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Available online at www.sciencedirect.cc ournal science @)oinecr: ofOrgano. metallic Chemistry R Journal of Organometallic Chemistry 686 (2003) 383 384 www.elsevier.com/locate/jorganchem Author Index of Volume 686 Abele, E., 52 Gehrhus, B., 321 Majechrzak, M., 228 Abele, R., 52 Girshberg, O., 202 Marciniec, B., 228 Acker, J., 151 Glatthaar, J., 341 Amemiya, R., 94 Gostevskii, B., 202 Matsumoto, H.. 175 Apeloig, Y., 58 Grelier, S., 306 Matsumoto, M.. 134 Apple, T., 272 Grinberga, S., 52 Matukhina, E.V., 313 Arisawa, M., 94 Gusel’nikov, L.E., 257 Mignani, G., 281 Auner, N., 313 Guselnikov, S.L.. 25 Minakata, S.. 368 Avakyan, V.G., 257 Miura, K., 242 Avent, A.G., 321 Haiduc, A.M., 379 Mohr, K., 75 Hatano, K.,. 118 Monse, C., 294 Baceiredo, A., 281 Hayamizu, T., 134 Miiller, T., 251 Ben, F., 281 Hayashida, J., 242 Murai, S., 134 Bessmertnykh, A., 281 Hitchcock, P.B., 321 Murr, B.L.. 198 Biondi, S., 363 Hiyama, T., 286 Bjerke-Kroll, B., 101 Hosomi, A., 242 Nagase, S., 118 Blaser, D., 294 Hwu, J.R.. 198 Nahar-Borchert, S., 127 Bleckmann, P., 332 Nishikori, H., 242 Boese, R., 294 Igi, K., 134 Nocentini, T., 363 Bohmhammel, K., 151 Interrante, L.V., 272 Nonami, H., 42 Bornemann, H., 294 Iwamoto, T., 105 Boury, B., 127 Ohashi, S.. 368 Bravo-Zhivotovskii, D., 58 Kabuto, C., 105 Ohshita, J.. 3 Briiggemann, T., 332 Kakiuchi, F., 134 Okada, A.. 368 Buzin, M.I., 313 Kalikhman, I., 202 Okita, J., 105 Kano, N.. 192 Olah, J.. 112 Kawashima, T., 192 Capperucci, A., 3 Kickelbick, G., 183 Pannell, K.H., 235, 379 Cervantes-Lee, F., Kira, M., 105 Picard, J.-P., 306 Chatani, N., 134 Kitagawa, H., 286 Chauhan, B.P.S., 24 Kliem, S., 16 Rath, N.P., 66 Chen, B.-L., 198 Klingebiel, U., 16 Rathore, J., 24 Chénedeé, A., 84 Kocher, N., 202 Reinke, H.. 158 Chojnowski, J., 373 Komatsu, F., 192 Reisenauer, H.P., 341 Corey, J.Y., 66 Komatsu, M., 368 Riedel, R., 127 Corriu, R., 1, 32 Korkin, $.D., 313 Corriu, R.J.P., 127 Cypryk, M., 164, 373 Korogodsky. G., 58 Saeki, T., 215 Kost, D., 202 Sakai, N.. 368 Krempner, C., 158 Salmon, R., 84 DaiB, J.O., 75 Kroke, E., 127 Sander, W., 294 Degl Innocenti, A., 363 Kuhn, A., 294 Sardar, R., 24 dell’ Erba, I.E., 42 Kunai, A., 3 Sasaki. T.. 118 Dini, F., 363 Kurahashi, T., 286 Sasamori, T., 118 Driess, M., 294 Kurjata. J., 373 Schmatz. S., 16 Duda-Johner, S., 75 Kuroda, K., 223 Schollmeier, T.. 3 2o9s Schubert, U.. 183 Erra-Balsells, R., 42 Lappert, M.F., 321 Schiirmann, M., : 29 ile Latif, U., 24 Shahin, A.M., 23 Fasce, D.P., 42 Lienhard, M., 272 Sharma, H.K., 235, 379 Fleisher, M., 52 Lin, C.-F., 198 Shchegolikhina, O.I., 313 Fleming, I., 84 Long, G.J., 235 Shimizu, M., 286 Fortis, F., 306 Lukevics, E., 52 Shimoyima, A., 223 Fujii, A., 94 Shimono, K., 286 Fukushima, T., 368 Maciejewski, H., 321 Sivaramakrishna, A., 202 Fukuyama, Y., 42 Maier, G., 341 Spirina, I.V., 3223 329 Elsevier B.V. doi: 10.1016/S0022-328X(03)01030-1 384 Author Index of Volume 686 Journalo f Organometallic Chemistry 686 (2003) 383 384 Stalke, D., 202 Tewari, P., 24 Stohr, F., 183 Veszprémi, T., 112 Thompson, §$.M., 183 Sturmayr, D., 183 Tokitoh, N., 118 Sugahara, Y., 145 Toshimitsu, A., 215 West. M.C., 84 Toulokhonova, I.. 10] West. R., 101 Tacke, R., 75 Trankler, K.A.. 66 Wiegand, C., 272 Tajima, T., 118 Tsarev, M.V., 332 Williams, R.J.J.. 42 Takagi, N., | 18 l'suchiya, K., 134 Takahashi, T., 242? Yamaguchi, M., 94 Takeda, N.. 118 Yamamura, M., 192 Takeda. ¥: 145 UUhclhiigm, arFu.,, 33Y2., 145 Yoshioka, S., 145 Tamao, K., 215 Umeda, N., 223 Tanaka -. 175 Zhao, X., 235 Unno, M.. 175 Zherlitsyna, L.N., 313 Available online at www.sciencedirect.com SCIENCE DIRECT? emistry ELSEVIER Journal of Organometallic Chemistry 686 (2003) 385—390 acer aenenon arate er amin www.elsevier.com/locate/jorganchem Subject Index of Volume 686 Ab initio calculations Bis-imination reactions Classical planar doubly bonded Si-substituted silenes—a boundary Syntheses of novel N-[bis(trimethylsilyl)methyl]-1,.2- and 1,3- system between olefins and heavier Group 14 analogs: diamines, 306 Geometric and electronic structures, rotational barriers about Bis(pentacoordinate) silicon compound the Si=C double bond, and comparison with the analogs and Thermolysis of bis(pentacoordinate) silicon compound bearing two isoelectronic phosphenes, further evidence against C-ylides of 1-fluorodisilanyl units at 4- and 8-positions on | ,5-bis(dimethy- silicon, 257 lamino)naphthalene ring: construction of disilapyrene skeleton Comparison of steric hindrance in silylentum and carbenium and cyclophane-shaped siloxane dimer, 215 cations and their complexes: Natural steric analysis, 164 Bis(silacyclopropa)benzenes Tertiary trisilyloxonium ion in cationic ring-opening polymerisation Syntheses and structures of silicon analogues of cyclopropaben- of a model cyclic siloxane, octamethyl-1,4-dioxatetrasilacyclo- zenes, 118 hexane, 373 t-bond energies Acid Catalyst Classical planar doubly bonded Si-substituted silenes—a boundary Acid-catalyzed intramolecular addition of a carboxy group to system between olefins and heavier Group 14 analogs vinylsilanes, 242 Geometric and electronic structures, rotational barriers about Activation energy the Si=C double bond, and comparison with the analogs and Compensation effect in trichlorosilane synthesis, 151 isoelectronic phosphenes, further evidence against C-ylides of ADMET copolymerization silicon, 2+ 57 Synthesis and structural characterization of trans-tactic siloxylene- Boron vinylene-p-phenylene polymers via ADMET copolymerization gem-Silylborylation approach for tri- and tetrametalmethanes: the and silylative coupling (SC) polycondensation, 228 first synthesis of boryl(germyl)(silyl)(stannyl)methanes, 2- 86 Alkenes Classical planar doubly bonded Si-substituted silenes—a boundary Caldine system between olefins and heavier Group 14 analogs: Syntheses of novel N-[bis(trimethylsilyl)methyl]-1,2- and Geometric and electronic structures, rotational barriers about diamines, 306 the Si=C double bond, and comparison with the analogs and Calorimetry isoelectronic phosphenes, further evidence against C-ylides of Compensation effect in trichlorosilane synthesis, 151 silicon, 257 Carbenium ion Allosteric modulators Comparison of steric hindrance in silylenium and carbenium Synthesis and pharmacological characterization of new silicon- cations and their complexes: Natural steric analysis, 164 based W84-type allosteric modulators for ligand binding to Carbenoid muscarinic M,; receptors, 75 gem-Silylborylation approach for tri- and tetrametalmethanes: the Allyisilane first synthesis of boryl(germyl)(silyl)(stannyl)methanes, 286 Cationic rearrangements controlled by the presence of a silyl group, Catalysis 84 GaCl,-catalyzed x-ethynylation reaction of silyl enol ethers, 94 A minosiloxanes H bond cleavage Intramolecular rearrangement of organosilyl groups between The ruthenium-catalyzed silylation of aromatic C—H bonds with oxygen and nitrogen in aminosiloxanes: A joint experimental triethylsilane, 134 theoretical study, 16 Chemical shift tensor Aromatic C-H bonds The chemical shift tensor of silylenes, 251 The ruthenium-catalyzed silylation of aromatic C—H bonds with Chloroethyne triethylsilane, 134 GaCl,-catalyzed x-ethynylation reaction of silyl enol ethers, 94 Azobenzene Chlorosilane Synthesis, crystal structure, and photoreaction of a disiloxane Hydrosilylation in the 2D interlayer space between inorganic layers bearing two 2-(phenylazo)phenyl groups, 192 reaction between immobilized C=C groups on the interlayer surface of layered perovskite HLaNb,O-;:xH,O and chlorohy- Base-coordinated silylene drosilanes, 145 Thermolysis of bis(pentacoordinate) silicon compound bearing two H/SiR; coupling 1-fluorodisilanyl units at 4- and 8-positions on 1,5-bis(dimethy- The ruthenium-catalyzed silylation of aromatic C—H bonds with lamino)naphthalene ring: construction of disilapyrene skeleton triethylsilane, 134 and cyclophane-shaped siloxane dimer, 215 Cocondensation Bicyclosilaoxolanes Dihalodimethylsilanes from silicon atoms and methyl halides: a Intramolecular cycloadditions of silacarbonyl ylides tethered to combined matrix-spectroscopic and density functional theory unactivated dipolarophiles: a new route to bicyclosilaoxolanes, study, 341 368 Co-hydrolysis and polycondensation Elsevier B.V. doi: 10.1016/S0022-328X(03)01028-3 Subject Index of Volume 686 / Journal of Organometallic Chemistry 686 (2003) 385-390 Synthesis of multilayered silica-based hybrid films from difunc- silicon, 257 tional organosilanes by co-hydrolysis and polycondensation 1,6-Dihydro-1,6-disilapyrene with tetraalkoxysilane, 223 Thermolysis of bis(pentacoordinate) silicon compound bearing two ‘ompensation effect 1-fluorodisilanyl units at 4- and 8-positions on 1,5-bis(dimethy- Compensation effect in trichlorosilane synthesis. 151 lamino)naphthalene ring: construction of disilapyrene skeleton ‘omputational chemistry and cyclophane-shaped siloxane dimer, 215 The chemical shift tensor of silylenes, 251 Dimerization ‘opper Relationship between stability and dimerization ability of silylenes, Synthesis and characterisation of bis(amino)silylene—nickel(0), 112 palladium(II),—platinum(0),—platinum(II) and copper(I) com- Dion—Jacobson phase plexes, 321 Hydrosilylation in the 2D interlayer space between inorganic layers: ‘opper reagent reaction between immobilized C=C groups on the interlayer Selective synthesis of halosilanes from hydrosilanes and utilization surface of layered perovskite HLaNb.O--xH,O and chlorohy- for organic synthesis, 3 drosilanes, 145 ‘rystallographic structural analysis Diphenylacetylene Syntheses and structures of silicon analogues of cyclopropaben- Thermolysis of bis(pentacoordinate) silicon compound bearing two zenes, 118 1-fluorodisilanyl units at 4- and 8-positions on 1|,5-bis(dimethy- ‘rystal structure lamino)naphthalene ring: construction of disilapyrene skeleton Tip-substituted cage and cyclic silanols, 175 and cyclophane-shaped siloxane dimer, 215 yanoethylation reactions 1,3-Diphosphacyclobutanes Syntheses of novel N-[{bis(trimethylsilyl)methyl]-1,.2- and 1,3- Classical planar doubly bonded Si-substituted silenes—a boundary diamines, 306 system between olefins and heavier Group 14 analogs ‘yclic siloxanes Geometric and electronic structures, rotational barriers about Tertiary trisilyloxonium ion in cationic ring-opening polymerisation the Si=C double bond, and comparison with the analogs and of a model cyclic siloxane, octamethyl-1.4-dioxatetrasilacyclo- isoelectronic phosphenes, further evidence against C-ylides of hexane, 373 silicon, 257 yclic stannasilanes 1,3-Dipoles Magnesium and chlorostannanes—building blocks for novel Intramolecular cycloadditions of silacarbonyl ylides tethered to tinmodified silanes, 332 unactivated dipolarophiles: a new route to bicyclosilaoxolanes, yclization 368 Acid-catalyzed intramolecular addition of a carboxy group to Direct reaction vinylsilanes, 242 Compensation effect in trichlorosilane synthesis, 151 “ycloadditions Disilacyclobutane x.fh-Unsaturated thioacylsilanes as efficient dienes in hetero Diels Synthesis and characterization of cyano-substituted disilacyclobu- Alder reactions, 363 tane rings and poly(silylenemethylene) polymers, 272 Cyclobutanes 1 ,3-Disilacyclobutanes Classical planar doubly bonded Si-substituted silenes—a boundary Classical planar doubly bonded Si-substituted silenes—a boundary system between olefins and heavier Group 14 analogs system between olefins and heavier Group 14 analogs Geometric and electronic structures, rotational barriers about Geometric and electronic structures, rotational barriers about the Si=C double bond, and comparison with the analogs and the Si=C double bond, and comparison with the analogs and isoelectronic phosphenes, further evidence against C-ylides of isoelectronic phosphenes, further evidence against C-ylides of silicon, 257 silicon, 257 Cyclophane Disilanes Thermolysis of bis(pentacoordinate) silicon compound bearing two Halide induced epimerization of meso-1,2-dihalo-1,2-diaryl-1,2- 1-fluorodisilanyl units at 4- and 8-positions on 1.5-bis(dimethy- dimethyldisilanes, 66 lamino)naphthalene ring: construction of disilapyrene skeleton Disiloxane and cyclophane-shaped siloxane dimer, 215 Synthesis, crystal structure, and photoreaction of a disiloxane 2+2 cycloreversion bearing two 2-(phenylazo)phenyl groups, 192 Classical planar doubly bonded Si-substituted silenes—a boundary 1 .1-Disilylcarbinol system between olefins and heavier Group 14 analogs Cationic rearrangements controlled by the presence of a silyl group, Geometric and electronic structures, rotational barriers about 84 the Si=C double bond, and comparison with the analogs and Divinyldisiloxane isoelectronic phosphenes, further evidence against C-ylides of Synthesis and structural characterization of trans-tactic siloxylene- silicon, 257 vinylene-p-phenylene polymers via ADMET copolymerization and silylative coupling (SC) polycondensation, 228 DFT calculations Dyotropic rearrangement Synthesis and molecular structure of fluoro(triphosphanyl)silane Synthesis, structure and isomerization of A,Si=SiB»-type tetra- and attempts to synthesize a silylidyne—phosphane, 294 kis(trialkylsilyl)disilenes, 105 Diaryldilithiosilane Syntheses and structures of silicon analogues of cyclopropaben- Electronic effect zenes, 118 Electronic and steric effects of silyl groups in silicon-directed 1,3-Digermacyclobutanes Norrish type cleavages, 198 Classical planar doubly bonded Si-substituted silenes—a boundary Epimerization system between olefins and heavier Group 14 analogs: Halide induced epimerization of meso-1,2-dihalo-1.2-diaryl-1,2- Geometric and electronic structures, rotational barriers about dimethyldisilanes, 66 the Si=C double bond, and comparison with the analogs and x-Ethynylation isoelectronic phosphenes, further evidence against C-ylides of GaCl,-catalyzed x-ethynylation reaction of silyl enol ethers, 94 Subject Index of Volume 686 / Journal of Organometallic Chemistry 686 (2003) 385-390 Excimer Donor-stabilized silyl cations: Part 7: Neutral hexacoordinate and Synthesis and photophysical properties of novel fluorescent ionic pentacoordinate silicon chelates with N-isopropylidenei- silicones, 101 mino-acylimidato ligands, 202 H-halogen exchange Ferrocenylenesilyl Selective synthesis of halosilanes from hydrosilanes and utilization Bis-silyl substituted ferrocenylenes, including dicyanovinyl electron- for organic synthesis, 3 withdrawing groups, as potential non-linear optical materials, Hybrid material 235 Synthesis of multilayered silica-based hybrid films from difunc- Flash-vacuum-pyrolyses tional organosilanes by co-hydrolysis and polycondensation Synthesis and molecular structure of fluoro(triphosphanyl)silane with tetraalkoxysilane, 223 and attempts to synthesize a silylidyne—phosphane, 294 Hybrid xerogels Fluorescence Synthesis and characterization of alkylene-bridged silsesquicarbo- Synthesis and photophysical properties of novel fluorescent diimide hybrid xerogels, 127 silicones, 101 Hydrogen bonding Fluoride ion Tip-substituted cage and cyclic silanols. 175 Novel fluoride ion mediated synthesis of unsymmetrical siloxanes Hydrosilane under phase transfer catalysis conditions, 52 Selective synthesis of halosilanes from hydrosilanes and utilization Fluorosilanes for organic synthesis, 3 Synthesis and molecular structure of fluoro(triphosphanyl)silane Hydrosilylation and attempts to synthesize a silylidyne—phosphane, 294 Hydrosilylation in the 2D interlayer space between inorganic layers Synthesis and reactivity of a novel oligosilyl anion, 158 reaction between immobilized C=C groups on the interlayer surface of layered perovskite HLaNb,O--xH,>O and chlorohy- Gallium(III) chloride drosilanes, 145 GaCl,;-catalyzed x-ethynylation reaction of silyl enol ethers, 94 m Hyperconjugation gem-Silylborylation Electronic and steric effects of silyl groups in silicon-directed gem-Silylborylation approach for tri- and tetrametalmethanes: the Norrish type cleavages, 198 first synthesis of boryl(germy!)(silyl)(stannyl)methanes, 286 Germenes Interlayer surface modification Classical planar doubly bonded Si-substituted silenes—a boundary Hydrosilylation in the 2D interlayer space between inorganic layers system between olefins and heavier Group 14 analogs: reaction between immobilized C=C groups on the interlayer Geometric and electronic structures, rotational barriers about surface of layered perovskite HLaNb>O--xH,0O and chlorohy- the Si=C double bond, and comparison with the analogs and drosilanes, 145 isoelectronic phosphenes, further evidence against C-ylides of Intranolecular cycloaddition silicon, 257 Intramolecular cycloadditions of silacarbonyl ylides tethered to Germy] unactivated dipolarophiles: a new route to bicyclosilaoxolanes, Silylgermylstannylmethanes, 379 368 Grafting reaction Ionization Hydrosilylation in the 2D interlayer space between inorganic layers Donor-stabilized silyl cations: Part 7: Neutral hexacoordinate and reaction between immobilized C=C groups on the interlayer ionic pentacoordinate silicon chelates with N-isopropylidenei- surface of layered perovskite HLaNb.O--xH,0O and chlorohy- mino-acylimidato ligands, 202 drosilanes, 145 Irradiation Group 14 Synthesis, crystal structure, and photoreaction of a disiloxane Silylgermylstannylmethanes, 379 bearing two 2-(phenylazo)phenyl groups, 192 Grubbs catalyst Isodesmic reaction energy Synthesis and structural characterization of trans-tactic siloxylene- Relationship between stability and dimerization ability of silylenes, vinylene-p-phenylene polymers via ADMET copolymerization 112 and silylative coupling (SC) polycondensation, 228 Isomerization Intramolecular rearrangement of organosilyl groups between Halogenation oxygen and nitrogen in aminosiloxanes: A joint experimental Halide induced epimerization of meso-1,2-dihalo-1,2-diaryl-1, 4 theoretical study, 16 dimethyldisilanes. 66 Synthesis, crystal structure. and photoreaction of a disiloxane Halohydrosilane bearing two 2-(phenylazo)phenyl groups, 192 Selective synthesis of halosilanes from hydrosilanes and utilization for organic synthesis, 3 y-lactone Halomethane Acid-catalyzed intramolecular addition of a carboxy group to gem-Silylborylation approach for tri- and tetrametalmethanes: the vinylsilanes, 242 first synthesis of boryl(germyl])(silyl)(stannyl)methanes, 286 Layered perovskite Halosilane Hydrosilylation in the 2D interlayer space between inorganic layers Selective synthesis of halosilanes from hydrosilanes and utilization reaction between immobilized C=C groups on the interlayer for organic synthesis, 3 surface of layered perovskite HLaNb,O--xH,>O and chlorohy- Hemilabile ligands drosilanes, 145 Reaction of hydrogenosilanes with dimethyl Pt(II) complexes Lithium promoted by hemilabile P.N-chelating ligands, 183 Synthesis of the first long-lived bis-silene, 58 Heterodienes (thiabutadienes) Lithium salts x.8-Unsaturated thioacylsilanes as efficient dienes in hetero Diels Intramolecular rearrangement of organosilyl groups between Alder reactions, 363 oxygen and nitrogen in aminosiloxanes: A joint experimental Hexacoordinate theoretical study, 16 Subject Index of Volume 686 / Journal of Organometallic Chemistry 686 (2003) 385-390 Magnesium Organoalkoxysilane Magnesium and chlorostannanes—building blocks for novel Synthesis of multilayered silica-based hybrid films from difunc- tinmodified silanes, 332 tional organosilanes by co-hydrolysis and polycondensation Matrix isolation with tetraalkoxysilane, 223 Dihalodimethylsilanes from silicon atoms and methyl halides: a Organosilicon chemistry combined matrix-spectroscopic and density functional theory Organosilicon chemistry and nanoscience, 32 study, 341 Oxidative addition Metallic nanoparticles Reaction of hydrogenosilanes with dimethyl Pt(II) complexes Synthesis, stabilization, and applications of nanoscopic siloxane promoted by hemilabile P,N-chelating ligands, 183 metal particle conjugates, 24 Metal silyl complexes Palladium Reaction of hydrogenosilanes with dimethyl Pt(II) complexes Synthesis and characterisation of bis(amino)silylene—nickel(0), promoted by hemilabile P,N-chelating ligands, 183 palladium(II),—platinum(0),—platinum(II) and copper(I) com- Methane plexes, 321 Silylgermylstannylmethanes, 379 Pentacoordinate Methyl/silyl exchange Donor-stabilized silyl cations: Part 7: Neutral hexacoordinate and Reaction of hydrogenosilanes with dimethyl Pt(II) complexes ionic pentacoordinate silicon chelates with N-isopropylidenei- promoted by hemilabile P,N-chelating ligands, 183 mino-acylimidato ligands, 202 Méssbauer Phase transfer catalysis Bis-silyl substituted ferrocenylenes, including dicyanoviny] electron- Novel fluoride ion mediated synthesis of unsymmetrical siloxanes withdrawing groups, as potential non-linear optical materials, under phase transfer catalysis conditions, 52 235 Phenylsilanetriol Muscarinic receptors Phenylsilanetriol synthesis, stability, and reactivity, 313 Synthesis and pharmacological characterization of new silicon- Phosphenes based W84-type allosteric modulators for ligand binding to Classical planar doubly bonded Si-substituted silenes —a boundary muscarinic M> receptors, 75 system between olefins and heavier Group 14 analogs: Geometric and electronic structures, rotational barriers about Nanomaterials the Si=C double bond, and comparison with the analogs and Organosilicon chemistry and nanoscience, : isoelectronic phosphenes, further evidence against C-ylides of Nanosience silicon, 257 Organosilicon chemistry and nanoscience, : Phosphorane Nano-size aggregate Classical planar doubly bonded Si-substituted silenes—a boundary Tip-substituted cage and cyclic silanols, 175 system between olefins and heavier Group 14 analogs: NBO theory Geometric and electronic structures, rotational barriers about Comparison of steric hindrance in silylenium and carbenium the Si=C double bond, and comparison with the analogs and cations and their complexes: Natural steric analysis, 164 isoelectronic phosphenes, further evidence against C-ylides of Nickel silicon, 257 Synthesis and characterisation of bis(amino)silylene—nickel(0), Phosphorus ylides palladium(II),—platinum(0),—platinum(II) and copper(I) com- Anionic ring-opening polymerization of cyclic organosiloxanes plexes, 321 using phosphorus ylides as strong non-ionic bases, 281 NLO Photoisomerizations Bis-silyl substituted ferrocenylenes, including dicyanovinyl electron- Dihalodimethylsilanes from silicon atoms and methyl halides: a withdrawing groups, as potential non-linear optical materials, combined matrix-spectroscopic and density functional theory 235 study, 341 NMR- and IR-spectroscopy Photolysis Phenylsilanetriol synthesis, stability, and reactivity, 313 Electronic and steric effects of silyl groups in silicon-directed NMR spectroscopy Norrish type cleavages, 198 Synthesis and characterization of cyano-substituted disilacyclobu- Platinum tane rings and poly(silylenemethylene) polymers, 272 Synthesis and characterisation of bis(amino)silylene—nickel(0), The chemical shift tensor of silylenes, 251 palladium(II),—platinum(0),—platinum(II) and copper(I) com- Non-ionic bases plexes, 321 Anionic ring-opening polymerization of cyclic organosiloxanes Polyamines using phosphorus ylides as strong non-ionic bases, 281 Syntheses of novel N-[bis(trimethylsilyl)methyl]-1,2- and 1,3- Norrish type cleavage diamines, 306 Electronic and steric effects of silyl groups in silicon-directed Polyhedral oligomeric silsesquioxanes (POSS) Norrish type cleavages, 198 Poly(silsesquioxanes) derived from the hydrolytic condensation of organotrialkoxysilanes containing hydroxyl groups, 42 Octamethylcyclotetrasiloxane Polymer Anionic ring-opening polymerization of cyclic organosiloxanes Synthesis, stabilization, and applications of nanoscopic siloxane using phosphorus ylides as strong non-ionic bases, 281] metal particle conjugates, 24 Octamethyl-1 ,4-dioxatetrasilacyclohexane Polymerization Tertiary trisilyloxonium ion in cationic ring-opening polymerisation Anionic ring-opening polymerization of cyclic organosiloxanes of a model cyclic siloxane, octamethyl-1.4-dioxatetrasilacyclo- using phosphorus ylides as strong non-ionic bases, 281 hexane, 373= Polysiloxanes OH-functionalized organotrialkoxysilanes Synthesis and photophysical properties of novel fluorescent Poly(silsesquioxanes) derived from the hydrolytic condensation of silicones, 101 organotrialkoxysilanes containing hydroxyl groups, 42 Synthesis, stabilization, and applications of nanoscopic siloxane Subject Index of Volume 686 | Journal of Organometallic Chemistry 686 (2003 ) 385-390 metal particle conjugates, 24 Synthesis of the first long-lived bis-silene, 58 Poly(silsesquioxanes) Silicon Poly(silsesquioxanes) derived from the hydrolytic condensation of Donor-stabilized silyl cations: Part 7: Neutral hexacoordinate and organotrialkoxysilanes containing hydroxyl groups, 42 ionic pentacoordinate silicon chelates with N-isopropylidenei- Poly(silylenemethylene) mino-acylimidato ligands, 202 Synthesis and characterization of cyano-substituted disilacyclobu- Electronic and steric effects of silyl groups in silicon-directed tane rings and poly(silylenemethylene) polymers, 272 Norrish type cleavages, 198 Porosity gem-Silylborylation approach for tri- and tetrametalmethanes: the Synthesis and characterization of alkylene-bridged silsesquicarbo- first synthesis of boryl(germyl)(silyl)(stannyl)methanes, 286 diimide hybrid xerogels, 127 Synthesis and pharmacological characterization of new silicon- based W84-type allosteric modulators for ligand binding to Reaction mechanisms muscarinic M, receptors, 75 Dihalodimethylsilanes from silicon atoms and methyl halides: a Synthesis and reactivity of a novel oligosilyl anion, 158 combined matrix-spectroscopic and density functional theory Synthesis, crystal structure, and photoreaction of a disiloxane study, 341 bearing two 2-(phenylazo)phenyl groups, 192 Reaction rate Synthesis of the first long-lived bis-silene, 58 Compensation effect in trichlorosilane synthesis, 151 Synthesis, structure and isomerization of A»,Si=SiB»-type Ring-opening polymerisation kis(trialkylsilyl)disilenes, 105 Tertiary trisilyloxonium ion in cationic ring-opening polymerisation Silicon-based drugs of a model cyclic siloxane, octamethyl-1,4-dioxatetrasilacyclo- Synthesis and pharmacological characterization of new silicon- hexane, 373 based W84-type allosteric modulators for ligand binding to Rotational barriers muscarinic M> receptors, 75 Classical planar doubly bonded Si-substituted silenes—a boundary Silicones system between olefins and heavier Group 14 analogs: Synthesis and photophysical properties of novel fluorescent Geometric and electronic structures, rotational barriers about silicones, 101 the Si=C double bond, and comparison with the analogs and Silicon—phosphorus compounds isoelectronic phosphenes, further evidence against C-ylides of Synthesis and molecular structure of fluoro(triphosphanyl)silane silicon, 257 and attempts to synthesize a silylidyne—phosphane, 294 Ruthenium catalysts Silsesquioxane The ruthenium-catalyzed silylation of aromatic C—H bonds with Tip-substituted cage and cyclic silanols, triethylsilane, 134 Silver organosols Ruthenium complex Synthesis, stabilization, and applications of nanoscopic siloxane Synthesis and structural characterization of trans-tactic siloxylene- metal particle conjugates, 24 vinylene-p-phenylene polymers via ADMET copolymerization Silyl and silylative coupling (SC) polycondensation, 228 Silylgermylstannylmethanes, 379 x-Silylamines Self-assembly Syntheses of novel N-[bis(trimethylsilyl)methyl]-1,2- and 1,3- Synthesis of multilayered silica-based hybrid films from difunc- diamines, 306 tional organosilanes by co-hydrolysis and polycondensation Silyl anions with tetraalkoxysilane, 223 Synthesis and reactivity of a novel oligosilyl anion, 158 Silacarbonyl ylides Silylative coupling Intramolecular cycloadditions of silacarbonyl ylides tethered to Synthesis and structural characterization of trans-tactic siloxylene- unactivated dipolarophiles: a new route to bicyclosilaoxolanes, vinylene-p-phenylene polymers via ADMET copolymerization 368 and silylative coupling (SC) polycondensation, 228 Silacyclopropabenzene Silylborane Syntheses and structures of silicon analogues of cyclopropaben- gem-Silylborylation approach for tri- and tetrametalmethanes: the zenes, 118 first synthesis of boryl(germyl)(silyl)(stannyl)methanes, 286 Silaesterifications x-Silyl carbocation Synthesis, stabilization, and applications of nanoscopic siloxane Cationic rearrangements controlled by the presence of a silyl group metal particle conjugates, 24 84 Silaethenes B-Silyl carbocation Synthesis of the first long-lived bis-silene, 58 Cationic rearrangements controlled by the presence of a silyl group, 84 Silanes Dihalodimethylsilanes from silicon atoms and methyl halides: a Silylcarbodiimides combined matrix-spectroscopic and density functional theory Synthesis and characterization of alkylene-bridged silsesquicarbo- study, 341 diimide hybrid xerogels, 127 Synthesis and reactivity of a novel oligosilyl anion, 158 Silyl cation Synthesis of the first long-lived bis-silene, 58 Donor-stabilized silyl cations: Part 7: Neutral hexacoordinate and Silanol ionic pentacoordinate silicon chelates with N-isopropylidenei- Tip-substituted cage and cyclic silanols, 175 mino-acylimidato ligands, 202 Silenes Silyl complexes Classical planar doubly bonded Si-substituted silenes—a boundary Synthesis and characterisation of bis(amino)silylene—nickel(0), system between olefins and heavier Group 14 analogs: palladium(I1),—platinum(0),—platinum(II) and copper(I) com- Geometric and electronic structures, rotational barriers about plexes, 321 the Si=C double bond, and comparison with the analogs and Silylcyanide isoelectronic phosphenes, further evidence against C-ylides of Synthesis and characterization of cyano-substituted disilacyclobu- silicon, 257 tane rings and poly(silylenemethylene) polymers, 272 390 Subject Index of Volume 686 / Journal of Organometallic Chemistry 686 (2003) 385 390 Silylene gem-Silylborylation approach for tri- and tetrametalmethanes: the The chemical shift tensor of silylenes, 251 first synthesis of boryl(germyl)(silyl)(stannyl)methanes, 286 Silylene complexes Tetrasilyldisilenes Synthesis and characterisation of bis(amino)silylene—nickel(0), Synthesis, structure and isomerization of A,Si=SiB>-type tetra- palladium(I1),—platinum(0),—platinum(II) and copper(I) com- kis(trialkylsilyl)disilenes, 105 plexes, 321 TGA Silylenes Phenylsilanetriol synthesis, stability, and reactivity, 313 Relationship between stability and dimerization ability of silylenes, Thioacylsilanes 112 x,B-Unsaturated thioacylsilanes as efficient dienes in hetero Diels Silylenium ion Alder reactions, 363 Comparison of steric hindrance in silylentum and carbenium Thioaldehydes cations and their complexes: Natural steric analysis, 164 x,B-Unsaturated thioacylsilanes as efficient dienes in hetero Diels Silyl enol ether Alder reactions, 363 GaCl,-catalyzed x-ethynylation reaction of silyl enol ethers, 94 Three-membered ring Silylidyne—phosphanes Syntheses and structures of silicon analogues of cyclopropaben- Synthesis and molecular structure of fluoro(triphosphanyl)silane zenes, 118 and attempts to synthesize a silylidyne—phosphane, 294 Transannular interaction *SINMR Thermolysis of bis(pentacoordinate) silicon compound bearing two Synthesis, structure and isomerization of A»Si=SiB,-type tetra- 1-fluorodisilanyl units at 4- and 8-positions on 1,5-bis(dimethy- kis(trialkylsilyl)disilenes, 105 lamino)naphthalene ring: construction of disilapyrene skeleton 'Si-NMR and cyclophane-shaped siloxane dimer, 215 Tertiary trisilyloxonium ion in cationic ring-opening polymerisation Trichlorosilane of a model cyclic siloxane, octamethyl-1,4-dioxatetrasilacyclo- Compensation effect in trichlorosilane synthesis, 151] hexane, 373 Trimethylsilylation Si-O-C bonds Phenylsilanetriol synthesis, stability, and reactivity, 313 Poly(silsesquioxanes) derived from the hydrolytic condensation of Triorganosilane organotrialkoxysilanes containing hydroxyl groups, 42 The ruthenium-catalyzed silylation of aromatic C—H bonds with Sol—gel process triethylsilane, 134 Synthesis of multilayered silica-based hybrid films from difunc- tional organosilanes by co-hydrolysis and polycondensation Unsymmetrical siloxanes with tetraalkoxysilane, 223 Novel fluoride ion mediated synthesis of unsymmetrical siloxanes Stability under phase transfer catalysis conditions, 52 Phenylsilanetriol synthesis, stability, and reactivity, 313 UV-MALDI-TOF MS Stannyl Poly(silsesquioxanes) derived from the hydrolytic condensation of Silylgermylstannylmethanes, 379 organotrialkoxysilanes containing hydroxyl groups, 42 Steric effect UV spectroscopy Comparison of steric hindrance in silylenium and carbenium The chemical shift tensor of silylenes, 251 cations and their complexes: Natural steric analysis, 164 Strain energies Vinylsilane Classical planar doubly bonded Si-substituted silenes—a boundary Acid-catalyzed intramolecular addition of a carboxy group to system between olefins and heavier Group 14 analogs vinylsilanes, 242 Geometric and electronic structures, rotational barriers about the Si=C double bond, and comparison with the analogs and Cationic rearrangements controlled by the presence of a silyl group, isoelectronic phosphenes, further evidence against C-ylides of R4 silicon, Substituent effect Wagner-Meerwein Classical planar doubly bonded Si-substituted silenes—a boundary Cationic rearrangements controlled by the presence of a silyl group, system between olefins and heavier Group 14 analogs: 84 Geometric and electronic structures, rotational barriers about Wide angle X-ray powder diffraction (WAX) the Si=C double bond, and comparison with the analogs and Phenylsilanetriol synthesis, stability, and reactivity, - isoelectronic phosphenes, further evidence against C-ylides of silicon, 257 X-ray crystallographic analysis Synthesis Synthesis, crystal structure, and photoreaction of a disiloxane Synthesis and characterization of alkylene-bridged silsesquicarbo- bearing two 2-(phenylazo)phenyl groups, 192 diimide hybrid xerogels, 127 X-ray crystallography Synthetic utilization Magnesium and chlorostannanes—building blocks for novel Selective synthesis of halosilanes from hydrosilanes and utilization tinmodified silanes, 332 for organic synthesis, 3 X-ray structural analysis Synthesis, structure and isomerization of A,Si=SiB,-type tetra- Tetrametalmethane kis(trialkylsilyl)disilenes, 105