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NATIONAL INSTITUTE OF TECHNOLOGY HAZRATBAL 190006, J&K PhD JRF-SRF Report On By Mohsin Suharwerdi 2018PHAECE005 (Ph.D.) Under the supervision of Dr Gausia Qazi Associate Professor Department of Electronics & Communication Engineering Autumn, 2022 TABLE OF CONTENTS 1 INTRODUCTION ..................................................................................................... 1 1.1 Image Sensors and Imaging ................................................................................ 1 1.2 CMOS Image Sensors (A TCAD perspective) ................................................... 1 2 FIGURES OF MERIT ............................................................................................... 5 2.1 Quantum Efficiency ............................................................................................ 5 2.2 Dynamic Range................................................................................................... 5 2.3 Signal to Noise Ratio .......................................................................................... 6 2.4 Dark Current ....................................................................................................... 6 3 DARK CURRENT MODEL...................................................................................... 7 3.1 Depletion Area Generation ................................................................................. 8 3.2 Field-Free Area Generation ................................................................................ 8 3.3 Transfer Gate Oxide Interface Generation .......................................................... 8 3.4 TCAD Validation of the Dark current Sources .................................................. 9 4 RESEARCH OBJECTIVES AND PROGRESS ..................................................... 13 4.1 Objective 1 ........................................................................................................ 13 4.2 Objective 2 ........................................................................................................ 13 4.3 Objective 3 (yet to be accomplished) ............................................................... 15 5 REFERENCES ......................................................................................................... 19 LIST OF FIGURES .............................................. 2 Figure 2 (a) Layout of a typical image sensor, (b) Front-end electrical structure of the device. ............................................................................................................................................... 2 Figure 3 (a) Front-end structure used in the electrical simulation, (b) Back-end structure used in the optical simulation. ............................................................................................... 3 Figure 4 Mixed-Mode CIS simulation with Read-out Spice Models (BSIM3 Level 8, Vth=0.63V). .......................................................................................................................... 4 Figure 5 (a) Absolute Power flux density (Wm-2) (b) Optical generation of the device in EM wave solver (cm-3s-1). ............................................................................................................ 4 Figure 6 Various image sensor figure of merits affecting the quality of an image (photo courtesy-NIT, Srinagar) ........................................................................................................ 5 Figure 7 Trap assisted generation process (Donor and Acceptor types) ............................... 7 Figure 8 Various Dark current sources in a CIS PPD. .......................................................... 7 Figure 9 Arrhenius curve for the sensor with activation energy close to 0.56ev .................. 9 Figure 10 PPD Capacitance vs photogenerated electrons Two Regimes clearly visible . 10 Figure 11 Modeled PPD Capacitance: (a) Depletion (fits low illumination) (b) Diffusion (fits high illumination). ....................................................................................................... 11 Figure 12 PPD Capacitance Analytical fit with change in Temperature ............................ 11 Figure 13 PPD Capacitance Analytical fit with change in (a) Trap Concentration (b) Trap Cross-Section. ..................................................................................................................... 12 Figure 14 Remodeling of CMOS image sensor compact model to capture the dark current generation effects. (a) Updated physics-based model, (b) Physical device (image sensor pixel). .................................................................................................................................. 12 Figure 15 3D visualization of surface potential: (a) TG=On (b) TG=Off. ......................... 13 Figure 16 The PPD extension & Depletion limits under the TG (Dimensions in µm). ...... 14 Figure 17 Streamlines driven by the gradient of eQF (a) VOTG=0V (b) VOTG=1V. ............ 14 Figure 18 Dark current evolution & FWC reduction with TG voltage (VOTG). .................. 15 Figure 19 TCAD 2-D distributions of the doping concentration showing the simulated device (a) with an enlargement of the TG gate over the PPD and (b) with an additional large gate over the PPD [19]. ....................................................................................................... 16 Figure 20 TCAD simulation of the dark current before and after irradiation for various designs [19]. ........................................................................................................................ 16 Figure 21 (a) and (b) Sketches of the top-view layouts and of the related cross sections of four 4T-pixel blocks with STI, respectively, and (c) and (d) hybrid isolation [20]. ........... 17 Figure 22 DC distributions as measured on one representative sample for each test array (186×84 pixels) of the STI-pixel and hybrid-isolation-pixel [20]. ..................................... 17 Figure 23 (a) Illustration of the plasma induced degradation mechanism (b) Minimum of the interface states density DIT [18]. .......................................................................................... 18 1 INTRODUCTION 1.1 Image Sensors and Imaging Cameras find applications in consumer devices like Digital cameras, Cell phones; in scientific research like Infrared, UV, X-ray imaging; and in industrial products like automobiles, security systems. The solid-state image sensor, which is the heart of the camera, has evolved greatly since its invention in the 1970s. Although the two variants of image sensors, viz. CCD (Charge Coupled Device) and CMOS (Complementary Metal Oxide Semiconductor) were intro applications far overweigh those of the former. The reason being the architectural differences in signal read-out principle. A CCD transfers the signal charge to the end of the output signal line as it is and converts it into a voltage signal through an amplifier. In contrast, a CMOS image sensor (CIS) converts the signal charge into a voltage signal at each pixel. This leads to Low power consumption in the CMOS image sensors. In high-speed operation, the in-pixel amplification configuration gives better gain-bandwidth than a configuration with one amplifier on a chip. Although the recent development of CMOS image sensors requires dedicated fabrication process technologies, CMOS image sensors are still based on standard mixed signal processes unlike CCD sensors. On the downside, in CCD image sensors, the signal charge is transferred simultaneously, which gives low noise compared to its competitor. In CMOS sensors, this issue is solved by the in-pixel amplification (active pixel) and other noise reduction techniques discussed in the figure of merits section 2. The delayed read-out of different row pixels - by-row read-out of the pixel values. This issue is solved by the use of four-transistor configuration with a transfer gate. Also due to additional transistors, the size of a CMOS pixel is larger than a CCD pixel. Although CMOS fabrication technology advances have benefited the development of CMOS image sensors, namely in shrinking the pixel size, yet the size of a CCD is smaller than the 4T-APS (four-transistor Active Pixel CMOS Sensor). 1.2 CMOS Image Sensors (A TCAD perspective) Passive pixel sensor (PPS) was the first commercially available MOS sensor [1], but due to SNR issues, its development was halted. An APS was first realized using a photogate (PG) as a photodetector and then by using a photodiode (PD) [1]. The sensitivity of a PG is not good since polysilicon as a gate material is opaque at the visible wavelength region. A three-transistor Active pixel sensor (3T-APS) although overcame the disadvantage of the PPS, but there is a tradeoff relation between the full-well capacity ( ) and the conversion gain ( ). A four-transistor configuration (4T-APS) solves this issue using a Floating diffusion capacitance (FD), which is independent of the PPD, and a readout transistor TX between them. For color information, four pixels (two green, one blue and one 3], represents one coordinate point of an image (Figure 1). 1 Figure 1 1.2.1 Structure & Doping distribution of the PPD (4T) The layout (with layers) and Front-end electrical structure of a typical pinned photodiode used in CMOS image sensors is shown in (Figure 2). The main elements are an n-type buried signal charge storage well (SW) region sandwiched between a lower p-type layer and a p+pinning layer at the top surface in contact with the lower active layer, a transfer gate (TG), and an n+output floating diffusion (FD). In a 180 nm process, the p+pinning layer might be about 100 nm thick, the n-layer about 2,500-5,000 nm thick, and the p-layer a few microns thick. The pnp PPD sandwich can be built using a p on p+epi substrate, or implemented by p-well in an n on n+epi substrate [4]. Figure 2 (a) Layout of a typical image sensor, (b) Front-end electrical structure of the device. The Back-end structure used in the optical simulation is shown in (Figure 3) vis-à- vis the Front-end layers. The major steps of the design flow are: 2 1. Substrate formation. 2. Shallow trench isolation. 3. Polysilicon gate formation. 4. Photodiode buried profile implantation. 5. Lightly doped drain (LDD) implantations. 6. Spacer creation. 7. Highly doped drain (HDD) implantation. 8. Rapid thermal annealing. 9. Electrical interconnects formation. 10. Planarization layer deposition 11. Color filters deposition. 12. Microlens formation. Figure 3 (a) Front-end structure used in the electrical simulation, (b) Back-end structure used in the optical simulation. The doping distribution is built from secondary ion mass spectrometry (SIMS) doping profiles [5]. For more accurate results, TCAD simulation in 2D, or for smaller pixels (e.g., 2.2 um pitch or less), simulation in 3D is required since 2D and 3D effects become important [4]. The planarization layer reduces the optical path between the active surface and the color filter [6]. 1.2.2 Opto-Electrical simulation TCAD optoelectrical simulation of a front side, linearly polarized plane wave (650 nm wavelength: red region) excited 4-Transistor CMOS image sensor (Figure 4) is considered (MOS dimensions from [7]). A harmonic plane wave with intensity 0.1 W/cm2 perpendicular to surface is used as a light source. The red filter absorbs light with a wavelength below 620 nm. Figure 5 shows the absolute power flux density (Wm-2) Optical generation (cm-3s-1) of the device in EM wave solver. In readout operation, signal charges in the PPD are transferred to FD by applying readout pulse to TG, and potential change of FD is detected by the Source Follower 3 Amplifier (SFA). One readout sequence involves (1) sensor part (PPD) (2) signal charge quantity measuring part (FD), and (3) scanning part (SFA). Figure 4 Mixed-Mode CIS simulation with Read-out Spice Models (BSIM3 Level 8, Vth=0.63V). Figure 5 (a) Absolute Power flux density (Wm-2) (b) Optical generation of the device in EM wave solver (cm-3s-1). As capacitance of FD can be designed without any change to PPD performance, it is possible to realize a higher charge voltage conversion factor, which is inversely proportional to C . This is advantageous for the later signal processing from the viewpoint FD of signal-to-noise ratio. But a too low capacitor volume may lead to charge spill-back to PPD and thus an inefficient charge transfer. From the I-V characteristics of the drive transistor and load device, the constant current source as a load device has the largest output change for a fixed input voltage change than the transistor followed by resistor load, but the area of the former is largest. Therefore, transistor is used as load device in most cases. Although the voltage gain of SFA is less than unity, the amount of charge is greatly multiplied by the ratio of output capacitance to input capacitance (100-10,000) of the SFA. This is important to drive the later circuit and reduce the impact of noise. 4 2 FIGURES OF MERIT An image sensor involves many figures of merit that affect the quality of the image it captures (Figure 6). Figure 6 Various image sensor figure of merits affecting the quality of an image (photo courtesy-NIT, Srinagar) 2.1 Quantum Efficiency sensor is the ratio of electrons produced in the photodiode ( to the number of photons absorbed in the depletion region , i.e., (where, ). So, if (wavelength of incident light) = 0.65µm, (incident optical power) = 0.49nW/µm-2, is around 48,150 photons. An of around 12,275 e-s gives a quantum efficiency of 25.5%. Modern image sensors report a quantum efficiency of more than 90%, thanks to the back-side illumination technique. 2.2 Dynamic Range The Dynamic Range (DR) of a pixel is the ratio of maximum ( ) to minimum ( ) detectable signal value, i.e., . So, if = 30,000 e-s and = 3 e-s, DR becomes 80dB. It directly depends on the full-well capacity (FWC) of the pixel. FWC is the number of charges that a photodiode accumulates and FWC = . For a Pinned Photodiode capacitance ( ) of 6 fF, pinning voltage ( , the maximum potential of the PPD) of 1.5V and Barrier potential ( , between the PPD and sense node) of 0.7V, the FWC is almost 30,000 e-s. A common DSLR camera image sensor has a DR and FWC of 80dB and 70,000 e-s respectively. Techniques like in- pixel lateral over-flow capacitors increase the FWC and indirectly the DR. 5 2.3 Signal to Noise Ratio Signal to Noise ratio (SNR) is the most important parameter for the sensitivity of an image sensor. It is the ratio of the signal received by the photodiode (S in e-s) to the various noises added to the signal readout of the sensor (N in e-s), i.e., SNR = S/N. The noises added to the signal may either be temporal (varies in time or space domain) or fixed-pattern noise (FPN). Correlated Double Sampling (CDS) circuitry in the column pitch of pixels can effectively remove the FPN noise. The remaining temporal noise further consists of shot noise (Poisson noise due to particle nature of light and discrete charges), thermal dark current noise (doubles for every 6 degree C), flicker or 1/f noise dominant at low-frequency operation, read noise (due to downstream pixel electronics) like random telegraph noise (RTN) due to scaling of transistors and kTC noise due to reset transistor connected to the sense node. Lowering the device temperature helps reduce the thermal dependent noise components. Most modern cameras report a read noise below 4 e-s and a value of above 80 SNR per pixel. 2.4 Dark Current In the absence of light, some charge generation takes place in the PPD and its surrounding area. This charge generation, which leads to a dark current in the sensor, is expedited by various process defects in the device bulk or surface and/or different impurities at the material interfaces. Being a temporal noise, the dark current increases linearly with the integration time of the irradiation. As it is a thermal noise, cooling the device reduces the dark current drastically. Most of the image sensors report a dark current of 1 to 2 e-s at the room temperature. Although many modern techniques employed have brought the dark current to a very low value, but still these techniques are insufficient to reduce generation at all interface regions. Dark current still remains a big hurdle for the modern scaled and radiation exposed image sensors. 6 3 DARK CURRENT MODEL In a field-free area, due to the thermal equilibrium, product of electron concentration ( ) and hole concentration ( ) is a constant ( ) ( is the intrinsic carrier concentration of the semiconductor). Therefore, at low temperature (low energy), rate of generation and recombination balance each other leading to a net zero carrier increase. On the other hand, in a depletion region (e.g., reverse biased photodiode) due to a high electric field (ionized impurities), the thermal equilibrium is disturbed leading to more rate of minority carrier generation than recombination. Due to the high electric field, these generated charges effectively drift and are collected in the potential well. At high temperature (high energy), the dark carriers may also be generated in the field-free area, but due to the absence of an electric field rarely diffuse to the potential well. In case of various process defects in the device bulk or surface and/or different impurities at the material interfaces, the dark current drastically increases. This is due to the impurities with energy states between the valence and conductance band which act as steps facilitating the transition of electrons between the valance and conductance bands (Figure 7). Figure 7 Trap assisted generation process (Donor and Acceptor types) In case of non-thermal equilibrium, the traps with energies E close to the intrinsic t Fermi level energy E of the semiconductor are the major contributors to the dark current F generation. Figure 8 shows different dark current sources in a CIS PPD. It is known that the trap density increases at the surface and interfaces between different materials due to impurities and process defects. Hence an important part of the dark current generation occurs at the level of the PPD surface and the Si-SiO interface under the transfer gate and 2 at the level of interfaces with shallow trench channel (STI). Figure 8 Various Dark current sources in a CIS PPD. 7

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