2005:89 LICENTIATE T H E S I S The Absorptance of Metallic Alloys to Nd: YAG and Nd: YLF Laser Light David Bergström Luleå University of Technology Department of Applied Physics and Mechanical Engineering Division of Manufacturing Systems Engineering 2005:89|: 02-757|: -c -- 05⁄89 -- Licentiate Thesis The Absorptance of Metallic Alloys to Nd:YAG and Nd:YLF Laser Light David Bergström Division of Manufacturing Systems Engineering Department of Applied Physics and Mechanical Engineering Luleå University of Technology Luleå, Sweden in cooperation with Department of Engineering, Physics and Mathematics Mid Sweden University Östersund, Sweden Luleå, November 2005 Dedicated to the Curious Mind. Preface The work presented in this Licentiate thesis is devoted to the theoretical and experimental study of the light absorption mechanisms in laser processing of metals and metallic alloys. The Licentiate thesis consists of a short introduction and a series of five papers, all dealing with different aspects of this topic. This work has been carried out at the Division of Manufacturing Systems Engineering at Luleå University of Technology and at the Department of Engineering, Physics and Mathematics at Mid Sweden University in Östersund, Sweden, from 2003 to 2005. I would like to express my gratitude to my supervisors Prof. Alexander Kaplan (LTU) and Prof. Torbjörn Carlberg (MIUN) for their advice and guidance during this intial phase of my PhD. My deepest thanks also to Dr. John Powell (Laser Expertise Ltd., Nottingham, UK) for our fruitful discussions, his proof reading of all my written work and his neverending curiosity and devotion to the subject which has worked as an inspiration for me. Thanks are also due to M.Sc. Rickard Olsson and his colleagues at LaserNova AB in Östersund, for their expertise and for letting me use parts of their machine park in my experiments. I would also like to thank Patrik Frihlén of Azpect Photonics AB and M.Sc. Ingemar Eriksson for helping me setting up the equipment for the laser lab at my university in Östersund. Further thanks goes to Doc. Mats Tinnsten and Dr. Leon Dahlén for providing the financial circumstances in making this work possible. Finally I would like to thank my family and especially my girlfriend Ulrika for her understanding, support and her sincere interest in what I do. Östersund, November 2005 David Bergström i Abstract In Laser Material Processing of metals, an understanding of the fundamental absorption mechanisms plays a vital role in determining the optimum processing parameters and conditions. The absorptance, which is the fraction of the incident laser light which is absorbed, depends on a number of different parameters. These include laser parameters such as intensity, wavelength, polarisation and angle of incidence and material properties such as composition, temperature, surface roughness, oxide layers and contamination. The vast theoretical and experimental knowledge of the absorptance of pure elements with smooth, contamination-free surfaces contrasts with the relatively sparse information on the engineering materials found in real processing applications. In this thesis a thorough investigation of the absorption mechanisms in engineering grade materials has been started. The Licentiate thesis consists of 5 papers. Paper 1 is a short review of some of the most important mathematical models used in describing the interaction between laser light and a metal. Paper 2 is a review of a few experimental methods of measuring the absorptance of an opaque solid such as a metal. Papers 3 and 4 are experimental investigations of the absorptance of some of the most frequently found metallic alloys used in Laser Material Processing today. Paper 5 is a co-authored paper on the cleaning of copper artefacts with the use of second harmonic generated Nd:YAG laser light. ii List of Papers Paper 1 Bergström, D.; Kaplan, A.; Powell, J.: ”Mathematical Modelling of Laser Absorption Mechanisms in Metals: A Review”. Presented at the M4PL16 workshop, Igls, Austria, January 2003. Paper 2 Bergström, D.; Kaplan, A.; Powell, J.: ”Laser Absorption Measurements in Opaque Solids”. Presented at the 10th Nordic Laser Materials Processing (NOLAMP) Conference, Piteå, Sweden, August 17-19, 2005, ed: A. Kaplan, published by Luleå TU, Sweden. Paper 3 Bergström, D.; Kaplan, A.; Powell, J.: ”The absorptance of steels to Nd:YAG and Nd:YLF laser light at room temperature”. Paper accepted for the 2nd Pacific International Conference on Applications of Lasers and Optics (PICALO), April 3-5, 2006, Melbourne, Australia, published by LIA, and submitted to Journal of Physics D: Applied Physics. Paper 4 Bergström, D.; Kaplan, A.; Powell, J.: ”The absorptance of non-ferrous alloys to Nd:YAG and Nd:YLF laser light at room temperature”. Paper accepted for the 2nd Pacific International Conference on Applications of Lasers and Optics (PICALO), April 3-5, 2006, Melbourne, Australia, published by LIA, and submitted to Applied Surface Science. Paper 5 Koh, Y.S.; Bergström, D.; Powell, J.; Åberg, G.; Grahn, J.; Kaplan, A.: ”Cleaning oxides from copper artifacts using a frequency-doubled Nd:YAG laser”. Paper accepted for the 2nd Pacific International Conference on Applications of Lasers and Optics (PICALO), April 3-5, 2006, Melbourne, Australia, published by LIA, and submitted to Studies in Conservation. iii
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