ebook img

Method 429 Determination of Polycyclic Aromatic - Air Resources PDF

128 Pages·2015·0.99 MB·English
by  
Save to my drive
Quick download
Download
Most books are stored in the elastic cloud where traffic is expensive. For this reason, we have a limit on daily download.

Preview Method 429 Determination of Polycyclic Aromatic - Air Resources

California Environmental Protection Agency Air Resources Board Method 429 citamo rcAilcycyl ofnPooitanimreteD Hydrocarbon (PAH) Emissions sec ryuroaSnoi tmaotrSf :detpodA rebmetpeS ,21 9891 79 9,1 8y2l u:JdednemA STNETNOC FO ELBAT egaP 1 NOITCUDORTNI .................................................................... 1 1.1 YTILIBACILPPA .................................................................. 1 1.2 ELPICNIRP ....................................................................... 1 1.3 SNOITAIVERBBA DNA SNOITINIFED ............................................... 1 2 PRTEH-PETR EOSTTO COL .......................................................... 4 2.1 TSYLANA DNA ,RETSET ,RESU DNE EHT FO SEITILIBISNOPSER ..................... 4 2.2 STNEMERIUQER TSET-ERP ....................................................... 5 2.3 ATAD LACITYLANA YRANIMILERP DERIUQER ..................................... 6 2.4 SNOITARTNECNOC HAP TEGRAT NI EGNAR DETCEPXE sHAP LAUDIVIDNI FO ............................................................. 7 2.5 EMULOV DNA ,EMIT ,SNUR GNILPMAS ............................................ 7 3 SECNEREFRETNI .................................................................. 10 4 STNEGAER DNA ,SLAIRETAM ,SUTARAPPA GNILPMAS ............................... 11 4.1 SUTARAPPA GNILPMAS ......................................................... 11 4.2 STNEGAER DNA SLAIRETAM GNILPMAS ......................................... 14 4.3 NOITARAPERP TSET-ERP ........................................................ 18 4.4 NOITCELLOC ELPMAS ........................................................... 20 4.5 SNOITALUCLAC ................................................................ 26 4.6 AIRETIRC CITENIKOSI ........................................................... 30 5 YREVOCER ELPMAS ............................................................... 30 5.1 SUTARAPPA YREVOCER ELPMAS ................................................ 30 5.2 STNEGAER YREVOCER ELPMAS ................................................. 31 5.3 ERUDECORP YREVOCER ELPMAS ................................................ 32 1J29u89l,7y egaP 924-M i 5.4 GNILDNAH DNA NOITAVRESERP ELPMAS ........................................ 33 6 NOITARAPERP LACITYLANA ....................................................... 34 6.1 YTEFAS ........................................................................ 34 6.2 ERAWSSALG YROTAROBAL FO GNINAELC ....................................... 34 6.3 SUTARAPPA .................................................................... 34 6.4 STNEGAER :NOITARAPERP ELPMAS .............................................. 35 6.5 NOITCARTXE ELPMAS .......................................................... 36 6.6 PUNAELC NMULOC ............................................................. 37 7 SISYLANA SM/CG .................................................................. 41 7.1 SUTARAPPA .................................................................... 41 7.2 STNEGAER ..................................................................... 42 7.3 NOITARBILAC LAITINI .......................................................... 45 7.4 NOITARBILAC GNIUNITNOC ..................................................... 47 7.5 SISYLANA SM/CG ............................................................... 48 7.6 SISYLANA EVITATILAUQ ........................................................ 49 7.7 SISYLANA EVITATITNAUQ ...................................................... 49 8 LORTNOC YTILAUQ/ECNARUSSA YTILAUQ ......................................... 51 8.1 SELPMAS AQ ................................................................... 51 8.2 AIRETIRC ECNATPECCA ......................................................... 53 8.3 85)LDM( TIMIL NOITCETED DOHTEM EHT FO NOITAMITSE )LQP( TIMIL NOITATITNAUQ LACITCARP DNA .................................... 55 8.4 ECNAMROFREP YROTAROBAL .................................................. 55 9. SNOITALUCLAC ................................................................... 56 9.1 SNOITALUCLAC S'TSYLANA ..................................................... 56 9.2 SNOITALUCLAC S'RETSET ....................................................... 60 1J29u89l,7y egaP 924-M ii 10 STNEMERIUQER GNITROPER .................................................... 63 10.1 PRE-TEPSRTO TOCOL ........................................................... 63 10.2 REPORT LABORATORY ......................................................... 64 10.3 TROPER TSET SNOISSIME ....................................................... 67 11 YHPARGOILBIB ................................................................... 69 SELBAT 1 setylanA tegraT 924 dohteM ........................................................ 70 2 sHAP tegraT rof stimiL noitatitnauQ lacitcarP ......................................... 71 3 HAP stoL tnereffiD fo SMRH yb sisylanA niseR denaelC fo ................................................................. 72 4 snoituloS gnikipS elpmaS eht fo noitisopmoC .......................................... 73 4A snoituloS gnikipS elpmaS evitanretlA fo noitisopmoC ................................... 74 5 noitarbilaC SM/CG gnikroW ni sHAP fo snoitartnecnoC yrtemortcepS ssaM noituloseR woL rof snoituloS dradnatS ............................... 75 6 noitarbilaC SM/CG gnikroW ni sHAP fo snoitartnecnoC yrtemortcepS ssaM noituloseR hgiH rof snoituloS dradnatS .............................. 77 6A noitarbilaC SM/CG gnikroW evitanretlA ni sHAP fo snoitartnecnoC yrtemortcepS ssaM noituloseR hgiH rof snoituloS dradnatS ............................... 79 7 sdradnatS dellebaL rof sleveL ekipS .................................................. 81 7A evitanretlA rof sdradnatS dellebaL rof sleveL ekipS emehcS gnikipS SMRH ............................................................ 82 8 tcartxE elpmaS ni sdradnatS dellebaL rof snoitartnecnoC tegraT ........................... 83 8A tcartxE elpmaS ni sdradnatS dellebaL rof snoitartnecnoC tegraT emehcS gnikipS SMRH evitanretlA htiw deniatbO ...................................... 84 9 elpmaS ekipS lortnoC yrotarobaL ni sdnuopmoc fo snoitartnecnoC ......................... 85 10 snoitidnoC gnitarepO cihpargotamorhC saG dednemmoceR sisylanA HAP rof ................................................................. 86 1J29u89l,7y iii egaP 924-M 11 sFRR fo noitaluclaC rof sdradnatS lanretnI fo stnemngissA sdradnatS etagorruS dna sHAP tegraT fo noitatitnauQ dna ................................ 87 11A sFRR fo noitaluclaC rof sdradnatS lanretnI fo stnemngissA etagorruS dna sHAP tegraT fo noitatitnauQ dna emehcS gnikipS SMRH evitanretlA gnisU sdradnatS .................................... 88 12 tnecreP fo noitanimreteD rof sdradnatS yrevoceR fo stnemngissA dradnatS etanretlA eht dna sdradnatS lanretnI fo seirevoceR ............................... 89 12A fo noitanimreteD rof sdradnatS yrevoceR fo stnemngissA dradnat Sf oe tsaenirreetvloAc eeRh tt ndencar esPdradnatS lanretnI emehcS gnikipS SMRH evitanretlA gnisU ............................................. 90 13 detceleS rof snoI noitamrifnoC dna noitatitnauQ SMRL/CGRH yb sHAP fo gnirotinoM noI ............................................ 91 14 gnirotinoM noI detceleS rof desU srotpircseD ssaM SMRH/CGRH yb sHAP fo ......................................................... 93 SERUGIF 1 trahcwolF 924 dohteM ............................................................ 95 2 niarT gnilpmaS HAP .............................................................. 96 3 HAP suoesaG fo noitcelloC rof parT tnebroS dna resnednoC .............................. 97 4 sutarappA gniyrD deB dezidiulF 2-DAX .............................................. 98 5 droceR ataD dleiF 924 dohteM ...................................................... 99 6 niarT gnilpmaS HAP fo yrevoceR ................................................... 100 7 rof punaelC dna noitcartxE ,gnilpmaS rof trahcwolF elpmaS tilpS a ni HAP fo noitanimreteD ............................................. 101 8 rof punaelC dna noitcartxE ,gnilpmaS rof trahcwolF elpmaS etisopmoC a ni HAP noitanimreteD ........................................... 102 9 snoitaluclaC tseT-erP fo elpmaxE ................................................... 103 10 droceR puteS niarT gnilpmaS )sHAP( 924 dohteM BRAC ............................... 104 11 droceR yrevoceR niarT gnilpmaS )sHAP( 924 dohteM BRAC ............................ 105 12 droceR elpmaS ydotsuC fo niahC ................................................... 106 1J29u89l,7y vi egaP 924-M 13 droceR goL ydotsuC fo niahC ...................................................... 107 14A rof )SMRH( tropeR yrammuS SM/CG fo elpmaxE 1# noituloS noitarbilaC laitinI ...................................................... 108 14B yrammuS )LACI( noitarbilaC laitinI fo elpmaxE ....................................... 109 14C yrammuS noitarbilaC gniunitnoC fo elpmaxE ......................................... 110 15A stluseR SCL fo tropeR yrammuS fo elpmaxE ......................................... 111 15B eneryp)a(ozneB rof seirevoceR SCL ................................................. 112 16A 23# nuR elpmaS rof )SMRH( tropeR yrammuS SM/CG elpmaxE ......................... 113 16B 23# nuR elpmaS rof stluseR HAP fo tropeR yrotarobaL elpmaxE ......................... 114 17A stropeR yrotarobaL fo yrammuS s'retseT fo elpmaxE ................................... 115 17B tseT snoissimE HAP rof yrammuS ataD dleiF ......................................... 116 17C tropeR tseT snoissimE fo elpmaxE .................................................. 117 A XIDNEPPA timiL noitceteD dohteM eht fo noitanimreteD ......................................... 118 1J29u89l,7y v egaP 924-M 9 2d4ohteM )HA Pn(obracord ycHitamo rcAilcycyl ofnPooitanimreteD secru oySranoita tmSo rsFnoissimE 1 NOITCUDORTNI 1.1 YTILIBACILPPA ni )HAP( snobracordyh citamora cilcycylop neetenin fo noitanimreted eht ot seilppa dohtem sihT .secruo sy. l1ye rteaalnmboiaitTtl aunt isn admceo trhsfci ilsh nweo riyast sieivsmieethiTsnes ehT lacimehc rehto fo snoitartnecnoc dna sepyt eht nopu dneped lliw elpmas nevig a rof deveihca eb .ytivitisnes tnemurtsni dna ezis elpmas lanigiro eht sa llew sa elpmas eht ni sdnuopmoc rojam a deredisnoc eb llahs dettimrep ylsserpxe esoht dnoyeb dohtem siht fo noitacifidom ynA ro draoB secruoseR riA ainrofilaC eht fo reciffO evitucexE eht yb lavorppa ot tcejbus noitacifidom .evitatneserper dezirohtua reh ro sih 1.2 ELPICNIRP no detcelloc dna kcats eht morf yllacitenikosi detcartxe era HAP esahp suoesag dna etalucitraP .)elzzon ,eborp ,retlif( stnenopmoc nyilanrOt gnilpmas maertspu ni ro ,sregnipmi ni ,niser 2-DAX .dohtem siht htiw denimre tteodn esba hn atcI snoissime kcats eht ni HAP hcae fo stnuoma latot eht fo evitatneserper si niart gnilpmas eht fo strap tnereffid eht ni gninoititrap eht taht detartsnomed neeb .HAP suoesag dna etalucitrap rof elpmas sag kcats eht ni gninoititrap eht noituloser hgih htiw denibmoc yrtemortceps ssam noitulid epotosi si dohtem lacitylana deriuqer ehT nwonk ni selpmas lla ot sdra d.nyahtpsa rlgaontraemtonrih cf os angoitidda eht sliatne sihT yranimilerp ,stnevlos cinagro etairporppa htiw elpmas eht fo noitcartxe cificeps-xirtam ,seititnauq -hgih gnisu HAP rof tcartxe dessecorp eht fo sisylana dna stcartxe fo punaelc dna noitanoitcarf ssam noituloser wol rehtie htiw delpuoc yhpargotamorhc sag nmuloc yrallipac noituloser .)SMRH/CGRH( yrtemortceps ssam noitulose re rhugsinhe rooT ,)SMRL/CGRH( yrtemortceps ta snoitacol detset lla ta detcelloc selpmas rof desu eb tsum dohtem SM emas eht ,stluser elbarapmoc .detset si noitacol eno naht erom erehw secruos esoht fo ytilauq eht erusne ot deifsitas eb tsum hcihw niereh deificeps era airetirc ecnamrofrep muminiM .atad lacitylana dna gnilpmas eht 1.3 SNOITAIVERBBA DNA SNOITINIFED 1.3.1 dradnatS lanretnI a si dradnats lanretni nA rehto dna s2knalb ,selpmas dleif lla ot dedda si hcihw HAP dellebal-H .sn o.intouiltocsa rntoxiet aerrboifleabc seehltp mnais tlnoerstenro pcl aoynstrliealt ansuIiq tI .sdnuopmoc etagorrus dna etylan ae reehhtT fo noitartnecnoc eht erusaem ot desu era sdradnats .setagorrus dna setylana tegrat eht fo hcae ot dengissa dradnats lanretni eno si 1J29u89l,7y M-4P2a91g e 1.3.2 dradnatS etagorruS eht fo niser 2-DAX eht ot tnuoma nwonk a ni dedda dnuopmoc dellebal a si dradnats etagorrus A era snoissime suoesag eht erofeb xirtam eht htiw etarbiliuqe ot dewolla dna ,niart gnilpmas ton si ,devloser yletelpmoc eb nac taht tne n.odpemlopcm aas eb ot sah dradnats etagorrus ehT .s tnci enfofie teacrntenreecfnroec tdnei ryunsaa eemv asht Iton seod dna ,elpmas eht ni tneserp eht no detcelloc HAP sniater niart gnilpmas eht ylevitceffe woh eht fo noitacidni na si tcartxe eht ot desu eb nac sknalb dleif eht ni s.dnriasdenra t2s- DeAtXagorrus eht fo yrevocer ehT eht hcihw rednu snoitidnoc ro emit yb desuac stceffe xirtam yna era ereht rehtehw enimreted .sisylana ot roirp derots dna detropsnart si elpmas 1.3.3 dradnatS etanretlA a si dradnats etanretla nA stnetnoc regnip2mi eht ot dedda si hcihw dnuopmoc HAP dellebal-H .elpmas regnipmi eht ni sHAP rof ycneiciffe noitcartxe eht etamitse ot noitcartxe ot roirp 1.3.4 dradnatS yrevoceR a si dradnats yrevocer A dleif lla fo st2cartxe eht ot dedda si hcihw dnuopmoc HAP dellebal-H .sisylana SM/CGRH erofeb se lephmta sn il otrntensoecr py toisllaau qs id ntaI ,sknalb ,selpmas si dradnats yrevocer eht ot evi t.anloeirt usldorsa dnnoaittsa rlbainlraectni eht fo esnopser ehT .nsad rsaid nyartesv olcaenrr edtrnaid neahtts floa nyrreetvnoic eerh Teht etamitse ot desu .sisylana eht fo ecnamrofrep llarevo eht fo rotacidni 1.3.5 rotcaF esnopseR evitaleR na fo tnuoma nwonk a ot retemortceps ssam eht fo esnopser eht si rotcaf esnopser evitaler ehT nwonk a ot evitaler )dradnats etagorrus ro dradnats lanretni( dnuopmoc dellebal ro etylana lanretni ro dradnats yrevocer( dnuopmoc dellebal rehtona ro dradnats lanretni na fo tnuoma .)dradnats 1.3.6 dradnatS ecnamrofreP .sdnuopmoc dradnats detceles fo s tsniu otmIa nwonk fo erutxim a si dradnats ecnamrofrep A .metsys SM/CG eht fo e csnkacmerhocf reespe heTlbatpecca deunitnoc etartsnomed ot desu dna ,yrevocer xirtam ,skcehc ytilauq ,skcehc noitarbilac ,skcehc ecnamrofrep metsys edulcni .seirevocer etagorrus 1.3.7 elpmaS noitaulavE ecnamrofreP sniatnoc taht seirotarobal rehto ro APE yb deraperp eno si elpmas noitaulave ecnamrofrep A ot seirotarobal elpitlum yb dezylana neeb sah dna ,setylana dohtem fo snoitartnecnoc nwonk si dohtem a nehw detcepxe eb nac taht noisicerp dna ycarucca eht yllacitsitats enimreted dleif lacipyt sa egna r. tesmyalsa neah tt nneit eepbm otcs uam ysbn odietmarrotfnreecpnoC .tsylana eht yb nwo n.ks etlopnm aesra snoitartnecnoc etylanA 1J29u89l,7y M-4P2a92g e 1.3.8 elpmaS lortnoC yrotarobaL si taht setylana dohtem fo snoitartnecnoc nwonk sniatnoc taht eno si elpmas lortnoc yrotarobal A dna snoitacifitnedi elbatpecca niatbo nac ti taht etartsnomed ot yrotarobal a yb dezylana .setylana emas eht gniniatnoc selpmas dleif ezylana ot desu eb ot serudecorp htiw stnemerusaem lor t.ntosc yelhatn ae reahpt eyrbp ntwsounm k yerroat asrnoobiatla rethnTecnoc etylanA .noitarbilac rof desu esoht morf yltnednepedni deraperp sdradnats kcots morf elpmas 1.3.9 resU dnE rof detcudnoc si dohtem tset siht fi resu dne eht deredisnoc eb llahs ycnega gnitaluger ehT siht fo sesoprup eht rof resu dne eht etangised llahs ycnega gnitaluger eht ro ,sesoprup yrotaluger tset siht gnimrofrep fo tsoc eht syarfed ohw ytr a.pd oehhtte meb llahs resu dne eht esiwrehtO .resu dne eht yfitnedi tsum )2 noitceS( .ldoochotteomrp tset-erp eht ,esac yna nI 1.3.10 retseT dna serudecorp gnilpmas eht smrofrep taht mrif gnireenigne tcartnoc a si retset eht yllausU a fo trap yllausu( puorg lacitylana na ot serudecorp lacitylana cificeps rof ytilibisnopser setageled .ycnega gnitaluger eht fo .t)rmarpi fe by ryoatma rroebtasle tg neihtt c,asretsnaocc beumsos nI dohtem tset siht fo ecnamrofrep eht rof elbisnopser yletamitlu ytrap eht eb llahs retset ehT dna puorg lacitylana eht fo stroffe eht fo noitanidro-oc eht hguorht yltceridni ro yltcerid rehtehw .puorg gnilpmas eht fo stroffe eht 1.3.11 tsylanA eht etareneg ot serudecorp lacitylana eht smrofrep taht puorg lacitylana eht ot srefer mret sihT .atad lacitylana deriuqer 1.3.12 noitartnecnoC tegraT ecruoS eht fo resu dne eht yb deificeps tseretni fo HAP dettime hcae rof noitartnecnoc tegrat eht si sihT rep ecnatsbus tegrat fo .ssstalmu sfeor sttsientu ni desserpxe eb llahs noitartnecnoc tegrat ehT smargorcim ro retem cibuc dradnats yrd rep smargonan era stinu lacipyt ;snoissime fo emulov )mcsd/gµ ro mcsd/gn( retem cibuc dradnats yrd rep 1.3.13 timiL noitceteD dohteM ehT etylana eht fo noitceted fo noisicerp eht no desab si )LDM( timil noitceted dohtem ehT neves fo noitaiv e.dt idmriald nnaotist ceehtt efd o ethct urdaoernp neohit tsair ttnIecnoc t s'tnedutS dna etylana eht fo snoitartnecnoc wol htiw dekips selpmas niser fo sesylana etacilper .%99 fo level ecnedifnoc a ta modeerf fo seerged 6 rof eulav 1.3.14 timiL noitatitnauQ lacitcarP ehT tsum atad hcihw woleb ro ta dnuopmoc hcae rof timil a si )LQP( timil noitatitnauq lacitcarp ehT ot niart gnilpmas eht ni detcelloc eb t.sduemt rtoaphetr sesba mt oenlpmas muminim eht si tI eht yb dehsilbatse stimil noisicerp eht nihtiw noitarepo yrotarobal enituor gnirud noitceted wolla 1J29u89l,7y M-4P2a93g e ton era taht HAP esoht rof LD M. neohitt asneimmirte t5e dt aL DdMetamitse eb lliw sLQP ehT knalb eht semit 5 ta deta m.intissee re be hltl ifwo rsetdnnainaimmeart neohct rof LQP ehT .level niser 2-DAX 2 LOCOTORP TSET ECRUOS EHT na ,detset eb ot ecruos eht fo rotarepo deifitnedi na evah llahs dohtem tset siht fo ecnamrofrep yrevE .dohtem tset siht smrofrep ohw retset deifitnedi na dna ,stluser dohtem tset eht fo resu dne deifitnedi ecnamrofrep dna noitanidrooc eht ni devlovni seitrap eht fo seitilibisnopser eht fo yrammus a si 1 erugiF yb nopu deerga dna dootsrednu eb dluohs erud e.ctosrept tescertu oesr iethnte feoht rof locotorp ehT .tset eht fo trats eht ot roirp seitrap elbisnopser eht 2.1 RETSET EHT DNA RESU DNE EHT FO SEITILIBISNOPSER 2.1.1 resU dnE ehT tegrat ecruos a yficeps llahs )9.3.1( stluser tset eht fo resu dne eht ,nigeb yam gnitset erofeB fo senilediug eht gnisu dohtem siht yb denimreted eb ot HAP eht fo hcae rof noitartnecnoc .1.2.2 noitceS dna tnemucod eht gniweiver retfa ylno locotorp tset ecruos eht evorppa llahs resu dne ehT .tem neeb evah ) 5.2 ot 2.2 snoitceS( stnemeriuqer tset-erp muminim eht taht gninimreted 2.1.2 retseT ehT ,dohtem tset eht fo ecnamrofrep eht rof ytilibisnopser yramirp eht evah llahs )01.3.1( retset ehT .puorg gnilpmas eht fo stroffe eht dna puorg lacitylana eht fo stroffe eht etanidro-oc llahs dna eht ni ecneirepxe detnemucod htiw tsylana na fo noitceles eht rof elbisnopser eb llahs retset ehT eht fo ll a. dtoshytleamn ae heth tf om oercfn anmiraotfbroe pl lyarhost craeftssietta sehT .sretemarap gnilpmas fo snoitaluclac tset-erp rof deriuqer era taht )3.2 noitceS( atad lacitylana tset ecruos a etirw dna poleved llahs retset eht ,dohtem siht fo tser eht gnimrofrep erofeB .deniatbo era stluser dohtem tse tl llauhfse srue ttsaehtt eehrTusne pleh ot )2.2 noitceS( locotorp dne efhot syybe vdreudsi vtosrept -neoript afmor osftnliu seehrt enhot d,erseasbu tset eht nalp .)2,2 noitceS( sretemarap gnitset ecruos tegrat fo snoitaluclac s'retset eht dna ,ecruos eht gnitroper lacitylana dna gnilpmas eht fo lla taht gnirusne rof elbisnopser eb llahs retset ehT .tem era )01 noitceS( stnemeriuqer 2.1.3 tsylanA ehT serudecorp lacitylana deriuqer eht fo lla gnimrofrep rof elbisnopser eb llahs tsylana ehT ,2.2.4 ,1.2.4 ,3.2 snoitceS yb deriuqer sa stluser eht gnitroper dna dohtem tset siht ni debircsed 10.1.11,0 .1.21,0 .1.3a,n1d0 .2). 1J29u89l,7y M-4P2a94g e

Description:
Jul 28, 1997 2 THE PRE-TEST PROTOCOL . PAH Analysis by HRMS of Different Lots Concentrations of PAHs in Working GC/MS Calibration.
See more

The list of books you might like

Most books are stored in the elastic cloud where traffic is expensive. For this reason, we have a limit on daily download.