Linear Polyatomic Molecules PDF
Preview Linear Polyatomic Molecules
New Series Numerical Data and Functional Relationships in Science and Technology GROUP II VOLUME 29 Molecular Molecules and Constants Radicals Mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy SUBVOLUME B Linear Polyatomic Molecules 123 Landolt-Börnstein / New Series Landolt-Börnstein Numerical Data and Functional Relationships in Science and Technology New Series Units and Fundamental Constants in Physics and Chemistry Elementary Particles, Nuclei and Atoms (Group I) (Formerly: Nuclear and Particle Physics) Molecules and Radicals (Group II) (Formerly: Atomic and Molecular Physics) Condensed Matter (Group III) (Formerly: Solid State Physics) Physical Chemistry (Group IV) (Formerly: Macroscopic Properties of Matter) Geophysics (Group V) Astronomy and Astrophysics (Group VI) Biophysics (Group VII) Advanced Materials and Technologies (Group VIII) Some of the group names have been changed to provide a better description of their contents. Landolt-Börnstein Numerical Data and Functional Relationships in Science and Technology New Series Group II: Molecules and Radicals Volume 29 Supplement to Volumes II/4, II/6, II/14, II/19, and II/24 Molecular Constants Mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy Subvolume B Linear Polyatomic Molecules Editor W. Hüttner Author G. Wlodarczak ISSN 1615-1852 (Molecules and Radicals) ISBN 978-3-540-60329-0 Springer Berlin Heidelberg New York Library of Congress Cataloging in Publication Data Zahlenwerte und Funktionen aus Naturwissenschaften und Technik, Neue Serie Vol. II/29B: Editor: W. Hüttner At head of title: Landolt-Börnstein. Added t.p.: Numerical data and functional relationships in science and technology. Tables chiefly in English. Intended to supersede the Physikalisch-chemische Tabellen by H. Landolt and R. Börnstein of which the 6th ed. began publication in 1950 under title: Zahlenwerte und Funktionen aus Physik, Chemie, Astronomie, Geophysik und Technik. Vols. published after v. 1 of group I have imprint: Berlin, New York, Springer-Verlag Includes bibliographies. 1. Physics--Tables. 2. Chemistry--Tables. 3. Engineering--Tables. I. Börnstein, R. (Richard), 1852-1913. II. Landolt, H. (Hans), 1831-1910. III. Physikalisch-chemische Tabellen. IV. Title: Numerical data and functional relationships in science and technology. QC61.23 502'.12 62-53136 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in other ways, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer-Verlag. Violations are liable for prosecution act under German Copyright Law. Springer is a part of Springer Science+Business Media springeronline.com © Springer-Verlag Berlin Heidelberg 2012 Printed in Germany The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Product Liability: The data and other information in this handbook have been carefully extracted and evaluated by experts from the original literature. Furthermore, they have been checked for correctness by authors and the editorial staff before printing. Nevertheless, the publisher can give no guarantee for the correctness of the data and information provided. In any individual case of application, the respective user must check the correctness by consulting other relevant sources of information. Cover layout: Erich Kirchner, Heidelberg Typesetting: Authors and Redaktion Landolt-Börnstein, Heidelberg SPIN: 10506650 63/3020 - 5 4 3 2 1 0 – Printed on acid-free paper Preface This is subvolume B of the Landolt-Börnstein Volume II/29 “Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy”, which is planned to appear as a series A1, A2, B, C, and D1, D2, D3 for the diamagnetic, and E for the paramagnetic linear and polyatomic species, respectively. Like in the preceding volumes II/24 and II/19, which have appeared around 1999 and 1992, the diamagnetic substances are arranged in the manner suggested by Hill (“Hill's system”, 1900), meaning an almost strict alphabetical order; details are given in the General Introduction on the following pages. The ionic species are included in the alphabetical arrangement of the neutral ones in each table. The number of publications appearing in the field of rotationally resolved molecular spectroscopic data is still quite large. The flexibility of the molecules under investigation increases, and so does the complexity of the spectral analyses, in terms of a growing number of molecular parameters. All quantities and symbols have been defined in the introductory remarks for each table. The less informed reader may, however, wish to consult the relevant literature which is cited. All relevant properties of a molecule and the corresponding parameters can be found concentrated under its sum formula in volume II/29. So we have changed the principle of grouping the rotational and related constants, the dipole moments, barriers to internal rotation, hyperfine coupling parameters, or Zeeman data separately in different tables which we followed in all previous volumes. The present subvolume II/29B contains data for diamagnetic linear molecules. Data for diatomic diamagnetic molecules are contained in the subvolumes II/29A1 and II29A2, and diamagnetic symmetric tops are dealt with in the subvolume II/29C. The large amount of data on asymmetric top molecules has led us to split subvolume II/29D in three parts, D1, D2, and D3. Finally, data on paramagnetic species will be contained in subvolume II/29E. For a better systematics in presenting their physical properties it has been chosen to order the paramagnetic species in a way which deviates from Hill’s rules. Thanks are due to the fellow authors for their careful and competent treatment of data; extracting it from the literature is an important but time consuming effort. It is a pleasure to acknowledge the fruitful cooperation with Dr. Jürgen Vogt and his coworkers in the Arbeitsgruppe Chemieinformationssysteme (formerly Sektion Spektren- und Strukturdokumentation) at the University of Ulm. Having access to their well organized documentation of the pertinent, ever growing literature is an invaluable advantage. Most of the figures have been designed in the “Arbeitsgruppe”. Thanks are again due to the staff of Landolt- Börnstein and SpringerMaterials, especially Dipl.-Phys. Antje Endemann, for their competent editorial work, and to Springer-Verlag for its care during the completion of this volume. Ulm, December 2011 The Editor Editor Wolfgang Hüttner Universität Ulm Institut für Quanteninformationsverarbeitung Albert-Einstein-Allee 11 D-89069 Ulm Germany Author Georges Wlodarczak Université Lille 1 Laboratoire de Physique des Lasers, Atomes et Molécules UMR 8523 CNRS-Lille 1 59655 Villeneuve d'Ascq Cedex France Landolt-Börnstein Editorial Office Tiergartenstraße 17 D-69121 Heidelberg, Germany e-mail: [email protected] Internet http://www.springermaterials.com Contents II/29 Molecular Constants Subvolume B 1 General Introduction 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.1 General remarks 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.2 Review articles and tables 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.3 Arrangement of tables, substances and parameters 1 . . . . . . . . . . . . . . . . . . . . . . . 1.4 Error notation 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.5 Selection of data 3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.6 Abbreviations used for experimental methods 3 . . . . . . . . . . . . . . . . . . . . . . . . . 1.7 Selected fundamental constants and conversion factors 3 . . . . . . . . . . . . . . . . . . . . 1.8 References for 1 5 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Linear Polyatomic Molecules: Introduction (G. WLODARCZAK) . . . . . . . . . . . . . . . . . 6 2.1 Rotational parameters 6 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.1.1 Defining equations 6 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.1.2 List of tabulated rotational parameters 11 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.1.3 References for 2.1 13 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.2 Hyperfine coupling constants 14 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.2.1 Quadrupole coupling constants, defining equations 14 . . . . . . . . . . . . . . . . . . . . . . 2.2.2 Magnetic-interaction constants, defining equations 16 . . . . . . . . . . . . . . . . . . . . . . 2.2.3 List of tabulated hfs parameters for polyatomic linear molecules 21 . . . . . . . . . . . . . . . . 2.2.4 References for 2.2 22 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.3 Electric dipole moments of polyatomic linear molecules 23 . . . . . . . . . . . . . . . . . . . . 2.3.1 References for 2.3 23 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.4 External field magnetic interaction parameters of polyatomic linear molecules 24 . . . . . . . . . 2.4.1 Defining equations 24 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.4.2 List of tabulated external field parameters for polyatomic linear molecules 24 . . . . . . . . . . . 3 Data (G. WLODARCZAK) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 1 AgArBr Silver bromide - argon (1/1) 25 . . . . . . . . . . . . . . . . . . . . . . . . . . 2 AgArCl Silver chloride - argon (1/1) 26 . . . . . . . . . . . . . . . . . . . . . . . . . . 3 AgArF Silver fluoride - argon (1/1) 27 . . . . . . . . . . . . . . . . . . . . . . . . . . 4 AgBrKr Silver bromide - krypton (1/1) 28 . . . . . . . . . . . . . . . . . . . . . . . . . 5 AgClKr Silver chloride - krypton (1/1) 29 . . . . . . . . . . . . . . . . . . . . . . . . . 6 AgClXe Silver chloride - xenon (1/1) 30 . . . . . . . . . . . . . . . . . . . . . . . . . 7 AgFKr Silver fluoride - krypton (1/1) 32 . . . . . . . . . . . . . . . . . . . . . . . . . 8 AgFXe Silver fluoride - xenon (1/1) 33 . . . . . . . . . . . . . . . . . . . . . . . . . . 9 ArAuBr Gold bromide - argon (1/1) 35 . . . . . . . . . . . . . . . . . . . . . . . . . . 10 ArAuCl Gold chloride - argon (1/1) 36 . . . . . . . . . . . . . . . . . . . . . . . . . . 11 ArAuF Gold fluoride - argon (1/1) 37 . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 ArBrCl Bromine chloride - argon (1/1) 38 . . . . . . . . . . . . . . . . . . . . . . . . . 13 ArBrCu Copper bromide - argon (1/1) 39 . . . . . . . . . . . . . . . . . . . . . . . . . 14 ArBrH Hydrogen bromide - argon (1/1) 40 . . . . . . . . . . . . . . . . . . . . . . . . VIII Contents 15 ArClCu Copper chloride - argon (1/1) 41 . . . . . . . . . . . . . . . . . . . . . . . . . 16 ArClH Hydrogen chloride - argon (1/1) 42 . . . . . . . . . . . . . . . . . . . . . . . . 17 ArClI Iodine chloride - argon (1/1) 43 . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 ArClNa Sodium chloride - argon (1/1) 44 . . . . . . . . . . . . . . . . . . . . . . . . . 19 ArCuF Copper fluoride - argon (1/1) 45 . . . . . . . . . . . . . . . . . . . . . . . . . . 20 ArHI Hydrogen iodide - argon (1/1) 46 . . . . . . . . . . . . . . . . . . . . . . . . . . 21 ArHN + Diazenylium - argon (1/1) 47 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 AuClKr Gold chloride - krypton (1/1) 48 . . . . . . . . . . . . . . . . . . . . . . . . . 23 AuFKr Gold fluoride - krypton (1/1) 49 . . . . . . . . . . . . . . . . . . . . . . . . . . 24 AuFXe Gold fluoride - xenon (1/1) 50 . . . . . . . . . . . . . . . . . . . . . . . . . . 25 BBrO Bromooxoborane 51 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26 BClO Chlorooxoborane 53 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27 BClS Chlorothioxoborane 55 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28 BFO Fluorooxoborane 58 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29 BFS Fluorothioxoborane 59 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30 BHO Oxoborane 62 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 BHS Thioxoborane 63 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32 BrClN Bromine chloride - dinitrogen (1/1) 66 2 . . . . . . . . . . . . . . . . . . . . . . 33 BrHN Hydrogen bromide - dinitrogen (1/1) 67 2 . . . . . . . . . . . . . . . . . . . . . . 34 BrHNe Hydrogen bromide - neon (1/1) 68 . . . . . . . . . . . . . . . . . . . . . . . . 35 CAgBrO Bromocarbonylsilver 70 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 CAgClO Carbonylchlorosilver 72 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 CAgFO Carbonylfluorosilver 74 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38 CAlN Aluminum cyanide 75 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 CAlN Aluminium isocyanide 76 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40 CAuBrO Bromocarbonylgold 78 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 CAuClO Carbonylchlorogold 80 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42 CAuFO Carbonylfluorogold 82 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43 CBrClO Carbon monoxide - bromine chloride (1/1) 83 . . . . . . . . . . . . . . . . . . 44 CBrCuO Bromocarbonylcopper 85 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45 CBrN Cyanogen bromide 87 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46 CBrNO Bromine isofulminate 91 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47 CClCuO Carbonylchlorocopper 99 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 CClNO Chlorine isofulminate 101 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49 CCuFO Carbonylfluorocopper 112 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50 CCuN Copper cyanide 113 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51 CGaN Gallium cyanide 114 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 CGaN Gallium isocyanide 115 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 CHArN Hydrogen cyanide - argon (1/1) 117 . . . . . . . . . . . . . . . . . . . . . . . 54 CHKrO Oxomethylium - krypton (1/1) 120 . . . . . . . . . . . . . . . . . . . . . . . . 55 CHN Hydrogen isocyanide 121 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56 CHN Hydrogen cyanide 123 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57 CHP Methylidynephosphine 125 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58 CHS+ Thiooxomethylium 126 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 CH N+ Methylidyneammonium 127 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60 CH N Hydrogen cyanide – dihydrogen (1/1) 128 3 . . . . . . . . . . . . . . . . . . . . . 61 CIN Iodine cyanide 129 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62 CInN Indium cyanide 130 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63 CInN Indium isocyanide 131 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Contents IX 64 CNiO Nickel monocarbonyl 132 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 COPd Palladium monocarbonyl 133 . . . . . . . . . . . . . . . . . . . . . . . . . . . 66 COPt Platinum monocarbonyl 135 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67 COS Carbonyl sulfide 137 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68 COSe Carbon oxide selenide 138 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69 C H– Acetylide 141 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70 C HF Fluoroethyne 142 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71 C HK Ethynylpotassium 144 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72 C HLi Ethynyllithium 145 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73 C HN + Cyanomethylidyneammonium 147 2 2 . . . . . . . . . . . . . . . . . . . . . . . . 74 C HNa Ethynylsodium 148 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75 C H Ne Ethyne - neon (1/1) 149 2 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76 C N O Ethanedinitrile N-oxide 150 2 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77 C NP Phosphinidyneacetonitrile 153 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . 78 C SSi (Thioxoethenylidene)silylene 157 2 . . . . . . . . . . . . . . . . . . . . . . . . . 79 C 1,2-Propadiene-1,3-diylidene 158 3 . . . . . . . . . . . . . . . . . . . . . . . . . . . 80 C FN 3-Fluoro-2-propynenitrile 159 3 . . . . . . . . . . . . . . . . . . . . . . . . . . . 81 C HN 2-Propynenitrile 164 3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82 C HN Isocyanoethyne 171 3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 83 C HP 2-Propynylidynephosphine 175 3 . . . . . . . . . . . . . . . . . . . . . . . . . . 84 C H N+ 2-Propynenitrilium 178 3 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 C OS 3-Thioxo-1,2-propadien-1-one 179 3 . . . . . . . . . . . . . . . . . . . . . . . . . 86 C H Buta-1,3-diyn-1-ide 182 4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87 C HF 1-Fluoro-1,3-butadiyne 183 4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88 C H 1,3-Butadiyne 184 4 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89 C NP 4-Phosphinidyne-2-butynenitrile 185 4 . . . . . . . . . . . . . . . . . . . . . . . . 90 C N 3-Isocyano-2-propynenitrile 187 4 2 . . . . . . . . . . . . . . . . . . . . . . . . . . 91 C SSi (4-Thioxo-1,2,3-butatrienylidene)silylene 189 4 . . . . . . . . . . . . . . . . . . . 92 C Si 4-Silanetetrayl-1,2,3-butadienylidene 190 4 . . . . . . . . . . . . . . . . . . . . . . 93 C HN 2,4-Pentadiynenitrile 192 5 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94 C HN 1-Isocyano-1,3-butadiyne 201 5 . . . . . . . . . . . . . . . . . . . . . . . . . . . 95 C HP 2,4-Pentadiynylidynephosphine 202 5 . . . . . . . . . . . . . . . . . . . . . . . . 96 C S 5-Thioxo-1,2,3,4-pentatetraenylidene 204 5 . . . . . . . . . . . . . . . . . . . . . . 97 C H– 1,3,5-Hexatriyn-1-ide 205 6 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98 C HF 1-Fluoro-1,3,5-hexatriyne 206 6 . . . . . . . . . . . . . . . . . . . . . . . . . . . 99 C SSi 6-Silanetetrayl-1,2,3,4,5-hexapentaene-1-thione 207 6 . . . . . . . . . . . . . . . . 100 C Si 6-Silanetetrayl-1,2,3,4,5-hexapentaenylidene 208 6 . . . . . . . . . . . . . . . . . . 101 C HN 2,4,6-Heptatriynenitrile 210 7 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102 C HN 1-Isocyano-1,3,5-hexatriyne 212 7 . . . . . . . . . . . . . . . . . . . . . . . . . 103 C S 7-Thioxo-1,2,3,4,5,6-heptahexaenylidene 213 7 . . . . . . . . . . . . . . . . . . . . 104 C H 1,3,5,7-Octatetrayn-1-ide 214 8 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105 C HF 1-Fluoro-1,3,5,7-octatetrayne 215 8 . . . . . . . . . . . . . . . . . . . . . . . . . 106 C Si 8-Silanetetrayl-1,2,3,4,5,6,7-octaheptaenylidene 216 8 . . . . . . . . . . . . . . . . 107 C HN 2,4,6,8-Nonatetraynenitrile 217 9 . . . . . . . . . . . . . . . . . . . . . . . . . . 108 C S 9-Thioxo-1,2,3,4,5,6,7,8-nonaoctaenylidene 219 9 . . . . . . . . . . . . . . . . . . . 109 C HN 2,4,6,8,10-Undecapentaynenitrile 220 11 . . . . . . . . . . . . . . . . . . . . . . . 110 C HN 2,4,6,8,10,12,14-Pentadecaheptaynenitrile 222 15 . . . . . . . . . . . . . . . . . . 111 C HN 2,4,6,8,10,12,14,16-Heptadecaoctaynenitrile 223 17 . . . . . . . . . . . . . . . . . 112 ClCuKr Copper chloride - krypton (1/1) 224 . . . . . . . . . . . . . . . . . . . . . . .
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