The Handbook of Environmental Chemistry 119 Series Editors: Damià Barceló · Andrey G. Kostianoy Yolanda Picó Julian Campo Editors Mass Spectrometry in Food and Environmental Chemistry The Handbook of Environmental Chemistry Volume 119 Founding Editor: Otto Hutzinger (cid:1) Series Editors: Damia Barcelo´ (cid:129) Andrey G. Kostianoy Editorial Board Members: Jacob de Boer, Philippe Garrigues, Ji-Dong Gu, Kevin C. Jones, Abdelazim M. Negm, Alice Newton, Duc Long Nghiem, Sergi Garcia-Segura, Paola Verlicchi In over four decades, The Handbook of Environmental Chemistry has established itselfasthepremierreferencesource,providingsoundandsolidknowledgeabout environmentaltopicsfromachemicalperspective.Writtenbyleadingexpertswith practical experience in the field, the series continues to be essential reading for environmental scientists as well as for environmental managers and decision- makersinindustry,government,agenciesandpublic-interestgroups. Two distinguished Series Editors, internationally renowned volume editors as wellasaprestigiousEditorialBoardsafeguardpublicationofvolumesaccordingto highscientificstandards. Presenting a wide spectrum of viewpoints and approaches in topical volumes, thescopeoftheseriescoverstopicssuchas • localandglobalchangesofnaturalenvironmentandclimate • anthropogenicimpactontheenvironment • water,airandsoilpollution • remediationandwastecharacterization • environmentalcontaminants • biogeochemistryandgeoecology • chemicalreactionsandprocesses • chemical and biological transformations as well as physical transport of chemicalsintheenvironment • environmentalmodeling Aparticularfocusoftheseriesliesonmethodologicaladvancesinenvironmen- talanalyticalchemistry. TheHandbookofEnvironmentalChemistryisavailablebothinprintandonline viahttps://link.springer.com/bookseries/698.Articlesarepublishedonlineassoon astheyhavebeenreviewedandapprovedforpublication. Meeting the needs of the scientific community, publication of volumes in subserieshasbeendiscontinuedtoachieveabroaderscopefortheseriesasawhole. Mass Spectrometry in Food and Environmental Chemistry Volume Editors: Yolanda Picó (cid:1) Julian Campo With contributions by D. Barcelo´(cid:1) W. Buchberger (cid:1) J. Campo (cid:1) B. Chen (cid:1) C. D. Chouinard (cid:1) Z. Cui (cid:1) M. Farre´ (cid:1) Y. Feng (cid:1) Y.-L. Feng (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) M. He M. Himmelsbach B. Hu C. W. Klampfl J. Ma (cid:1) (cid:1) (cid:1) (cid:1) A. S. Maia K. A. Maloof A. Mpupa S. P. Neal P.N.Nomngongo(cid:1)A.Nqombolo(cid:1)Y.Pico´ (cid:1)A.R.L.Ribeiro(cid:1) C. Ribeiro (cid:1) A´. R´ıos (cid:1) Y. Sapozhnikova (cid:1) M. E. Tiritan (cid:1) (cid:1) (cid:1) (cid:1) K. R. Tucker C. Xu Q. Zhang M. Zougagh Editors YolandaPico´ JulianCampo FoodandEnvironmentalSafetyResearch FoodandEnvironmentalSafetyResearch Group(SAMA-UV) Group(SAMA-UV) DesertificationResearch DesertificationResearch Centre-CIDE(CSIC-UV-GV) Centre-CIDE(CSIC-UV-GV) Moncada,Valencia,Spain Moncada,Valencia,Spain ISSN1867-979X ISSN1616-864X (electronic) TheHandbookofEnvironmentalChemistry ISBN978-3-031-19092-6 ISBN978-3-031-19093-3 (eBook) https://doi.org/10.1007/978-3-031-19093-3 © The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature SwitzerlandAG2023 Thisworkissubjecttocopyright.AllrightsaresolelyandexclusivelylicensedbythePublisher,whether thewholeorpartofthematerialisconcerned,specificallytherightsoftranslation,reprinting,reuseof illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmissionorinformationstorageandretrieval,electronicadaptation,computersoftware,orbysimilar ordissimilarmethodologynowknownorhereafterdeveloped. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publicationdoesnotimply,evenintheabsenceofaspecificstatement,thatsuchnamesareexempt fromtherelevantprotectivelawsandregulationsandthereforefreeforgeneraluse. Thepublisher,theauthors,andtheeditorsaresafetoassumethattheadviceandinformationinthisbook arebelievedtobetrueandaccurateatthedateofpublication.Neitherthepublishernortheauthorsorthe editorsgiveawarranty,expressedorimplied,withrespecttothematerialcontainedhereinorforany errorsoromissionsthatmayhavebeenmade.Thepublisherremainsneutralwithregardtojurisdictional claimsinpublishedmapsandinstitutionalaffiliations. ThisSpringerimprintispublishedbytheregisteredcompanySpringerNatureSwitzerlandAG Theregisteredcompanyaddressis:Gewerbestrasse11,6330Cham,Switzerland Series Editors Prof. Dr. Dami(cid:1)a Barcelo´ Prof. Dr. Andrey G. Kostianoy Department of EnvironmentalChemistry, ShirshovInstituteofOceanology Barcelona, Spain RussianAcademyofSciences and Moscow,Russia Catalan InstituteforWaterResearch (ICRA) and Scientific and Technological Parkof the S.Yu.WitteMoscowUniversity University ofGirona Moscow,Russia Girona, Spain [email protected] [email protected] Editorial Board Members Prof. Dr. Jacob de Boer VUUniversityAmsterdam, Amsterdam, The Netherlands Prof. Dr. Philippe Garrigues Universite´ de Bordeaux,Talence Cedex,France Prof. Dr. Ji-Dong Gu Guangdong Technion-Israel Instituteof Technology, Shantou,Guangdong,China Prof. Dr. Kevin C. Jones Lancaster University, Lancaster, UK Prof. Dr. Abdelazim M. Negm Zagazig University, Zagazig,Egypt Prof. Dr. Alice Newton Universityof Algarve, Faro,Portugal Prof. Dr. Duc Long Nghiem Universityof TechnologySydney, Broadway, NSW,Australia Prof. Dr. Sergi Garcia-Segura ArizonaState University, Tempe, AZ,USA Paola Verlicchi Universityof Ferrara, Ferrara, Italy Series Preface Withremarkablevision,Prof. OttoHutzingerinitiatedTheHandbook ofEnviron- mentalChemistry in1980andbecamethe foundingEditor-in-Chief.Atthattime, environmental chemistry was an emerging field, aiming at a complete description of the Earth’s environment, encompassing the physical, chemical, biological, and geologicaltransformationsofchemicalsubstancesoccurringonalocalaswellasa global scale. Environmental chemistry was intended to provide an account of the impact of man’s activities on the natural environment by describing observed changes. Whileaconsiderableamountofknowledgehasbeenaccumulatedoverthelast four decades, as reflected in the more than 150 volumes of The Handbook of Environmental Chemistry, there are still many scientific and policy challenges ahead due to the complexity and interdisciplinary nature of the field. The series will therefore continue to provide compilations of current knowledge. Contribu- tions are written by leading experts with practical experience in their fields. The Handbook of Environmental Chemistry grows with the increases in our scientific understanding, and provides a valuable source not only for scientists but also for environmental managers and decision-makers. Today, the series covers a broad rangeofenvironmentaltopicsfromachemicalperspective,includingmethodolog- icaladvancesinenvironmentalanalyticalchemistry. Inrecentyears,therehasbeenagrowingtendencytoincludesubjectmatterof societal relevance in the broad view of environmental chemistry. Topics include life cycle analysis, environmental management, sustainable development, and socio-economic, legal and even political problems, among others. While these topics are of great importance for the development and acceptance of The Hand- bookofEnvironmentalChemistry,thepublisherandEditors-in-Chiefhavedecided tokeepthehandbookessentiallyasourceofinformationon“hardsciences”witha particular emphasis on chemistry, but also covering biology, geology, hydrology andengineeringasappliedtoenvironmentalsciences. Thevolumesoftheseriesarewrittenatanadvancedlevel,addressingtheneeds ofbothresearchersandgraduatestudents,aswellasofpeopleoutsidethefieldof vii viii SeriesPreface “pure” chemistry, including those in industry, business, government, research establishments, and public interest groups. It would be very satisfying to see these volumes used as a basis for graduate courses in environmental chemistry. Withitshighstandardsofscientificqualityandclarity,TheHandbookofEnviron- mental Chemistry provides a solid basis from which scientists can share their knowledge on the different aspects of environmental problems, presenting a wide spectrumofviewpointsandapproaches. TheHandbookofEnvironmentalChemistryisavailablebothinprintandonline viahttps://link.springer.com/bookseries/698.Articlesarepublishedonlineassoon as they have been approved for publication. Authors, Volume Editors and Editors-in-Chief are rewarded by the broad acceptance of The Handbook of Envi- ronmentalChemistrybythescientificcommunity,fromwhomsuggestionsfornew topicstotheEditors-in-Chiefarealwaysverywelcome. Dami(cid:1)aBarcelo´ AndreyG.Kostianoy SeriesEditors Preface ThescienceofEnvironmentalChemistryincludesavastarrayofdisciplinesaiming at a complete description of the Earth’s environment. It encompasses geological, chemical, physical, and biological transformations of chemical substances occur- ring on the natural environment, at different scales, providing an overview of the impact of human activities on it. In this regard, the UN have launched the 2030 AgendaforSustainableDevelopment,whichaimstoprovideasharedblueprintfor peaceandprosperityforpeopleandtheplanet,nowandinthefuture.Thisagenda proposes 17 Sustainable Development Goals that are an urgent call to guarantee foodsecurityandpromotesustainableuseofterrestrialecosystems.Environmental chemistry is directly related to these SDGs, helping to study and understand the effectsoftheincreasinguseofresourcestofulfilltheconsumer’sdemandforgoods andservices. In recent times, great progress has been made in environmental analysis tech- niques with special attention to mass spectrometry (MS), omics approaches, min- iaturization, automatization, nano- and biosensors, and green chemistry. In this book,recentadvancesintechniquesandinnovativeusesofMSinfoodsafetyand environmental quality are summarized and discussed. The latest developments in samplepreparationtogetherwithimprovementsinMSplatformshaveallowedthe study of different omics together with the screening of emerging contaminants (ECs)andnanomaterials.MassSpectrometryinFoodandEnvironmentalChemis- tryoffersusefulandrelevantinformationonthemostrecentanalyticaltechniques aswellasallmajortopicsoffoodsafetyandenvironmentalqualityanalyzableby them. The book contains thirteen chapters written by worldwide experts discussing themes such as elemental and isotopic mass spectrometry as well as chromato- graphic-high resolution and chromatographic–mass spectrometry-based screening methodsinfoodandenvironmentalchemistryanalyses.Otherapproachessuchas omics, thermal desorption, and pyrolysis together with chiral mass spectrometry, ambientionizationtechniques,ionmobility,andimagingmassspectrometryhave alsobeendiscussednotforgettinglastdevelopmentssuchaschip-basedseparation ix x Preface devices coupled to mass spectrometry and their role in food and environmental chemistry.Thisbookisaimedatanyoneseekingtolearnaboutnewtechniquesand developments including a broad audience of researchers, from environmental and food chemists, biologists, and food technologists to the food industry and official food and environment control laboratories, together with other professionals responsible for resources management and decision-makers. Important tools for problem-solving in chemical and biological analyses are discussed in detail. The differentadvancesandpromisingapplicationsdescribedherearestateoftheartand willbeofparamountimportanceforensuringfoodsafetyandenvironmentalhealth forcurrentandfuturegenerations. Finally,wewouldliketothankallthechapters’authorsfortheircontinuousand devoted effort and patience. All of them deserve our deepest thanks because without them this book would have been impossible. I also thank the anonymous reviewers of the project for their suggestions. We would also acknowledge with greatgratitudeProf.Dami(cid:1)aBarcelo´ (SeriesEditor)whogaveustheopportunityof editing this book and the assistance of the Editorial Office of Springer and espe- ciallyofDr.SofiaCosta(Editor)andMs.RamyaVenkitachalam(ProjectCoordi- natorforSpringerNature).Wehopethatthisvolumelivesuptotheexpectationsof the readers starting or with a long experience in food and environmental quality analysis.Thisbookisintendedforallofyou. Valencia,Spain YolandaPico´ JulianCampo