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Clean Energy Production Technologies Series Editors: Neha Srivastava · P. K. Mishra Manish Srivastava P. K. Mishra Editors NanoBioenergy: Application and Sustainability Assessment Clean Energy Production Technologies SeriesEditors NehaSrivastava,DepartmentofChemicalEngineeringandTechnology,IIT(BHU) Varanasi,Varanasi,UttarPradesh,India P.K.Mishra,DepartmentofChemicalEngineeringandTechnology,IIT(BHU) Varanasi,Varanasi,UttarPradesh,India Theconsumptionoffossilfuelshasbeencontinuouslyincreasingaroundtheglobe and simultaneously becoming the primary cause of global warming as well as environmentalpollution.Duetolimitedlifespanoffossilfuelsandlimitedalternate energyoptions,energycrisesisimportantconcernfacedbytheworld.Amidstthese complex environmental and economic scenarios, renewable energy alternates such as biodiesel, hydrogen, wind, solar and bioenergy sources, which can produce energy with zero carbon residue are emerging as excellent clean energy source. Formaximizingtheefficiencyandproductivityofcleanfuelsviagreen&renewable methods, it’s crucial to understand the configuration, sustainability and techno- economicfeasibilityofthesepromisingenergyalternates.Thebookseriespresents a comprehensive coverage combining the domains of exploring clean sources of energyandensuringitsproductioninaneconomicalaswellasecologicallyfeasible fashion.Seriesinvolvesrenownedexpertsandacademiciansasvolume-editorsand authors, from all the regions of the world. Series brings forth latest research, approaches and perspectives on clean energy production from both developed and developing parts of world under one umbrella. It is curated and developed by authoritativeinstitutionsandexpertstoservesglobalreadershiponthistheme. (cid:129) Manish Srivastava P. K. Mishra Editors NanoBioenergy: Application and Sustainability Assessment Editors ManishSrivastava P.K.Mishra DepartmentofChemicalEngineeringand DepartmentofChemicalEngineeringand Technology Technology IndianInstituteofTechnology(BHU) IndianInstituteofTechnology(BHU) Varanasi,UttarPradesh,India Varanasi,UttarPradesh,India ISSN2662-6861 ISSN2662-687X (electronic) CleanEnergyProductionTechnologies ISBN978-981-19-6233-2 ISBN978-981-19-6234-9 (eBook) https://doi.org/10.1007/978-981-19-6234-9 ©TheEditor(s)(ifapplicable)andTheAuthor(s),underexclusivelicensetoSpringerNatureSingapore PteLtd.2023 Thisworkissubjecttocopyright.AllrightsaresolelyandexclusivelylicensedbythePublisher,whether thewholeorpartofthematerialisconcerned,specificallytherightsoftranslation,reprinting,reuseof illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similarordissimilarmethodologynowknownorhereafterdeveloped. Theuseofgeneraldescriptivenames,registerednames,trademarks,servicemarks,etc.inthispublication doesnotimply,evenintheabsenceofaspecificstatement,thatsuchnamesareexemptfromtherelevant protectivelawsandregulationsandthereforefreeforgeneraluse. The publisher, the authors, and the editorsare safeto assume that the adviceand informationin this bookarebelievedtobetrueandaccurateatthedateofpublication.Neitherthepublishernortheauthorsor theeditorsgiveawarranty,expressedorimplied,withrespecttothematerialcontainedhereinorforany errorsoromissionsthatmayhavebeenmade.Thepublisherremainsneutralwithregardtojurisdictional claimsinpublishedmapsandinstitutionalaffiliations. ThisSpringerimprintispublishedbytheregisteredcompanySpringerNatureSingaporePteLtd. The registered company address is: 152 Beach Road, #21-01/04 Gateway East, Singapore 189721, Singapore Preface This book entitled, NanoBioenergy: Application and Sustainability Assessment, provides ecofriendly nanomaterials as green catalysts to enhance biofuels. Nanomaterials work as catalysts in various steps of different biofuels production optionsinordertoimprovetheproductivityofthebioenergy.Nevertheless,synthesis cost of the nanomaterial may be the hindrance to limit the biofuels production process. Therefore, green synthesis of nanomaterial may play a potential role to improvesustainabilityofoverallbiofuelsprocess.Basedonthisconcept,thisbook has been divided into nine focused chapters in which Chaps. 1 and 2 explore feasibilityandapplicationsofnanomaterialtoimprovebiofuelsproduction.Whereas Chaps. 3 and 4 deal with the possibility of nanomaterial application in gaseous biofuels and biosynthesis of nanomaterial through microbial process. Further, Chaps.5and6arefocusedongreensynthesisofironnanomaterialforbiohydrogen and other biofuels applications while Chaps.7, 8, and 9 discuss green synthesis of nanomaterials using waste biomass and microbial cultures and contributions of nanomaterialsinmicrobialfuelcellsapplication.Thebookcertainlysetsapotential milestone that overcomes the high production cost and low productivity issues relatedtowastetobioenergyproduction. Varanasi,UttarPradesh,India ManishSrivastava P.K.Mishra v Acknowledgments The editors are thankful to all the academicians and scientists whose contributions have enriched this volume. We also express our deep sense of gratitude to our parents whose blessings have always prompted us to pursue academic activities deeply.Itisquitepossible thatinaworkofthisnature,somemistakes might have crept in text inadvertently and for these we owe undiluted responsibility. We are grateful to all authors for their contribution to this book. We are also thankful to SpringerNature forgivingthisopportunitytoeditorsandDepartmentofChemical Engineering and Technology, IIT (BHU) Varanasi, Uttar Pradesh, India, for all technicalsupport.Wethankthemfromthecoreofourheart. vii Contents 1 ApplicationofNanomaterialsforRenewableEnergyProduction. .. 1 GauravKumarPandit,RiteshKumarTiwari,Shanvi,ManishaVerma, VeerSingh,KundanKunal,GhufranAhmed,andRameshChandra 2 ApplicationsofNanomaterialsinLiquidBiofuelsProduction. . . . . . 21 B.S.NaveenPrasad,S.Sivamani,andB.Saikat 3 ApplicationsofNanomaterialsinGaseousBiofuelsProduction. . . . . 43 B.S.NaveenPrasad,B.Saikat,andS.Sivamani 4 MicrobialAssistedSynthesisofNanophotocatalystsforDark FermentativeHydrogenGeneration. . . . . . . . . . . . . . . . . . . . . . . . . 79 ShanthipriyaAjmera,SouvikRoy,M.Noorjahan,J.ImmanuelSuresh, andDebashreeBorthakur 5 GreenRouteSynthesizedIronNanoparticlesforBiohydrogen Production. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109 DharmPal,DhrutiSundarPattanayak,JyotiMishra, andNareshKumarSahoo 6 SynthesisandApplicationofNanoengineeredCellulosicBiomass inBiohydrogenProduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 135 DikshaVerma,TanviSahni,SachinKumar,andLoveleenKaurSarao 7 Microbial-MediatedSynthesisofNanoparticlesandTheirRole inBioethanolProduction. . . . .. . . . . .. . . . .. . . . . .. . . . .. . . . . .. 169 SreedeviSarsan,ShanthipriyaAjmera,SindhuraPodduturi, andSaiPrashanthiGovumoni 8 GreenSynthesisofNanomaterialsfromBiomassWaste forBiodieselProduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 211 ZeenatArif,NareshK.Sethy,P.K.Mishra,andP.Kumar ix Editors and Contributors About the Editors Manish Srivastava is currently working as SERB- ResearchScientistintheDepartmentofChemicalEngi- neeringandTechnologyIIT(BHU),Varanasi,India.He hasworkedasDSTINSPIREfacultyintheDepartment ofPhysicsandAstrophysics,UniversityofDelhi,India during June 2014 to June 2019. He has published 46 research articles in peer-reviewed journals, edited 8booksforpublishersofinternationalrenown,authored severalbookchapters,and filedone patent.He worked as a postdoctoral fellow in the Department of BIN Fusion Technology, Chonbuk National University, South Korea from August 2012 to August 2013. He wasanassistantprofessorintheDepartmentofPhysics, DIT School of Engineering, Greater Noida, from July 2011toJuly2012.HereceivedhisPhDinPhysicsfrom the Motilal Nehru National Institute of Technology, Allahabad, India, in 2011. Presently, he is working on thesynthesisofgraphene-basedmetaloxidehybridsand their applications as catalysts. His areas of interest are synthesisof nanostructuredmaterials and their applica- tionsascatalystforthedevelopmentofelectrodemate- rials in energy storage, biosensors, and biofuels production. xi xii EditorsandContributors P. K. Mishra is currently Professor and Head in the Department of Chemical Engineering and Technology, IndianInstituteofTechnology(BHU), Varanasi,India. He has authored/co-authored over 60 technical papers published inreputednational/international journals and supervised more than 20 doctoral students. He has received several awards and honours and has 5 patents with1TechnologyTransfer.HeisFellowofInstitution ofEngineersIndia.Hehasreceivedseveralawardsand honoursatNational/Internationallevels. Contributors GhufranAhmed ICMRRajendraMemorialResearchInstitute,Patna,Bihar,India Shanthipriya Ajmera Department of Microbiology, Palamuru University, Mahabubnagar,Telangana,India ZeenatArif DepartmentofChemicalEngineeringandTechnology,IndianInstitute ofTechnology(BHU),Varanasi,India DebashreeBorthakur AssamDonBoscoUniversity,Guwahati,Assam,India Ramesh Chandra Department of Zoology, S S College, Shahjahanpur, Uttar Pradesh,India SaiPrashanthi Govumoni Department ofMicrobiology,St.Pious XDegreeand PGCollegeforWomen,Hyderabad,Telangana,India P.Kumar DepartmentofChemical Engineering andTechnology,IndianInstitute ofTechnology(BHU),Varanasi,India SachinKumar PunjabAgriculturalUniversity,Ludhiana,Punjab,India KundanKunal ICMRRajendraMemorialResearchInstitute,Patna,Bihar,India Jyoti Mishra Department of Chemistry (Environmental Science and Technology Program),ITER, Siksha‘O’Anusandhan (Deemed tobe)University,Bhubaneswar, Odisha,India P.K.Mishra DepartmentofChemicalEngineeringandTechnology,IndianInsti- tuteofTechnology(BHU),Varanasi,India B. S. Naveen Prasad Chemical Engineering Section, Engineering Department, University of Technology and Applied Sciences (Salalah College of Technology), Salalah,Oman