Molecular Gels: Materials with Self-Assembled Fibrillar Networks PDF
Preview Molecular Gels: Materials with Self-Assembled Fibrillar Networks
MOLECULAR GELS Molecular Gels Materials with Self-Assembled Fibrillar Networks Edited by RICHARD G. WEISS Department of Chemistry, Georgetown University, W ashington, DC, U.S.A. and PIERRE TERECH CNRS-Atomic Energy Center-Grenoble University, Grenoble, France AC.I.P. Catalogue record for this book is available from the Library of Congress. ISBN-10 1-4020-3352-4 (HB) ISBN-13 978-1-4020-3352-0 (HB) ISBN-10 1-4020-3689-2 (e-book) ISBN-13 978-1-4020-3689-7 (e-book) Published by Springer, P.O. Box 17, 3300 AADordrecht, The Netherlands. www.springeronline.com Printed on acid-free paper All Rights Reserved © 2006 Springer No part of this work may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, microfilming, recording or otherwise, without written permission from the Publisher, with the exception of any material supplied specifically for the purpose of being entered and executed on a computer system, for exclusive use by the purchaser of the work. Printed in the Netherlands. Dedication ForJeanneandInna,ourhumanserendipity TABLE OF CONTENTS ListofContributors xi Introduction 1 RichardG.WeissandPierreTe´rech THEORY 1 TheoryofMolecularAssociationand ThermoreversibleGelation 17 FumihikoTanaka 2 GrowthandChiralityAmplificationinHelical SupramolecularPolymers 79 JeroenvanGestel,PaulvanderSchootandM.A.J.Michels 3 Self-AssemblingPeptideGels 99 A.Aggeli,N.Boden,L.M.Carrick,T.C.B.Mcleish, I.A.NyrkovaandA.N.Semenov 4 KineticsofNucleation,AggregationandAgeing 131 JürnW.P.Schmelzer 5 SoftGlassyRheology 161 PeterSollich vii viii Tableofcontents 6 RheologicalChaosinWormlikeMicellesand NematicHydrodynamics 193 MoumitaDas,RanjiniBandyopadhyay,BuddhapriyaChakrabarti, SriramRamaswamy,ChandanDasguptaandA.K.Sood 7 WettingofFibers 223 EliseLorenceau,TimSendenandDavidQuéré TECHNIQUES 8 GelFormation:PhaseDiagramsUsingTabletop RheologyandCalorimetry 241 SrinivasaR.RaghavanandBaniH.Cipriano 9 Direct-ImagingandFreeze-FractureCryo-Transmission ElectronMicroscopyofMolecularGels 253 DganitDaninoandYeshayahuTalmon 10 MolecularGelsandSmall-AngleScattering 275 PierreTérech 11 X-RayDiffractionofPoorlyOrganizedSystemsand MolecularGels 325 MichelAnne 12 OpticalSpectroscopicMethodsasToolstoInvestigate GelStructures 363 HenriBouas-LaurentandJean-PierreDesvergne 13 CircularDichroismforStudyingGel-LikePhases 431 GiovanniGottarelli,GianPieroSpadaandEttoreCastiglioni Tableofcontents ix SYSTEMS–ORGANOGELS 14 LowMolecular-MassOrganicGelators 449 MathewGeorgeandRichardG.Weiss 15 DesignandFunctionofLowMolecular-MassOrganic Gelators(LMOGs)BearingSteroidandSugarGroups 553 NorifumiFujitaandSeijiShinkai 16 SafinGelsWithAmphiphilicMolecules 577 ReikoOda SYSTEMS–HYDROGELS 17 AdvancesinMolecularHydrogels 613 SantanuBhattacharya,UdayMaitra,SamratMukhopadhyay andAasheeshSrivastava 18 AqueousGelsMadeofChiralLipid-and Porphyrin-Amphiphiles 649 Jürgen-HinrichFuhrhop,TianyuWang,SheshanathBhosale, SidhanathBhosaleandMatthiasLauer ANALYSESOFSPECIFICSYSTEMS 19 RheologyofWormlikeMicelles:Equilibrium PropertiesandShearBandingTransitions 667 Jean-FrançoisBerret 20 Cryo-Tem,X-RayDiffractionandModelingofan OrganicHydrogel 721 LaraA.EstroffandAndrewD.Hamilton x Tableofcontents 21 GelationofaLiquid-CrystallineL PhaseInducedbythe α ProliferationofTopologicalDefects 743 PatrickDavidson APPLICATIONS 22 GelsofLiquidCrystalsandIon-ConductingFluids 773 RifatA.MHikmet 23 ElectronConductingandMagneto-SensitiveGels 793 FrédéricFages 24 PhotoresponsiveGels 817 AndréDelGuerzoandJean-LucPozzo 25 GelsofLowMolecular-MassOrganicGelatorsas TemplatesforTranscription 857 AriannaFriggeri,KjeldJ.C.vanBommelandSeijiShinkai 26 ResponsiveMolecularGels 895 JaapJ.D.deJong,BenL.FeringaandJanvanEsch 27 GelsasCleaningAgentsinCulturalHeritageConservation 929 EmilianoCarrettiandLuigiDei ColorSection 941 Index 000 LIST OF CONTRIBUTORS AmaliaAggeli SidhanathBhosale CentreforSelf-OrganisingMolecular FreieUniversitätBerlin,FBBiologie, SystemsandSchoolofChemistry, Chemie,Pharmazie,Institutfür UniversityofLeedsLS29JT, Chemie/OrganischeChemie,Takustr.3, UnitedKingdom D-14195Berlin,Germany [email protected] NevilleBoden MichelAnne CentreforSelf-OrganisingMolecular LaboratoiredeCristallographie,CNRS, SystemsandSchoolofChemistry, 25avenuedesMartyrs,BP166, UniversityofLeedsLS29JT, 38042Grenoble,Cedex09,France UnitedKingdom [email protected] [email protected] KjeldJ.C.vanBommel RanjiniBandyopadhyay BiOMaDeTechnologyFoundation, DepartmentofPhysicsandAstronomy, Nijenborgh4,9747AGGroningen, TheJohnsHopkinsUniversity, TheNetherlands Baltimore,MD21218,USA [email protected] Jean-FrançoisBerret HenriBouas-Laurent MatièreetSystèmesComplexes, ◦ LaboratoiredeChimieOrganiqueet UMRCNRSn 7057,UniversitéDenis Organométallique,UMR5802,CNRS Diderot,140ruedeLourmel,75015 UniversitéBordeaux1,33405 Paris,France TALENCECedex,France [email protected] [email protected] SantanuBhattacharya EmilianoCarretti DepartmentofOrganicChemistry, DepartmentofChemistry&CSGI IndianInstituteofScience, Consortium,UniversityofFlorence,via Bangalore560012,India dellaLastruccia,3,I-50019Sesto [email protected] Fiorentino,Italy [email protected]fi.it SheshanathBhosale FreieUniversitätBerlin,FBBiologie, LisaM.Carrick Chemie,Pharmazie,Institutfür CentreforSelf-OrganisingMolecular Chemie/OrganischeChemie,Takustr.3, Systems,UniversityofLeedsLS29JT, D-14195Berlin,Germany UnitedKingdom xi xii Listofcontributors EttoreCastiglioni Jean-PierreDesvergne JASCOEUROPEsrl,viaConfalonieri25, LaboratoiredeChimieOrganiqueet 23894Cremella,Italy Organométallique,UMR5802,CNRS UniversitéBordeaux1,33405 TALENCECedex,France BuddhapriyaChakrabarti [email protected] DepartmentofPhysics,Universityof Massachusetts,Amherst,MA01003, USA DganitDanino [email protected] DepartmentofBiotechnologyandFood Engineering,Technion-IsraelInstitute ofTechnology,Haifa32000,Israel BaniH.Cipriano [email protected] DepartmentofChemicalEngineering, UniversityofMaryland,CollegePark, MD20742,USA JanH.vanEsch OrganicandMolecularInorganic Chemistry,StratinghInstitute, MoumitaDas UniversityofGroningenNijenborgh4, DepartmentofPhysics,IndianInstituteof 9747AGGroningen,TheNetherlands Science,Bangalore560012,India [email protected] [email protected]. LaraA.Estroff ChandanDasgupta DepartmentofChemistry,YaleUniversity, DepartmentofPhysics,IndianInstituteof POBox208107,NewHaven, Science,Bangalore560012, CT06520-8107,USA India [email protected] [email protected] FrédéricFages PatrickDavidson UMRCNRS6114,Universitédela LaboratoiredePhysiquedesSolides,Bât. Méditerranée,FacultédesSciencesde 510,UMR8502CNRS,Université Luminy,13288MarseilleCedex9, Paris-Sud91405OrsayCedex,France France [email protected] [email protected] LuigiDei BenL.Feringa DepartmentofChemistry&CSGI OrganicandMolecularInorganic Consortium,UniversityofFlorence,via Chemistry,StratinghInstitute, dellaLastruccia,3,I-50019Sesto UniversityofGroningenNijenborgh4, Fiorentino,(Florence)Italy 9747AGGroningen,TheNetherlands [email protected]fi.it [email protected] AndréDelGuerzo AriannaFriggeri PhotochemistryforNanoscience,CNRS BiOMaDeTechnologyFoundation, UMR5802,UniversitéBordeaux1,351 Nijenborgh4,9747AGGroningen, coursdelaLibération,33405Talence, TheNetherlands France [email protected]
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