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Pearson New International Edition Mineralogy Dexter Perkins Third Edition International_PCL_TP.indd 1 7/29/13 11:23 AM ISBN 10: 1-292-03911-6 ISBN 13: 978-1-292-03911-4 Pearson Education Limited Edinburgh Gate Harlow Essex CM20 2JE England and Associated Companies throughout the world Visit us on the World Wide Web at: www.pearsoned.co.uk © Pearson Education Limited 2014 All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, without either the prior written permission of the publisher or a licence permitting restricted copying in the United Kingdom issued by the Copyright Licensing Agency Ltd, Saffron House, 6–10 Kirby Street, London EC1N 8TS. All trademarks used herein are the property of their respective owners. The use of any trademark in this text does not vest in the author or publisher any trademark ownership rights in such trademarks, nor does the use of such trademarks imply any affi liation with or endorsement of this book by such owners. ISBN 10: 1-292-03911-6 ISBN 10: 1-269-37450-8 ISBN 13: 978-1-292-03911-4 ISBN 13: 978-1-269-37450-7 British Library Cataloguing-in-Publication Data A catalogue record for this book is available from the British Library Printed in the United States of America Copyright_Pg_7_24.indd 1 7/29/13 11:28 AM 11111112466902367891193719137795 P E A R S O N C U S T O M L I B R AR Y Table of Contents Glossary Dexter Perkins 1 1. Elements and Minerals Dexter Perkins 23 2. Crystallization and Classification of Minerals Dexter Perkins 47 Crystallization and Classification of Minerals Color Plates Dexter Perkins 67 3. Mineral Properties: Hand Specimen Mineralogy Dexter Perkins 69 Mineral Properties: Hand Specimen Mineralogy Color Plates Dexter Perkins 95 4. Optical Mineralogy Dexter Perkins 101 Optical Mineralogy Color Plates Dexter Perkins 129 5. Igneous Rocks and Silicate Minerals Dexter Perkins 133 Igneous Rocks and Silicate Minerals Color Plates Dexter Perkins 167 6. Sedimentary Minerals and Sedimentary Rocks Dexter Perkins 171 Sedimentary Minerals and Sedimentary Rocks Color Plates Dexter Perkins 189 7. Metamorphic Minerals and Metamorphic Rocks Dexter Perkins 191 I 222223333444555555511337014678922334455779359379735937133 Metamorphic Minerals and Metamorphic Rocks Color Plates Dexter Perkins 215 8. Ore Deposits and Economic Minerals Dexter Perkins 217 Ore Deposits and Economic Minerals Color Plates Dexter Perkins 237 9. Crystal Morphology and Symmetry Dexter Perkins 239 10. Crystallography Dexter Perkins 273 11. Unit Cells, Points, Lines, and Planes Dexter Perkins 305 12. X-ray Diffraction and Mineral Analysis Dexter Perkins 319 13. Atomic Structure Dexter Perkins 343 Descriptions of Minerals Dexter Perkins 367 Descriptions of Minerals Color Plates Dexter Perkins 479 Appendix: Classified List of Minerals Dexter Perkins 487 Appendix: Mineral Identification Tables Dexter Perkins 493 Appendix: Minerals Separated by Optic System and Sign, and Ordered by Index of Refraction Dexter Perkins 525 Appendix: Minerals Ordered by Birefringence and Interference Colors in Thin Section Dexter Perkins 529 Appendix: Minerals Ordered by Hardness Dexter Perkins 533 Appendix: Minerals Ordered by Specific Gravity Dexter Perkins 537 Coordination Numbers and Effective Ionic Radii Dexter Perkins 541 List of Mineral Properties Dexter Perkins 543 Periodic Table of the Elements Dexter Perkins 553 II 555 Index 555 III This page intentionally left blank GLOSSARY Absolute hardness. A numerical measure of a mineral’s Andesite. An extrusive igneous rock of intermediate com- hardness; typically determined by indentation measurements position containing plagioclase as the only major feldspar; (c.f.relative hardness). minor K-feldspar or quartz, pyroxene, biotite, and horn- blende may be present. Accessory mineral. A mineral present in small amounts in a rock, unimportant for rock naming or classification. Angle of incidence. The angle that an impinging ray makes with a normal to an interface. Accessory plate. A plate that may be inserted in the tube of a polarizing light microscope to produce interference Angle of refraction. The angle that a refracted ray makes colors of known birefringence. Typically made of quartz, with a normal to an interface. gypsum, or mica. Anhedral. A crystal that lacks well-developed crystal faces Acicular. Having a needle-like shape. or that has rounded or irregular form due to crowding by adjacent crystals. Actinide. Elements (such as Th, Pa, and U) with atomic numbers 90 through 103 and valence electrons in 5f Anion. An ion having a negative charge. orbitals. Anionic complex. A tightly bonded, negatively charged Acute bisectrix. A line bisecting the angle formed by the molecular group; in mineral formulas, often surrounded by two optic axes in a biaxial mineral. parentheses. Acute bisectrix figure (Bxa). The interference figure seen Anisodesmic. Describing an ionic compound in which the when looking down an acute bisectrix. ionic bonds are not all of the same strength. Adamantine. A type of luster that is bright, sparkly, and Anisotropic. Having different physical properties in differ- shiny, similar to that of diamonds. ent directions. Aggregate (of crystals). A mass of crystals, of the same or Anomalous interference colors. Interference colors that different minerals, that may be physically separated, per- are not represented on the Michel Lévy Chart; typically as- haps with some difficulty. sociated with minerals of extremely low birefringence, such as chlorite. Albite law. A common twin law in triclinic feldspars, often resulting in polysynthetic twins. Aphanitic. Having no mineral grains that are visible to the naked eye. Alchemy. Chemistry of the Middle Ages that combined sci- ence, magic, and philosophy. Aqueous solution. A water-rich solution, usually contain- ing dissolved elements or complexes. Alkali element. Any element (such as Li, Na, or K) of the Arborescent. A term describing an aggregate of crystals first group in the Periodic Table of the Elements; alkali ele- having a tree-like appearance (see alsodendritic). ments typically ionize to form monovalent cations. Arenite. General term for detrital sedimentary rocks com- Alkaline earth element. Any element (such as Be, Mg, or posed of sand-sized grains and lithic fragments; includes sand- Ca) of the second group in the Periodic Table of the stone, graywacke, arkose, and others (see alsopsammite). Elements; alkaline earth elements typically ionize to form divalent cations. Arkose. A feldspar-rich sandstone. Allochromatic. A term describing a mineral that gets its Asbestiform. A crystal habit characterized by fine thread- color from minor or trace elements (see alsoidiochromatic). like, fibrous, or acicular crystals; more specifically, some- times defined as a crystal habit with a length:diameter ratio Alloy. A noncrystalline mixture of two or more metals. of more than 3:1. Alluvium. Unconsolidated sediment deposited by a stream. Asbestos. A general term referring to minerals that have an Amorphous. Having a random atomic structure (see also asbestiform habit; chrysotile, amosite, and crocidolite are noncrystalline). typical asbestos minerals. Amphibolite (facies). One of the principal metamorphic Association (mineral). A group of minerals found to- facies introduced by Eskola, corresponding to high-grade gether in a rock. conditions of about 450 to 650 °C and 3 to 8 kbar. Asterism. The play of colors seen in some minerals that Amphibolite (rock). A metamorphic rock containing pri- produces a rayed or star-shaped figure when viewed in di- marily hornblende and plagioclase. rect light; a star sapphire is one example. Analyzer. A polarizing filter that can be inserted in the Atmophile. An element that tends to concentrate in the upper column of a polarizing light microscope to view Earth’s atmosphere. minerals under crossed-polarized light (see also upper Atomic absorption spectrophotometer. An analytical polarizer). instrument in which composition is determined by measur- Anatexis. Partial melting of preexisting rock, generally as- ing the absorption of characteristic wavelengths of light by sociated with high-grade metamorphism. an atomized and flamed sample. From the Glossary of Mineralogy, Third Edition, Dexter Perkins. Copyright © 2011 by Pearson Education, Inc. Published by Pearson Prentice Hall. All rights reserved. 1 Glossary Atomic absorption spectroscopy (AAS). A technique for Bauxite. Name given to a rock or a mineral-like material determining the concentration of a particular element in a sam- composed primarily of a mixture of aluminum oxides and ple that is based on light absorption by an atomized sample. hydroxides such as boehmite and gibbsite; bauxite is the most significant aluminum ore. Atomic mass unit (amu). Unit for expressing atomic mass, equal to approximately 1.6610 ×10-27kg. Baveno twin. An uncommon twin law in feldspar. Atomic number (Z). The number of protons in the Becke line. A bright line, visible under a microscope, that nucleus of an atom of an element. separates substances of different refractive indices. Atomic weight. The weight of an atom or compound in Bentonite. A clay-rich, earthy material formed by devitri- atomic mass units; generally close to the total number of fication and alteration of tuff or volcanic ash; sometimes protons and neutrons. used more generally to refer to any clay deposit rich in montmorillonite. Aufbau principle. The principle that states that electrons fill orbitals in a systematic way from the lowest energy Berman balance. A type of balance scale used to deter- orbitals to the highest. mine specific gravity. Augen. Large lenticular mineral grains or mineral aggre- Bertrand lens. A lens that can be inserted in the tube of a polarizing light microscope to facilitate observation of in- gates in a foliated metamorphic rock. terference figures. Augen gneiss. A gneiss containing augen. Biaxial. Describing a crystal having two optic axes and Aureole. A contact metamorphic zone surrounding an three principal indices of refraction (α, β, and γ). Such igneous intrusion (see alsocontact aureole). crystals belong to the orthorhombic, monoclinic, and tri- Authigenic. Formed or generated in place; used to de- clinic crystal systems. scribe minerals that form in a sediment or sedimentary Binary solution. A solid solution series that can be char- rock after deposition of an original sediment. acterized by two end members. Avogadro’s number. 6.022 * 1023, equivalent to the Biogenic. Produced by living organisms or biological number of atoms or molecules in a mole. processes. Axial ratio The ratio of unit cell lengths along each crys- Birefringence (property). The property of a crystal that tallographic axis, a: b: c. causes double refraction. Axis (crystallographic). One of three axes used to de- Birefringence (value). The difference between the great- scribe the geometry of a crystal lattice and the locations of est and least indices of refraction of a crystalline substance. points and planes in a unit cell. Bladed. Having the appearance of blades. Axis (rotational). A symmetry element that relates iden- Blocky. A term used to describe crystals that have a tical crystal faces or other things by rotation of 60°, 90°, block-like appearance, generally with a nearly square 120°, 180°, or 360°about an axis. cross section. Backscatter electrons. High-energy electrons that are es- Blueschist (facies). One of the principal metamorphic fa- sentially reflected by the surface of a sample. cies introduced by Eskola, corresponding to high pressure– Banded iron formation (BIF). A layered rock contain- low temperature conditions. ing chert, silicate, carbonate, or oxide layers, giving a Blueschist facies series. A facies series characterized by banded appearance. high pressures at relatively low temperatures; typical of Barrovian facies series. The “normal” metamorphic facies subduction zone environments. : series described by George Barrow; the most common se- Blueschist (rock). A vague term used to describe fine- y y r g quence of metamorphic rocks that forms at mid-crustal depths. grained, bluish colored rocks diagnostic of the blueschist sa alo Basal cleavage. A term used to describe the cleavage in facies. Key minerals include blue amphiboles (glauco- s er minerals such as micas that allows the mineral to break phane and riebeckite), lawsonite, jadeite, and aragonite. Glo Min into plates or sheets. Body centered. Said of a unit cell that has an extra lattice Basalt. An extrusive igneous rock of mafic composition point at its center. containing plagioclase as the only major feldspar; clinopy- Body diagonal. A line passing through the center of a roxene ; orthopyroxene ; olivine are typically present cube or other three-dimensional geometric shape and con- (see alsogabbro). necting opposite corners. Basement rock. Metamorphic and igneous rocks that Bohr model of the atom. A fundamental model of an underlie sediments and sedimentary rocks observed at Earth’s atom that describes electrons orbiting atomic nuclei in or- surface; often, though not exclusively, of Precambrian age. bits associated with specific energy levels. Basis. A sufficient set of symmetry operators for describ- Bomb. A laboratory reactor vessel used to conduct exper- ing the symmetry of crystals (point symmetry) or of atomic iments and synthesize gems and minerals at high pressure structures (space symmetry). and temperature. Batholith. A large mass of intrusive igneous rock that so- Bort. Diamond of low quality that is unsuitable as a gem lidified within the earth. but useful in industrial applications. 2 Glossary Botryoidal. A term used to describe a mineral habit that Cathode ray tube. Vacuum tube in which beams of high- appears like a bunch of grapes. energy electrons pass through magnetic fields and hit a fluorescent screen. Boule. A oblong-shaped synthetic mineral crystal that is produced from the Verneuil technique. Cation. An ion having a positive charge. Bowen’s reaction series. A hypothetical series that de- Cementation. Lithification of clastic sediments resulting scribes the order of crystallization of minerals from a from the deposition or precipitation of minerals in the magma. spaces between individual clastic grains; it may occur at the time of deposition or during diagenesis. Bragg law. A mathematical law that describes the rela- tionship between the angle of diffraction (θ), X-ray wave- Centered. Said of a unit cell that has (an) extra lattice length (λ), and atomic plane spacing (d); nλ=2dsinθ. point(s) at its center, in the center of its faces, or in the center of two opposing faces. Bravais lattices. The fourteen possible three-dimensional lattices that can describe mineral structures. Chain silicates. Silicate minerals characterized by SiO 4 tetrahedra joining to form chains either one tetrahedron or Brazil law. A common type of twinning in quartz. two tetrahedra wide (see alsoinosilicates). Breccia. A clastic sedimentary rock composed of large Chalcophile. An element that tends to concentrate in sul- (> 2mm diameter) angular broken rock fragments in a fide minerals and ores. finer grained matrix. Characteristic radiation. High-intensity radiation of one Bridging oxygen. An oxygen atom in a crystal structure or a few wavelengths emitted by the target of an X-ray that is shared by two or more equivalent coordinating tube; the wavelength(s) of characteristic radiation depend polyhedra. on the elements in the target. Brittle. A term used to describe minerals that shatter or Chatoyancy. The play of colors seen in some minerals in break easily when struck. which a silky sheen is seen to form a narrow band that Buchan facies series. A facies series characterized by changes position as the mineral is turned; for example, similar temperatures but lower pressures than the cat’s-eye chrysoberyl. Barrovian facies series, characterized by the presence of Chemical precipitate. A solid that precipitates from an andalusite and sometimes cordierite. aqueous solution, typically due to supersaturation. Brucite layer. A sheet of Mg(OH) octahedra in a layered 6 Chemical sedimentary rock. A sedimentary rock crystal structure. composed primarily of material formed by precipitation Burial metamorphism. Metamorphism affecting a large from solution; for example, most limestones and all region; caused by pressure related to depth in Earth and evaporites. temperature related to geothermal gradient (see also re- Chemical sediments. Sediments produced by dissolu- gional metamorphism). tion and precipitation resulting from chemical weathering; Cabochon. A gemstone that has been ground and pol- they may precipitate where weathering occurs or at a dif- ished into a domed shape. ferent place. Calcine. To heat material, such as limestone, to high tem- Chemical weathering. Type of weathering involving perature, breaking down minerals and driving off carbon chemical reactions that transform or decompose minerals dioxide or other volatiles. and rock. Capillary. Having a hair-like or thread-like appearance Chert. A hard sedimentary rock composed primarily of (see alsofiliform). cryptocrystalline silica, generally in the form of fibrous chalcedony with lesser amounts of quartz and opal. Carbonate (mineral). A group of minerals with formulas characterized by (CO )2- radicals. Chromophores. Elements that give minerals their color. 3 Carbonate (radical). The (CO )2- anionic group. Class. Seecrystal class. 3 Carbonate (rock). A chemical sedimentary rock domi- Clast. A mineral grain, lithic fragment, or organic remnant nated by carbonate minerals; limestone or dolostone. that is produced by mechanical weathering and becomes part of a clastic sediment or rock. Carbonation reaction. Reaction of a mineral or minerals with CO to produce a product carbonate mineral. Clastic. Being composed of fragments (clasts) derived 2 from preexisting rocks. Carlsbad twin. A common twin law in orthoclase, less com- mon in other feldspars, often resulting in penetration twins. Clastic rock. Sedimentary rock formed by the lithification of clastic sediments; for example, sandstone, shale, and Cartesian coordinate system. An X-Y-Z coordinate sys- siltstone. tem in which all axes are at 90° and the unit distances along all axes are equal. Clausius-Clapeyron equation. An equation relating the slope of a reaction on a pressure-temperature diagram to the Cataclastic metamorphism. Metamorphism caused by a entropy and volume change of the reaction: dP/dT =Δ S/Δ V. transient high-pressure condition such as a meteorite impact (see also shock metamorphism and dynamic meta- Clay (grain size). A clastic fragment of any composition morphism). smaller than silt, having a diameter less than 1 mm. >256 3

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