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MATERIALS SCIENCE OF POLYMERS Plastics, Rubber, Blends, and Composites © 2015 by Apple Academic Press, Inc. MATERIALS SCIENCE OF POLYMERS Plastics, Rubber, Blends, and Composites Edited by A. K. Haghi, PhD, Eduardo A. Castro, PhD, Sabu Thomas, PhD, P. M. Sivakumar, PhD, and Andrew G. Mercader, PhD © 2015 by Apple Academic Press, Inc. CRC Press Apple Academic Press, Inc Taylor & Francis Group 3333 Mistwell Crescent 6000 Broken Sound Parkway NW, Suite 300 Oakville, ON L6L 0A2 Boca Raton, FL 33487-2742 Canada © 2015 by Apple Academic Press, Inc. Exclusive worldwide distribution by CRC Press an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works Version Date: 20150514 International Standard Book Number-13: 978-1-4822-9913-7 (eBook - PDF) This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmitted, or utilized in any form by any electronic, mechanical, or other means, now known or hereafter invented, including photocopying, microfilming, and recording, or in any information stor- age or retrieval system, without written permission from the publishers. For permission to photocopy or use material electronically from this work, please access www.copy- right.com (http://www.copyright.com/) or contact the Copyright Clearance Center, Inc. (CCC), 222 Rosewood Drive, Danvers, MA 01923, 978-750-8400. CCC is a not-for-profit organization that pro- vides licenses and registration for a variety of users. For organizations that have been granted a photo- copy license by the CCC, a separate system of payment has been arranged. Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and are used only for identification and explanation without intent to infringe. Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the CRC Press Web site at http://www.crcpress.com For information about Apple Academic Press product http://www.appleacademicpress.com © 2015 by Apple Academic Press, Inc. ABOUT THE EDITORS A. K. Haghi, PhD A. K. Haghi, PhD, holds a BSc in urban and environmental engineering from Uni- versity of North Carolina (USA); a MSc in mechanical engineering from North Carolina A&T State University (USA); a DEA in applied mechanics, acoustics and materials from Université de Technologie de Compiègne (France); and a PhD in engineering sciences from Université de Franche-Comté (France). He is the author and editor of 165 books as well as 1,000 published papers in various journals and conference proceedings. Dr. Haghi has received several grants, consulted for a num- ber of major corporations, and is a frequent speaker to national and international au- diences. Since 1983, he served as a professor at several universities. He is currently Editor-in-Chief of the International Journal of Chemoinformatics and Chemical Engineering and Polymers Research Journal and on the editorial boards of many international journals. He is a member of the Canadian Research and Development Center of Sciences and Cultures (CRDCSC), Montreal, Quebec, Canada. Eduardo A. Castro, PhD Eduardo A. Castro, PhD, is a Superior Researcher at the Argentina National Re- search Council. He is a full professor of theoretical chemistry at the Universidad Nacional de La Plata and a career investigator with the Consejo Nacional de Inves- tigaciones Cientificas y Tecnicas, both based in Buenos Aires, Argentina. He is the author of nearly 1,000 academic papers in theoretical chemistry and other topics, and he has published several books. He serves on the editorial advisory boards of several chemistry journals and is often an invited speaker at international confer- ences in South America and elsewhere. Sabu Thomas, PhD Dr. Sabu Thomas is the Director of the School of Chemical Sciences, Mahatma Gandhi University, Kottayam, India. He is also a full professor of polymer science and engineering and the Director of the International and Inter University Centre for Nanoscience and Nanotechnology of the same university. He is a fellow of many professional bodies. Professor Thomas has authored or co-authored many papers in international peer-reviewed journals in the area of polymer processing. He has organized several international conferences and has more than 420 publications, 11 books, and two patents to his credit. He has been involved in a number of books both as author and editor. He is a reviewer to many international journals and has © 2015 by Apple Academic Press, Inc. vi About the Editors received many awards for his excellent work in polymer processing. His h-Index is 42. Professor Thomas is listed as the 5th position in the list of Most Productive Researchers in India, in 2008. P. M. Sivakumar, PhD P. M. Sivakumar, PhD, is a Foreign Postdoctoral Researcher (FPR) at RIKEN, Wako Campus, in Japan. RIKEN is Japan’s largest comprehensive research institution re- nowned for high-quality research in a diverse range of scientific disciplines. He received his PhD from the Department of Biotechnology, Indian Institute of Tech- nology Madras, India. He is a member of the editorial boards of several journals and has published papers in international peer-reviewed journals and professional conferences. His research interests include bionanotechnology and biomaterials. Andrew G. Mercader, PhD Andrew G. Mercader, PhD, studied physical chemistry at the Faculty of Chemistry of La Plata National University (UNLP), Buenos Aires, Argentina, from 1995 to 2001. Afterwards he joined Shell Argentina to work as Luboil, Asphalts and Distil- lation Process Technologist, as well as Safeguarding and Project Technologist from 2001 to 2006. His PhD work, on the development and applications of QSAR/QSPR theory, was performed at the Theoretical and Applied Research Institute located at La Plata National University (INIFTA), from 2006 to 2009. After that he obtained a postdoctoral scholarship to work on theoretical-experimental studies of biflavo- noids at IBIMOL (ex PRALIB), Faculty of Pharmacy and Biochemistry, University of Buenos Aires (UBA), from 2009 to 2012. He is currently appointed as a member of the Scientific Researcher Career in the Argentina National Research Council at INIFTA. © 2015 by Apple Academic Press, Inc. CONTENTS List of Contributors ........................................................................................ix List of Abbreviations ....................................................................................xiii List of Symbols ..............................................................................................xv Preface ........................................................................................................xvii 1. A Detailed Review on Characteristics, Application and Limitation of Amorphous Glassy Polymers as Natural Nanocomposites .........................1 G. V. Kozlov, I. V. Dolbin, Jozef Richert, O. V. Stoyanov, and G. E. Zaikov 2. Structure of Graphitic Carbons: A Comprehensive Review .....................51 Heinrich Badenhorst 3. Radiation Crosslinking of Acrylonitrile-Butadiene Rubber .....................81 Katarzyna Bandzierz, Dariusz M. Bielinski, Adrian Korycki, and Grazyna Przybytniak 4. Rubber Vulcanizates Containing Plasmochemically Modified Fillers .....91 Dariusz M. Bieliński, Mariusz Siciński, Jacek Grams, and Michał Wiatrowski 5. Modification of the Indian Rubber in the Form of Latex with Ozone ...103 L. A. Vlasova, P. T. Poluektov, S. S. Nikulin, and V. M. Misin 6. Influence of the Structure of Polymer Material on Modification of the Surface Layer of Iron Counterface in Tribological Contact ...................111 Dariusz M. Bieliński, Mariusz Siciński, Jacek Grams, and Michał Wiatrowski 7. Boron Oxide as a Fluxing Agent for Silicone Rubber-Based Ceramizable Composites ............................................................................125 R. Anyszka, D. M. Bieliński, and Z. Pędzich 8. Application of Micro-dispersed Silicon Carbide Along with Slurries as a Functional Fin Fire and Heat Resistant Elastomer Compositions ....139 V. S. Liphanov, V. F. Kablov, S.V. Lapin, V. G. Kochetkov, O. M. Novopoltseva, and G. E. Zaikov 9. Thermal Stability of Elastic Polyurethane................................................145 I. A. Novakov, M. A. Vaniev, D.V. Medvedev, N. V. Sidorenko, G. V. Medvedev, and D. O. Gusev © 2015 by Apple Academic Press, Inc. viii Contents 10. PAN/Nano–ТіО–S Composites: Physico–Chemical Properties .............155 2 M. M. Yatsyshyn, A. S. Kun’ko, and O. V. Reshetnyak 11. Viscoelastic Properties of the Polystyrene ................................................173 Yu. G. Medvedevskikh, O. Yu. Khavunko, L. I. Bazylyak, and G. E. Zaikov 12. Nanostructured Polymeric Composites Filled with Nanoparticles ........211 A. K. Mikitaev, A. Yu. Bedanokov, and M. A. Mikitaev 13. Structure, Properties and Application of Dendritic Macromolecules in Various Fields: Molecular Simulation Techniques in Hyperbranched Polymer and Dendrimers ...........................................................................241 M. Hasanzadeh and B. Hadavi Moghadam 14. A Study on Influence of Electrospinning Parameters on the Contact Angle of the Electrospun PAN Nanofiber Mat Using Response Surface Methodology (RSM) and Artificial Neural Network (ANN) ...................261 B. Hadavi Moghadam and M. Hasanzadeh 15. Fabrication and Characterization of the Metal Nano-Sized Branched Structures and the Composite Nanostructures Grown on Insulator Substrates by the EBID Process ................................................................279 Guoqiang Xie, Minghui Song, Kazuo Furuya, and Akihisa Inoue 16. A Case Study on Hyperbranched Polymers .............................................297 Ramin Mahmoodi, Tahereh Dodel, Tahereh Moieni, and Mahdi Hasanzadeh 17. A Study on Network of Sodium Hyaluronate with Nano-Knots Junctions ......................................................................................................307 Shin-ichi Hamaguchi and Toyoko Imae 18. The Magnetic Photocatalyst Conversion to the Magnetic Dye-Adsorbent Catalyst via Hydrothermal Followed by Typical Washing and Thermal Treatments ...................................................................................................323 Satyajit Shukla 19. Solid Polymer Fuel Cell: A Three-Dimensional Computation Model and Numerical Simulations ........................................................................339 Mirkazem Yekani, Meysam Masoodi, Nima Ahmadi, Mohamad Sadeghi Azad, and Khodadad Vahedi Index .............................................................................................................363 © 2015 by Apple Academic Press, Inc. LIST OF CONTRIBUTORS Nima Ahmadi Mechanical Engineering Department, Urmia University, of Technology, Iran R. Anyszka Lodz University of Technology, Faculty of Chemistry, Institute of Polymer and Dye Technology, 90-924, Lodz, Poland Mohamad Sadeghi Azad Mechanical Engineering Department, Urmia University, of Technology, Iran Heinrich Badenhorst SARChI Chair in Carbon Materials and Technology, Department of Chemical Engineering, University of Pretoria, Pretoria, Gauteng, 0002, Gauteng, 0169, South Africa, Email: [email protected] Katarzyna Bandzierz Faculty of Chemistry, Lodz University of Technology, Poland L. I. Bazylyak Physical Chemistry of Combustible Minerals Department, Institute of Physical–Organic Chemistry and Coal Chemistry named after L. M. Lytvynenko, National Academy of Sciences of Ukraine, 79053, Lviv, Ukraine D. M. Bieliński Institute for Engineering of Polymer Materials and Dyes, Division of Elastomers and Rubber Technol- ogy, 05-820 Piastow, Poland Tahereh Dodel Amirkabir University of Technology, Iran I. V. Dolbin Kabardino-Balkarian State University, Nal’chik, 360004, Russian Federation Kazuo Furuya High Voltage Electron Microscopy Station, National Institute for Materials Science, Tsukuba, 305-0003, Japan Jacek Grams Institute of General and Ecological Chemistry, Technical University of Łódź, Łódź, Poland. D. O. Gusev Volgograd State Technical University, 400005, Volgograd, Russia Shin-ichi Hamaguchi Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan M. Hasanzadeh Department of Textile Engineering, University of Guilan, Rasht, Iran © 2015 by Apple Academic Press, Inc. x List of Contributors Toyoko Imae Graduate Institute of Engineering, National Taiwan University of Science and Technology, Taipei 10607, Taiwan; Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan Akihisa Inoue WPI Advanced Institute for Materials Research, Tohoku University, Sendai, 980-8577, Japan V. F. Kablov Volzhsky Polytechnical Institute (branch) Volgograd State Technical University, Volzhsky, Volgograd Region, 404121, Russian Federation, E-mail: [email protected]; www.volpi.ru O. Yu. Khavunko Physical Chemistry of Combustible Minerals Department, Institute of Physical–Organic Chemistry and Coal Chemistry named after L. M. Lytvynenko, National Academy of Sciences of Ukraine, 79053, Lviv, Ukraine, e–mail: [email protected] V. G. Kochetkov Volzhsky Polytechnical Institute (branch) Volgograd State Technical University, Volzhsky, Volgograd Region, 404121, Russian Federation, E-mail: [email protected]; www.volpi.ru Adrian Korycki Faculty of Chemistry, Lodz University of Technology, Poland G. V. Kozlov Kabardino-Balkarian State University, Nal’chik, 360004, Russian Federation, E-mail: [email protected] A. S. Kun’ko Department of Physical and Colloidal Chemistry, Ivan Franko National University of L’viv, 79005, L’viv, Ukraine, e–mail: [email protected] S. V. Lapin Volzhsky Polytechnical Institute (branch) Volgograd State Technical University, Volzhsky, Volgograd Region, 404121, Russian Federation, E-mail: [email protected]; www.volpi.ru V. S. Liphanov Volzhsky Polytechnical Institute (branch) Volgograd State Technical University, Volzhsky, Volgograd Region, 404121, Russian Federation, E-mail: [email protected]; www.volpi.ru Ramin Mahmoodi Amirkabir University of Technology, Iran Meysam Masoodi Department of Chemical Engineering-Faculty of Engineering- Imam Hossein University, Tehran, Iran D. V. Medvedev Elastomer Limited Liability Company, 400005, Volgograd, Russia G. V. Medvedev Volgograd State Technical University, 400005, Volgograd, Russia Yu. G. Medvedevskikh Physical Chemistry of Combustible Minerals Department, Institute of Physical–Organic Chemistry and Coal Chemistry named after L. M. Lytvynenko, National Academy of Sciences of Ukraine, 79053, Lviv, Ukraine, e–mail: [email protected] A. K. Mikitaev Kabardino Balkarian State University, Nalchik, Russia © 2015 by Apple Academic Press, Inc.

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