Metal-Containing Polymeric Materials

507 Pages·1996·44.391 MB·English

by  Charles E. Carraher Jr., B.M. Culbertson, C.U. Pittman Jr., J.E. Sheats, Martel Zeldin

Metal-Containing
Polymeric Materials
Metal-Containing
Polymeric Materials
Edited by
Charles U. Pittman, Jr.
Mississippi State University
Mississippi State, Mississippi
Charles E. Carraher, Jr.
Florida Atlantic University
Boca Raton, F/orida
Martei Zeldin
City University ofN ew York
New York, New York
John E. Sheats
Rider College
Lawrenceville, New Jersey
and
Bill M. Culbertson
Ohio State University
Columbus, Ohio
Springer Science+Business Media, LLC
L1brary of Congress Catalog1ng-1n-Publ1cat1on Data
Metal-containing polymeric materials 1 edited by Charles U. Pittman,
Jr .... [et al. l.
p. cm.
"Proceedings of the International Symposium an Metal-containing
Polymeric Materials, held August 21-25, 1994, at the 208th American
Chemical Society Meeting in Washington, D.C."--T.p. versa.
Includes bibliographical references and index.
1. Polymeric composites--Congresses .. 2. Metallic composites-
-Congresses. 3. Silicon polymers--Congresses. I. Pittman, Charles
U. II. International Symposium an Metal-containing PolyNeric
Materials (1994: Washington, D.C.l III. American Chemical Society.
Meeting <208th : 1994 : Washington, D.C. >
TA418.9.C6M459 1996
620.1'92--dc20 96-1765
CIP
Proceedings of the International Symposium on Metal-Containing Polymeric Materials,
held August 21 -25, 1994, at the 208th American Chemical Society Meeting in Washington D.C.
ISBN 978-1-4613-8018-4 ISBN 978-1-4613-0365-7 (eBook)
DOI 10.1007/978-1-4613-0365-7
© 1996 Springer Science+Business Media New York
Originally published by Plenum Press, New York in 1996
Softcover reprint of the hardcover 1s t edition 1996
10987654321
Ali rights reserved
No part of this book may be reproduced, stored in a retrieval system, or transmitted in any form or by any
means, electronic, mechanical, photocopying, microfilming, recording, or otherwise, without written
permission from the Publisher
PREFACE
Metal-containing polymeric materials now represent a major niche area within
polymer science. This topic, once a curiosity among polymer scientists, owes its growth to
the explosive development of organometallic chemistry since the early 1960s. The huge
increase in knowledge concerning the chemistry of main group metals, transition metals
and lanthanide/actinide metals has been followed by a variety of applications and mergers
of these chemistries with polymer science. In the 1960s and early 1970s vinyl ferrocene
and other polymerizable ferrocene derivatives were incorporated into polymers as a direct
outgrowth of the rapidly developing field of organometallic chemistry of 1t-complexed
transition metal systems. Likewise, the expansion of metal cluster chemistry was followed
by incorporation of metal clusters into polymers. Silicon chemistry advances led directly to
polysilanes and two-dimensional sheet systems involving silicon. Inorganic ceramic
chemistry advances spurred research on metal-containing fiber development for preceramic
applications. Current explosive growth in materials science, optical properties, catalysis,
three-dimensional networks, etc. are fueling interesting mergers of organometallic,
inorganic, and polymer chemistry. In order to follow and emphasize these trends, the
editors organized the "International Symposium on Metal-Containing Polymeric Materials"
at the 208th National American Chemical Society Meeting in Washington, DC, August 20-
25, 1994. Following the symposium selected authors were asked to prepare chapters both
introducing and summarizing their work for this book. This was the sixth such symposia
which we organized. The previous symposia were in 1977, 1979, 1983, 1987 and 1989
four of which were subsequently published in book form. This and the earlier books
provide a glimpse of the field's evolution.
As one would expect from a field of study involving polymer science, materials
chemistry, organometallic and inorganic chemistry, catalysis, and biochemical concepts,
metal-containing polymers has become a highly interdisciplinary topic. This becomes
apparent simply looking at the chapter titles. Scientists from around the world have
contributed discussions of topics ranging from structure and functioning of
metalloenzymes, shish kabob polymers with metals along the spine, preceramic polymers,
metal-cluster containing materials, mixed-metal polymers, polymer-bound Ziegler Natta
catalysts, polymer precursors for conducting and ferromagnetic materials, synthesis of
three-dimensional cage and channel networks, plant growth regulators, novel
polyelectrolytes, metallized polyimides to novel photonic materials. Synthetic
methodologies such as ring-opening polymerization of strained metallocenophanes, liquid
crystalline transition metal-containing polymers, thermosetting systems, vinyl polymers,
coordination polymers condensation polymerization and oxidative polymerizations have
been applied to metal-containing polymers and all these topics represented herein.
v
There was no 'best' way in which to organize this text. The method selected
was to follow the introductory overview chapter with six major thematic divisions.
Synthesis and characterization of new systems was the first theme. Ten chapters fall
into this general classification. This is followed by a section containing seven chapters
on silicon-containing polymers, preceramic systems, 3-D cages and networks. Then
eight chapters have been grouped under the theme: electrical, magnetic, photonic, and
ion-exchange properties. This is followed by the sections: polyelectrolytes and ion
binding systems (four chapters) and one chapter on mass spectroscopy. The final
section of the text covers biopolymers and their structure, function, and reactivity
relationships (three chapters). One chapter is a major review by G. B. Jameson on
transition metal-containing biopolymers and models.
In closing, I would like to acknowledge the special efforts of John E. Sheats of
Rider University who is mainly responsible for the introductory chapter. I also want to
thank Donna P. Murrah who played a major role in the clerical and technical aspects of
bringing the text together. She also played a pivotal role in composing the subject
index. Along with the other editors, I want to thank these individuals and all the
authors for making this text possible.
Charles U. Pittman, Jr.
vi
CONTENTS
Inorganic and Organometallic Polymers - An Overview . . . . . . . . . . . . . . . . 3
J.E. Sheats, C.E. Carraher, Jr., C.U. Pittman, Jr., M. Zeldin, and
B.M. Culbertson
SYNTHESIS AND CHARACTERIZATION OF NEW SYSTEMS
Ring-opening Polymerization (ROP) of Strained Metallocenophanes 39
J.K. Pudelski, D.A. Foucher, and I. Manners
Cluster-containing Metal (Co)Polymers: Production, Structure and Thermal
Properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51
N.M. Bravaya, A.D. Pomogailo, V.A. Maksakov, and V.P. Kirin
Variability of Mixed-unit Chains in Metal-containing Polymers 63
G.I. Dzhardimalieva and A.D. Pomogailo
Metal Coordination Polymers: Eight-coordinate Cerium(IV) and
Zirconium(IV) Polymers with Varied Flexibility, Conjugation,
and Stability through Ligand Variation ................ . 81
R.D. Archer, H. Chen, J.A. Cronin, and S.M. Palmer
Structural Characterization and Effects of Gibberellic Acid-containing
Organometallic Polymers as Plant Growth Regulators . . . . . . . . . . . . . 93
H.H. Stewart, C.E. Carraher, Jr., W.J. Soldani, L. Reckleben,
J. de la Torre, and S.L. Miao
The Use of Ruthenium-containing Polythiols for Solar Energy Conversion 109
C.E. Carraher. Jr. and Q. Zhang
vii
Synthesis and Characterization of Aliphatic Aromatic Polyamide-metal
Complexes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119
U.D.N. Bajpai, S. Rai, and A. Bajpai
Synthesis and Characterization of Poly(thiooxamide) Metal Complexes . . . . . . . 129
A. Bajpai, M. Khandwe, and U.D.N. Bajpai
Multi-electron Transfer Process of a Vanadium Dinuclear Complex for
Molecular Conversions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139
E. Tsuchida, K. Yamamoto, and K. Oyaizu
Synthesis of High Molecular Weight Poly(phenylene sulfide) through
Oxidative Polymerization with Oxygen . . . . . . . . . . . . . . . . . . . . . . 151
K. Yamamoto and E. Tsuchida
SILICON-CONTAINING POLYMERS, PRECERAMIC SYSTEMS,
3-D CAGES AND NETWORKS
Chemical Modifications of Halomethylated Poly(methylphenylsilane).
A New and Facile Route to Functionalized Polysilanes . . . . . . . . . . . . 161
A.C. Swain, S.J. Holder, R.G. Jones, A.J. Wiseman, M.J. Went,
and R.E. Benfield
Siloxane Polymers with Pendant Metal Carbonyl Groups . . . . . . . . . . . . . . . . 177
F.B. McCormick, B.B. Wright, and J.W. Williams
Reaction of Trimethylsilylmethyl Substituted Silanes with Alkali
Metals: Syntheses of Polycarbosilanes and Polysilanes . . . . . . . . . . . . . 189
G. Ouyang, R. Simons, and C. Tessier
Preparation and Properties of Novel Titanosiloxane and Zirconosiloxane . . . . . . 199
T. Gunji and Y. Abe
Synthesis of Thermosetting Preceramic Copolymer . . . . . . . . . . . . . . . . . . . 209
0. Funayama, T. Aoki, and T. lsoda
Conversion of Molecules and Clusters to Extended 3-D Cage and
Channel Networks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 219
O.M. Yaghi
Poly(phenylmetallosiloxane)s: Synthesis, Structure and Properties . . . . . . . . . . 229
0.1. Shchegolikhina, I.V. Blagodatskikh, Y.A. Pozdnyakova,
and A.A. Zhdanov
viii
CATALYTIC SYSTEMS
Polymer-supported Ziegler-Natta Catalysts for the Polymerization of
a-Olefins and Butadiene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 241
R. Ran and C.U. Pittman, Jr.
Prearranged Poly-4-vinylpyridine Nickel Complexes as Catalysts for the
Hydrogenation of Allyl Alcohol . . . . . . . . . . . . . . . . . . . . . . . . . . 255
A.A. Efendiev, J.J. Orujev, E.B. Amanov, and Y.M. Sultanov
Polymers with Ligated Peroxotungstic Units: Organophosphoryl
Macroligands for the Catalytic Epoxidation of Alkenes . . . . . . . . . . . . 265
G. Gelbard, D.C. Sherrington, F. Breton, M. Benelmoudeni,
M.-T. Charreyre, and D. Dong
ELECTRICAL, MAGNETIC, PROTONIC, AND
ION-EXCHANGE PROPERTIES
Cobalt Dicarbollide Containing Polymer Resins for Cesium and Strontium
Uptake ......................................... 277
W.P. Steckle, Jr., J.R. Duke, Jr., and B.S. Jorgensen
Magnetic Investigations on Cu(II)- and Fe(III)-containing Liquid
Crystalline Metallopolymers ................. . . .. 287
W. Haase, K. Griesar, E.A. Soto-Bustamante, and Yu.G. Galyametdinov
Novel Photonic Materials Containing Porphyrin Rings . . 301
Z. Bao and L. Yu
Metal-containing Polymers as Precursors for the Production of
Ferromagnetic and Superconducting Materials . . . . . . . . . . . . . . . . . . 313
A.D. Pomogailo, A.S. Rozenberg, and G.l. Dzhardimalieva
Bridged Macrocyclic Transition Metal-oligomers, Synthesis and Electrical
Properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 331
M. Hanack
Enhancement of Dimensional Stability in Soluble Polyimides via
Lanthanide(III) Additives .................... . . . . . 337
R.E. Southward, D.S. Thompson, D.W. Thompson, and A.K. St. Clair
Preparation of Silvered Polyimide Mirrors via Self-metallizing
Poly(amic acid) Resins ................... . . .... 349
R.E. Southward, D.S. Thompson, D.W. Thompson, M.L. Caplan,
and A.K. St. Clair
ix
Polyimides Doped with Silver-n: Surface Conductive Films . . . . . . . . . . . . . . 357
A.F. Rubira, J.D. Rancourt, and L.T. Taylor
POLYELECTROLYTES AND ION-BINDING SYSTEMS
Investigation of the Ion-bonding Properties of Tactic Poly(methacrylic acids)
Using Terbium(III) Ion as a Fluorescent Probe . . . . . . . . . . . . . . . . . 369
H. Lujan-Upton andY. Okamoto
Rational Design of Novel Polyelectrolytes: Aluminosilicate/Poly(ethylene glycol)
Copolymers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 383
G.C. Rawsky and D.F. Shriver
Determination of Acidity in the Interior of the Cross-linked Polyelectrolyte
Grain by the Use of pH-sensitive Probes . . . . . . . . . . . . . . . . . . . . . 395
L.S. Molochnikov, E.G. Kovalyova, LA. Grigor'ev, and V.A. Reznikov
Molecular Complexes of Cellulose with Metals. New Development 403
N.E. Kotelnikova, D. Fengel, and V.P. Kotelnikov
NL\SSSPECTROSCOPY
Electron Impact Mass Spectroscopy of Condensation Metal-containing
Polymers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 409
C.E. Carraher, Jr., J.W. Louda, D. Sterling, E. Baker, A. Rivalta,
and Q. Zhang
BIOWGICAL SYSTEMS
Model Systems and Structure, Function and Reactivity Relationships
in Transition Metal-containing Biopolymers . . . . . . . . . . . . . . . . . . . 421
G. B. Jameson
Incorporation of Square-planar Metal Binding Sites into Protein Polymeric
Structures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 481
E. Long, P.D. Eason, and D;F. Shullenberger
Dynamic Aspects of Electron-transfer Reactions in Metalloprotein
Complexes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 491
N. M. Kostic
Contributors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 501
Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 505
X