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Nanostructure Science and Technology Series Editor: David J. Lockwood Thimmaiah Govindaraju Katsuhiko Ariga Editors Molecular Architectonics and Nanoarchitectonics Nanostructure Science and Technology SeriesEditor David J. Lockwood, FRSC, National Research Council of Canada, Ottawa, ON, Canada Nanostructure science and technology now forms a common thread that runs throughallphysicalandmaterialssciencesandisemerginginindustrialapplications asnanotechnology.The breadthof thesubject material isdemonstratedbythefact that it covers and intertwines many of the traditional areas of physics, chemistry, biology, and medicine. Within each main topic in this field there can be many subfields. For example, the electrical properties of nanostructured materials is a topic that can cover electron transport in semiconductor quantum dots, self- assembled molecular nanostructures, carbon nanotubes, chemically tailored hybrid magnetic-semiconductor nanostructures, colloidal quantum dots, nanostructured superconductors, nanocrystalline electronic junctions, etc. Obviously, no one book cancopewithsuchadiversityofsubjectmatter.Thenanostructuredmaterialsystem is, however, of increasing significance in our technology-dominated economy and thissuggeststheneedforaseriesofbookstocoverrecentdevelopments. The scope of the series is designed to cover as much of the subject matter as possible – from physics and chemistry to biology and medicine, and from basic science to applications. At present, the most significant subject areas are concen- tratedinbasicscienceandmainlywithinphysicsandchemistry,butastimegoesby moreimportancewillinevitablybegiventosubjectsinappliedscienceandwillalso include biology and medicine. The series will naturally accommodate this flow of developments in the sciences and technology of nanostructures and maintain its topicalitybyvirtueofitsbroademphasis.Itisimportantthatemergingareasinthe biological and medical sciences, for example, not be ignored as, despite their diversity, developments in this field are often interlinked. The series will maintain therequiredcohesivenessfromajudiciousmixofeditedvolumesandmonographs that while covering subfields in depth will also contain more general and interdis- ciplinarytexts. Thus the series is planned to cover in a coherent fashion the developments in basic research from the distinct viewpoints of physics, chemistry, biology, and materialsscienceandalsotheengineeringtechnologiesemergingfromthisresearch. Eachvolumewillalsoreflectthisflowfromsciencetotechnology.Astimegoesby, theearlierseriesvolumeswillthenserveasreferencetextstosubsequentvolumes. Moreinformationaboutthisseriesathttp://www.springer.com/series/6331 (cid:129) Thimmaiah Govindaraju Katsuhiko Ariga Editors Molecular Architectonics and Nanoarchitectonics Editors ThimmaiahGovindaraju KatsuhikoAriga BioorganicChemistryLaboratory,New InternationalCenterforMaterials ChemistryUnitandSchoolofAdvanced Nanoarchitectonics(WPI-MANA),National Materials(SAMat) InstituteforMaterialsScience(NIMS) JawaharlalNehruCentreforAdvanced Ibaraki,Tsukuba,Japan ScientificResearch DepartmentofAdvancedMaterialsScience Bengaluru,Karnataka,India GraduateSchoolofFrontierSciences,The UniversityofTokyo Chiba,Japan ISSN1571-5744 ISSN2197-7976 (electronic) NanostructureScienceandTechnology ISBN978-981-16-4188-6 ISBN978-981-16-4189-3 (eBook) https://doi.org/10.1007/978-981-16-4189-3 ©TheEditor(s)(ifapplicable)andTheAuthor(s),underexclusivelicensetoSpringerNatureSingapore PteLtd.2022 Thisworkissubjecttocopyright.AllrightsaresolelyandexclusivelylicensedbythePublisher,whether thewholeorpartofthematerialisconcerned,specificallytherightsoftranslation,reprinting,reuseof illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similarordissimilarmethodologynowknownorhereafterdeveloped. Theuseofgeneraldescriptivenames,registerednames,trademarks,servicemarks,etc.inthispublication doesnotimply,evenintheabsenceofaspecificstatement,thatsuchnamesareexemptfromtherelevant protectivelawsandregulationsandthereforefreeforgeneraluse. The publisher, the authors, and the editorsare safeto assume that the adviceand informationin this bookarebelievedtobetrueandaccurateatthedateofpublication.Neitherthepublishernortheauthorsor theeditorsgiveawarranty,expressedorimplied,withrespecttothematerialcontainedhereinorforany errorsoromissionsthatmayhavebeenmade.Thepublisherremainsneutralwithregardtojurisdictional claimsinpublishedmapsandinstitutionalaffiliations. ThisSpringerimprintispublishedbytheregisteredcompanySpringerNatureSingaporePteLtd. The registered company address is: 152 Beach Road, #21-01/04 Gateway East, Singapore 189721, Singapore Preface Introduction: Molecular Architectonics to Nanoarchitectonics Manycurrentproblems,includingenvironmental,energy,andbiomedicalproblems, must be solved with rational developments of science and technology. The performances depend not only on the quality of materials but also on the rational organization of the internal structures of materials. Therefore, structural studies of objects at nanoscopic, atomic, and molecular levels are a major concern of recent sciences and technologies. Fortunately, the research developments of past decades enableustoobserve,analyze,andmanipulatenanoscopicobjectsprecisely,whichis of course known as a great success of nanotechnology. However, functional materials witharational organizationcannotbecreated directlybytop-downnanotech- nology-related approaches alone. Therefore, a new research paradigm must be developed alongside nanotechnology tocreate functional materials from molecular and nanoscale units. This task can be assigned to an emerging concept, molecular architectonicsandnanoarchitectonics. Bengaluru,Karnataka,India ThimmaiahGovindaraju Ibaraki,Tsukuba,Japan KatsuhikoAriga Kashiwa,Chiba,Japan v Contents PartI MolecularArchitectonicsandNanoarchitectonics 1 MolecularArchitectonics. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . 3 MouliKonarandThimmaiahGovindaraju 2 Nanoarchitectonics. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 KatsuhikoAriga PartII ArchitectonicsofFunctionalMolecules 3 TopologicalSupramolecularPolymer. . . . . . . . . . . . . . . . . . . . . . . 47 YasukiKato,SougataDatta,andShikiYagai 4 MolecularArchitectonicsGuidetotheFabrication ofSelf-CleaningMaterials. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71 MouliKonarandThimmaiahGovindaraju 5 FunctionalDiscoticLiquidCrystalsThroughMolecular Self-Assembly:TowardEfficientChargeTransportSystems. . . . . . 89 InduBala,JoydipDe,andSantanuKumarPal PartIII ArchitectonicsofPeptides 6 Dopamine-BasedMaterials:RecentAdvancesinSynthesis MethodsandApplications. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133 HongLiandJunbaiLi 7 Peptide-BasedNanoarchitectonics:Self-Assemblyand BiologicalApplications. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165 LuyangZhaoandXuehaiYan vii viii Contents 8 PeptideCross-βNanoarchitectures:CharacterizingSelf-Assembly Mechanisms,Structure,andPhysicochemicalProperties. . . . . . . . . 179 ChristopherW.Jones,HannahE.Distaffen,andBradleyL.Nilsson 9 Function-InspiredDesignofMolecularHydrogels: Paradigm-ShiftingBiomaterialsforBiomedicalApplications. . . . . . 209 AshishDhayani,PreethemSrinath,SujanthiEaswaraPrasad, AfsanaNaaz,MukeshDhanka,SanjeebKalita, andPraveenKumarVemula 10 SmartPeptideAssemblyArchitecturestoMimicBiology’s AdaptivePropertiesandApplications. . . . . . . . . . . . . . . . . . . . . . . 233 DebasishHaldar PartIV ArchitectonicsofNucleicAcids 11 Bio-inspiredFunctionalDNAArchitectures. . . . . . . . . . . . . . . . . . 259 EugenStulz 12 FunctionalMolecule-TemplatedDNAMolecularArchitectonics. . . 281 LakshmiPriyaDatta,DebasisGhosh,andThimmaiahGovindaraju 13 ArchitecturesofNucleolipidAssembliesandTheirApplications. . . 307 ManishaB.Walunj,SwagataDutta,andSeergazhiG.Srivatsan 14 Nucleobase-andDNA-FunctionalizedHydrogelsandTheir Applications. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 335 ApurbaK.Das,AnkanBiswas,SouravBhowmik,andTapasGhosh 15 RNANanoarchitecturesandTheirApplications. . . . . . . . . . . . . . . 365 ShahajiH.More,AbhishekBastiray,andAshwaniSharma PartV ArchitectonicsofComplexSystemsandAdvancedObjects 16 CovalentOrganicFrameworksasTunableSupportsforHER, OER,andORRCatalysts:ANewAdditiontoHeterogeneous Electrocatalysts. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 389 RamanathanVaidhyanathan 17 Ligand-FunctionalizedNanostructuresandTheirBiomedical Applications. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 445 KoushikDebnathandNikhilR.Jana 18 BiomimeticCompositeMaterialsandTheirBiological Applications. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 459 SvetlanaBatasheva,EkaterinaNaumenko,andRawilFakhrullin Contents ix 19 CombiningPolymers,Nanomaterials,andBiomolecules: NanostructuredFilmswithFunctionalPropertiesand Applications. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 481 AndressaR.Pereira,AntonioF.A.A.Melo,FrankN.Crespilho, andOsvaldoN.OliveiraJr 20 ResponsivePolymericArchitecturesandTheirBiomaterial Applications. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 509 LiliChen,MazayaNajimina,andMitsuhiroEbara Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 525 Part I Molecular Architectonics and Nanoarchitectonics