MAGNESIUM ALLOYS (cid:883) DESIGN, PROCESSING AND PROPERTIES Edited by Frank Czerwinski Magnesium Alloys - Design, Processing and Properties Edited by Frank Czerwinski Published by InTech Janeza Trdine 9, 51000 Rijeka, Croatia Copyright © 2011 InTech All chapters are Open Access articles distributed under the Creative Commons Non Commercial Share Alike Attribution 3.0 license, which permits to copy, distribute, transmit, and adapt the work in any medium, so long as the original work is properly cited. After this work has been published by InTech, authors have the right to republish it, in whole or part, in any publication of which they are the author, and to make other personal use of the work. Any republication, referencing or personal use of the work must explicitly identify the original source. Statements and opinions expressed in the chapters are these of the individual contributors and not necessarily those of the editors or publisher. No responsibility is accepted for the accuracy of information contained in the published articles. The publisher assumes no responsibility for any damage or injury to persons or property arising out of the use of any materials, instructions, methods or ideas contained in the book. Publishing Process Manager Iva Lipovic Technical Editor Teodora Smiljanic Cover Designer Martina Sirotic Image Copyright Masekesam, 2010. Used under license from Shutterstock.com First published January, 2011 Printed in India A free online edition of this book is available at www.intechopen.com Additional hard copies can be obtained from [email protected] Magnesium Alloys - Design, Processing and Properties, Edited by Frank Czerwinski p. cm. ISBN 978-953-307-520-4 free online editions of InTech Books and Journals can be found at www.intechopen.com Contents Preface IX Chapter 1 Hardening and Softening in Magnesium Alloys 1 Pavel Lukáč and Zuzanka Trojanová Chapter 2 Deformation Structures and Recrystallization in Magnesium Alloys 21 Étienne Martin, Raj K. Mishra and John J. Jonas Chapter 3 Mechanisms of Plastic Deformation in AZ31 Magnesium Alloy Investigated by Acoustic Emission and Electron Microscopy 43 Miloš Janeček and František Chmelík Chapter 4 Thermo - Physical Properties of Iron - Magnesium Alloys 69 Krisztina Kádas, Hualei Zhang, Börje Johansson, Levente Vitos and Rajeev Ahuja Chapter 5 Precipitates of γ–Mg17Al12 Phase in AZ91 Alloy 95 Katarzyna N. Braszczyńska-Malik Chapter 6 Evaluation Method for Mean Stress Effect on Fatigue Limit of Non-Combustible Mg Alloy 113 Kazunori MORISHIGE, Yuna MAEDA, Shigeru HAMADA and Hiroshi NOGUCHI Chapter 7 Fatigue Endurance of Magnesium Alloys 129 Mariana Kuffová Chapter 8 Ultrasonic Grain Refinement of Magnesium and Its Alloys 163 M. Qian and A. Ramirez Chapter 9 Bulk Ultrafine-Grained Magnesium Alloys by SPD Processing: Technique, Microstructures and Properties 187 Jinghua JIANG and Aibin MA VI Contents Chapter 10 Mechanical Properties of Fine-Grained Magnesium Alloys Processed by Severe Plastic Forging 219 Taku Sakai and Hiromi Miura Chapter 11 Grain Refinement of Magnesium Alloy by Multiaxial Alternative Forging and Hydrogenation Treatment 245 Kunio Funami and Masafumi Noda Chapter 12 Improving the Properties of Magnesium Alloys for High Temperature Applications 265 Kaveh Meshinchi Asl Chapter 13 Microstructure and Properties of Elektron 21 Magnesium Alloy 281 Andrzej Kiełbus Chapter 14 Magnesium Sheet; Challenges and Opportunities 297 Faramarz Zarandi and Stephen Yue Chapter 15 Contemporary Forming Methods of the Structure and Properties of Cast Magnesium Alloys 321 Leszek Adam Dobrzański, Tomasz Tański, Szymon Malara, Mariusz Król and Justyna Domagała-Dubiel Chapter 16 The Recent Research on Properties of Anti-High Temperature Creep of AZ91 Magnesium Alloy 351 Xiulan Ai and Gaofeng Quan Chapter 17 Hot Forming Characteristics of Magnesium Alloy AZ31 and Three-Dimensional FE Modeling and Simulation of the Hot Splitting Spinning Process 367 He Yang, Liang Huang and Mei Zhan Chapter 18 Study on Thixotropic Plastic Forming of Wrought Magnesium Alloy 389 Hong Yan Chapter 19 Study on Semi-solid Magnesium Alloys Slurry Preparation and Continuous Roll-casting Process 407 Shuisheng Xie, Youfeng He and Xujun Mi Chapter 20 Design and Development of High-Performance Eco-Mg Alloys 431 Shae K. Kim Chapter 21 Welding and Joining of Magnesium Alloys 469 Frank Czerwinski Contents VII Chapter 22 High Strength Magnesium Matrix Composites Reinforced with Carbon Nanotube 491 Yasuo Shimizu Chapter 23 Magnesium Alloys Based Composites 501 Zuzanka Trojanová, Zoltán Száraz, Peter Palček and Mária Chalupová Preface The global manufacturing using light metals is on the edge of substantial growth and opportunity. Among light metals of strategic importance that include titanium, alumi- num and magnesium the latt er one with its density of 1.74 g/cm3 is the lightest metal, commonly used for structural purposes. In addition to low density, magnesium is rec- ognized for its high strength to weight ratio, high electrical and thermal conductivity, vibration damping, biocompatibility, recycling potential and esthetics. Magnesium is used in the form of alloys and usually subjected to casting, rolling, extruding or forg- ing. Further fabrication frequently involves a wide range of operations such as form- ing, joining, machining, heat treatment or surface engineering. In parallel with application expansion there is also tremendous interest in magnesium research at academic and industrial levels. A number of conferences devoted to mag- nesium and research papers published indicate that magnesium-related activities are present at large number of universities and government institutions. Recent downturn in economy that reduced industrial research contributions shift ed more responsibil- ity to academia. There is also a shift in geography of research activities. An essential change in global location of primary magnesium production which took place in late 90s and its transfer to Asia is followed by expansion of magnesium research there. Despite the progress, there are still challenges which limit use of magnesium. They include oft en not suffi cient creep resistance at elevated temperatures, low formability at room temperature, poor castability of some alloys, especially those with reactive elements, general corrosion resistance or electrochemical corrosion in joints with dis- similar metals. The breakthrough in that areas would remove the presently existing application barriers. This book was created by contributions from experts in diff erent fi elds of magnesium science and technology from over 20 research centers. It off ers a broad review of recent global developments in theory and practical applications of magnesium alloys. The volume covers fundamental aspects of alloy strengthening, recrystallization, details of microstructure and a unique role of grain refi nement. Due to the importance of grain size, its refi nement methods such as ultrasonic and multi-axial deformation are considered. The theory is linked with elements of alloy design and specifi c properties including fatigue and creep resistance. Several chapters are devoted to alloy process- ing and component manufacturing stages and cover sheet rolling, semi-solid forming, welding and joining. Finally, an opportunity of creation of metal matrix composites based on magnesium matrix is described, along with carbon nanotubes as an eff ective X Preface reinforcement. At the end of each chapter there is a rich selection of references, useful for further reading. A combination of fundamentals, advanced knowledge, theory as well as intricate tech- nological details makes the book very useful for a broad audience of scientists and engineers from academia and industry. I anticipate this book will also att ract readers from outside the magnesium fi eld, not only to generate genuine interest but also to cre- ate new application opportunities for this promising light metal. December 2010 Frank Czerwinski Bolton, Ontario, Canada [email protected]