LECTURES ON QUANTUM STATISTICS Volume I Quantum Statistics LECTURES ON QUANTUM STATISTICS by N. N. BOGOLIUBOV (in two volumes) Volume I Quantum Statistics Volume 2 The Model Hamiltonian LECTURES ON QUANTUM STATISTICS VOLUME I QUANTUM STATISTICS by N. N. BOGOLIUBOV Steklov Mathematical Institute Academy of Science, Moscow, U.S.S.R. Translated from the Ukranian English Edition Revised by..}/. N. BOGOL[pBOV Edited by L. KLEIN and S. tLASS, Howard University, Washington, D. C. GORDON AND BREACH, Science Publishers New York • London • Paris Copyright© 1967 by GORDON AND BREACH, Science Publishers, Inc. 150 Fifth Avenue, New York, N. Y. 10011 For Great Britain and Europe: Gordon and Breach, Science Publishers Ltd. 61 Carey Street, Chauncery Lane London W.C.2 , England Library of Congress Catalog Card Number 66-28060 Distribution en France par: Dunod Editeur 92, rue Bonaparte Paris 6, France Distribution in Canada by: The Ryerson Press 299 Queen Street West Toronto 2B, Ontario Printed in the United States of America EDITOR'S PREFACE This small volume is a translation of a set of lecture notes delivered in the Ukranian language by Prof. N. N. Bogoliubov at Kiev University. These remarkable notes were originally published in the U.S.S.R. in a limited edition which rapidly became a collector's item. Today, although these notes are extensively quoted in the literature and generally considered to be a classic introduction to modern methods in Quantum Statisical Mechanics, they are unavailable except in a Japanese language edition. The editors have carefully checked the text and formulae and have corrected typographical errors and misprints in the original. The translation follows closely Professor Bogoliubov's original Ukranian text. This book is of far more than historical interest, although first published over fifteen years ago. It is especially valuable to graduate students because of the meticulous care with which all details of calculations and derivations are presented. In addition, research workers in many fields of modern physics will find that these notes bring together in a unified and comprehensive treatment many topics which have appeared in various places in the literature. In the first chapter, the basic principles of Quantum Statistical Mechanics are discussed, The I, 2, ... , n, particle density matrices are also introduced in this chapter and the equations of motion which lead to the BBGKY hierarchy are derived. Also discussed are probability distributions in momentum space and fluctuations of particle number in a region in configuration space. The second chapter presents a comprehensive treatment of the method of second quantization based on the original concepts intro duced by W. A. Fock. The fundamental ideas are introduced and carefully discussed for the separate cases of Fermi and Bose Statistics and the connection with the method of statistical operators developed. Chapter Three contains a discussion of the Bose-Einstein gas and applications to superfluidity. Landau's theory of superfluidity is pre sented and a rigorous justification of its postulates from the micro scopic theory of Bogoliubov is given. v The fourth chapter is of particular interest to scientists in solid state research. It contains a thorough and detailed exposition of the polar theory of metals. Second quantized notation is used throughout and operator algebra techniques are utilized. For example, these techniques are used to develop a perturbation theory method which leads to an "effective Hamiltonian" £or the polar model of a metal. In addition, operators are introduced which -permit a calculation of the electric current associated with the spin waves. The notation used in this volume is standard, except that every where h appears it is to he understood as Planck's constant divided by 211", Thus, the h in this volume is the Ii, of modern texts. Finally, we would like to thank Professor Bogoliuhov for his interest in this translation. He has very kindly sent further unpublished material which discusses more recent developments, including a treat ment of the Green function method and quasi-averai:res. The editors plan to publish this material in a second volume which is to he a companion to the present text. December 1966 L. S. KLEIN S. G. GLASS vi INTRODUCTION In recent years new and effective methods have been developed for the statistical mechanics of quantum systems. Among these is the method of statistical operators of molecular complexes which is closely related to the method of second quantization. Previously, these methods were presented in various places in the scientific literature and this monograph is the first attempt at a systematic presentation with applications. Special attention is given to the application of the above method to the structure of the molecular theory of superfluidity and to the theory of. the polar model of a metal. In addition, as an aid to the reader, introductory chapters are included on quantum statistics and on the method of second quantization. In preparation of the material included in this monograph, the author has carefully considered the relationship of second quantization with the method of statistical operators. This relationship has con siderably simplified the presentation. Most of the subject matter in this monograph is based upon material presented in specialized lectures in Statistical Physic!' which were given by the author in Moscow and Kiev. N. N. BOGOLIUBOV vii