Mo Organomolybdenum Compounds

409 Pages·1992·9.78 MB·English

by  Hans Schumann (auth.)

2 Hel 10 Ne I 18 Ar I 36 Kr I 54 Xe I 86 Rn I H,231
~
I
I H2 9 F5 17 Cl 6 35 Br 7 53 I 8 85 At8a
8 0 3 16 s 9 34 Se 10 52 Te II 84 p12 0 71 Lu 103 Lr 71
7 N 4 15 p 16 33 As 17 51 Sb 18 83 Bi 19 70 Yb 102 No 71
6 c 14 14 Si 15 32 Ge45 50 Sn 46 82 Pb 47 69 Tm 101 Md 71
bers 5 B 13 13 Al35 31 Ga36 49 In 37 81 Tl 38 68 Er 100 Fm 71
m Num 30 Zn 32 48 Cd 33 80 Hg34 67 Ho 99 Es 71
n Syste 29 Cu 60 47 Ag 61 79 Au 62 66 Dy 98 Cf 71
e Gmeli 28 Ni 57 46 Pd 65 78 Pt 68 65 Tb 97 Bk71
with th 27 Co 58 45 Rh64 77 Ir 67 64 Gd 96 cm71
ments 26 Fe 59 44 Ru 63 76 Os 66 63 Eu 95 Am71
e
of the El 25 Mn 56 43 Tc 69 75 Re 70 62 Sm 94 Pu 71
Table 24 Cr 52 42 Mo 53 74 w54 61 Pm 93 71 Np
eriodic 23 V 48 41 Nb49 73 Ta 50 105 71 60 Nd 92 u 55
P :
22 Ti 41 40 Zr 42 72 Hf 43 104 71 59 Pr 91 Pa 51 --
21 Sc 39 39 39 y 57** La 39 89*** Ac40 58 Ce i~44 '
4 Be26 12 Mg27 20 Ca 28 38 Sr 29 56 Ba 30 88 Ra31 an ides 39 ides
I H 2 3 Li 20 II Na21 19 * K 22 37 Rb24 55 Cs 25 87 Fr25a *Lanth **Actin
* ~

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Gmelin Handbook of lnorganic
and Organametallic Chemistry
8th Edition
Gmelin Handbock of lnorganic
and Organametallic Chemistry
8th Edition
Gmelin Handbuch der Anorganischen Chemie
Achte, völlig neu bearbeitete Auflage
PREPARED Gmelin-lnstitut für Anorganische Chemie
AND ISSUED BY der Max-Planck-Gesellschaft
zur Förderung der Wissenschaften
Director: Ekkehard Fluck
FOUNDED BY Leopold Gmelin
8TH EDITION 8th Edition begun under the auspices ot the
Deutsche Chemische Gesellschaft by R. J. Meyer
CONTINUED BY E. H. E. Pietsch and A. Kotowski, and by
Margot Becke-Goehring
Springer-Verlag Berlin Heidelberg GmbH 1992
Gmelin-lnstitut für Anorganische Chemie
der Max-Planck-Gesellschaft zur Förderung der Wissenschaften
ADVISORY BOARD
Prof. Dr. K. Dehnicke (Philipps-Universität, Marburg), Prof. Dr. H. Grünewald (Bayer AG,
Leverkusen), Prof. Dr. H. Harnisch, Chairman (Hoechst AG, Frankfurt/Main-Höchst), Prof. Dr.
H. Nöth (Universität München), Prof. Dr. H. Ottermanns (Degussa AG, Frankfurt/Main), Prof.
Dr. A. Sirnon (Max-Planck-lnstitut für Festkörperforschung, Stuttgart), Prof. Dr. Dr. h.c. mult.
G. Wilke (Max-Planck-lnstitut für Kohlenforschung, Mülheim/Ruhr), Prof. Dr. H. F. Zacher
(Präsident der Max-Planck-Gesellschaft, München)
DIRECTOR
Prof. Dr. Dr. h. c. Ekkehard Fluck
CORRESPONDENT MEMBERS OF THE SCIENTIFIC STAFF Dr. U. Krüerke, Dr. R. H. Miller, Dr. A. R.
Pebler, Dr. K. Rumpf
EMERITUS MEMBER OF THE INSTITUTE Prof. Dr. Dr. E. h. Margot Becke
CORRESPONDENT MEMBERS OF THE INSTITUTE Prof. Dr. Dr. h.c. Hans Bock
Prof. Dr. Dr. Alois Haas, Sc. D. (Cantab.)
GMELIN HANDBOOK
Dr. J. von Jouanne
Dr. L. Berg, Dr. H. Bergmann, Dr. J. Faust, J. Füssel, Dr. H. Katscher, Dr. R. Keim, Dr. E. Koch,
Dipl.-Phys. D. Kaschet, Dr. A. Kubny, Dr. P. Merlet, Dr. M. Mirbach, Prof. Dr. W. Petz, Dr. F. A.
Schröder, Dr. A. Slawisch, Dr. W. Töpper
Dr. R. Albrecht, Dr. G. Bär, D. Barthel, Dr. N. Baumann, Dr. K. Behrends, Dr. W. Behrendt, D.
Benzaid, Dr. R. Bohrer, K. D. Bann, Dr. U. Busch, A.-K. Castro, Dipl.-lng. V. A. Chavizon, E.
Cloos, A. Dittmar, Dipl.-Geol. R. Ditz, R. Dowideit, Dr. H.-J. Fachmann, B. Fischer, Dipl.-lng. N.
Gagel, Dipl.-Phys. D. Gras, Dr. K. Greiner, Dipl.-Bibl. W. Grieser, Dr. R. Haubold, Dipl.-Min. H.
Hein, Dipl.-Phys. C. Heinrich-Sterze!, H.-P. Hente, H. W. Herold, U. Hettwer, G. Hoell, Dr. G.
Hönes, Dr. W. Hoffmann, G. Horndasch, Dr. W. Huisl, Dr. M. lrmler, B. Jaeger, Dr. R. Jotter,
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Chem. C. Koeppel, Dr. M. Körfer, R. Kalb, Dr. M. Kotowski, E. Kranz, E. Krawczyk, Dipl.-Chem.
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E. Meinhard, M. Meßer, C. Metz, K. Meyer, E. Mlitzke, Dipl.-Chem. B. Mohsin, Dr. U. Neu
Becker, K. Nöring, Dipl.-Min. U. Nohl, Dr. U. Ohms-Bredemann, I. Rangnow, Dipl.-Phys. H.-J.
Richter-Ditten, E. Rudolph, G. Rudolph, Dipl.-Chem. S. Ruprecht, Dr. B. Sarbas, Dr. H. Schäfer,
Dr. R. Schemm, Dr. D. Schiöberg, V. Schlicht, Dipl.-Chem. D. Schneider, E. Schneider, A.
Schwärzet, Dr. B. Schwager, R. Simeone, Dr. C. Strametz, Dr. G. Swoboda, Dr. D. Tille, A.
Tuttas, Dipl.-Phys. J. Wagner, R. Wagner, Dr. E. Warkentin, Dr. C. Weber, Dr. A. Wietelmann,
Dr. M. Winter, Dr. B. Wöbke, K. Wolff
GMELIN ONLINE
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Maass, Dr. K. Müller, Dr. A. Nebel, Dipl.-Chem. R. Nohl, Dr. M. Nohlen, H. Reinhardt, Dr. B.
Rempter, Dipl.-lng. H. Vanecek
Organometallic Compounds in the Gmelin Handbook
The following Listing indicates in which volumes these compounds are discussed or are
referred to:
Ag Silber B 5 (1975)
Au Organogold Compounds (1980)
Be Organoberyllium Compounds 1 (1987)
Bi Bismut-Organische Verbindungen (1977)
Co Kobalt-Organische Verbindungen 1, 2 (1973), Kobalt Erg.-Bd. A (1961), B 1 (1963),
B 2 (1964)
Cr Chrom-Organische Verbindungen (1971)
Cu Organocopper Compounds 1 (1985), 2 (1983), 3 (1986), 4 (1987), Index (1987)
Fe Eisen-Organische Verbindungen A 1 (1974), A 2 (1977), A 3 (1978), A 4 (1980), A 5
(1981), A 6 (1977), A 7 (1980), Organoiron Compounds A 8 (1986), A 9 (1989), A 10
(1991), Eisen-Organische Verbindungen B 1 (partly in English; 1976), Organoiron
Compounds B 2 (1978), Eisen-Organische Verbindungen B 3 (partly in English; 1979),
B 4, B 5 (1978), Organoiron Compounds B 6, B 7 (1981), B 8, B 9 (1985), B 10 (1986),
B 11 (1983), B 12 (1984), B 13 (1988), B 14, B 15 (1989), B 16a, B 16b, B 17 (1990), B 18
(1991), B 19 (1992), Eisen-Organische Verbindungen C 1, C2 (1979), Organoiron
Compounds C 3 (1980), C 4, C 5 (1981), C 6a (1991), C 6b (1992), C 7 (1985), and Eisen
B (1929-1932)
Ga Organogallium Compounds 1 (1986)
Ge Organogermanium Compounds 1 (1988), 2 (1989), 3 (1990)
Hf Organohafnium Compounds (1973)
ln Organoindium Compounds 1 (1991)
Mo Organomolybdenum Compounds 5 (1992), 6 (1990), 7 (1991), 8 (1992) present volume
Nb Niob B 4 (1973)
Ni Nickel-Organische Verbindungen 1 (1975), 2 (1974), Register (1975), Nickel B 3( 1966),
and C 1 (1968), C 2 (1969)
Np, Pu Transurane C (partly in English; 1972)
Os Organoosmium Compounds A 1( 1992)
Pb Organolead Compounds 1 (1987), 2 (1990), 3 (1992)
Po Polonium Main Volume (1941)
Pt Platin C (1939) and D (1957)
Re Organorhenium 1, 2 (1989), 3 (1992)
Ru Ruthenium Erg.-Bd. (1970)
Sb Organoantimony Compounds 1, 2 (1981), 3 (1982), 4 (1986), 5 (1990)
Sc, Y, D 6 (1983)
La to Lu
Sn Zinn-Organische Verbindungen 1, 2 (1975), 3, 4 (1976), 5 (1978), 6 (1979), Organotin
Compounds 7 (1980), 8 (1981), 9 (1982), 10 (1983), 11 (1984), 12 (1985), 13 (1986), 14
(1987), 15, 16 (1988), 17 (1989), 18 (1990)
Ta Tantal B 2 (1971)
Ti Titan-Organische Verbindungen 1 (1977), 2 (1980), Organotitanium Compounds 3
(1984), 4 and Register (1984), 5 (1990)
U Uranium Suppl. Vol. E 2( 1980)
V Vanadium-Organische Verbindungen (1971), Vanadium B (1967)
Zr Organozirconium Compounds (1973)
Gmelin Handbock of lnorganic
and Organemetallic Chemistry
8th Edition
Mo
Organomolybdenum
Compounds
Part 8
With 55 illustrations
AUTHOR Hans Schumann (Bielefeld)
FORMULA INDEX Bernd Kalbskopf, Uwe Nohl, Hans-Jürgen Richter-Ditten,
Edgar Rudolph
EDITOR Manfred Winter
CHIEF EDITOR Wolfgang Petz
Springer-Verlag Berlin Haideiberg GmbH 1992
LlTERATURE CLOSING DATE: END OF 1989
IN SOME CASES MORE RECENT DATA HAVE BEEN CONSIDERED
Library of Congress Catalog Card Number: Agr 25-1383
ISBN 978-3-662-08859-3 ISBN 978-3-662-08857-9 (eBook)
DOI 10.1007/978-3-662-08857-9
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© by Springer-Verlag Berlin Heidelberg 1992
Originally published by Springer-Verlag Berlin Heidelberg New York Tokyo in 1992
Softcover reprint of the hardcover Bth edition 1992
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Preface
This volume 8 is the fourth in a series dealing with organomolybdenum compounds. An
Empirical Formula Index and a Ligand Formula Index provide ready access to the compounds
covered.
Volume 5 describes mononuclear organomolybdenum compounds with isocyanide,
carbene, carbyne, alkynyl, alkene, alkyne, 3L, and 4L ligands with and without additional CO
groups. Volume 6 starts the description of mononuclear organomolybdenum compounds with
one 5L Ligand, a Ligand bonded to molybdenum by five carbon atoms. The compounds contain
either zero or one CO group bonded to the molybdenum atom. Volume 7 continues the
description of 5L-molybdenum compounds containing two CO groups, but no additional nl
ligands. This volume describes 5L-molybdenum compounds with two CO groups and additional
1L to 4L ligands. Following the nomenclature used in this series of organomolybdenum com
pounds, nl is an organic Ligand bonded by n C atoms to molybdenum, and mo is an electron
donor Ligand with m donor electrons. Thus 20 denotes a Ligand such as PR3.
Many of the data, particular those in tables, are given in an abbreviated form without units;
for explanations see p. X. Additional information, if necessary, is given before the individual
table.
Frankfurt am Main Manfred Winter
November 1992 Wolfgang Petz