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Microscopic theory of equilibrium properties of F/S/F trilayers with weak ferromagnets PDF

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Preview Microscopic theory of equilibrium properties of F/S/F trilayers with weak ferromagnets

Microscopic theory of equilibrium properties of F/S/F trilayers with weak ferromagnets R. M´elin∗ Centre de Recherches sur les Tr`es Basses Temp´eratures (CRTBT)†, Boˆıte Postale 166, F-38042 Grenoble Cedex 9, France 4 0 The aim of this paper is to explain the non monotonic temperature dependence of the self- 0 consistentsuperconductinggapofferromagnet/superconductor/ferromagnet (F/S/F)trilayerswith 2 weak ferromagnets in the parallel alignment (equivalent to F/S bilayers). We show that this is n due to Andreev bound states that compete with the formation of a minigap. Using a recursive a algorithmwediscussindetailtherolesofvariousparameters(thicknessesofthesuperconductorand J ferromagnets, relative spin orientation of the ferromagnets, exchange field, temperature, disorder, 3 interface transparencies). 2 PACSnumbers: 74.78.Na,74.45.+c,74.50.+r ] l l a I. INTRODUCTION netic layers15,16,17,18,19. The bad quality of interfaces h may however also play a role in these experiments20,21. - s Direct evidences of the π-coupling have been obtained e Inconventionalsuperconductivitythe attractiveinter- recently22,23,24,25. The proximity effect at F/Sinterfaces m action mediated by phonons binds electrons into Cooper isrelatedtotheformationoftheso-calledAndreevbound . pairs that condense in the BCS groundstate with a zero t states. Andreev bound states were first discussed by a temperaturegap∆tothefirstquasiparticleexcitations1. de Gennes and Saint-James26 and Andreev27 for normal m In ferromagnetism electron interactions generate a spin metal(N)/Sinterfaces. Severaltheoreticalinvestigations - symmetry breaking that can be described by the Stoner ofAndreevboundstatesatF/Sinterfaceshavebeenpre- d modelinwhichelectronssubjecttoanexchangefieldh n ex sentedrecently21,28,29 as wellasnumericalinvestigations acquire a Zeeman energy. o of the proximity effect at F/S interfaces, based on simu- c Many physical phenomena are involved at the inter- lations of the Bogoliubov-de Gennes equations30. [ faces between superconductors (Ss) and ferromagnets The interest in the inverse proximity effect (the prop- 2 (Fs). For instance it was shown in the early 1970’s that ertiesofthesuperconductor)atF/Sinterfacesdatesback v the Fermi surface spin polarization of a ferromagnetic tothe1960’s31,32,33whereitwasshownthatwithinsulat- 9 metal could be measured by spin-resolved tunneling be- ing ferromagnets an exchange field is induced in the su- 2 tween a ferromagnet and a superconducting film in the 0 presence of Zeeman splitting2. The Fermi surface spin perconductingelectrodeofaF/S/Ftrilayerinthe paral- 2 lelalignment. Thetheoreticalpredictionbyde Gennes31 polarization was measured more recently3,4 by Andreev 1 was further confirmed by experiments in the late 1960’s reflection at F/S interfaces5 with highly transparent in- 3 with metallic32 and insulating33 ferromagnets. Recent 0 terfaces, not in thin film geometries. The non equilib- experimentswerecarriedoutwithmetallicferromagnets, / riumspinpopulationintheferromagnetplaysalsoarole t whichconfirmedthe effect onthe criticaltemperature34. a in Andreev reflection at F/S interfaces6,7,8. Andreev re- It was shown recently35,36 that an exchange field in the m flection with Zeeman splitting in a thin film geometry superconductor exists also with metallic ferromagnets - could be another way to probe the Fermi surface spin but the sign of the magnetization in the superconduc- d polarization9. n tor is opposite to the magnetization in the ferromagnet. o These experiments can be interpreted without dis- An exchange field in a superconductor is pair breaking. c cussing the proximity effect (the pair correlations in- As a consequence the superconducting transition tem- v: duced in the normal metal or ferromagnet) that has fo- perature in the parallel alignment is smaller than in the i cused an important interest recently. It is well estab- antiparallel alignment. X lished both theoretically and experimentally that the With metallic ferromagnets the proximity effect may r pair amplitude induced in a ferromagnetic metal oscil- a influence the value of the superconducting gapandtran- lates in space and can become negative10,11,12,13,14, giv- sition temperature. It was realized recently36,37,38,39,40 ing rise to the π-coupling. The π-coupling generates that the proximity effect in F/S/F trilayers is quite oscillations of the critical temperature of F/S multi- special since under some conditions the zero temper- layers as a function of the thickness of the ferromag- ature superconducting gap in the parallel alignment can be larger than in the antiparallel alignment. This was established36,37 within a model of multitermi- nal hybrid structure originally proposed for transport ∗E-mail: [email protected] †U.P.R.5001duCNRS,Laboratoireconventionn´eavecl’Universit´e properties41,42,43,44,45 and is related to spatially sepa- JosephFourier ratedsuperconducting correlationsamong the two ferro- 2 magnets. The same behavior was found within a model D of F/S/F trilayer with atomic thickness and half-metal ferromagnets39, which was finally extended to Stoner ferromagnets40. H (a) F S F y Other physical effects take place with weak ferromag- x nets for which the exchange field is smaller than the su- perconducting gap, as indicated by the reentranceof the z L L 0 F L F critical temperature of F/S superlattices as a function S of the exchange field46,47, and by the reentrance of the critical temperature of F/S bilayers as a function of the thickness of the ferromagnet38,48,49. The full tempera- (b) W S F ture dependence of the self-consistent superconducting gap was calculated in Ref. 40 and it was shown that for F/SbilayersorF/S/Ftrilayerswithatomicthicknessthe superconductinggapcanhaveanonmonotonictempera- d’ ture dependence: withina givenrangeofparametersthe d superconducting gap first increases as temperature T is reduced,reachesa maximum, anddecreasesto zero asT FIG. 1: (a) Schematic representation of the F/S/F trilayer. D and H are sent to to infinity (infinite planar geometry). is further reduced. Within a narrow range of interface transparencies there exists also a reentrant behavior of Theferromagnets(superconductor)aremadeofLF (LS)lay- ers stacked in the lateral (z) direction. (b) Schematic repre- the superconducting gap at low temperature40. sentation of the 2D F/S interface model29 considered in sec- tion VIIB. d′ is sent to infinity. The purpose of this article is to show that this behav- ior is related to the formation of Andreev bound states Ferromagnet Superconductor Ferromagnet that can compete with the formation of a superconduct- L =4 L =3 L =4 F S F ing minigap. We find a systematic correlation between Andreev boundstatesatthe Fermilevelanda reduction of the low temperature self-consistent superconducting gap, which constitutes the main result of this article. y The article is organized as follows. Preliminaries are given in section II in which we discuss the models and Layer a’ Layer a Layerα Layer β Layer b Layer b’ the Green’s functions formalism. A recursive algorithm, 0 z more efficient that the direct inversion of the Dyson matrix40, is presented in section III. Different regimes FIG. 2: Cut in the (z,y) plane of the F/S/F trilayer with canbeobtaineddependingonhowthelateraldimensions L of the superconductor and L of the ferromagnets (LS/a0,LF/a0) = (3,4), where a0 is the interplane spacing. S F The ferromagnets and the superconductor are infinite in the compare respectively (i) to the zero temperature lateral x and y directions. The left ferromagnet ends at the layers superconducting coherence length ξ(⊥) = 2t a /π∆28, a′ and a. The right ferromagnet ends at the layers b and b′. S 0 0 where t is the lateral hoping amplitude, and a is equal The superconductorends at layers α and β. 0 0 to the interatomic distance in the tranverse direction; and (ii) to the zero temperature lateral exchange length ξ(⊥) = 2t a /πh 28. We present a detailed investiga- F 0 0 ex II. PRELIMINARIES tion of the different regimes L ,L ξ(⊥) (section IV); F S ≪ S L . ξ(⊥) and L ξ(⊥) (section V); L ξ(⊥) and LS & ξS(⊥) (sectioFn V≪I).FWe cannot carrySou≪t a Ssystem- A. The models F F atic study of the regime L ξ(⊥) , L & ξ(⊥) which is S ∼ S F F too demanding from a computational point of view. In We suppose that the two ferromagnets of the F/S/F section VII we provide a comparison with other models trilayer have the same thickness L . We note L the F S proposed recently to describe Andreev bound states in thickness of the superconductor (see Fig. 1). The three F/S hybrids28,29. Concluding remarks are given in sec- electrodesaremadeof2Dplanesstackedalongthez axis tion VIII. (see Fig. 2). Eachsuperconducting plane is describedby 3 the BCS Hamiltonian B. Green’s functions (2D) = ǫ(k)c+ c (1) HBCS k,σ k,σ 1. Zero temperature Green’s functions k,σ X + ∆ c+ c+ +c c , The Green’s functions of an isolated superconduc- k,↑ −k,↓ k,↓ −k,↑ tor can be gathered in a 4 4 matrix in the spin Xk (cid:16) (cid:17) × ⊗ Namburepresentationbutintheabsenceofnoncollinear where the wave vector k is parallel to the 2D layer. The magnetizations44,50,51,52 the quantization axis can be freeelectrondispersionrelationwithinonelayerisǫ(k)= chosen parallel to the exchange field so that the 4 4 ~2k2/2m. The ferromagnets are described by the Stoner × Green’s functions reduce to two separate 2 2 matrices, model × one in each spin sector. For practical purpose we work in the spin-up sector. The Green’s function is given by (2D) = ǫ(k)c+ c (2) HStoner Xk,σ k,σ k,σ gˆx,y(t,t′)=−i (5) h c+ c c+ c , T c (t),c+ (t′) T (c (t),c (t′)) − ex k,↑ k,↑− k,↓ k,↓ h t x,↑ y,↑ i h t x,↑ y,↓ i , Xk (cid:16) (cid:17)  T (cid:16)c+ (t),c+ (t′)(cid:17) T c+ (t),c (t′)  h t x,↓ y,↑ i h t x,↓ y,↓ i where hex is the exchange field. The coupling between  (cid:16) (cid:17) (cid:16) (cid:17)  where x and y are two arbitrary sites in the supercon- twoplanesbelongingtothesamesuperconductingorfer- ductor and T is the usual T-product53. The “11” com- romagnetic electrode is given by t ponent describes the propagation of a spin-up electron, = =t c+ c +c+ c , the “22”component describes the propagationofa spin- WF−F WS−S 0 xL,σ xR,σ xR,σ xL,σ down hole and the “12” and “21” components describe xXL,σ(cid:0) (cid:1) superconductingcorrelations. AfterFouriertransforming (3) weobtainastandardexpressionforthedifferentelements whereas the coupling between the ferromagnets and the of the Green’s function53: superconductor is given by u2 v2 WF−S =t c+xL,σcxR,σ+c+xR,σcxL,σ , (4) gα1,,1α(ξ,ω) = ω−Ekk+iη + ω+Ekk−iη (6) xXL,σ(cid:0) (cid:1) f1,2(ξ,ω) = ∆ . (7) where the summation runs over all sites at the inter- α,α −[ω Ek+iη][ω+Ek iη] − − face (xL corresponds to a site on the left side and xR The variable ξ is related to the kinetic energy: ξk = is the corresponding site on the right side). The pa- ~2k2/(2m) ǫ whereǫ =~2k2/2mistheFermienergy. rameters are such that the coherence length within one E = ∆2−+Fξ2istheqFuasiparFticleenergyandu2 =(1+ lξa(y⊥e)r=ξS(2kt) =a /~πvF(∆k)/a∆realanrdgetrhtehtarnantvheerwseidctohheLrenocfetlheengstuh- fξakkc/tEor)sp/.2 and vk2k = (1−ξk/E)/2 are the BCS cokherence S 0 0 S perconductor. Themodelshouldstricktlyspeakingapply The Green’s function of a spin-up ferromagnet is di- to ballistic systems whereas real samples are usually in agonal in Nambu space. The “11” component is given the diffusive regime. However we can include disorder by in one particular case (the F/S/F trilayer with atomic 1 thickness, see section IVC). In this case the qualitative g1,1(ξ,ω)= , (8) a,a [ω ξ+h +iη sgn(ξ h )] behavior is robust against increasing disorder. Fabry- − ex − ex Perot resonances generate parity effects for small values andtheGreen’sfunctionsofaspin-downferromagnetare ofL andL inthe ballistic model. These parityeffects obtained by changing h into h . are Snot expFected to occur in the diffusive regime, but The Green’s functionesxGˆx,y−of etxhe connected trilayer do not occur either in our simulations if LS and LF are aregivenbytheDysonequationGˆ =gˆ+gˆ Σˆ Gˆ,where sufficiently large. By increasing LF and LS we obtain ina compactnotationΣˆ is the self-energy⊗corr⊗esponding a cross-over between the regime LF,LS . λF and the to the tunnel Hamiltonian (4) and corresponds to a regime λ . L ,L ξ(⊥). We find the same quali- summation over spatial variables and⊗a convolution over F F S ≪ S tative effects in the two regimes. Moreover we obtain in time variables. We look for non perturbative solutions sectionVanonmonotonicvariationoftheself-consistent of the Dyson equations suitable for describing Andreev superconducting gap as a function of the exchange field. bound states. This is compatible with the non monotonic variation of the critical temperature as a function of the exchange field38,48,49 obtained in the context of linearized Usadel 2. Finite temperature Green’s functions equations for disordered conductors. The compatibility between the two behaviors indicates the validity of our Finite temperature Green’s functions are obtained approach. through the analytic continuation ω iω and by sum- → 4 ming over the Matsubara frequencies ωn = (2n+1)πT B. Green’s functions of the connected trilayer where T is the temperature53. The superconducting gap is determined from the BCS self-consistency equation53 We note Gˆ the Green’s functions of the connected F/S/F trilayer (see Fig. 2). Layers a and α are con- d2k nected by a tunnel amplitude t = t and layers b ∆ =λT G1,2(k,iω ), (9) a,α α,a x (2π)2 x,x n and β are connected by a tunnel amplitude t = t . b,β β,b n Z X We use the notation t=t =t and denote by t the a,α b,β 0 tunnelamplitudewithineachlayer(seeEq.3andEq.4). whereλisthestrengthoftheattractiveelectron-electron The definition of the tunnel Hamiltonian that we use interaction. To evaluate (9) we change variable to ξ = ~2k2/(2m) ǫ and restrict the integral to ξ < ω . for the F/S/F trilayer is slightly different from the con- F D − | | ventional definition given by (4): To avoidintroducing new parameters we use ω =ǫ = D F ~2k2/2m. We note ∆ the superconducting gap of an t F 0 = c+ c +c+ c (12) isolated 2D layer. All energy scales will be compared to WFSF √2 x,y,α,σ x,y,a,σ x,y,a,σ x,y,α,σ x,σ ∆0. X(cid:0) (cid:1) t + c+ c +c+ c . √2 x,y,β,σ x,y,b,σ x,y,b,σ x,y,β,σ Xx,σ(cid:16) (cid:17) III. RECURSIVE ALGORITHM FOR THE With the factors √2 the F/S/F trilayer with L /a = 1 S 0 F/S/F TRILAYER in the parallelalignment is equivalent to the F/S bilayer with L /a =1 and a tunnel amplitude equal to t. The S 0 A. Green’s functions of an isolated electrode correspondence between the bi and trilayer is useful for checking the numerical simulations. For L /a 2 we S 0 ≥ carry out the simulations of the F/S/F trilayer but we We aim to describe F/S/F trilayers with a fi- notethatintheparallelalignmentthequalitativepredic- nite thickness of all electrodes. In this respect the tions are valid also for F/S bilayers as long as the thick- (L /a ,L /a ) = (1,1) trilayer is just viewed as a toy- S 0 F 0 ness of the superconductor is smaller than the coherence model: we use a mean field approach that does not in- length. corporate the phase fluctuations of the order parameter We note Kˆ = hˆ tˆ hˆ tˆ , Kˆ = andwe do notconsiderpossible instabilities suchasspin α,α α,α α,a a,a a,α β,β or charge density wave. hˆβ,βtˆβ,bhˆb,btˆb,β, Kˆα,β = hˆα,βtˆβ,bhˆb,btˆb,β, Kˆβ,α = The ferromagnetic and superconducting electrodes of hˆβ,αtˆα,ahˆa,atˆa,α. The Green’s function Gˆα,α is given by the F/S/F trilayer consist of a finite number of layers −1 −1 stacked along the z axis and labeled from 1 to L (see Gˆ = Iˆ Kˆ Kˆ Iˆ Kˆ Kˆ (13) α,α α,α α,β β,β β,α − − − Fig.2). Twoconsecutivelayersnandn+1arecoupledby (cid:20) h i (cid:21) atunnelamplitudet . WeuseGreen’sfunctionsthatare −1 n ˆh +Kˆ Iˆ Kˆ ˆh , parametrized by the wave vector in the (x,y) direction × α,α α,β − β,β β,α and by the spatial coordinate in the lateral direction. (cid:20) h i (cid:21) and Gˆ is given by We note hˆ(L) the Green’s functions of the system of L β,α i,j layers in a given electrode and gˆi,i the Green’s function Gˆ = Iˆ Kˆ −1 hˆ +Kˆ Gˆ . (14) oftheisolatedlayernumberi. TheGreen’sfunctionˆh(L) β,α − β,β β,α β,α α,α L,L h i h i canbecalculatedrecursivelythroughamatrixcontinued TheGreen’sfunctionGˆ isdeducedfromGˆ through α,β β,α fraction: the relation Gˆτ1,τ2 = Gˆτ2,τ1, where τ and τ are the α,β β,α 1 2 ˆh(L) = Iˆ gˆ tˆ hˆ(L−1) tˆ −1gˆ . (10) Nambu indexes. Gˆβ,β is given by L,L − L,L L−1 L−1,L−1 L−1 L,L −1 h i Gˆβ,β = Iˆ Kˆβ,β hˆβ,β +Kˆβ,αGˆα,β . (15) − The local Green’s functions of the system of L stacked h i h i WededucethevaluesofGˆ ,Gˆ ,Gˆ andGˆ aswell layers are obtained through a,a b,b a,b b,a as G in the superconductor: i,i hˆ(L) =ˆh(L−1)+hˆ(L−1)tˆ ˆh(L)tˆ hˆ(L−1), (11) Gˆ = hˆ +hˆ tˆ Gˆ tˆ hˆ +hˆ tˆ Gˆ tˆ hˆ i,i i,i i,L−1 L−1 L,L L−1 L−1,i i,i i,i i,α α,a a,a a,α α,i i,α α,a a,b b,β β,i + hˆ tˆ Gˆ tˆ ˆh +hˆ tˆ Gˆ tˆ hˆ . (16) i,β β,b b,a a,α α,i i,β β,b b,b b,β β,i where hˆ(L) and ˆh(L) are calculated recursively through i,L L,i To obtain the pair amplitude in the ferromagnets and the relations hˆ(LL,i) = hˆ(LL,L)tˆL−1hˆL(L−−11,i) and hˆ(i,LL) = superconductor we first calculate recursively the ˆh’s and hˆi(,LL−−11)tˆL−1hˆL(L,L). The computation time required to ob- next evaluate Gˆ1,2. The evaluation of the self-consistent superconducting gap is done either by dichotomy if tain hˆ(L) is proportional to L whereas it is proportional L,L LS/a0 =1,2orbyiterationsoftheself-consistencyequa- to L2 if one wants to calculate all the ˆh(L). tion (9) if L /a 3. i,i S 0 ≥ 5 1 0.75 ttt /// ∆∆∆t 000/ ===∆ 0000 =...578 1706 t tttt/ ////∆ ∆∆∆∆0 0000= ==== 1 57891.....70371 0.5 (att //) ∆∆00 == 10..47 (ctt //) ∆∆00 == 10..47 (et /)t ∆/ 0∆ =0 =2 .08 0.5 (LS,LF) = (1,1) (LS,LF) = (1,2) s) 0.25 0.25 nit 0 (a) (b) u ∆∆(T) / 0.705 tttt //// ∆∆∆∆0000 ==== 0011....89123715 ttttt ///// ∆∆∆∆∆00000 ===== 24578.....82603 OS (arb. 0.05 (btt //) ∆∆00 == 22..81 (dtt //) ∆∆00 == 22..81 (ftt )// ∆∆00 == 85..36 0.5 D (LS,LF) = (1,3) (LS,LF) = (1,4) L 0.25 0.25 (c) (d) 0 0 0 0.25 0.5 0.75 0 0.25 0.5 0.75 1 -2.5 0 2.5-2.5 0 2.5-2.5 0 2.5 T / ∆ 0 E / ∆ 0 FIG.3: Temperaturedependenceoftheself-consistentsuper- FIG.4: Energydependenceofthespin-upLDOS(inarbitrary conducting gap for the F/S/F trilayer in the parallel align- units) in the superconducting layer of the F/S/F trilayer in ment with (LS/a0,LF/a0) = (1,1) (a), (1,2) (b), (1,3) (c), (1,4) (d), with weak ferromagnets (hex/∆0 = 0.83). LF the parallel alignment with (LS/a0,LF/a0) = (1,3). The superconducting gap, equal to ∆ , is not self-consistent. (a) and LS are small compared to ξS(⊥,0) = 2t0a0/π∆0 = 17.7a0, and(b)correspondtoh /∆ =00,ξ(⊥) =∞(N/Sinterface). ξF(⊥) = 2t0a0/πhex = 21.2a0 and λF = 6.28a0. We use (c)and(d)correspondetxoh 0/∆ =F0.83, ξ(⊥) =21.2a (F/S ∆0/ǫF =0.014 and t0/ǫF =0.4. interface with weak ferromeaxgnet0s). (e) anFd (f) corre0spond to h /∆ = 13.9, ξ(⊥) = 1.3a (F/S interface with strong ex 0 F 0 IV. F/S/F TRILAYERS WITH LS,LF ≪ξS(⊥),ξF(⊥) f8e.r3r×om1a0g−n3e,tλs)F. =We6.u28sea0∆.0/ǫF =0.014. t0/ǫF =0.4, η/∆0 = In this section we consider the regime L ,L S F ≪ ξ(⊥),ξ(⊥), establishaconnectionbetweenthe LDOSand nant case (see Figs. 3-(a) and (c)). This is because the S F the self-consistent superconducting gap, and show that effective couplingbetweenthe superconductorandferro- the regime h /∆ 1 is characterized by Andreev magnets is much weaker in the off-resonant case due to ex 0 bound states compet∼ing with the formation of a mini- the differences in the density of states. gap. 2. Role of the exchange field A. Self-consistent superconducting gap for weak ferromagnets in the parallel alignment We repeated the simulations for the F/S/F trilayer with (L /a ,L /a ) = (2,2) but with different values S 0 F 0 1. Role of the thicknesses of the electrodes of h /∆ . For the smallest value of h /∆ (h /∆ = ex 0 ex 0 ex 0 0.28)we obtaineda monotonicdecreaseof the supercon- ductinggapasafunctionoftemperatureforallvaluesof We have shownonFig. 3 the temperature dependence the tunnel amplitude. Forh /∆ =0.56,0.83,1.11,1.39 of the superconducting gap for values of (L ,L ) such ex 0 S F that L ,L ξ(⊥),ξ(⊥). We used L /a = 1 on Fig. 3 weobtainedanonmonotonictemperaturedependenceof S F ≪ S F S 0 the superconductinggapsimilarto Fig.3-(a)andFig.3- but similar results were obtained with L /a = 2. As S 0 (b). Thenonmonotonicvariationofthesuperconducting expected from Appendix A the breakdown of supercon- gap occurs typically for h being a fraction of ∆ up to ductivity in the resonant F/S/F trilayer in the parallel ex 0 values slightly above ∆ . alignment resembles the case (L /a ,L /a ) = (1,1)40: 0 S 0 F 0 as temperature is reduced the superconducting gap in- creases, reaches a maximum and decreases to zero. We B. Relation between the local density of states and obtain a reentrant behavior in a narrow range of inter- the self-consistent superconducting gap face transparencies (not shown on Fig. 3). By contrast we obtain a monotonic behavior for off-resonant values of (L /a ,L /a ), as expected from Appendix A. 1. Local density of states in the parallel alignment S 0 F 0 The values of the tunnel amplitude needed to destroy superconductivity for off-resonant trilayers (see Figs. 3- The spin-up LDOS ρ (ω) in the superconductor is ↑ (b) and (d)) is almost ten times larger than in the reso- shown on Fig. 4 for the F/S/F trilayer in the paral- 6 lel alignment, for (LS/a0,LF/a0) = (1,3). We ob- 0.3 tained similar results for (LS/a0,LF/a0) = (2,2). The TT/∆/∆0 = = 0 0.0.1576 spin-down LDOS ρ (ω) is obtained through the relation T/∆0 = 0.28 ↓ ) 0 s ρ↓(ω) = ρ↑(−ω). The zero temperature superconduct- nit ing gap ∆ is fixed to the BCS value ∆0 of an isolated u 0.2 superconducting layer. b. r The caseof a N/S interface is shownonFig. 4-(a) and a ( Fig. 4-(b). The LDOS is symmetric with respect to a S O 0.1 change of sign in energy, as expected in the absence of D an exchange field. There exists a minigap at the Fermi L energy so that superconductivity is robust against in- creasing the tunnel amplitude t. Increasing t gives rise 0 -2.5 0 2.5 topairsofAndreevboundstatesatoppositeenergies(see E/∆ Fig.4-(a)). Eachpeakcorrespondstoaminiband,which 0 is visible on Fig. 4-(b) obtained with larger values of t. FIG. 5: Energy dependence of the finite temperature The formation of the minibands is related to the infinite spin-up LDOS (in arbitrary units) in the superconducting planar geometry: the layers are infinite in the x and y layer of the F/S/F trilayer in the parallel alignment with directions (see Fig. 1) and there is thus a degeneracyas- (LS/a0,LF/a0) = (1,3). The zero temperature LDOS cor- sociated to the position of the Andreev bound state in responds to Fig. 4-(c) with t/∆ =1.4. 0 the (x,y) plane. The bound state can delocalize in the (x,y) plane and thus acquire a dispersion which would not occur if the dimensions H and D (see Fig. 1) were temperature LDOS is found to be smallcomparedtotheBCScoherencelength,asituation considered in Ref. 28. ρ(ω′) ρ (ω)= dω′ , (17) For weak ferromagnets with t, h and ∆ having the T 4T cosh2 ω′−ω ex Z 2T same order of magnitude (panel (c) on Fig. 4) we obtain (cid:0) (cid:1) one Andreev bound state miniband inside the gap and where ρ(ω) is equal to the zero temperature LDOS. one resonant scattering state above the gap. The An- We calculated the finite temperature LDOS of the dreev bound state miniband moves to the Fermi energy (L /a ,L /a )=(1,3)trilayerintheparallelalignment S 0 F 0 as the tunnel amplitude t increases (see Fig. 4-(c)) and (see Fig. 5). Increasing temperature tends to reduce the appears at a positive energy for larger values of t (see intensity of the Andreev bound state at the Fermi en- Fig. 4-(d)). ergyon Fig.4-(c) so that the LDOS atthe Fermienergy For larger values of the exchange field the Andreev decreases if T increases. For relatively large values of bound state miniband disappears from the LDOS. For T the peak structure has almost disappeared from the h /∆ 1 the induced exchange field is opposite to LDOS but there remains a minimum associated to the ex 0 the magn≫etization in the ferromagnets35,36. superconducting gap that is significantly filled. As T in- creases there is thus a first cross-overwhere the peak at There are thus two qualitatively different depairing theFermienergydisappearsandasuperconductingmini- mechanisms for strong and weak ferromagnets. For gapis restored,andasecondcross-overwherethe super- strong ferromagnets with h /∆ 1 (see Figs. 4-(e) ex 0 ≫ conducting gap disappears. The first cross over occurs and 4-(f)) the breakdown of superconductivity is due atatemperature equalto the bandwidth ofthe Andreev mainlytoZeemansplitting. Thecaseofveryweakferro- bound state miniband and the second cross-over occurs magnets (h /∆ 1) resembles that case h /∆ = 0: ex 0 ≪ ex 0 at a temperature comparable to the zero temperature non perturbative Andreev bound states are generatedin superconducting gap. The finite temperature LDOS is the superconducting gap approximately at opposite en- thus in a qualitative agreement with the non monotonic ergies. In the case h /∆ 1 the Andreev bound state ex 0 ∼ self-consistent superconducting gap. minibandcanbeatzeroenergy,thereforedestructingthe Reentrance obtained in a narrow range of interface minigap. transparencies40canalsobeexplainedbythisqualitative picture: if the Andreev bound state miniband is narrow and located at a slightly positive energy like on Fig. 4- (c) then the LDOS at the Fermi energy is vanishingly 2. Finite temperature local density of states small at T = 0 since the Fermi energy is not in the An- dreev bound state miniband. By increasing T the width The spin-up LDOS at a finite temperature T is re- of the Andreev bound state miniband increases so that latedtheconductanceofascanningtunnelingmicroscope the density of states at the Fermi energy increases. By (STM)inwhichthetipismadeofahalf-metalferromag- further increasing T the intensity of the Andreev bound net. The finite temperature currentatan arbitraryvolt- stateminibandisreduced,andthedensityofstatesatthe age is obtained through Keldysh formalism. The finite Fermienergydecreases. Thisbehavioriscompatiblewith 7 1 nits) 0.5 t( at/ ∆/) ∆0 0= = 0 1.7.40 t( b/t ∆/) ∆0 0= = 0 .17.04 t( ct/ /∆) ∆0 0= = 1 81..31 0.75 tt // ∆∆00 == 00..7907 ttt /// ∆∆∆000 === 001...792075 u b. ar 0.25 0.5 ( S O 0.25 D 0 (a) (b) L 0 -2.5 0 2.5-2.5 E 0/ ∆0 2.5-2.5 0 2.5 ∆∆(T) / 0.705 tttt //// ∆∆∆∆0000 ==== 0111....92587531 t ttt/ ///∆ ∆∆∆0 000= === 1 5821....6381 FIG. 6: Energy dependence of the spin-up LDOS (in arbi- traryunits)inthesuperconductinglayeroftheF/S/Ftrilayer 0.5 in the antiparallel alignment with (LS/a0,LF/a0) = (1,3). The superconductinggap, equalto ∆ , is not self-consistent. 0.25 0 (a) and (b) correspond to h /∆ = 0.83, ξ(⊥) = 21.1a (c) (d) ex 0 F 0 (weak ferromagnets). (c) corresponds to h /∆ = 2.78, 0 ex 0 0 0.25 0.5 0.75 0 0.25 0.5 0.75 1 tξ0F(⊥/ǫ)F==6.04.a40, η(s/t∆ro0n=gf8e.r3ro×m1a0g−n3etasn).dWλFeu=se6d.2∆8a00/.ǫF =0.014, T / ∆0 FIG. 7: Temperature dependence of the self-consistent su- perconductinggapoftheF/S/Ftrilayerintheparallelalign- a reentrantbehavior of the self-consistent superconduct- mentwith(LS/a0,LF/a0)=(1,1)inthepresenceofdisorder ing gap. The correlation between the low temperature in the superconducting layer. Without vertex corrections we superconducting gap and the LDOS at the Fermi energy use h /∆ = 0.83, δ(0) = 6.2 (a), δ(0) = 7.6 (b), δ(0) = 9.8 ex 0 S S S is further established in section VI. (c). (d) corresponds to δ(0) =9.8 with vertex corrections. In S all cases we use δ(0) =0. F 3. Local density of states in the parallel alignment ferromagnets. We obtain a significant effect of disorder The spin-up LDOS in the antiparallel alignment is for relatively large values of δ(0) and δ(0). shown on Fig. 6. The LDOS is symmetric with respect S F to a change of sign of energy, but not equivalent to the LDOS of a N/S interface (see Fig. 4-(a) and Fig. 4-(b)). 1. Disorder in the superconducting and ferromagnetic Thereexistsawell-definedminimumattheFermienergy layers corresponding to the superconducting minigap. The en- ergy dependence of the LDOS in the antiparallel align- The temperature dependence of the self-consistent su- ment shows that superconductivity is stronger than in perconducting gap in the presence of disorder in the su- the parallel alignment, both for weak and strong ferro- perconductor is shown on Fig. 7 for (L /a ,L /a ) = magnets. This is expected because of the exchange field S 0 F 0 (1,1) in the parallel alignment. In the absence of disor- induced in the superconductor in the antiparallel align- ment is reduced compared to the parallel alignment31. derFig.7correspondstoFig.3-(a). Theeffectofdisorder is to reduce the effect of the tunnel amplitude40 so that Theself-consistentsuperconductinggaphasamonotonic if disorder increases a larger value of t is needed to de- temperature dependence in this case which is because a stroysuperconductivity. ComparingFig.3andFig.7we well-defined minigap is obtained in the LDOS. see that the variations of ∆(T) are affected by a weak disorder especially if the F/S/F trilayer in the parallel alignment is close to the breakdown of superconductiv- C. Role of disorder for weak ferromagnets and for ity. In this case the dimensionless parameter controlling the F/S/F trilayer with atomic thickness (0) the strength of disorder is δ = δ ∆ /∆(T) which can S S 0 Disorder plays an important role in the proximity ef- be much larger than δ(0). S fect. Diffusive N/S interfaces are described by quasi- classical theory54. A small disorder can be incorporated in our description based on microscopic Green’s func- 2. Vertex corrections tions like in Ref. 53 (see Appendix B). The strength of disorder in the superconductor is characterized by There exist two perturbative series: one in the hop- δS(0) = nαu2α/∆0, where nα is the concentration of im- pingamplitudet andthe otherinthe disorderscattering purities and uα is the scattering potential, and we use potential u. Vertex corrections arise from diagrams that p a similar parameter δ(0) to characterize disorder in the mix the two series (see Appendix B2). The tempera- F 8 ature dependence of the self-consistent superconducting 0.75 hex/∆0 = 0.56 gap (not shown on Fig. 8). 0 0.5 ∆ ∆ / 0.25 FERRVOI.MAFGINNIETTEST(HLSIC≪KξNS(⊥E)SASNINDTLHF E&ξF(⊥)) (a) T/∆0 = 0.14 (b) 0 We discuss now the regime L ξ(⊥) and L &ξ(⊥). 0 0.5 1 1.5 0 0.25 0.5 S ≪ S F F h / ∆ T / ∆ We find Andreev bound states at the Fermi energy in ex 0 0 theparallelalignmentforstrongferromagnets,correlated FIG. 8: (a) Variation of the self-consistent superconduct- withnonmonotonictemperaturedependencesoftheself- ing gap calculated at T/∆ = 0.14 in the parallel (P) align- consistent superconducting gap. 0 ment (open symbols) and in the antiparallel (AP) align- The regime L & ξ is characterized by oscillations F F ment (filled symbols) as a function of hex/∆0. (b) Vari- of the self-consistent superconducting gap, critical tem- ation of the self-consistent superconducting gap calculated perature and pair amplitude as a function of L . We F withhex/∆0 =0.56intheparallelalignment,asafunctionof obtainboundstateswithin thesuperconducting gapand T/∆0. Weusedinbothcases(LF/a0,LS/a0)=(11,11). The resonant scattering states outside the superconducting Fermi wave length is λF =6.28a0. We use t/∆0 =5.6 ((cid:3) in gap. We calculated systematically the LDOS and the thePalignmentand(cid:4)intheAPalignment),t/∆ =8.3(◦in 0 self-consistentsuperconductinggapfor L /a =1,2and thePalignmentand•intheAPalignment),andt/∆ =11.1 S 0 0 (△ in the Palignment and N in theAPalignment). LF/a0 =1,...,100, in the parallel and antiparallel align- ments (see Fig. 9). The systematic calculation of the finite temperature LDOS given by Eq. (17) is too de- manding from a computational point of view. Instead ture dependence of the self-consistent superconducting we calculate the LDOS at zero temperature with η =T. gap with the vertex corrections is shown on Fig. 7-(d). Theconsistencybetweenthetwocalculationswasverified The critical temperature is larger if vertex corrections in a few cases. Depending on the interface transparen- are included. We obtain a non monotonic temperature cies∆(L /a )/∆ tendseithertoafinitevalueortozero dependence ofthe superconductinggapeveninthe pres- F 0 0 in the limit L /a + . We concentrate on the first ence of vertexcorrections. The role ofvertex corrections F 0 → ∞ case only. For 1 L /a 40 we see on Fig. 9 that increasesift increasessince the vertexcorrectiontermis F 0 ≤ ≤ proportional to n t2u2. on average the superconducting gap is smaller when the α α LDOS at the Fermi energy is larger. For L /a =1 and S 0 t/∆ = 2.8 (see Fig. 9-(b)) we obtain ∆(T)/∆ = 0 0 0 for four values of L /a (L /a = 4,6,11,13). For F 0 F 0 V. FINITE THICKNESS IN THE three other values of L /a (L /a = 16,23,25)we ob- SUPERCONDUCTOR (LS .ξS(⊥) AND LF ≪ξF(⊥)) tain a non monotonicFvari0atioFn of0∆(T)/∆ . For two 0 other values of L /a (L /a = 32 and L /a = 35) F 0 F 0 F 0 In this section we include a finite thickness in the su- ∆(T)/∆ is monotonic but far from the BCS variation. perconductor for LF ≪ ξF(⊥). For weak ferromagnets in These ni0ne values of LF/a0 with an anomalous temper- theregimehex/∆0 1weobtainnonmonotonictemper- ature dependence of the self-consistent superconducting ∼ aturedependences ofthe self-consistentsuperconducting gap have large values of the LDOS at the Fermi energy gap in the parallel alignment, therefore confirming sec- (ρ(ω =0)>0.045onFig.9-(b),inarbitraryunits). Like tion IV. in section IVB1 Andreev bound states near the Fermi We have shown on Fig. 8-(a) the variation of the self- energycorrelatewithunconventionaltemperaturedepen- consistent superconducting gap in the middle of the su- dences of the superconducting gap. perconductor as a function of the reduced exchangefield For 40 L /a 100 corresponding to L ξ(⊥), h /∆ . As expected from the variation of the critical ≤ F 0 ≤ F ≫ F ex 0 we obtain a cloud of points with a small dispersion and temperature38,47,48 weobtainaminimumiftheexchange withnocorrelationbetweenthesuperconductinggapand fieldiscomparabletothesuperconductinggap. Moreover the LDOS at the Fermi energy. This corresponds to the we obtain a minimum also in the antiparallel alignment cross-overto the F/S/F trilayer with bulk ferromagnets. thatisrelatedtotheminigapformedinbetweenAndreev We obtain bound states within the superconducting bound states at opposite energies (see section IVB3). gapand unconventionaltemperature dependences of the The full temperature dependence of the self-consistent superconductinggapwithstrongferromagnetsinthepar- superconducting gap in the parallel alignment is shown allelalignment. Bycontrastwithstrongferromagnetswe onFig.8-(b)forLS/a0 =11(comparabletoξS(⊥)/a0)and obtainaconventionaltemperaturedependenceofthe su- L /a = 11 (much smaller than ξ(⊥)/a ). We obtain a perconducting gap for the F/S/F trilayer with smaller F 0 F 0 maximum in the variation of ∆(T)/∆ in the parallel values of (L /a ,L /a )40. 0 S 0 F 0 alignment. We carried out the same simulation in the We carriedout the same simulation in the antiparallel antiparallel alignment and found a monotonic temper- alignment and found that ∆(T)/∆ is close to the BCS 0 9 0.15 1 (a) (c) (e) 0.1 0.5 ∆ nits)0.05 E / 0 u b. 0 -0.5 ar (a) (b) S ( (b) (d) (f) -1 O 0.1 0 1000 2000 3000 4000 0 1000 2000 3000 4000 5000 D LF/a0 L 0.05 FIG.10: ReducedenergyE/∆oftheAndreevboundstatesas afunction of thenumberof sites LF/a0 in theferromagnetic 0 chain for weak ferromagnets (h /∆ = 0.5). We used the 0 0.5 1 0 0.5 1 0 0.5 1 ex ∆/∆ parameters ∆/t = ∆0/tF = 0.01, t/tS = 0.01 , LS = 105a0. 0 The entire spectrum is kept in (a). Only the levels with a residue larger than 2 are kept in (b). The superconducting FIG. 9: Correlation between ∆/∆ and the LDOS at the 0 gap is not self-consistent. Fermi energy (in arbitrary units) for LS/a0 = 1 and LF/a0 between 1 and 40. The temperature is T/∆ = 0.14. In the 0 calculation of theLDOSthe superconductinggap is not self- consistent. We use strong ferromagnets with h /∆ = 13.9 ex 0 and ξF(⊥) = 1.3a0. We use LS/a0 = 1 and t/∆0 = 2.1 (a); LS/a0 = 1 and t/∆0 = 2.8 (b); LS/a0 = 2 and t/∆0 = 3.5 A. A one dimensional model (c); LS/a0 = 2 and t/∆0 = 4.2 (d); LS/a0 = 1 and t/∆0 = 2.8 (e); LS/a0 = 1 and t/∆0 = 3.3 (f). (a), (b), (c), (d) correspond to the parallel alignment. (e) and (f) correspond Wesupposethatthesuperconductorandferromagnets totheantiparallelalignment. Thesolidlinein(b)corresponds to ρ(ω=0)=0.045 (see text). are described by 1D chains with open boundary condi- tions with L /a sites in the superconductor and L /a S 0 F 0 sites in the ferromagnet. We denote by t (t ) the hop- S F pingamplitudeinthesuperconductor(ferromagnet)and temperature dependence of the superconducting gap for we use t = t . The energy level spacing in the super- S F all values of LS/a0 between 1 and 100. A larger density conductorismuchsmallerthanthesuperconductinggap of states at the Fermi energycorrelateswith smaller val- ∆. ues of the self-consistentsuperconducting gaplike in the parallel alignment (see Fig. 9-(e) and (f)). Because of We have shown on Fig. 10 the evolution of the energy the minigap that can be formed since the bound states of Andreev bound states as a function of the length of are at opposite energies (see Fig. 6) we do not obtain theferromagneticchainobtainedwiththealgorithmpre- the points with large values of the density of states at sented in Appendix C. The spectrum is symmetric un- the Fermi energy like in the parallel alignment. The ab- derachangeofsigninenergyifwe keepallenergylevels sence of large values of the LDOS at the Fermi energy intoaccount. Andreevboundstatesarisingfromthegap is related to the fact that the Andreev levels in the an- edges move to the Fermi energy as L /a increases28. F 0 tiparallelalignmentdo notcrossthe Fermienergyasthe ThereislevelrepulsionbetweenAndreevboundstateand interface transparency is increased. oscillationsof the energylevels with a periodof order10 times ξ = 2t a /πh . These oscillations do not exist F F 0 ex in Ref. 28. Among all Andreev bound states obtainedat a fixed L /a some have a spectral weight much larger F 0 thantheother. Wekeeponlythelevelshavingaspectral VII. COMPARISON WITH OTHER MODELS weight larger than a given cut-off. The evolution of the remaining Andreev bound states as a function of L /a F 0 Thediscussioninthe precedingsectionswasrestricted is then in agreement with Ref. 28. tothe infinite planargeometry. NowwediscussAndreev bound states in other geometries without imposing self- In connection with the discussion in section IVB1 we consistencyonthesuperconductinggap. InsectionVIIA see that Andreev bound states near the Fermi energy we improve the discussion of a model proposed by re- occur only if the ferromagnetic chain is long enough, cently Vecino et al.28 in which a ferromagnetic chain is largerthanapproximately10timesξ =2t a /π∆. This S S 0 connected to a superconductor55. In section VIIB we should be contrasted with the LDOS in the infinite pla- compare the LDOS to a model discussed recently by narlimit discussedin sectionIVB1,andwith the model Cserti et al.29. discussed in section VIIB. 10 a minigap, which explains why the self-consistent super- s) 300 (a) (b) conducting gap is weakened by the formation of an An- nit dreev bound state miniband near the Fermi energy. In- u b. 200 Z = 1000 Z = 40 creasing temperature decreases the intensity of the An- ar Z = 200 Z = 8 dreev bound state peak in the LDOS which correlates ∆E/) ( 100 wsuiptheracornedduuccttiinogngoafpt.he low temperature self-consistent ρ( We found non monotonic temperature dependences 0 of the superconducting gap with weak ferromagnets for -1 0 - 11 0 1 E/∆ L ,L ξ(⊥),ξ(⊥) as well as for L ξ(⊥) and F S ≪ F S S ∼ S L ξ(⊥). In the regime L ξ(⊥) and L & ξ(⊥) FIG.11: DensityofAndreevboundstates(inarbitraryunits) F ≪ F S ≪ S F F we obtain non monotonic temperature dependences for ρ(E/∆) as a function of reduced energy E/∆ for Z = 1000 some values of L /a for strong ferromagnets. and Z = 200 (a); Z = 40 and Z = 8 (b). We used the F 0 FortheF/S/Ftrilayerintheparallelalignmentwefind parameters ∆/ǫF =0.02, ∆ =0.01, hex/∆=0.5, d=λF/2, W ≃15900λF where λF =2π/kF is theFermi wave length. pairs of Andreev bound states at opposite energies but there exists a minigap so that the self-consistent super- conducting gap decreases monotonically with tempera- ture. However at a fixed temperature the self-consistent B. Bogoliubov-de Gennes equations superconducting gap is non monotonic as a function of theexchangefieldwhichisduetopairsofAndreevbound WeconsidernowthemodelproposedbyCsertietal.29 states at opposite energies in the regime h /∆ 1 ex 0 inwhicha2Dferromagneticdotwitharectangularshape ∼ ≪ t/∆ . of dimensions (d,W) is connected to a superconductor 0 Concerning the induced exchange field in the F/S/F (see Fig.1-(b)). The superconductorhas a width W but trilayer in the parallel alignment we find that for weak isinfiniteintheotherdirection(d′ =+ onFig.1). Us- ∞ ferromagnets the exchange field is in the same direction ing the solution of this model29 based on Bogoliubov-de asintheferromagneticelectrodeswhereasitisintheop- Gennes equations we generatedthe set E of Andreev { n} posite direction for strong ferromagnets. The change of boundstateenergies. LikeforthedeGennes-SaintJames sign is visible both in the LDOS and in the magnetiza- model26 the density of bound states is not equal to the tion profile. As the exchange field in the ferromagnets is LDOSinthesuperconductor28. Theevolutionoftheden- increased we find a first order transition to the normal sityofAndreevboundstatesasafunctionoftheinterface state, as for paramagnetically limited superconducting transparency is shown on Fig. 11. The interface trans- films in an applied magnetic field. parency is parametrized by the dimensionless coefficient Z, equal to the repulsive interface potential in units of the Fermi energy56. For large values of Z (correspond- ACKNOWLEDGMENTS ing to tunnel interfaces) we obtain an Andreev bound state miniband around E/∆ = h /∆ . As the inter- 0 ex 0 face transparency decreases the miniband broadens and The author wishes to thank D. Feinberg for fruitful splits into two separate minibands (see Fig. 11). This is discussions and useful comments on the manuscript. inaqualitativeagreementwithsectionIVB1(seeFig.4- (c) and Fig. 4-(d)) where we obtain also Andreev bound state minibands that evolve inside the superconducting APPENDIX A: RESONANCES IN LATERAL gap and can generate a large density of states at the CONFINEMENT Fermienergyforsomevaluesoftheinterfacetransparen- cies. In this Appendix we account for the differences be- tweentheresonantandoff-resonantF/S/Ftrilayers. The wavefunctioninthelateraldirectionwithinagivenelec- VIII. CONCLUSIONS trode is described by the tight binding Hamiltonian =t [z+1 z + z z+1], (A1) We havepresentedadetailedanalysisofF/S/Ftrilay- H 0 | ih | | ih | erswithweakferromagnetsbasedonmicroscopicGreen’s Xz functions. The exchange field induced in the supercon- where t is the hopping between neighboring layers,and 0 ductorintheregimeh /∆ 1generatesZeemansplit- ex 0 z/a isanintegerbetween0toL/a 1. Theeigenstates ≫ 0 0 tingoftheLDOStheregimeh /∆ 1ischaracterized − ex 0 with open boundary conditions are given by ≪ byAndreevboundstates. Inthenonperturbativeregime t/∆ h /∆ 1 the Andreev bound state miniband 0 ∼ ex 0 ∼ 2a L/a0−1 z+a crosses the Fermi energy as the interface transparency ψ = 0 sin nπ 0 z , (A2) n is increased therefore competing with the formation of | i rL+a0 z=0 (cid:18) L+a0(cid:19)| i X

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