Macromolecular Self-Assembly

275 Pages·2016·3.64 MB·English

by  Laurent Billon, Oleg Borisov

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MACROMOLECULAR
SELF-ASSEMBLY
Editedby
LAURENTBILLON
OLEGBORISOV
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LibraryofCongressCataloging-in-PublicationData:
Names:Billon,Laurent,1968-editor.|Borisov,Oleg,editor.
Title:Macromolecularself-assembly/editedbyLaurentBillon,OlegBorisov.
Description:Hoboken,NewJersey:JohnWiley&Sons,Inc.,[2016]|Includes
bibliographicalreferencesandindex.
Identifiers:LCCN2016015704(print)|LCCN2016021455(ebook)|ISBN
9781118887127(cloth)|ISBN9781118887844(pdf)|ISBN9781118887974
(epub)
Subjects:LCSH:Biopolymers.|Macromolecules.|Self-assembly(Chemistry)
Classification:LCCTP248.65.P62M3252016(print)|LCCTP248.65.P62(ebook)
|DDC572–dc23
LCrecordavailableathttps://lccn.loc.gov/2016015704
Setin10/12pt,TimesLTStdbySPiGlobal,Chennai,India.
PrintedintheUnitedStatesofAmerica
10987654321
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CONTENTS
ListofContributors vii
Preface xi
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1 ASupramolecularApproachtoMacromolecularSelf-Assembly:
CyclodextrinHost/GuestComplexes 1
BernhardV.K.J.SchmidtandChristopherBarner-Kowollik
1.1 Introduction, 1
1.2 SyntheticApproachestoHost/GuestFunctionalizedBuildingBlocks, 3
1.2.1 CDFunctionalization, 3
1.2.2 SuitableGuestGroups, 5
1.3 SupramolecularCDSelf-Assemblies, 7
1.3.1 LinearPolymers, 7
1.3.2 BranchedPolymers, 12
1.3.3 CyclicPolymerArchitectures, 17
1.4 HigherOrderAssembliesofCD-BasedPolymerArchitecturesToward
Nanostructures, 17
1.4.1 Micelles/Core-ShellParticles, 17
1.4.2 Vesicles, 19
1.4.3 NanotubesandFibers, 20
1.4.4 NanoparticlesandHybridMaterials, 21
1.4.5 PlanarSurfaceModification, 22
1.5 Applications, 23
1.6 ConclusionandOutlook, 26
References, 26
iii
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iv CONTENTS
2 Polymerization-InducedSelf-Assembly:TheContributionofControlled
RadicalPolymerizationtoTheFormationofSelf-StabilizedPolymer
ParticlesofVariousMorphologies 33
MurielLansalot,JuttaRieger,andFranckD’Agosto
2.1 Introduction, 33
2.2 PreliminaryCommentsUnderlyingControlledRadicalPolymerization, 36
2.2.1 Introduction, 36
2.2.2 MajorMethodsBasedonaReversibleTerminationMechanism, 37
2.2.3 MajorMethodsBasedonaReversibleTransferMechanism, 39
2.3 PisaViaCRPBasedonReversibleTermination, 40
2.3.1 PISAUsingNMP, 40
2.3.2 UsingATRP, 46
2.4 PisaViaCRPBasedonReversibleTransfer, 48
2.4.1 UsingRAFTinEmulsionPolymerization, 48
2.4.2 UsingRAFTinDispersionPolymerization, 61
2.4.3 UsingTERP, 70
2.5 ConcludingRemarks, 71
Acknowledgments, 73
Abbreviations, 73
References, 75
(cid:2) 3 AmphiphilicGradientCopolymers:SynthesisandSelf-Assemblyin (cid:2)
AqueousSolution 83
EliseDeniau-Lejeune,OlgaBorisova,PetrŠteˇpánek,LaurentBillon,
andOlegBorisov
3.1 Introduction, 83
3.2 SyntheticStrategiesforThePreparationofGradientCopolymers, 86
3.2.1 PreparationofGradientCopolymersbyControlledRadical
Copolymerization, 87
3.2.2 PreparationofBlock-GradientCopolymersUsingControlled
RadicalPolymerization, 106
3.3 Self-Assembly, 110
3.3.1 GradientCopolymers, 110
3.3.2 Diblock-GradientCopolymers, 111
3.3.3 Triblock-GradientCopolymers, 113
3.4 ConclusionandOutlook, 114
Abbreviations, 115
References, 117
4 ElectrostaticallyAssembledComplexMacromolecularArchitecturesBased
onStar-LikePolyionicSpecies 125
DmitryV.PergushovandFelixA.Plamper
4.1 Introduction, 125
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CONTENTS v
4.2 Core-CoronaCo-AssembliesofHomopolyelectrolyteStarsComplexed
withLinearPolyions, 127
4.3 Core-Shell-CoronaCo-AssembliesofStar-LikeMicellesofIonic
AmphiphilicDiblockCopolymersComplexedwithLinearPolyions, 130
4.4 VesicularCo-AssembliesofBis-HydrophilicMiktoarmStarsComplexed
withLinearPolyions, 133
4.5 Conclusions, 137
Acknowledgment, 137
References, 137
5 SolutionPropertiesofAssociatingPolymers 141
OlgaPhilippova
5.1 Introduction, 141
5.2 StructuresofAssociatingPolyelectrolytes, 142
5.3 AssociatingPolyelectrolytesinDiluteSolutions, 142
5.3.1 IntramolecularAssociation, 145
5.3.2 IntermolecularAssociation, 147
5.4 AssociatingPolyelectrolytesinSemidiluteSolutions, 151
5.5 Conclusions, 155
References, 155
(cid:2) 6 MacromolecularDecorationofNanoparticlesforGuiding (cid:2)
Self-Assemblyin2Dand3D 159
ChristianKuttner,MunishChanana,MatthiasKarg,andAndreasFery
6.1 Introduction, 159
6.2 GuidingAssemblybyDecorationwithArtificialMacromolecules, 160
6.2.1 DecorationofNanoparticles, 161
6.2.2 DistanceControlin2Dand3D, 166
6.2.3 BreakingtheSymmetry, 171
6.3 GuidingAssemblybyDecorationwithBiomacromolecules, 173
6.3.1 DNA-AssistedAssembly, 173
6.3.2 Protein-AssistedAssembly, 177
6.4 ApplicationofAssemblies, 181
6.5 ConclusionsandOutlook, 183
References, 184
7 Self-AssemblyofBiohybridPolymers 193
Dawid Kedracki, Jancy Nixon Abraham, Enora Prado, and Corinne
Nardin
7.1 Introduction, 193
7.1.1 Amphiphiles, 194
7.1.2 PackingParameterandInterfacialTension, 195
7.1.3 InteractionForcesinSelf-Assembly, 196
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vi CONTENTS
7.2 Self-AssemblyofBiohybridPolymers, 198
7.2.1 Polymer-DNAHybrids, 198
7.2.2 PolypeptideBlockCopolymers, 204
7.2.3 BlockCopolypeptides, 205
7.3 Self-AssemblyDrivenNucleationPolymerization, 207
7.3.1 Polymer-DNAHybrids, 209
7.3.2 Polymer-PeptideHybrids, 209
7.3.3 DNA-PeptideHybrids, 212
7.4 Self-AssemblyDrivenbyElectrostaticInteractions, 213
7.4.1 DNA/PolymerBio-IPECs, 216
7.4.2 DNA/CopolymerBio-IPECs, 216
7.5 Conclusion, 218
References, 219
8 BiomedicalApplicationofBlockCopolymers 231
MartinHrubý,SergeyK.Filippov,andPetrŠteˇpánek
8.1 Introduction, 231
8.2 DiblockandTriblockCopolymers, 234
8.3 GraftandStatisticalCopolymers, 240
8.4 ConcludingRemarks, 245
Acknowledgment, 245
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References, 245
Index 251
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LIST OF CONTRIBUTORS
JancyNixonAbraham,UniversityofGeneva,SciencesII,Departmentofinorganic
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andanalyticalchemistry,quaiErnestAnsermet30,1211,Geneva4,Switzerland
Christopher Barner-Kowollik, Preparative Macromolecular Chemistry, Institut
für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology
(KIT), Engesserstr. 18, 76128 Karlsruhe, Germany and Institut für Biologische
Grenzflächen,KarlsruheInstitutofTechnology(KIT),Hermann-von-Helmholtz-
Platz1,76344Eggenstein-Leopoldshafen,Germany
Laurent Billon, Institut des Sciences Analytiqueset de Physico-Chimie pour
l’EnvironnementetlesMatériauxIPREM,CNRS-UMR5254,UniversitédePau
&Paysdel’Adour,64053Pau,France
OlgaBorisova,DepartmentofPolymerScience,MoscowStateUniversity,Leninskie
Gory,Moscow119191,Russia
Oleg Borisov, Institut des Sciences Analytiqueset de Physico-Chimie pour
l’EnvironnementetlesMatériauxIPREM,CNRS-UMR5254,UniversitédePau
&Paysdel’Adour,64053Pau,France
MunishChanana,ETHZürich,InstituteofBuildingMaterials,Stefano-Franscini-
Platz3,8093Zürich,Switzerland,UniversityofBayreuth,PhysicalChemistryII,
Universitätsstrasse30,95440Bayreuth,Germany
FranckD’Agosto,UniversitédeLyon,Univ.Lyon1,CPELyon,CNRSUMR5265,
Laboratoire de Chimie, Catalyse, Polymères et Procédés (C2P2), LCPP group,
69616Villeurbanne,France
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viii LISTOFCONTRIBUTORS
EliseDeniau-Lejeune,InstitutdesSciencesAnalytiquesetdePhysico-Chimiepour
l’EnvironnementetlesMatériauxIPREM,CNRS-UMR5254,UniversitédePau
&Paysdel’Adour,64053Pau,France
Andreas Fery, Leibniz-Institut für Polymerforschung Dresden e.V., Institute of
Physical Chemistry and Polymer Physics, Technische Universität Dresden,
Physical Chemistry of Polymeric Materials and Cluster of Excellence Centre
for Advancing Electronics Dresden (cfaed), Hohe Strasse 6, 01069 Dresden,
Germany, University ofBayreuth, Physical ChemistryII,Universitätsstrasse30,
95440Bayreuth,Germany
SergeyK.Filippov,InstituteofMacromolecularChemistryASCR,Prague,Czech
Republic
Martin Hrubý, Institute of Macromolecular Chemistry AS CR, Prague, Czech
Republic
MatthiasKarg,HeinrichHeineUniversityDüsseldorf,PhysicalChemistryI,Uni-
versitätsstrasse1,40225Düsseldorf,Germany,UniversityofBayreuth,Physical
ChemistryI,Universitätsstrasse30,95440Bayreuth,Germany
Dawid Kedracki, University of Geneva, Sciences II, Department of inorganic and
analyticalchemistry,quaiErnestAnsermet30,1211,Geneva4,Switzerland
(cid:2) ChristianKuttner,Leibniz-InstitutfürPolymerforschungDresdene.V.,Instituteof (cid:2)
PhysicalChemistryandPolymerPhysics,TechnischeUniversitätDresden,Clus-
terofExcellenceCentreforAdvancingElectronicsDresden(cfaed),HoheStrasse
6, 01069 Dresden, Germany, University of Bayreuth, Physical Chemistry II,
Universitätsstrasse30,95440Bayreuth,Germany
MurielLansalot,UniversitédeLyon,Univ.Lyon1,CPELyon,CNRSUMR5265,
Laboratoire de Chimie, Catalyse, Polymères et Procédés (C2P2), LCPP group,
69616Villeurbanne,France
Corinne Nardin, University of Geneva, Sciences II, Department of inorganic and
analyticalchemistry,quaiErnestAnsermet30,1211,Geneva4,Switzerland
Dmitry V. Pergushov, Department of Chemistry, M.V. Lomonosov Moscow State
UniversityLeninskieGory1/3,119991Moscow,Russia
OlgaPhilippova,PhysicsDepartment,MoscowStateUniversity,119991Moscow,
Russia
Felix A. Plamper, Institute of Physical Chemistry II, RWTH Aachen University
Landoltweg2,52056Aachen,Germany
EnoraPrado,UniversityofGeneva,SciencesII,Departmentofinorganicandana-
lyticalchemistry,quaiErnestAnsermet30,1211,Geneva4,Switzerland
JuttaRieger,UPMCUniv.Paris6,SorbonneUniversitésandCNRS,Laboratoirede
ChimiedesPolymères,UMR7610,3rueGalilée,94200Ivry,France
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