Modern dehydrogenative amination reactions. vom Fachbereich Chemie der Technischen Universität Kaiserslautern zur Verleihung des akademischen Grades “Doktor des Naturwissenschaften” genehmigte Dissertation D 386 Vorgelegt von Marie-Laure Louillat Habermeyer, M.Sc. Geboren in Dijon (France) Betreuer Prof. Dr. Frederic W. Patureau Kaiserslautern, 2015 Promotionskommission: Vorsitzender: Prof. Dr. Werner Thiel Berichterstatter: Prof Dr. Frederic W. Patureau Berichterstatter: Prof. Dr. Stefan Kubik Datum der wissenschaftlichen Aussprache: 27/02/2015 Die vorliegende Arbeit entstand in der Zeit zwischen February 2012 und December 2014 in den Laboratorien des Fachbereichs Chemie an der Technischen Universität Kaiserlsautern. Eidesstattliche Erklärung Hiermit versichere ich, dass ich die vorliegende Arbeit eigenständig verfasst, keine anderen als die angegebenen Quellen und Hilfsmittel verwendet und Literaturzitate kenntlich gemacht habe. Ich erkläre außerdem, dass diese Arbeit weder in gleicher noch in ähnlicher Form bereits in einem anderen Prüfungsverfahren vorgelegen hat. Kaiserslautern, den_________2015 ___________________________ Marie-Laure Louillat Habermeyer Acknowledgements None of this work would have been possible without the help, the support and the availability of my Director of Thesis, Dr. Frederic Patureau, Professor at the University of Kaiserslautern. It was for me a great pleasure and a privilege to spend these three years of PhD under his management. I thank him for his confidence, his advice, the experience and his vision of chemistry that he provided to me during many scientific discussions that we have the opportunity to share. Thanks to you! I would like to thank Dr. Werner Thiel and Dr. Stefan Kubik, Professors at the University of Kaiserslautern, for being in the examination committee of my dissertation. For the financial support during my Ph.D., I thank the DFG-funded Transregional Collaborative Research Center SFB/TRR 88 ‘‘Cooperative effects in homo- and heterometallic complexes (3MET)’’ and the DFG funded project PA 2395/2-1. I also thank Dr. Harald Kelm and Mrs Christiane Müller from NMR facility, Mrs. Biel, Mrs. Dusch, Mrs. Ellmer and Mrs Bergstässer from the analytical department, and Mr. Napast, Mr Rahm, Mr. Schröer from the chemical storage facility. Thanks to Dr. Harald Kelm, from the University of Kaiserlsautern, for all crystal structure analysis. I want to thank everyone who participated directly or indirectly during these three years including my co-workers and friends Agostino Biafora for the nice project of lauternamines, Alexandre Jones for the project of phenylcarbazoles and Rongwei Jin for the project of lauternols, without forgetting the trainees that I had the pleasure to supervise: Luca Agnetta and Fabien Legros. This has been particularly pleasant to work close to the group of Prof. Dr. Lukas Goossen whom I warmly thank especially Gregory Danoun, Sabrina Baader, Stefania Trita, Agostino Biafora, Christian Matheis, Bilguun Bayarmagnai, Sukalyan Bhadra, Wojciech Dzik, Dmitry Katayev, Kevin Jouvain, Andreas Fromm, Bingrui Song, Jie Tang, Matthias Grünberg, Patrizia Mamone and Patricia Podsiadly, Benjamin Erb, Eugen Risto, Kai Pfister, Thilo Krause, Timo Wendling, Dagmar Hackenberger for good time, help and nice party. I would like to thank my husband who let me accomplish my dream of PhD far from him. Mes derniers mots vont à ma famille qui m’a toujours encouragée et soutenue dans tous mes projets. i ii
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