result of the efforts and many fine suggestions put forward by the Organiz- ing and Program Committee and the Advisory Committee. As always, in the background of any successful conference is a co- terie of students, research associates, and faculty colleagues who see that things get done. Our coterie consisted of the following individuals, whom we owe much gratitude: C. C. Andrews, K. G. Balke, M. G. Blain, C. J. Brumlik, R. N. Burns, Z. Cai, F. Cheng, J. F. Chepin, B. H. Chu, D. P. Dave, J. J. Garris, A. Roy-Ghatak, W. B. Kinard, W. R. Klima, P. S. Kobiela, J. Lei, F. Li, Y. X. Liu, J. R. McBride, E. C. Palm, M. A. Park, R. Pathak, B. Radie, L. R. Richards, G. Spencer, T. Szafranski, W. Szott, M. Tierney, R. Tsumura, A. L. Vandervort, C. Wang, and W. K. Yue. We are indebted to Professor Glenn Agnolet for his many helpful suggestions, to Professors Wayne M. Saslow, Chia-Ren Hu, Joseph H. Ross, and Dr. John N. Randall for their help in judging the posters, and especially to the Publi- cations Secretary, Phil R. Reagan, for his invaluable assistance in organizing the conference proceedings. Each of the referees, who helped review the contributions, deserve much praise from us. Our greatest thanks and appreciation, however, goes to the Symposium Secretary, Mary J. Miller, who tackled innumerable details with great proficiency. Finally, financial support from our sponsors listed on a nearby page is gratefully acknowledged and in particular we thank Dr. Larry R. Cooper for his special interests in helping us secure the needed support. Mark A. Reed Wiley P. Kirk Dallas, Texas College Station, Texas May 1989 May 1989 Organizing and Program Committee Wiley P. Kirk,Chairman,Texas A&M University Mark A. Reed, Co-Chair, Texas Instruments Robert T. Bate, Texas Instruments Alex L. de Lozanne, University of Texas, Austin John N. Randall, Texas Instruments Mark H. Weichold, Texas A&M University Advisory Committee Leroy Chang, IBM, T. J. Watson Research Center Larry R. Cooper, Office of Naval Research John D. Dow, University of Notre Dame Robert C. Dynes, AT&T Bell Laboratories David K. Ferry, Arizona State University Karl Hess, University of Illinois Klaus v. Klitzing, Max Planck Institut, Stuttgart Michael Pepper, University of Cambridge William J. Skocpol, Boston University Horst L. Stornier, AT&T Bell Laboratories Michael A. Stroscio, U. S. Army Research Office Gerald L. Witt, Air Force Office of Scientific Research Sponsors Office of Naval Research Air Force Office of Scientific Research Defense Advanced Research Projects Agency U.S. Army Research Office American Vacuum Society, Texas Chapter Texas Instruments, Inc. Texas A&M University Physics Department Electrical Engineering Department College of Science Texas Engineering Experiment Station Industrial Sponsors and Exhibitors EKC Technology Grant Associates MKS Group Five Kurt J. Lesker Balzers Chapter 1 Overview and Background "At any rate, it seems that the laws of physics present no barrier to reducing the size of computers until bits are the size of atoms, and quantum behavior holds dominant sway." Richard P. Feynman (from "Quantum Mechanical Computers", Optics News, pp. 11-20, February 1985, published by the Optical Society of America.) OVERVIEW A ND B A C K G R O U ND Mark Λ. Reed Texas Instruments Incorporated Dallas, Texas 75265 Wiley P. Kirk Texas AfcM University College Station, Texas 77843 1. I N T R O D U C T I ON In 1957 J. R. Schrieffer [1] suggested that the narrow confinement poten- tial of an inversion layer may lead to the observation of non-classical electron transport behavior. This was unambiguously demonstrated in 1966 [2,3] by low-temperature magnetotransport, and initiated an intense effort in the ex- ploration of 2-dimensional electrons gas (2DEG) systems. The compelling attraction of the field was and is the ability to observe macroscopic quan- tum size effects and (to a certain extent) control system parameters that determined these effects [4]. Until recently, only in areas of low-temperature physics has there been any opportunity to study and gain experience with macroscopic quantum mechanical effects. Unfortunately, the number of low- temperature systems available for study has been few and mostly limited to liquid and solid states of helium and a finite number of a few types of superconductors. Moreover, these low-temperatures systems always incorpo- rate rather complex many-body effects that make them exceedingly difficult to control and understand on a first principle basis. Now, however, we are rapidly approaching a level of solid-state structural fabrication in which the energy and length scales are such that macroscopic quantum effects are man- ifest. We have, for the first time, reached a stage where it is possible to observe and perhaps even control large scale quantum effects in a variety of materials and states of condensed matter. NANOSTRUCTURE PHYSICS 3 Copyright © 1989 by Academic Press, Inc. AND FABRICATION All rights of reproduction in any form reserved. ISBN 0-12-585000-X The advent of ultra-thin epitaxial film growth techniques ushered in the era of reduced dimensionality physics, and it became clear that heterojunc- tion interfaces with large energy band discontinuities were a reality. These structures are inherently two-dimensional; thus investigations concentrated on heterostructures, where quantum effects are due to confinement in the epitaxial direction; i.e., quantum wells (more properly, "quantum planes") which are 2-dimensional systems [5]. The ability to vary composition, band offset, periodicity, and other variables results in nearly limitless possibilities in creating structures for physical exploration as well as for electron and optical device applications. Within the last few years, advances in microfabrication technology have allowed laboratories around the world to impose additional lateral dimen- sions of quantum confinement on 2-dimensional systems with length scales approaching those of epitaxial lengths in the growth direction. The achieve- ment of quantum wires [6,7,8] and quantum dots [9] have demonstrated that electronic systems with different dimensionality are now available to the ex- perimentalist. The quantum limit of electronic transport has been demon- strated [10,11], leading to a fundamentally distinct approach to the under- standing of mesoscopic electronic systems. Yet as late as 1986, "low dimensional structures" implicitly meant 2DEGs or quantum wells. At the 1986 International Conference on the Physics of Semiconductors in Stockholm, Sweden, there were less than 10 papers (out of a total of 405 papers) on fabricated nanostructures. However, these few pa- pers framed the beginnings of a new era in semiconductor transport. One of the major motivational reasons for examining small electronic systems was the observation of "universal conductance fluctuations" and weak localization ef- fects in silicon [12] and GaAs [13] nanostructures. These works demonstrated that coherent and random quantum interference, respectively, are observable in few-electron systems, and perhaps could even be dominant in appropriate structures. However, fabrication processes and tolerances were not sufficiently well developed to create structures that would exhibit large quantum inter- ference or quantum size effects; the observations were at most small, noisy perturbations. A conceptually more pleasing investigation at the time, at least to trans- port physicists, was the observation of Aharonov-Bohm oscillations in small metallic ring structures [14]. These observations appeared to be the first clear observation of quantum interference of the electron wavefunction in a nanofabricated structure. At the time, there appeared to be little connection between this esoteric effect and conductance fluctuation work, except for their embodiment in small electronic systems. During this time, a renaissance was occurring in vertical electronic trans- port through multilayer heterostructures. Large quantum tunneling effects were achieved in resonant tunneling structures [15] nearly a decade after the initial (rather disappointing) investigations by Chang et al. [16]. The im- 4 portance of this renaissance was not the specific realization of the tunneling structure, but a realization that artificially-structured quantum states could indeed show nonclassical electronic transport. Around the same time, the achievement of ballistic transport (i.e., electronic transport in which carriers (electrons) traverse without undergoing a scattering event) in vertical hot- electron structures was reported [17,18]. The turning point in the understanding of nanometer scale electronic transport was the development of reliable semiconductor fabrication tech- niques on the nanometer scale, an example of which is the fabrication of semiconductor quantum wires [7], which allowed the fabrication of electronic systems in a totally new regime. The realization of ballistic structures had been done in the epitaxial dimension, but not in the lateral dimensions due to the small dimensional scales (tens of nanometers) involved. However, the advancement of electron beam lithography and the incorporation of this di- mensional scale onto high mobility 2DEGs allowed one, for the first time, to create structures that were smaller than the relevant length scales (elastic, inelastic, phase-breaking, etc). In this regime, quantum transport becomes dominant and the wave nature of the electron becomes apparent. An elegant example of the behavior of electrons on this length scale was the creation of electron "wraveguides" [8], which are surprisingly akin to their microwave counterparts that are nearly six orders of magnitude larger. If structures are created where the interference of electron waves are a dominant effect, how is the system measured? In such systems, the "contacts" to the system are no longer ideal - they are now by definition part of the entire (interacting and interfering) electron wave system. Thus, electrical leads become intractably invasive [19]. This topic has spawned an active area of current research, especially with regard to measurements in the quantum limit. An obvious area of interest is the limit of electrical conduction; i.e., what is the relevant physics when the number of carriers (or current carrying chan- nels) in the system are countably small. Though this limit was theoretically explored by Landauer over 30 years ago, the realization of such systems has only now been possible. The recent discovery of quantized conductance in bal- listic "point contacts" [10,11] , which is predicted by the Landauer formalism, has opened up a new era of nanostructure physics where one can fabricate nanostructures whose behavior is dominated by quantum interference effects. This new capability has enthused the experimentalist and theorist alike, an excitement akin to the advent of quantum well technology, with limitless pos- sibilities for physical exploration and device technology on the nanoscale. It is within this context that the International Symposium on Nanostructure Physics and Fabrication was held. 5

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