M ECHANICS AND P C , HYSICS OF REEP S , HRINKAGE AND D URABILITY OF C ONCRETE A Tribute to Zdeněk P. Bažant PROCEEDINGS OF THE NINTH INTERNATIONAL CONFERENCE ON CREEP, SHRINKAGE, AND DURABILITY MECHANICS (CONCREEP-9) September 22–25, 2013 Cambridge, Massachusetts SPONSORED BY IA-CONCREEP Engineering Mechanics Institute of ASCE American Concrete Institute Concrete Sustainability Hub at MIT Groupement de Recherche International “Multi-scale Materials Under the Nanoscope” of CNRS EDITED BY Franz-Josef Ulm Hamlin M. Jennings Roland Pellenq Published by the American Society of Civil Engineers Library of Congress Cataloging-in-Publication Data International Conference on Creep, Shrinkage, and Durability Mechanics (9th : 2013 : Cambridge, Mass.) Mechanics and physics of creep, shrinkage, and durability of concrete : a tribute to Zdenek P. Bažant : proceedings of the Ninth International Conference on Creep, Shrinkage, and Durability Mechanics (CONCREEP-9), September 22-25, 2013 Cambridge, Massachusetts / sponsored by IA- CONCREEP, Engineering Mechanics Institute of ASCE, American Concrete Institute, Concrete Sustainability Hub at MIT, Groupement de recherche international "multi-scale materials, under the nanoscope" of CNRS ; edited by Franz-Josef Ulm, Hamlin M. Jennings, Roland Pellenq. pages cm Includes bibliographical references. ISBN 978-0-7844-1311-1 (print : alk. paper) -- ISBN 978-0-7844-7796-0 (ebook) 1. Concrete-- Creep--Congresses. 2. Concrete--Expansion and contraction--Congresses. I. Bažant, Z. P. II. Ulm, F.-J. (Franz-Josef) III. Jennings, Hamlin. IV. Pellenq, Roland. V. Engineering Mechanics Institute. VI. Title. TA440.I5225 2013 624.1'834--dc23 2013030292 American Society of Civil Engineers 1801 Alexander Bell Drive Reston, Virginia, 20191-4400 www.pubs.asce.org Any statements expressed in these materials are those of the individual authors and do not necessarily represent the views of ASCE, which takes no responsibility for any statement made herein. No reference made in this publication to any specific method, product, process, or service constitutes or implies an endorsement, recommendation, or warranty thereof by ASCE. The materials are for general information only and do not represent a standard of ASCE, nor are they intended as a reference in purchase specifications, contracts, regulations, statutes, or any other legal document. ASCE makes no representation or warranty of any kind, whether express or implied, concerning the accuracy, completeness, suitability, or utility of any information, apparatus, product, or process discussed in this publication, and assumes no liability therefore. This information should not be used without first securing competent advice with respect to its suitability for any general or specific application. Anyone utilizing this information assumes all liability arising from such use, including but not limited to infringement of any patent or patents. ASCE and American Society of Civil Engineers—Registered in U.S. Patent and Trademark Office. Photocopies and permissions. Permission to photocopy or reproduce material from ASCE publications can be obtained by sending an e-mail to [email protected] or by locating a title in ASCE's online database (http://cedb.asce.org) and using the "Permission to Reuse" link. Bulk reprints. Information regarding reprints of 100 or more copies is available at http://www.asce.org/reprints. Copyright © 2013 by the American Society of Civil Engineers. All Rights Reserved. ISBN 978-0-7844-1311-1 Manufactured in the United States of America. Preface Concrete, the solid that forms at room temperature from mixing Portland cement with water, sand, and aggregates, is the backbone material of our society’s legitimate need for housing, shelter, hospitals, energy, and transport. But concrete suffers from time- dependent deformation under load. This creep occurs at a rate that deteriorates the durability and truncates the lifespan of concrete structures. However, the fundamental causes of concrete creep are still an enigma and have deceived many decoding attempts from both experimental and theoretical sides. In the United States alone, concrete creep is partly responsible for an estimated 78.8 billion dollars required annually for highway and bridge maintenance. In some applications, concrete creep and shrinkage is considered a serious threat to longevity and safety of our built concrete infrastructure, including bridges, containment structures, oil and gas well cement seals, and so on. The contributions assembled in this book all aim at contributing to dissecting the very physical origin of creep and shrinkage of concrete, and to propel this knowledge from the scale of a few atoms to the scale of day-to-day engineering applications. They comprise both the invited and contributed papers presented at the Ninth International Conference on Creep, Shrinkage, and Durability Mechanics (ConCreep-9@MIT), held at the Massachusetts Institute of Technology, Cambridge, MA, U.S.A., from September 22–25, 2013. Now in its 9th edition, ConCreep-9@MIT continues a highly successful conference series on Creep, Shrinkage, and Durability Mechanics of Concrete and other Quasi-Brittle Materials, that started more than a half a century ago in Munich (1958,1968), Leeds (1978), Evanston (1986), Barcelona (1993), Cambridge (2001), Nantes (2005), and Ise-Shima (2008). Hosted by the Concrete Sustainability Hub at MIT (http://web.mit.edu/cshub/), ConCreep-9@MIT brings together scientists and engineers at the leading edge of research and implementation of innovation related to creep, shrinkage, and durability mechanics of concrete and concrete structures. While the main objective of Concreep- 9@MIT remains true to the original objectives of this conference series, to review and discuss novel efforts in both research and engineering practice on physical origin, prediction, and structural effects of time-dependent deformation, we recognize that the development of the next generation of science-enabled engineering solutions requires an outreach to fields that have classically not been associated with the ConCreep community. Specifically, through the co-sponsorship of this conference by the Groupement de Recherche International Multi-scale Materials Under the Nanoscope (GDRI, M2UN), we extend the outreach to the community of soft matter scientists, glasses physicists, and computational materials scientists. The results of this synergy can be traced throughout this book, from molecular and mesoscale scale iii simulations and measurements to loss of prestress assessment due to creep and shrinkage using the latest advances in engineering design creep models. We dedicate this collective work of the state-of-the-art of the science and engineering of creep and shrinkage of concrete to Zdeněk P. Bažant, the McCormick Institute Professor, Walter P. Murphy Professor of Civil and Environmental Engineering, Mechanical Engineering and Material Science and Engineering at Northwestern University, Evanston, Illinois, at the occasion of his 75th birthday. Zdeněk P. Bažant epitomizes like no other the theme of this conference series at the cross-road of fundamental physics and engineering. A native of Prague, Zdeněk P. Bažant’s first encounter with creep and shrinkage was during his early practice as a Structural Bridge Engineer in the early 1960s in the former communist Czechoslovakia, which culminated in his 1963 doctoral dissertation on creep effects in concrete structures (subsequently published as a book). His postdoctoral studies in Paris and Toronto, during the short-lived period of liberalization in communist Czechoslovakia that preceded the Prague Spring in 1968, brought him to the West and to the forefront of research on creep and shrinkage of concrete. It culminated in his early fundamental contribution to the surface thermodynamics of volume change, hindered adsorbed water and disjoining pressure, which laid the foundation for the modern theory of creep and shrinkage mechanisms and its application in constitutive modeling and engineering design codes. After more than 45 years, this topic continues to be focus of cutting edge research. In the fall of 1969, he joined the faculty at Northwestern University. For more than four decades, Zdeněk P. Bažant continues to shape and redefine the engineering sciences in civil and mechanical engineering in general and of creep, shrinkage, and fracture of concrete and other quasi-brittle materials in particular. He is member of the National Academy of Engineers and the National Academy of Sciences of the United States of America and the founding president of IA-Concreep, the international association organizing the ConCreep conference series. As the future of sustainable concrete engineering solutions is at stake, we trust that the conference papers in the ConCreep-9@MIT Proceedings will significantly contribute to Concrete Science and Engineering in the 21st Century and be a permanent tribute to the groundbreaking work of a scientist and engineer, educator, mentor, and friend, Zdeněk P. Bažant. Franz-Josef Ulm Hamlin M. Jennings Roland Pellenq Cambridge, MA, June 2013 iv Contents Keynote Lectures Progress in Creep and Shrinkage Prediction Engendered by Alarming Bridge Observations and Expansion of Laboratory Database ........................................................ 1 Z. P. Bažant, M. H. Hubler, R. Wendner, and Q. Yu Structure and Small Angle Scattering of Polydisperse Granular Porous Materials: A Fingerprint for Cement Paste ........................................................................................... 18 P. Levitz and S. Brisard Nanoscale Numerical Study of C-S-H Precipitation and Gelation ................................... 30 Emanuela Del Gado and Katerina Ioannidou The Counteracting Effects of Capillary Porosity and of Unhydrated Clinker Grains on the Macroscopic Strength of Hydrating Cement Paste: A Multiscale Model ...................................................................................................................................... 40 Bernhard Pichler, Christian Hellmich, Josef Eberhardsteiner, Jaromír Wasserbauer, Pipat Termkhajornkit, Rémi Barbarulo, and Gilles Chanvillard Creep Properties of Cementitious Materials from Indentation Testing: Significance, Influence of Relative Humidity, and Analogy Between C-S-H and Soils ......................................................................................................................................... 48 M. Vandamme, Q. Zhang, F.-J. Ulm, R. Le Roy, B. Zuber, E. Gartner, and P. Termkhajornkit A Depinning Model for Creep and Plasticity of Disordered Materials ............................ 62 David Bouttes and Damien Vandembroucq Molecular and Meso-Scale Simulations and Characterization NANO-CREEP of Synthetic CSH Produced using 1.5 and 0.7 CAO/SIO Mixture 2 Ratios ...................................................................................................................................... 70 Michelle L. Begaye, Sherif H. Aboubakr, Jung J. Kim, and Mahmoud M. Reda Taha Applying Tools from Glass Science to Study Calcium-Silicate- Hydrates ....................... 78 MJ. Abdolhosseini Qomi, M. Bauchy, R. J-M. Pellenq, and F-J. Ulm Mechanical Behaviour of Ordered and Disordered Calcium Silicate Hydrates under Shear Strain Studied by Atomic Scale Simulations ................................................. 86 H. Manzano, E. Masoero, I. Lopez-Arbeloa, and H. M. Jennings Hydrothermal and Mechanical Stability of Metal-Organic Frameworks ....................... 98 François-Xavier Coudert, Aurélie Ortiz, Marta De Toni, Anne Boutin, and Alain H. Fuchs NMR Investigations of Water Retention Mechanism by Cellulose Ethers in Cement-Based Materials .................................................................................................... 102 J.-P. Korb, L. Patural, A. Govin, and Ph. Grosseau vii Water Sorption Hysteresis in Cement Nano Slits .............................................................. 110 Wen Hui Duan, Shu Jian Chen, and Mija Hubler Interpretation of Full Sorption-Desorption Isotherms as a Tool for Understanding Concrete Pore Structure ...................................................................................................... 118 Matthew B. Pinson, Hamlin M. Jennings, and Martin Z. Bazant Multi-scale Hydric Transport in Hardened Cement Pastes and Reference Porous Silicate Materials ................................................................................................................. 126 H. Chemmi, V. Tariel, D. Petit, J-P. Korb, R. Denoyel, and P. Levitz Water Isotherms, Shrinkage and Creep of Cement Paste: Hypotheses, Models and Experiments ......................................................................................................................... 134 Hamlin M. Jennings, Enrico Masoero, Matthew B. Pinson, Elena G. Strekalova, Patrick A. Bonnaud, Hegoi Manzano, Q. Ji, Jeffrey J. Thomas, Roland J.-M. Pellenq, Franz-Josef Ulm, Martin Z. Bazant, and Krystyn J. Van Vliet Diffusion Properties of Sodium and Lithium Silicates through Cement Pastes and its Mitigating Effect on Alkali-silica Reaction .................................................................. 142 Irfan Prasetia, Soyo Asano, and Kazuyuki Torii New Experimental Approach to Study Creep and Shrinkage Mechanisms of Concrete on the Nano-scale Level ...................................................................................... 150 Harald S. Müller, Joerg-Detlef Eckhardt, and Michael Haist Infinitesimal Shrinkage as Determined by Inverse Analysis Based on Drying and Shrinkage Tests .................................................................................................................... 158 B. Villmann, V. Slowik, P. Wang, and F. H. Wittmann Kinetic Simulation of the Logarithmic Creep of Cement ................................................ 166 E. Masoero, H. Manzano, E. Del Gado, R. J.-M. Pellenq, F.-J. Ulm, and S. Yip Recent Developments in Durability Mesomechanics of Concrete, Including Cracking via Interface Elements ....................................................................................... 174 Joaquin Liaudat, Mariana Rodriguez, Carlos Lopez, and Ignacio Carol Finite Element Based Characterization of the Creep Properties of the Cement Paste Phases by Coupling Nanoindentation Technique and SEM-EDS ......................... 182 L. Sorelli, D.-T. Pham, D. Vallée, J. Chen, and M. Fafard In-situ Chemo-Mechanical Characterization of Cementitious Microstructures with Coupled X-Ray Microanalysis and Indentation Technique .................................... 190 Konrad J. Krakowiak, William Wilson, Simon James, and Franz.-J. Ulm Micromechanics of Creep and Shrinkage Efficient Homogenization of Ageing Creep of Random Media: Application to Solidifying Cementitious Materials ................................................................................... 201 J. Sanahuja Multi-scales Characterization of the Early-age Creep of Concrete ................................. 211 M. Farah, F. Grondin, M. Matallah, A. Loukili, and J. Saliba Coupled Damage and Multiscale Creep Model Applied to Cementitious Materials .... 219 B. Bary, Q.-C. He, and M.-Q. Thai viii Micromechanical Model of Concrete Creep ..................................................................... 227 Lev Khazanovich and Kairat Tuleubekov Experimental Analysis of Drying Shrinkage Cracking in Coating Mortars by Digital Image Correlation ................................................................................................... 235 F. Benboudjema, T. Mauroux, P. Turcry, A. Ait-Mokthar, and O. Deves Numerical Analysis of Cracking Induced by Drying Shrinkage in Concrete using a Mesoscopic Approach: Influence of Aggregates Restraint and Skin Effect ................... 243 M. Briffaut and F. Benboudjema Delayed Strains of Cementitious Materials – Impact of Heterogeneities and Creep on Cracking Induced by Drying ........................................................................................ 251 C. De Sa, C. Benboudjema, and A. Michou Influence of the Initial Water Saturation of Aggregates on Concrete Shrinkage .......... 261 E. Roziere, R. Cortas, A. Loukili, A. Hamami, and S. Staquet Multiscale Creep, Shrinkage, Fracture and Durability Properties Freeze-Thaw Resistance of Fiber Reinforced Composites with Superhydrophobic Admixtures ........................................................................................................................... 269 Scott Muzenski, Ismael Flores-Vivian, and Konstantin Sobolev Experimental Study on Effect of Internal Cracking on Corrosion Rate of Reinforcement in Concrete ................................................................................................. 277 Isao Ujike, Shinichiro Okazaki, and Ryoichi Sato Mechanical Properties of Deteriorated Hardened Cement Paste ................................... 285 K. Kurumisawa, H. Owada, and M. Shibata Microstructure Improvement of Cementitious Systems using Nanomaterials: A Key for Enhancing the Durability of Concrete ................................................................. 293 L.P. Singh, S.K. Bhattacharyya, U. Sharma, G. Mishra, and S. Ahalawat The use of Superabsorbent Polymers to Mitigate Shrinkage of Concrete ..................... 301 A. Assmann and H.W. Reinhardt Measuring the Chemical Shrinkage of Alkali-Activated Slag Cements Using the Buoyancy Method ................................................................................................................ 308 Christopher P. Cartwright, Farshad Rajabipour, and Aleksandra Radlińska An Apparatus for Dissecting Volumetric Changes in Hydrating Cement Paste ............ 316 M. Abuhaikal, S. Musso, J. Thomas, and F.-J. Ulm Effectiveness of Various Superabsorbent Polymers (SAP) in Mitigating Autogenous Shrinkage of Cement-based Materials ......................................................... 324 V. Mechtcherine, C. Schroefl, and M. Gorges Macrocrack Propagation in a Concrete Specimen Subjected to a Sustained Loading: Influence of Tensile Creep .................................................................................. 332 Pierre Rossi and Jean-Louis Tailhan Experimental Research and Numerical Simulation of Post-Crack Creep Behavior of SFRC Loaded in Tension ................................................................................................ 340 Guanyu Zhao, Marco di Prisco, and Lucie Vandewalle ix Analysis of Concrete Creep in Compression, Tension and Bending: Numerical Modeling .............................................................................................................................. 348 A. Hilaire, F. Benboudjema, A. Darquennes, Y. Berthaud, and G. Nahas Improvement of Crack Resistance of Slag Concrete by Utilizing High Alite Cement ................................................................................................................................. 356 Huynh Phuong Nam and Akira Hosoda Experimental Determination of Early Age Fracture Toughness and Fracture Process Zone Size in Cement Pastes .................................................................................. 364 C. Hoover The Significance of Nanosilica on Degradation of Oil Well Cement in Carbonated Brine Environments ............................................................................................................ 372 Andrew S. Griffin, Muhammad K. Rahman, Jung J. Kim, and Mahmoud Reda Taha Optimization of Anti-creep Admixtures for Plasterboards ............................................. 380 J. Colombani and M. Bellotto Role of Recycled Concrete Aggregates on the Long-term Behavior of Structural Concrete ............................................................................................................................... 388 C. Mazzotti, S. Manzi, and M.C. Bignozzi Effects of Poly Vinyl Alcohol Fibers in Fracture Energy of Concrete ............................ 396 H. R. Ahmadian and M. Ganji From Material Creep and Shrinkage to Structural Design Desiccation Shrinkage of Large Structures: Is there a Size Effect? ............................... 404 J. M. Torrenti and F. Benboudjema Development of Comprehensive Platform for the Estimation of Volume Change and Damage in Cementitious Material .............................................................................. 412 T. Tanabe, S. Ono, H. Morimoto, H. Nakamura, and Y. Ishikawa Simulation of Time-dependent Tensile Behavior of Concrete under Various Loading and Drying Path ................................................................................................... 421 T. Shimomura, Y. Aoki, and H. Obata The B4 Model for Multi-decade Creep and Shrinkage Prediction ................................. 429 R. Wendner, M. H. Hubler, and Z. P. Bažant Improved Estimation of Long-Term Relaxation Function of Aging Concrete from Its Compliance Function ..................................................................................................... 437 Z. P. Bažant, M. H. Hubler, and M. Jirásek Overall Stiffness Reduction of Cracked Reinforced Concrete Beams Due to Long Term Effects ......................................................................................................................... 443 Arnaud Castel, Raymond Ian Gilbert, and Gianluca Ranzi An Effective Flexural Stiffness Equation for Long Term Deflection of Prestressed Concrete with and without Cracks .................................................................................... 451 R. Sato, K. Nakarai, Y. Ogawa, and K. Kawai x Viscoplastic Constitutive Relation for Relaxation of Prestressing Steel at Varying Strain and Temperature ...................................................................................................... 459 Qiang Yu and Zdenĕk P. Bažant Material Law on the Time-dependent Stress-strain Behavior of Young Concretes ...... 467 Isabel Anders and Harald S. Müller Inverse Estimation of Thermal Properties of Concrete During Hydrating Process ..... 475 Osvaldo D. Quintana, Antonio Aquino, Rubén López, Jean Marie Désir, and Eduardo M. B. Campello Effect of Heat Elimination by Pipe Cooling System for Temperature Rise with Heat of Cement Hydration in Beam Using High Strength Engineered Cementitious Composites ................................................................................................... 483 T. Mizobuchi, T. Kanda, and M. Kunieda Development of FEM Thermal Analysis for Concrete Structures with Pipe Cooling System .................................................................................................................................. 491 Yasuaki Ishikawa, Toshiaki Mizobuchi, and Tada-aki Tanabe xi Progress in Creep and Shrinkage Prediction Engendered by Alarming Bridge Observations and Expansion of Laboratory Database Z. P. Bažant1, M. H. Hubler2, R. Wendner3, and Q. Yu4 1 Northwestern University, Department of Civil and Environmental Engineering, Tech 2145 Sheridan Rd. A135, Evanston, IL 60208-3109; PH (847) 491-4025; email: z- [email protected] 2 Northwestern University, Department of Civil and Environmental Engineering, Tech 2145 Sheridan Rd. A236, Evanston, IL 60208-3109; email: m- [email protected] 3 University of Natural Resources and Life Sciences Vienna, Institute of Structural Engineering, Peter Jordanstr. 82, Vienna, Austria; email: [email protected] 4 University of Pittsburgh, Department of Civil and Environmental Engineering, 3700 O'Hara Street 730 Benedum Hall, Pittsburgh, PA 15261; PH (412) 624-9899; email: [email protected] ABSTRACT This keynote lecture presents a broad yet concise overview of the advances at Northwestern University since ConCreep-8, triggered by the success in 2008 in enforcing the release of the (legally sealed) data on the tragic 1996 collapse and the preceding, grossly excessive, deflections of the record-span segmental box-girder bridge in Palau. Subsequent analysis put the main blame for the excessive deflections on wrong design codes or recommendations. This revelation stimulated an extensive effort, generously funded by DoT and NSF, to advance the knowledge of concrete creep. First, several advances, presented in detail in other papers at ConCreep-9, are briefly reviewed; they include: 1) assembly of a greatly enlarged database of laboratory creep and shrinkage data for various concretes without and with admixtures; 2) collection of a database on deflections of 69 segmental bridges, mostly excessive; 3) development of an improved creep and shrinkage prediction model, labeled B4, and its joint statistical calibration by both databases; 4) improved rate- type algorithm for creep analysis in which the inverse Laplace transform is used in each time step to obtain the current retardation spectrum; 5) a realistic viscoplastic constitutive law for prestressing steel, applicable to time-varying strain and temperature; and 6) an improved algebraic formula for converting the aging compliance function to the relaxation function. Development of new formula for cyclic creep is described next, in detail. The formula is derived from Paris’ law for the growth of micrometer size cracks. Its consequences for segmental bridges of various spans are discussed. The final discussion outlines new theoretical results showing that one mechanism causing the hysteresis of nanopore water sorption- 1