Materials for Electrochemical Energy Conversion and Storage (Ceramic Transactions, Vol. 127) (Ceramic Transactions Series)

272 Pages·2002·22.641 MB·English

by  Arumugam Manthiram, Prashant N. Kumta, S. K. Sundaram, Gerbrand Ceder

Materials for
Electrochemical
Energy
Conversion
and Storage
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Materials for
Electrochemical
Cuereante ,.
transactions
Volume 127
Energy
Conversion
and Storage
Papers from the Electrochemical Materials, Processes, and
Devices symposium at the 102nd Annual Meeting of The
American Ceramic Society, held April 29-May 3, 2000, in St
Louis, Missouri, and the Materials for Electrochemical Energy
Conversion and Storage symposium at the 103rd Annual
Meeting of The American Ceramic Society, held April 22-25,
2001, in Indianapolis, Indiana, USA.
Edited by
Arumugam Manthiram
University ofTexas at Austin
Prashant N. Kumta
Carnegie Mellon University
S.K. Sundaram
Pacific Northwest National Laboratory
Gerbrand Ceder
Massachusetts Institute ofTechnology
Published by
The American Ceramic Society
735 Ceramic Place
Westerville, Ohio 43081
www.ceramics.org
Papers from the Electrochemical Materials, Processes, and Devices symposium at the 102nd Annual
Meeting of The American Ceramic Society, held April 29-May 3, 2000, in St. Louis, Missouri, and the
Materials for Electrochemical Energy Conversion and Storage symposium at the 103rd Annual
Meeting of The American Ceramic Society, held April 22-25, 2001, in Indianapolis, Indiana, USA.
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Cover photo:"SEM micrograph of the cross-section of a fuel cell fracture surface showing the dense
electrolyte between the porous anode and cathode layers," is courtesy ofS. Huss, R. DoshiJ. Guan,
G. Lear, K. Montgomery, N. Minh, and E. Ong, and appears as figure 4 in the paper "Materials and
Microstructures for Improved Solid Oxide Fuel Cells," which begins on page 109.
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Printed in the United States of America.
4 3 2 1-05 04 03 02
ISSN 1042-1 122
ISBN 1-57498-135-8
ontents
Preface ix
Papers from 2000 Annual Meeting
Oxygen Permeation Properties of the Intergrowth
Oxide Sr, La Fe., Co O, 3
R
3-x x 2-y y 7-δ
F. Prado,T. Armstrong, A, Manthiram, and A. Caneiro
Structural Stability of Lithium-Extracted Li, Ni, Co O, II
' l-x l-y y 2
R.V. Chebiam, F. Prado, and A. Manthiram
Reaction Kinetics and Mechanism of Formation
of LiNi0 from Particulate Sol-Gel (PSG)
2
Derived Precursors 19
C. C. Chang, J.Y Kim, Z. G.Yang, and R N. Kumta
Phase Evolution as a Function of Synthesis Temperature
in the Li Mn 0 (0.7 $ y =£ 1.33) System 27
3 4t8
S. Choi and A. Manthiram
Si/TiN Nanocomposite Anodes by High-Energy
Mechanical Milling 35
l.-S. Kim, R N. Kumta, and G. E. Blomgren
Papers from 2001 Annual Meeting
Gas Separation Membranes
Oxygen Permeation Through Mixed Conducting
Perovskite Oxide Membranes 49
H. J. M. Bouwmeester and L M. van der Haar
Oxygen Permeation Properties of Perovskite-Related
Intergrowth Oxides in the Sr-Fe-Co-O System 59
F. Prado,T. Armstrong, and A. Manthiram
v
Fe-Doped LaGa0 -Based Perovskite Oxide as an Oxygen-
3
Separating Membrane for CH Partial Oxidation 69
4
T. Ishihara.YTsuruta, H. Nishiguchi, andYTakita
Synthesis and Oxygen Permeation Properties of
Sr, La ,Fe, M 0 (M = Mn, Co and Ni) 79
7 n 7S
2.7 0.3 2-y y 7-8 v '
F. Prado and A. Manthiram
Fuel Cells
Low-Cost Manufacturing Processes for Solid
Oxide Fuel Cells 91
M. M. Seabaugh, B. E, McCormick, K. Hasinska, C.T. Holt,
S. L Swartz, and W. J. Dawson
Manufacturing Routes and State of the Art of the
Planar Julich Anode-Supported Concept for Solid
Oxide Fuel Cells 99
W. A. Muelenberg, N. H. Menzler, H. R Buchkremer, and D. Stover
Materials and Microstructures for Improved Solid
Oxide Fuel Cells 109
S. Huss, R. DoshiJ. Guan, G. Lear, K. Montgomery, N. Minh, and E. Ong
Pulsed Laser Deposition and DC-Sputtering of Yttria-
Stabilized Zirconia for Solid Oxide Fuel Cell Applications ... 117
B. Hobein.W. A. Muelenberg, F.Tietz, D. Stover,
E. W. Kreutz, M. Cekada, and R Panjan
Microstructure-Electrical Property Relationship in
Nanocrystalline Ce0 Thin Films 127
2
V. Petrovsky, B. R Gorman, H. U. Anderson, and T Petrovsky
Electrical Measurements in Doped Zirconia-
Ceria Ceramics 137
C. R. Foschini, L Perazolli.J. A. Várela, D. R F. Souza, and R I. R Filho
Effects of Dissolution and Exsolution of Ni inYSZ 147
S. Linderoth and N. Bonanos
Multilayered Ceramic Reactor for the Steam Reforming
of Methanol into Hydrogen-Enriched Gas 157
D. Gervasio, S. Rogers, R. Koripella, S.Tasic, D. Zindel, R. Changrani,
C. K. Dyer J. Hallmark, and D.Wilcox
VI
Si0 -P 0 -Zr0 Sol-Gel/Nafion Composite
2 2 5 2
Membranes for PEMFC 167
M. Aparicio, L C. Klein, K.I Adjemian, and A, B. Bocarsly
Study of Glass/Metal Interfaces Under an Electric Field:
Low Temperature/High Voltage 177
M.A.Alvarez and L C. Klein
Lithium-Ion Batteries
Olivine-Type Cathodes for Lithium Batteries 189
A.Yamada, M. Hosoya, S. C. Chung, and K. Hinokuma
Amorphous Manganese Oxide Cathodes for
Rechargeable Lithium Batteries 205
D. Im and A. Manthiram
Synthesis and Electrochemical Properties of Spinel LiCo 0
2 4
Cathodes 215
S. Choi and A. Manthiram
Designing Structurally Stable Layered Oxide Cathodes
for Lithium-Ion Batteries 225
S. Choi and A. Manthiram
Modeling and Design of Intermetallic Electrodes for
Lithium Batteries 235
R. BenedekJ.T.Vaughey, and M. M.Thackeray
New Nanostructured Silicon and Titanium Nitride
Composite Anodes for Li-Ion Batteries 249
l.-S. Kim, R N. Kumta, and G. E. Blomgren
Index 259
Vll