Advances in Atom and Single Molecule Machines Series Editor: Christian Joachim Xavier Baillin Christian Joachim Gilles Poupon Editors Nanopackaging: From Nanomaterials to the Atomic Scale Proceedings of the 1st International Workshop on Nanopackaging, Grenoble 27–28 June 2013 Advances in Atom and Single Molecule Machines Series editor Christian Joachim, Toulouse, France Editorial Board L. Grill F. Jelezko D. Martrou T. Nakayama G. Rapenne F. Remacle K. Ohmori More information about this series at http://www.springer.com/series/10425 Xavier Baillin Christian Joachim (cid:129) Gilles Poupon Editors Nanopackaging: From Nanomaterials to the Atomic Scale Proceedings of the 1st International Workshop on Nanopackaging, – Grenoble 27 28 June 2013 123 Editors Xavier Baillin Gilles Poupon CEAGrenoble CEAGrenoble Grenoble Grenoble France France Christian Joachim CEMES-CNRS University PaulSabatier Toulouse France ISSN 2193-9691 ISSN 2193-9705 (electronic) Advances in AtomandSingle Molecule Machines ISBN978-3-319-21193-0 ISBN978-3-319-21194-7 (eBook) DOI 10.1007/978-3-319-21194-7 LibraryofCongressControlNumber:2015943834 SpringerChamHeidelbergNewYorkDordrechtLondon ©SpringerInternationalPublishingSwitzerland2015 Thisworkissubjecttocopyright.AllrightsarereservedbythePublisher,whetherthewholeorpart of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission orinformationstorageandretrieval,electronicadaptation,computersoftware,orbysimilarordissimilar methodologynowknownorhereafterdeveloped. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publicationdoesnotimply,evenintheabsenceofaspecificstatement,thatsuchnamesareexemptfrom therelevantprotectivelawsandregulationsandthereforefreeforgeneraluse. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authorsortheeditorsgiveawarranty,expressorimplied,withrespecttothematerialcontainedhereinor foranyerrorsoromissionsthatmayhavebeenmade. Printedonacid-freepaper SpringerInternationalPublishingAGSwitzerlandispartofSpringerScience+BusinessMedia (www.springer.com) Preface Single atom and molecule manipulations are now possible thanks to the scanning tunnelingmicroscope(STM)anditsderivativesopeninganewtechnologicalfield, named “Atom Technology” with the objective to produce one-day atomic scale logic circuits. STM operates in ultra-high vacuum (UHV) and thanks to its picometerscaleprecision,isabletoconstructorpatternanatomicscalecircuitona specific surface. The electronic chip such achieved and connected will be only suitableforinsituoperationintheUHV.Therequirementforfutureapplicationsis to get a standalone chip, similar to electronics ones currently produced. Consequently, it clearly appears a special need for developing a dedicated pack- aging technology for this new kind of chip. The most constraining specification concernstheUHVcontrolinside thepackage. Moreover,thesurfacequality needs to as perfect as possible (atomic roughness and large terraces) with a controlled surface structure and material band gap suitable for atom by atom manipulations. Among the available existing materials, silicon (100) wafers, commonly used in microelectronicsmanufacturing,areverypromisingbecausetheyaresatisfyingthe requirement of surface quality and benefit from the very important know-how developed in the microelectronics industry. The first exploration of such a nano-packaging technology has been launched with the Integrated European Project AtMol on January 1, 2011. A first interna- tional AtMol workshop took place at MINATEC, France, on June 2013 with participantscomingfromuniversitylaboratories,researchinstitutes,andindustries. This volume compiles most of the contributions presented during this event. Besides the first driver for nano-packaging as described above, this workshop was also opened to a second trend which concerns nanomaterials for microelec- tronics. Nanomaterials bring new solutions for detection not only in sensor appli- cation or in passive components technology, but also in improving packaging of actual microelectronics components. In particular, CNT could be a solution for highlyelectricallyandthermallyconductiveinterconnections.CNTincorporatedin an insulator matrix could also make the composite conductor. Biomaterials also appear as a new solution for nanoscale interconnections. By analyzing actual and future microelectronics and packaging requirements, it seems that solutions could v vi Preface befoundattheinterfacebetweenatop-downapproachlyingonsiliconandatomic scale technologies and a bottom-up approach consisting in the integration of functionalized nano-objects. We thank the European Commission’s ICT-FET program and the staff of Springer Verlag for their help in producing this book. The organizing committee also wishes to thank all the participants for their fantastic participation to the workshop. Xavier Baillin Christian Joachim Gilles Poupon Contents Utilization of Peridynamic Theory for Modeling at the Nano-Scale . . . 1 E. Oterkus, C. Diyaroglu, N. Zhu, S. Oterkus and E. Madenci DNA Metallization Processes and Nanoelectronics. . . . . . . . . . . . . . . . 17 Arianna Filoramo EvaluationofLeakageCurrentin1-DSilicon Dangling-Bond Wire Due to Dopants. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33 R. Robles, M. Kepenekian and N. Lorente Direct Integration of Carbon Nanotubes in Si Microsystems . . . . . . . . 41 Knut E. Aasmundtveit Nanopackaging Requests for Atomic Scale Circuits and Molecule-Machines . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 Christian Joachim Single-Crystal Au Triangles as Reconfigurable Contacts for Atomically Smooth Surfaces: Ultra-High Vacuum Transfer-Printing. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 83 Cedric Troadec, René Heimbuch, Deng Jie, Olga Neucheva, Ramesh Thamankar, Yap Tiong Leh and Christian Joachim Site-SelectiveSelf-AssemblyofNano-ObjectsonaPlanarSubstrate Based on Surface Chemical Functionalization. . . . . . . . . . . . . . . . . . . 93 FranciscoPalazon,PedroRojoRomeo,AliBelarouci,CélineChevalier, HassanChamas,ÉlianeSouteyrand,AbdelkaderSouifi,YannChevolot and Jean-Pierre Cloarec vii viii Contents Silicon Technologies for Nanoscale Device Packaging . . . . . . . . . . . . . 113 AurélieThuaire,Gaëlle LeGac,GuillaumeAudoit,FrançoisAussenac, Caroline Rauer, Emmanuel Rolland, Jean-Michel Hartmann, Anne-Marie Charvet, Hubert Moriceau, Pierrette Rivallin, Patrick Reynaud, Severine Cheramy, Nicolas Sillon and Xavier Baillin Designing Carbon Nanotube Interconnects for Radio Frequency Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 137 Christophe Brun, Chin Chong Yap, Dominique Baillargeat and Beng Kang Tay Packaging of Buckyballs/Buckytubes in Transparent Photo-Active Inorganic Polymers: New Hope in the Area of Electronics and Optoelectronics. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155 Radhaballabh Debnath Novel Nanostructured Passives for RF and Power Applications: Nanopackaging with Passive Components. . . . . . . . . . . . . . . . . . . . . . 175 P. Markondeya Raj, Parthasarathi Chakraborti, Dibyajat Mishra, Himani Sharma, Saumya Gandhi, Srikrishna Sitaraman and Rao Tummala Utilization of Peridynamic Theory for Modeling at the Nano-Scale E. Oterkus, C. Diyaroglu, N. Zhu, S. Oterkus and E. Madenci Abstract Peridynamic theory is a new continuum mechanics formulation that has several advantages over the traditional approaches, such as Classical Continuum Mechanics (CCM) and Molecular Dynamics (MD). Due to its length-scale parameter, horizon, it is capable of capturing phenomena occurring at different length scales, including the nano-scale. Furthermore, van der Waals forces can be represented in a straightforward manner using a buffer-layer approach. In this chapter, various demonstration problems are presented to show the capability of peridynamics at the nano-scale, including nano-indentation and failure analysis of graphene sheets. 1 Introduction Traditionally,thereexisttwomainapproachestosimulatethemechanicalbehavior of materials at the nano-scale. The first approach is based on Classical Continuum Mechanics (CCM) when the continuum assumption is valid. When nano-scale effects become significant, it is no longer applicable since it does not have a length-scale parameter. Furthermore, its equation of motion is not suitable for problems including discontinuities since the spatial derivatives are not defined in such cases. The second approach is based on Molecular Dynamics (MD). It is a powerful tool as long as the interactions between atoms and molecules are well defined.However,evenwithcurrentpowerfulsupercomputers,thetotalsimulation time and size of the models are still limited. Therefore, it is necessary to use a methodology that is based on continuum mechanics and have a length-scale E.Oterkus(&)(cid:1)C.Diyaroglu(cid:1)N.Zhu DepartmentofNavalArchitecture,OceanandMarineEngineering, UniversityofStrathclyde,100MontroseStreet,GlasgowG40LZ,UK e-mail:[email protected] S.Oterkus(cid:1)E.Madenci DepartmentofAerospaceandMechanicalEngineering,UniversityofArizona, 1130N.MountainAvenue,Tucson,AZ85721,USA ©SpringerInternationalPublishingSwitzerland2015 1 X.Baillinetal.(eds.),Nanopackaging:FromNanomaterials totheAtomicScale,AdvancesinAtomandSingleMoleculeMachines, DOI10.1007/978-3-319-21194-7_1