Nanosized Tubular Clay Minerals Halloysite and Imogolite

758 Pages·2016·62.17 MB·English

by  Peng Yuan, Antoine Thill and Faïza Bergaya (Eds.)

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Dedication
To the memory of my father, Xueqian Yuan, for the
10th anniversary of his passing away.
Peng Yuan
v
Contributors
NumbersinParenthesesindicatethepagesonwhichtheauthor’scontributionsbegin.
E. Abdullayev (554), Ennis-Flint Science and Technology Center, Thomasville, NC,
UnitedStates
C.Aguzzi (708),University ofGranada, Granada, Spain
M.S. Amara (254), Laboratoire de Physique des Solides, CNRS, Univ. Paris-Sud,
Universite´ Paris-Saclay,Orsay Cedex, France
N. Arancibia-Miranda (458), Center for the Development of Nanoscience and
Nanotechnology, CEDENNA; Facultad de Qu´ımica y Biolog´ıa, Universidad de
Santiagode Chile,Santiago, Chile
I.Basile-Doelsch(49),Aix-MarseilleUniversite´,CNRS,IRD,CEREGEUM34,USC
INRA,Aix en Provence, France
L.Belloni(361),LIONS,NIMBE,CEA,CNRS,Universite´Paris-Saclay,CEA/Saclay,
Gif-sur-Yvette,France
F. Bergaya (1, 735), CNRS—ICMN (Interfaces, Confinement, Mate´riaux et
Nanostructures),Orle´ansCedex 2, France
B.Bonelli(279,672),INSTMUnitofTorinoPolitecnico,PolitecnicodiTorino,Turin,
Italy
E.Carazo(708),University ofGranada, Granada, Spain
P.Cerezo (708), Universityof Granada, Granada, Spain
P. Davidson (308), Laboratoire de Physique des Solides, UMR8502, CNRS, Univ.
Paris-Sud,Universite´ Paris-Saclay, Orsay Cedex,France
I. Dozov (308), Laboratoire de Physique des Solides, UMR8502, CNRS, Univ.
Paris-Sud,Universite´ Paris-Saclay, Orsay Cedex,France
P. Du (167), CAS Key Laboratory of Mineralogy and Metallogeny / Guangdong
ProvincialKeyLaboratoryofMineralPhysicsandMaterials,GuangzhouInstitute
ofGeochemistry, ChineseAcademy ofSciences (CAS), Guangzhou, China
H.A. Duarte (331), Grupo de Pesquisa em Qu´ımica Inorg^anica Teo´rica (GPQIT),
InstitutodeCi^enciasExatas,UniversidadeFederaldeMinasGerais(UFMG),Belo
Horizonte,MG, Brazil
M.Escudey(458),CenterfortheDevelopmentofNanoscienceandNanotechnology,
CEDENNA; Facultad de Qu´ımica y Biolog´ıa, Universidad de Santiago de Chile,
Santiago,Chile
xviii
Contributors xix
A. Fernandez-Martinez (202), ISTerre, CNRS; ISTerre, Univ. Grenoble Alpes,
Grenoble, France
E. Garrone (672), INSTM Unit of Torino Politecnico, Politecnico di Torino, Turin,
Italy
B.C. Guo (509),SouthChina Universityof Technology, Guangzhou, China
Y.Higaki(628),InstituteforMaterialsChemistryandEngineering,andInternational
InstituteforCarbon-NeutralEnergyResearch(WPI-I2CNER),KyushuUniversity,
Fukuoka, Japan
J. Huang(509), SouthChina Universityof Technology, Guangzhou, China
M.-C. Jaurand (485), Institut National de la Sante´ et de la Recherche Me´dicale
(INSERM), UMR-S 116, 27 rue Juliette Dodu; Universite´ Paris Descartes, Labex
Immuno-Oncology, SorbonneParis Cite´,Faculte´ de Me´decine,Paris, France
E. Joussein (12), Universite´ de Limoges, FST, GRESE ‘Groupement de Recherche
Eau Sol Environnement’,Limoges,France
J.T. Kloprogge (115), School of Earth Sciences, The University of Queensland,
St.Lucia, QLD, Australia
T.Kogure(92),GraduateSchoolofScience,TheUniversityofTokyo,Tokyo,Japan
P. Launois (254), Laboratoire de Physique des Solides, CNRS, Univ. Paris-Sud,
Universite´ Paris-Saclay,Orsay Cedex,France
C.Levard(49),Aix-MarseilleUniversite´,CNRS,IRD,CEREGEUM34,USCINRA,
Aix en Provence, France
D. Liu (167), CAS Key Laboratory of Mineralogy and Metallogeny / Guangdong
ProvincialKeyLaboratoryofMineralPhysicsandMaterials,GuangzhouInstitute
of Geochemistry, ChineseAcademyof Sciences (CAS), Guangzhou, China
Y. Lvov(554), Institutefor Micromanufacturing, Louisiana Tech University, Ruston,
LA,United States
W. Ma (628), Institute for Materials Chemistry and Engineering, and International
InstituteforCarbon-NeutralEnergyResearch(WPI-I2CNER),KyushuUniversity,
Fukuoka, Japan
J.Matusik(409,606),FacultyofGeology,GeophysicsandEnvironmentalProtection,
AGH University ofScience and Technology,Krakow, Poland
L.J. Michot (202), Sorbonne Universite´s, UPMC Univ. Paris 06, CNRS, Laboratoire
PHENIX, Case 51,4 placeJussieu, Paris,France
J.Niu(387),SchoolofMaterialsScienceandEngineering,ChinaUniversityofMining
and Technology, Xuzhou,PRChina
J. Ouyang (67), Centre for Mineral Materials, School of Minerals Processing and
Bioengineering; Key Laboratory for Mineral Materials and Application of Hunan
Province,CentralSouthUniversity,Changsha,China
E. Paineau (254), Laboratoire de Physique des Solides, CNRS, Univ. Paris-Sud,
Universite´ Paris-Saclay,Orsay Cedex,France
xx Contributors
O.Poncelet (726),CEA DRT/LITEN/DTMN, GrenobleCedex 9,France
S. Rouzie`re (254), Laboratoire de Physique des Solides, CNRS, Univ. Paris-Sud,
Universite´ Paris-Saclay,Orsay Cedex, France
G.Sandri(708),University ofPavia, Pavia, Italy
J.Skrzypski (726),CEA DRT/LITEN/DTMN, GrenobleCedex 9,France
A. Takahara (628), Institute for Materials Chemistry and Engineering, and
International Institute for Carbon-Neutral Energy Research (WPI-I2CNER),
KyushuUniversity, Fukuoka, Japan
D. Tan (167), Key Laboratory of Solid Waste Treatment and Resource Recycle,
MinistryofEducation,SouthwestUniversityofScienceandTechnology,Mianyang;
CASKeyLaboratoryofMineralogyandMetallogeny/GuangdongProvincialKey
LaboratoryofMineralPhysicsandMaterials,GuangzhouInstituteofGeochemistry,
ChineseAcademyofSciences(CAS),Guangzhou,China
Z.H. Tang (509),South China Universityof Technology, Guangzhou,China
A. Thill (1, 223, 361, 429, 735), Laboratoire Interdisciplinaire sur l’Organisation
Nanome´triqueetSupramole´culaire,NIMBE,CEA,CNRS,UniversityParis-Saclay,
Paris,France
C.Viseras (708),Universityof Granada, Granada, Spain
H. Yang (67), Centre for Mineral Materials, School of Minerals Processing and
Bioengineering; Key Laboratory for Mineral Materials and Application of Hunan
Province,Central SouthUniversity, Changsha, China
P. Yuan (1, 137, 167, 735), CAS Key Laboratory of Mineralogy and Metallogeny /
GuangdongProvincialKeyLaboratoryofMineralPhysicsandMaterials,Guangzhou
InstituteofGeochemistry,ChineseAcademyofSciences(CAS),Guangzhou,China
X.H.Zhang(509),South ChinaUniversity ofTechnology, Guangzhou, China
Y. Zhang (67), Centre for Mineral Materials, School of Minerals Processing and
Bioengineering; Key Laboratory for Mineral Materials and Application of Hunan
Province,Central SouthUniversity, Changsha, China
Acknowledgements
The editors, Peng Yuan, Antoine Thill and Faiza Bergaya, would like to
acknowledge all the authors of this volume, who have summarized the vast
amount of information in their respective fields of expertise. They also thank
the anonymous reviewers who helped to improve the quality of the chapters.
Peng Yuan would like to express great gratitude to Faiza Bergaya, the
investigator of this volume, for her invitation to act as first editor of this
book. He genuinely thanks her for their long-term, close scientific collabo-
ration focused on clay science, especially for the collaborative research on
tubular clay minerals performed in recent years. Peng Yuan also appreci-
ates the kind hospitality of the family of Faiza Bergaya, her husband,
Badreddine, and her two daughters, Sonia and Rym, during his stay for
3 months in Orleans. Thanks to them, his trip to France was really enjoy-
able and memorable. Peng Yuan deeply appreciates the kind collaboration
of Antoine Thill for coediting this volume. In addition, he cherishes the
happy memory of a coffee break at sunny noontime in Orleans, when the
three coeditors brainstormed together to share great inspirations. Finally,
he is grateful to the enthusiastic encouragement of his colleagues, students
and friends, who gave much assistance since this project began two-and-
a-half years ago.
AntoineThillexpresseshisgratitudetoFaizaBergaya,whoinvitedhimto
act as a coeditor of this volume in July 2013 in Brazil. This foolish task was
accepted with pleasure (maybe with the help of some pin˜a coladas that eased
thestressfromtheforthcomingworkload).Hegreatlyappreciatedthiscollab-
oration and learned a lot from the experience of working on this edition.
I want also to thank Peng Yuan, who was a brilliant and efficient first editor
for this book. I wish I could have spent more time with him, and I hope that
the sunny brainstorming afternoon in Orleans will soon lead to common
projects.
FaizaBergayaisdeeplygratefultoherhusbandforhispatienceduringthe
longhoursshespentinfrontofthecomputer.Shewishesalsotoacknowledge
Peng Yuan and Antoine Thill for accepting her proposal to share the task of
editing this book, and also CNRS for giving her the opportunity as Director
Emeritus, to ensure continuity of her work as Series Editor of the Develop-
ments in Clay Science.
xxi
xxii Acknowledgements
Theauthor(s)ofsomechapterswishtopresentsomeacknowledgementsin
the following:
l The author of Chapter 2 expresses acknowledgement to the main halloy-
site producers for provided samples: Imerys Tableware NZ Ltd. and
Imerys Ceramics Centre, Limoges France for the Matauri Bay sample,
PTH Intermark for the Dunino one, Esan Eczacibasi for the Turkish one,
andfinallyAppliedMineralsInc.fortheDragonitesamples.Characteriza-
tion data were performed using the CarMaLim platforms in the European
Ceramic Center, Limoges, France.
l TheauthorsofChapter4thanktheNationalScienceFundforDistinguished
Young Scholars (51225403), the National Natural Science Foundation of
China (51304242), the Postdoctoral Science Foundation of Central South
University (155219) and the Hunan Provincial Co-Innovation Centre for
Clean and Efficient Utilization of Strategic Metal Mineral Resources for
their support.
l The authorsof Chapters 7 and 8 are grateful tothe financial support from
the Natural Scientific Foundation of China (Grant Nos. 41472045,
41072032 and 41502027), the National Key Technology Research and
Development Program of the Ministry of Science and Technology of
China (Grant No. 2013BAC01B02) and the Team Project of Natural Sci-
ence Foundation of Guangdong Province, China (S2013030014241).
l One of the authors of Chapter 11, Mohamed Salah Amara, is grateful to
C’Nano Ile de France for financial support of his PhD work. Germanium
imogolite nanotubes were elaborated at LIONS/CEA, under the supervi-
sion of Antoine Thill.
l The authors of Chapter 13 are deeply indebted to M.S. Amara, M. Bacia-
Verloop, L. Belloni, D. Constantin, J.C. Gabriel, M.E. Krapf, P. Launois,
C. Levard, P. Levitz, N. Matskova, E. Paineau, O. Poncelet, S. Rouzie`re,
J. Rose, A. Thill and M. Zinsmeister for their help with the experiments
and for helpful discussions.
l The author of Chapter 14 would like to thank the Brazilian agencies Fun-
dac¸a˜o de Amparo à Pesquisa de Minas Gerais (FAPEMIG), Coordenac¸a˜o
de Aperfeic¸oamento de Pessoal de N´ıvel Superior (CAPES) and Conselho
Nacional para o Desenvolvimento Cient´ıfico e Tecnolo´gico (CNPq) for the
continuing support of their research. Acknowledgment is also due to the
BrazilianinitiativeNationalInstituteofScienceandTechnologyforMineral
Resources, Water and Biodiversity, INCT-ACQUA for their support.
l The author of Chapter 16 acknowledges the financial support from the
National Natural Science Foundation of China (Grant No. 41502032),
the Natural Science Foundation of Jiangsu Province, China (BK20140212)
and the Fundamental Research Funds for the Central Universities
(2012QNA08).
Acknowledgements xxiii
l The author of Chapters 17 and 23 is thankful to all coworkers for help
in analyses and their interpretation. The research regarding morphology
transformation of Polish kaolin-group minerals shown in Chapter 17 was
conducted under supervision of Professor Krzysztof Bahranowski
(AGH-UST) and involved several scientists from Krako´w (Poland): AGH
UniversityofScienceandTechnology(AGH-UST)andInstituteofCataly-
sis and Surface Chemistry (Polish Academy of Sciences). The research on
adsorption properties of Polish halloysite from Dunino deposits reported
in Chapter 23 resulted from teamwork which gathered several scientists
from Krako´w (Poland): AGH-UST and Polish Academy of Sciences. The
author thanks Dr Jo´zef Sołtys, Managing Director of the Intermark Com-
pany,forsupplying the mineralsamples fromtheDuninodeposits. Finally,
he is especially grateful to students who participated in the research: Anna
Koteja, Lucyna Matykowska, Anna S´mietana (Ws´cisło), Paulina Maziarz
and Anna Prokop. Support by the Polish National Science Centre (Grant
No. DEC-2011/01/ST10/06814) is also acknowledged.
l The authors of Chapter 21 gratefully acknowledge the National Basic
Research Program of China (Grant No. 2015CB654703), and National
Natural Science Foundation (Grant No. 51222301, 51333003, 51473050
and U1462116) for financial supports.
l TheauthorsofChapter 24acknowledges the financial supportofaGrant-
in-Aid for Scientific Research (A) (No. 19205031) and (No. 26248053)
from the Japan Society for the Promotion of Science. The synchrotron
radiation experiments were performed at BL02B2 in SPring-8 with the
approval of the JASRI (Proposal No. 2010A1454).
l The authors of Chapter 26 thank the Andalusian project RNM1897 and
Andalusian group CTS-946 for the financial support.
P. Yuan, A. Thill and F. Bergaya
December 2015
Chapter 1
General Introduction
P. Yuana,*, F. Bergayab and A. Thillc
aCASKeyLaboratoryofMineralogyandMetallogeny/GuangdongProvincialKeyLaboratoryof
MineralPhysicsandMaterials,GuangzhouInstituteofGeochemistry,ChineseAcademyof
Sciences(CAS),Guangzhou,China
bCNRS-ICMN(Interfaces,Confinement,Mate(cid:1)riauxetNanostructures),Orle(cid:1)ansCedex2,France
cLaboratoireInterdisciplinairesurl’OrganisationNanome(cid:1)triqueetSupramole(cid:1)culaire,NIMBE,
CEA,CNRS,UniversityParis-Saclay,Paris,France
*Correspondingauthor:e-mail:[email protected]
The development of clay science in recent decades has benefited substantially
from its intermingling with a number of related scientific disciplines, which
have opened up new frontiers in the multidisciplinary and interdisciplinary
research of this science. The development of modern characterisation techni-
ques and computational methods enabled advances in our knowledge of the
structure and properties of clay minerals at the molecular and even atomic
scales. With the revelation ofthe variety and versatility of various clay miner-
als, our understanding of the distribution and roles of clay minerals in Earth
systems has become deeper. Furthermore, the applications of clay minerals in
a variety of fields can be extended, and novel clay-based materials developed.
The research on and applications of nanosized tubular clay minerals per-
fectly exemplifies the above-mentioned multidisciplinary features. Nanosized
tubular clay minerals, as the name implies, are clay minerals with tubular
nanostructures, which means that they have at least one dimension between
1 and 100nm (Annabi-Bergaya, 2008; Schoonheydt and Bergaya, 2011) and
ahollow tubularstructure.Attentionwaspaid tothevery smalltubular struc-
tureofmineralslongbeforetheconceptof‘nanotechnology’wasfirstdefined
and used in the 1970s (Hochella et al., 2008), and the concept of ‘nano’ and
the term ‘nanotube’ in the context of materials science have been popular
sincethe1990s(Iijima,1991).Already,Pauling(1930)hadproposedtheexis-
tence of cylindrical structures formed by minerals in nature. Based on his
observations of the structure of asbestos-related minerals, he suggested that
a structural mismatch will exist between the layers, leading to structural
deformation and curvature if the two faces of a mineral are not symmetrical.
Subsequently,beginninginthe1950s,thestructuresofnanosizedtubularclay
DevelopmentsinClayScience,Vol.7.http://dx.doi.org/10.1016/B978-0-08-100293-3.00001-7
©2016ElsevierLtd.Allrightsreserved. 1
2 CHAPTER 1 GeneralIntroduction
minerals, such as chrysotile, halloysite and imogolite (Bates et al., 1950a,b;
Cradwick et al., 1972), have been identified using microscopic and spectro-
scopic methods. However, for a long time thereafter, there was very little
research on nanosized tubular clay minerals (Yuan et al., 2015), and relevant
papers were published only occasionally.
The renewed interest in nanosized tubular clay minerals can be partially
attributed to the boom in studies on nanostructured materials and related
applications since the 1990s, when the first observation of carbon nanotubes
(CNT) was reported (Iijima, 1991) and several nanotube materials, eg,
MoS , WS and BN (Feldman et al, 1995), were synthesized. In fact, it was
2 2
proposed that many inorganic compounds (eg, the dichalcogenides of many
group IV and V metals) possess layered structures comparable to that of
graphite and could possibly form nanotubes, and these nanotubes have found
many important applications, such as in catalysis, inorganic polymer nano-
composites and adsorption (Tenne, 2014). Various synthetic strategies have
been developed for the synthesis of such inorganic nanotubes. However, the
synthesis of nanotubes is somewhat more difficult than that of porous
compounds.Forexample,whenfacileself-assemblymethodsarenotstraight-
forward with respect to the desired nanotube product (particularly its
morphology),templatemethodshavebeenemployedusingCNTasconsump-
tivetemplatestoobtainthenanotubestructuresofmetaloxides(Ajayanetal.,
1995). The time-consuming preparation and production of small amounts of
nanotubes result in high material costs and, accordingly, limit their actual
applications. By contrast, the naturally occurring analogs of manufactured
nanotubes(eg,nanosizedtubularclayminerals)aredistinctintheireconomic
viability and environmental benefits in comparison with artificially synthe-
sized tubular materials such as CNT and metal oxide nanotubes. Therefore,
it is not surprising that nanosized tubular clay minerals are again attracting
the attention of researchers.
The interest in nanosized tubular clay minerals is driven not only by the
increasing demand for advanced nanotube materials, but also by the desire
to understand the geological and environmental effects of nanominerals
on the local, regional and even global scale. According to the definition of
nanogeoscience that has developed over the past 20 years, nanosized tubular
clay minerals should be classified as typical nanominerals, based on a classi-
fication scheme proposed by Hochella et al. (2008). In this classification,
nanominerals exist as one of three types of nanoscale minerals (nanorods,
nanosheets and nanoparticles); that is, there are no bulk equivalents of
nanominerals. By contrast, mineral nanoparticles that exist in the nano-range
can also exist as larger materials. Because of the high specific surface area
and strong surface reactivity of nanominerals and mineral nanoparticles,
measuring and elucidating their roles and behaviours—ie, their origin
(biotic or abiotic, natural or anthropogenic), geographic distribution, relevant