Nano/Micro-Structured Materials for Energy and Biomedical Applications: Latest Developments, Challenges and Future Directions PDF
Preview Nano/Micro-Structured Materials for Energy and Biomedical Applications: Latest Developments, Challenges and Future Directions
Bingbing Li Editors Tifeng Jiao Nano/Micro- Structured Materials for Energy and Biomedical Applications Latest Developments, Challenges and Future Directions Nano/Micro-Structured Materials for Energy and Biomedical Applications Bingbing Li Tifeng Jiao (cid:129) Editors Nano/Micro-Structured Materials for Energy and Biomedical Applications Latest Developments, Challenges and Future Directions 123 Editors BingbingLi TifengJiao Department ofChemistry andBiochemistry Schoolof Environmental andChemical Central Michigan University Engineering Mount Pleasant,MI Yanshan University USA Qinhuangdao China ISBN978-981-10-7786-9 ISBN978-981-10-7787-6 (eBook) https://doi.org/10.1007/978-981-10-7787-6 LibraryofCongressControlNumber:2017962543 ©SpringerNatureSingaporePteLtd.2018 Thisworkissubjecttocopyright.AllrightsarereservedbythePublisher,whetherthewholeorpart of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission orinformationstorageandretrieval,electronicadaptation,computersoftware,orbysimilarordissimilar methodologynowknownorhereafterdeveloped. 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Theregisteredcompanyaddressis:152BeachRoad,#21-01/04GatewayEast,Singapore189721,Singapore Contents 1 Polymer Nanodielectrics: Current Accomplishments and Future Challenges for Electric Energy Storage . . . . . . . . . . . . . 1 Guoqiang Zhang, Elshad Allahyarov and Lei Zhu 2 Magnetoelectric Effect in Single-Phase Multiferroic Materials . . . . . 49 Yanjie He, James Iocozzia and Zhiqun Lin 3 Recent Advances in Electrospun Poly(ɛ-caprolactone)-Based Materials and Their Biomedical Applications. . . . . . . . . . . . . . . . . . 77 Lin Wang, Reem A. Ghubayra, Adam J.-P. Bauer, Mir Hadi R. Kondelaji, Zachary B. Grim and Bingbing Li 4 Biomorphic Mineralization-Mediated Self-assembly Nanomaterial and Activity Study . . . . . . . . . . . . . . . . . . . . . . . . . . . 131 Dawei Gao, Tian Yin, Kexin Bian and Ruiyan Zhu 5 Polymer Nanostructures Using Nanoporous Templates. . . . . . . . . . . 165 Chun-Wei Chang, Hao-Wen Ko and Jiun-Tai Chen 6 Peptide-Based Hydrogels/Organogels: Assembly and Application. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205 Juan Wang and Xuehai Yan 7 Self-assembled Graphene/Graphene Oxide-Based Nanocomposites Toward Photodynamic Therapy Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 227 Tifeng Jiao, Ruirui Xing, Lexin Zhang and Jingxin Zhou 8 Nanostructured Materials in Tissue Engineering . . . . . . . . . . . . . . . 255 Thomas W. Eyster and Peter X. Ma v Contributors Elshad Allahyarov Center of Layered Polymeric Systems (CLiPS) and Department of Macromolecular Science and Engineering, Case Western Reserve University, Cleveland, OH, USA; Institut für Theoretische Physik II, Weiche Materie, Heinrich-Heine Universität, Düsseldorf, Germany; Theoretical Department, Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow, Russia AdamJ.-P.Bauer DepartmentofChemistryandBiochemistry,CentralMichigan University, Mount Pleasant, MI, USA Kexin Bian Applying Chemistry Key Laboratory of Hebei Province, Yanshan University, Qinhuangdao, China Chun-Wei Chang Department of Applied Chemistry, National Chiao Tung University, Hsinchu, Taiwan Jiun-Tai Chen Department of Applied Chemistry, National Chiao Tung University, Hsinchu, Taiwan ThomasW.Eyster DepartmentofBiologicandMaterialsSciences,Universityof Michigan, Ann Arbor, MI, USA Dawei Gao Applying Chemistry Key Laboratory of Hebei Province, Yanshan University, Qinhuangdao, China Reem A. Ghubayra Department of Chemistry and Biochemistry, Central Michigan University, Mount Pleasant, MI, USA Zachary B. Grim Department of Chemistry and Biochemistry, Central Michigan University, Mount Pleasant, MI, USA Yanjie He School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA, USA vii viii Contributors Tifeng Jiao Hebei Key Laboratory of Applied Chemistry, School of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, China; State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, China JamesIocozzia SchoolofMaterialsScienceandEngineering,GeorgiaInstituteof Technology, Atlanta, GA, USA Hao-WenKo DepartmentofAppliedChemistry,NationalChiaoTungUniversity, Hsinchu, Taiwan Mir Hadi R. Kondelaji Department of Chemistry and Biochemistry, Central Michigan University, Mount Pleasant, MI, USA Bingbing Li Department of Chemistry and Biochemistry, Central Michigan University, Mount Pleasant, MI, USA Zhiqun Lin School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA, USA Peter X. Ma Department of Biologic and Materials Sciences, University of Michigan, Ann Arbor, MI, USA; Department of Biomedical Engineering, University of Michigan, Ann Arbor, MI, USA; Macromolecular Science and Engineering Center, University of Michigan, Ann Arbor, MI, USA Juan Wang State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, China Lin Wang Department of Chemistry and Biochemistry, Central Michigan University,MountPleasant,MI,USA;BeijingKeyLaboratoryforGreenCatalysis and Separation, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing, People’s Republic of China Ruirui Xing Hebei Key Laboratory of Applied Chemistry, School of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, China; State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, China Xuehai Yan State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, China; Center for Mesoscience, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, China Tian Yin Applying Chemistry Key Laboratory of Hebei Province, Yanshan University, Qinhuangdao, China GuoqiangZhang CenterofLayeredPolymericSystems(CLiPS)andDepartment of Macromolecular Science and Engineering, Case Western Reserve University, Cleveland, OH, USA Contributors ix Lexin Zhang Hebei Key Laboratory of Applied Chemistry, School of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, China Jingxin Zhou Hebei Key Laboratory of Applied Chemistry, School of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, China Lei Zhu Center of Layered Polymeric Systems (CLiPS) and Department of Macromolecular Science and Engineering, Case Western Reserve University, Cleveland, OH, USA Ruiyan Zhu Applying Chemistry Key Laboratory of Hebei Province, Yanshan University, Qinhuangdao, China Chapter 1 Polymer Nanodielectrics: Current Accomplishments and Future Challenges for Electric Energy Storage Guoqiang Zhang, Elshad Allahyarov and Lei Zhu Abstract In response to the need for high energy density and low-loss film capacitors in various electrical and power applications, polymer nanocomposite dielectricsornanodielectricshaveattractedsubstantialattentioninrecentyears.The idea is to combine the high dielectric constant property from inorganic nanoparti- cles and the high breakdown strength and low-loss properties from the polymer matrices. Both theoretical and experimental studies have carried out to testify this idea.Inthischapter,wereviewboththeoreticalandexperimentalachievementsand fundamental understanding on this topic. In particular, we focus on the dielectric loss mechanisms in polymer nanodielectrics. It is found that high permittivity contrast between the nanofillers and the polymer matrices tends to decrease the dielectric breakdown strength because of nonuniform electric field distribution. Highconductivitycontrastbetweenceramicnanofillersandthepolymermatrixwill induce internal electronic conduction loss. For polymer/metallic nanoparticle dielectrics, field electron emission from metallic nanoparticles under a high field tends to increase the electronic conduction and thus decrease the dielectric break- down strength. In the future, research should focus on mitigating these dielectric loss mechanisms in order to achieve viable polymer nanodielectrics for film capacitor applications. G.Zhang(cid:1)E.Allahyarov(cid:1)L.Zhu(&) CenterofLayeredPolymericSystems(CLiPS)andDepartmentofMacromolecularScience andEngineering,CaseWesternReserveUniversity,Cleveland,OH44106-7202,USA e-mail:[email protected] E.Allahyarov InstitutfürTheoretischePhysikII,WeicheMaterie,Heinrich-HeineUniversität, Universitätsstrasse1,40225Düsseldorf,Germany E.Allahyarov TheoreticalDepartment,JointInstituteforHighTemperatures,RussianAcademy ofSciences,Izhorskaya13/19,117419Moscow,Russia ©SpringerNatureSingaporePteLtd.2018 1 B.LiandT.Jiao(eds.),Nano/Micro-StructuredMaterialsforEnergy andBiomedicalApplications,https://doi.org/10.1007/978-981-10-7787-6_1 2 G.Zhangetal. (cid:1) Keywords Polymer nanodielectrics Ferroelectric nanoparticles (cid:1) (cid:1) (cid:1) Barium titanate Metallic nanoparticles Dielectric constant Dielectric (cid:1) breakdown strength Energy density 1 Introduction to Polymer Nanodielectrics 1.1 The Need for Next-Generation Polymer Film Capacitors Advanced energy technologies in the twenty-first century, e.g., pulsed power, power conditioning, power electronics in hybrid/electric vehicles, and medical/ consumer electronics, create an urgent need for lightweight, compact, and cost-efficientenergy conversionandstorage components suchascapacitors, which featurehighenergydensity,highpowerdensity,broadoperatingtemperaturerange, as well as good environmental stability [1, 2]. Among various technologies, polymer film capacitors have gained importance in applications that require high power and high energy density, fast charge/discharge rates, high voltage and tol- erancetohighripplecurrents,becausetheirpowerdensityisthehighestcompared to other types of capacitors such as ceramic and electrolytic capacitors. Unlike batteries, electrochemical capacitors, and fuel cells, energy storage using electro- static capacitors is purely a physical process based on separation of opposite static charges under an applied electric field. Therefore, stable capacitance over a wide temperature range and a long cycle lifetime represent a unique feature for linear dielectric film capacitors. Ideally, a high-performance dielectric material should qualify the following factors, including large permittivity or dielectric constant (e), high dielectric r breakdown strength (E ), high discharge efficiency (η), high resistivity, and broad b operatingtemperaturewindow.However,barelyanycurrentlyavailablematerialis able to perform well in all aspects. For example, there are a few shortcomings for current state-of-the-art polymer film capacitors. First, they have a lower energy density than electrolytic and ceramic capacitors because of their low dielectric constants (typically 2–5). This limits the miniaturization and often results in large form factor and low energy-to-weight ratio (*0.01–0.1 kWh/kg) for film capaci- tors. Second, the temperature rating for current state-of-the-art biaxially oriented polypropylene (BOPP) film capacitors is limited at 85 °C. This is primarily attributedtothedefectinitiationandgrowthinBOPPatelevatedtemperatures.Asa result,thebreakdownstrengthandlifetimewillsubstantiallydecreasecomparedto those at room temperatures. Current research focuses on enhancing the energy density and temperature tolerance, while keeping ultra-low losses for dielectric polymers [3, 4]. Theoverallperformanceofanelectrostaticcapacitorislargelydeterminedbythe dielectric material placed between two metal electrodes. For linear dielectrics, the energy density (U ) has a linear relationship with the relative permittivity e, and a e r
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