Molten Salt Coolants: Transferring Heat From Reactors to H Facilities 2 The Advanced High-Temperature Reactor for H Production 2 Charles Forsberg (ORNL) Paul Pickard (SNL) Per Peterson (U.C.-Berkeley) Oak Ridge National Laboratory P.O. Box 2008; Oak Ridge, TN 37831-6179 Tel: (865) 574-6783; E-mail: [email protected] DOE Nuclear Hydrogen Planning Meeting Hilton Head, South Carolina March 13, 2003 The submitted manuscript has been authored by a contractor of the U.S. Government under contract DE-AC05-00OR22725. Accordingly, the U.S. Government retains a nonexclusive, royalty-free license to publish or reproduce the published form of this contribution, or allow others to do so, for U.S. Government purposes. File name: DOE.Hydrogen.HiltonHead.March13.2003 The Advanced High-Temperature Reactor for Hydrogen Production Passive Decay Reactor Hydrogen Production Heat Removal Options Molten Fluoride Salt Oxygen Hydrogen (Example: NaF/ZrF ) 4 750o to 1000oC Hot Air Out Control Pump Rods Thermochemical Hot Electrolysis Nuclear-Assisted Air Inlet Cooling Steam Reforming Water of Natural Gas Fuel Reactor Vessel Radiation Heat Water Transfer (Operates at Higher Temperatures) Guard Vessel 03-022 The AHTR Is NOT a Molten Salt Reactor (MSR) • MSR − Fuel dissolved in the Off-gas System molten salt Separate Facility Primary Secondary (Colocated Salt Pump NaBF4_NaF Salt Pump or off-site) Coolant Salt Converter (CR~0.9) − Aircraft Reactor Waste Burner Experiment operated at Purified Electricity Salt Graphite (Helium/Gas Turbine) Moderator 815 °C Heat Exchanger or Hydrogen • AHTR Reactor (Thermochemical) Fuel Salt Freeze − Solid fuel Plug Coupled to Reactor − Molten salt coolant Critically Safe, Passively Cooled Breeder Dump Tanks (Emergency Cooling and Shutdown) − Uses MSR experience The AHTR and VHTR Use the Same Coated-Particle Fuel Fuel Handling Fuel Rod Hole Dowel Pin Annular Coolant Fuel Kernel Coated Channel Fuel Plug High Density PyC Particle Graphite SiC Fuel Block Low Density PyC Compact Graphite 8 mm Sleeve 0.92 mm 580 mm 39 mm 34 mm Dowel Socket 26 mm 360 mm Fuel Compact Fuel Rod Fuel Block ORNL DWG 2001-45 AHTR Molten Salt Reactor Technology Was Developed in the Aircraft Nuclear Propulsion Program with Test Reactor Operations to 860°C (Requirements: Low Pressure and Efficient Heat Transfer) A Molten-Salt-Cooled Reactor Reduces Reactor Temperatures Compared to Gas-Cooled Reactors Bulk Coolant Temperature Rise Temperature Rise From Coolant Across Reactor To Fuel Centerline Reactor Coolant Reactor Nuclear Fuel Entrance Coolant Exit Bulk Coolant Peak Temperature Temperature Temperature Temperature 600° 600° k ant ea 500° 500° e P Pl ve ure vn ot oe ba bg 400° Aer 400° Ao ) dr C) mp Cy °e re (°he H 300° ure (nt T 300° Helium uT ta ato Helium raol erT 200° peCo 200° pe m mr k u el et Tu Ta B 100° 100° t er Molten Salt np Molten Salt am l Temperature Of o e o T 0 Delivered Heat To 0 C Hydrogen Plant 03-017 Power Reactor Experience Shows That Liquid Coolants Minimize Peak Reactor Temperatures 1000 AHTR or MSR 1000°C 850°C 925°C Hydrogen Production 800 750°C AHTR or MSR 665°C ) C 675°C ° e ( 600 545°C HTGR-GT r 491°C u (General Atomics) t a er LMFBR 395°C p (Super Phenix) m 400 e AGR 310°C T 319°C (Hinkley Point B) PWR 299°C 200 (Point Beach) Liquid Gas 0 Inlet Outlet Delivered Heat 02-130 The AHTR Is the Child of GenIV: It Was Developed in the GenIV Process and Combines GenIV Technologies High-Temperature Molten Salt Reactor Technology Reactor Technology Fuel Coolant Advanced High Temperature Reactor Fusion (Molten Molten Salt Salt Cooling) (Fueled) Reactor 03-040 There Is a Massive R&D Overlap Between the AHTR and VHTR Common R&D • Nuclear Fuels • Materials • Hydrogen Production AHTR VHTR − Nuclear Assisted Steam Reforming − Thermochemical 03-016 Molten-Salt Heat Transfer Loops May Be Preferred To Transfer Heat From a Reactor to the H Facilities 2 (German Studies Supported Molten Salt Coolant Between Gas-Cooled Reactors and H Facilities; Molten Salts Used in the Chemical Industry) 2 Nuclear Safety by Isolation Hydrogen Safety by Dilution Oxygen Hot Air Out Control Rods Molten Salt H 2 Air Inlet Water Molten Salt Heat-Transfer Loop • High Heat Capacity • Low Pumping Costs • Low Pressure • Industrial Experience 02-176