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Available online at www.sciencedirect.com ournal ‘i SCIENCE DIRECT? of rgano. a metallic \3 Chemistry ER Journal of Organometallic Chemistry 667 (2003) 209 www.elsevier.com/locate/jorganchem Author Index of Volume 667 Ackermann, M.N., 81 Iwata, A., 90 Paredes, P., 120 Albert, J., 192 Park, K., 96 Angharad Baber, R., 112 Jain, V.K., 61 Parker, D.J., 66 Arroyo, M., 120 Jeffery Leigh, G., 73 Petrusova, L., 154 Auner, N., 66 Jehle, H., 35 Pons, J., 126 Jutzi, P., 167 Bassindale, A.R., 66 Ratcliffe, D.A., 112 Baumgartner, J., 149 Kayser, C., 149 Reiche, C., 24 Bennett, M.A., 8 Kim, C., 96 Rifat, A., | Berlekamp, U.H., 167 Kim, H., 96 Ros, J., 126 Binnewies, M., 35 Kliem, S., 24 Bohra, R., 61 Klingebiel, U., 24 Salvini, A., 197 Bolanio, S., 103 Kopp, M.R., 8 Sasage, T., 135 Bravo, J., 103 Kubista, J., 154 Satoh, Y., 42 Kunai, A., 90 Schmatz, S., 24 Castro, J., 103 Kursky, Y.A., 176 Schumacher, D., 35 Clarke, M.L., 112 Schwenzer, B., 16 Colligan, A.S., 81 Lee, D.-h., 53 Sharma, R.K., 61 Cisafova, I., 154 Lee, 1, 53 Shavirin, A.S., 176 Li, F., 5 Sdger, N., 35 Dodonov, V.A., 176 Li, X.-F., 185 Song, L.-C., 143 Donnadieu, B., 126 Li, Y.-R., 185 Stammler, H.-G., 167 Drake, J.E., 61 Li, Y.-S., 185 Stépni¢ka, P., 154 Light, M.E., 61 Esquius, G., 126 Lugan, N., 126 Tavera, R., 192 Taylor, P.G., 66 Fischer, H., 16 Ma, C., 5 Thomas-Wohlever, J.A., 81 Frank, D., 149 Mach, K., 154 Togrou, M., 73 Frediani, P., 197 Mahon, M.F., | Toyoshima, Y., 90 Malisch, W., 35 Garcia-Fontan, S., 103 Marschner, C., 149 Villafafe, F., 120 Giannelli, C., 197 Mathieu, R., 126 Granell, J., 192 Miguel, D., 120 Voit, C., 24 Gupta, A., 61 Mix, A., 167 Gushchin, A.V., 176 Mochida, K., 135 Wang, D., 5 Guy Orpen, A., 112 Moiseev, D.V., 176 Warren, K.J., 81 Moore, K.B., 81 Weller, A.S., | Hayashida, T., 90 Wenger, E., 8 Herbst-Irmer, R., 24 Nakayama, Y., 42 Willis, A.C., 8 Herrschaft, B., 66 Nanjo, M., 135 Wu, H., 143 Hitchcock, P.B., 73 Neumann, B., 167 Horaéek, M., 154 Noh, S.K., 53 Yafiez, R., 126 Hu, Q.-M., 143 Noltemeyer, M., 24 Yasuda, H., 42 Hursthouse, M.B., 61 Yin, H., 5 Ochi, T., 90 Yu, G.-A., 143 lanelli, S., 197 Ohshita, J., 90 Ikitake, N., 42 Okuno, S., 42 Zhu, W.-F., 143 Elsevier Science B.V. PII: S0022-328X(03)00026-3 Available online at www.sciencedirect.com ectance @poinzcr Png ing metallic Chemistry Journal of Organometallic Chemistry 667 (2003) 211-214 www.elsevier.com/locate/jorganchem Subject Index of Volume 667 Alcoholysis Cage compound Polychlorinated metallo-siloxanes of iron, molybdenum and Synthesis and characterization of alkylgermasesquioxanes, 135 tungsten - structure of 1-[dicarbonyl(n°-cyclopentadieny])fer- e-Caprolactone rio}-1,1,3,3,3-pentachlorodisiloxane, 35 Syntheses of bis- and tetra(trimethylsilyl) substituted lanthanocene Alkali-aminosilanolates methyl complexes and their catalyses for polymerizations of Aminosilanolates as precursors of four- and eight-membered methyl methacrylate, e-caprolactone and t-lactide, 42 (SiNSiO)-rings, 24 Carbonyls Alkene complexes The first pyrazole molybdenum(0) complexes: cis-[Mo(CO),- Reduction-induced double bond coordination and multiple C—H (Hdmpz)>] crystallizes as a N-H---OC hydrogen-bonded activation in fully-substituted titanocenes bearing a pendant dimer, 120 double bond or an eight-membered hydrocarbyl ansa-chain, Carbosilane 154 Diels—Alder reaction of anthracene and N-ethylmaleimide on the Alkenes carbosilane dendrimer, 96 Pd-catalyzed C-arylation of unsaturated compounds with pentava- Carbyne complexes lent triarylantimony dicarboxylates, 176 Alkynylcarbyne(bipyridine)dicarbonyl(triflouroacetato) complex- Allenylidenes es—synthesis and detection of reversible association in solu- Synthesis of Ru(II) complexes of the new _ 1-[(P-diphenyl)-2- tion, 16 phosphinoethyl]-3,5-dimethylpyrazole ligand and study of their Catalysts reactivity toward terminal alkynes, 126 New neutral nickel(I1) complexes bearing pyrrole-imine chelate Aminosiloxanes ligands: synthesis, structure and norbornene polymerization Aminosilanolates as precursors of four- and eight-membered behavior, 185 (SiNSiO)-rings, 24 C-H activation ansa -Titanocenes Dehydrogenation of cyclohexenes to cyclohexadienes by Reduction-induced double bond coordination and multiple C—H [((PPh;)»Rh]*. The isolation of an intermediate in the dehy- activation in fully-substituted titanocenes bearing a pendant drogenation of cyclohexane to benzene: crystal structure of [(n7- double bond or an eight-membered hydrocarbyl ansa-chain, C,.Hxs)Rh(PPh;)>][c/oso-CB,, H¢Brg], 1 154 Reduction-induced double bond coordination and multiple C—H Antimony(V) activation in fully-substituted titanocenes bearing a pendant Pd-catalyzed C-arylation of unsaturated compounds with pentava- double bond or an eight-membered hydrocarbyl ansa-chain, lent triarylantimony dicarboxylates, 176 154 Arylation Clusters Pd-catalyzed C-arylation of unsaturated compounds with pentava- Synthesis and characterization of organotransition metal double lent triarylantimony dicarboxylates, 176 i3-RCCo»M (M=Mo, W) cluster complexes containing Aryne complex bridged dicyclopentadienyl ligands. Crystal structure of [p1- Generation of nickel(0)—aryne and nickel(II)—biphenyldiyl com- MeCCo3Mo(CO)<]> [n°-CsHyC(O) CH], 143 plexes via in situ dehydrohalogenation of arenes. Molecular Cobalt structures of [Ni(2,2’-Cg.H4C.H4)(dcpe)] and C)-hexabenzotri- Synthesis and characterization of organotransition metal double phenylene, 8 u3-RCCo»M (M=Mo, W) cluster complexes containing bridged dicyclopentadienyl ligands. Crystal structure of [p3- MeCCo,Mo(CO)<]> [n°-CsHyC(O) CH}, 143 Benzyl-benzylidene-amine On the mechanism of the cyclopalladation reaction of benzyl- Complexes benzylidene-amine with palladium(II) acetate in acetic acid, 192 Ruthenium complexes with 1,1’-biisoquinoline as ligand. Synthesis Bridged dicyclopentadienyl ligands and hydrogenation activity, 197 Synthesis and characterization of organotransition metal double Concentration-dependence u3-RCCo.sM (M=Mo, W) cluster complexes containing Alkynylcarbyne(bipyridine)dicarbonyl(triflouroacetato) complex- bridged dicyclopentadienyl ligands. Crystal structure of [p13- es—synthesis and detection of reversible association in solu- MeCCo,Mo(CO)<}> [n°-CsHyC(O) CH>}, 143 tion, 16 Bromogermane Constrained geometry catalyst PdCl, and NiCl.,-catalyzed hydrogen—halogen exchange for the Syntheses of dinuclear titanium constrained geometry complexes convenient preparation of bromo- and iodosilanes and with polymethylene bridges and their copolymerization proper- germanes, 90 ties, 53 Bromosilane Co-ordination chemistry PdCl, and NiCl.,-catalyzed hydrogen—halogen exchange for the Synthesis and transition metal chemistry of ‘phosphomide’ ligands: convenient preparation of bromo- and iodosilanes and a comparison of the reactivity and electronic properties of germanes, 90 diphenyl-P -perfluoro-octanoyl-phosphine, P-acetyl-diphenyl- Elsevier Science B.V. PII: S0022-328X(03)00024-X Subject Index of Volume 667 / Journal of Organometallic Chemistry (2003) 211-214 phosphine and P-anisoyl-diphenylphosphine. X-ray crystal Germasesquioxane structure of [RhCp*(Ph»PC(O)CH;)Cl], 112 Synthesis and characterization of alkylgermasesquioxanes, 135 Cross-coupling Germoxane Pd-catalyzed C-arylation of unsaturated compounds with pentava- Synthesis and characterization of alkylgermasesquioxanes, 135 lent triarylantimony dicarboxylates, 176 Hafnocene Crystal structure Reactions of oligosilyl potassium compounds with Group 4 Synthesis and crystal structure of a novel pentanuclear complex of tin (IV) with heterocyclic sulfur and nitrogen donor ligands, 5 metallocene dichlorides, 149 Cyclohexene Hemilabile ligands Synthesis of Ru(II) complexes of the new 1-[(P-diphenyl)-2- Dehydrogenation of cyclohexenes to cyclohexadienes by phosphinoethy]]-3,5-dimethylpyrazole ligand and study of their {(PPh;),Rh]~. The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(n*- reactivity toward terminal alkynes, 126 C,Hs)Rh(PPh;)>][c/o-sCoB , |H ¢Bre], | Homogeneous catalysis Cyclometallation Ruthenium complexes with 1,1’-biisoquinoline as ligand. Synthesis and hydrogenation activity, 197 On the mechanism of the cyclopalladation reaction of benzyl- Hydride compounds benzylidene-amine with palladium(II) acetate in acetic acid, 192 Rhenium pentahydride complexes: characterisation and protona- Cyclotrimerisation tion reactions. Crystal structure of ReH;L'L? (L' = Ph,PO- Generation of nickel(0)—aryne and nickel(II)—biphenyldiyl com- (CH>),OPPh>; L* = P(OCH3)3, P(OCH2CHs)s), 103 plexes via in situ dehydrohalogenation of arenes. Molecular Hydroformylation structures of [Ni(2,2’-C,.H4C,H4)(depe)] and C>-hexabenzotri- Synthesis and transition metal chemistry of ‘phosphomide’ ligands: phenylene, 8 a comparison of the reactivity and electronic properties of diphenyl-P -perfluoro-octanoyl-phosphine, P-acetyl-diphenyl- Dehydrogenation phosphine and P-anisoyl-diphenylphosphine. X-ray crystal Dehydrogenation of cyclohexenes to cyclohexadienes by structure of [RhCp*(Ph,PC(O)CH;)C1,], 112 {(PPh;)»Rh]~. The isolation of an intermediate in the dehy- Hydrogenation drogenation of cyclohexane to benzene: crystal structure of [(n*- Ruthenium complexes with 1,1’-biisoquinoline as ligand. Synthesis C,Hg)Rh(PPh;)>][c/oso-CB,,H¢Bre], | and hydrogenation activity, 197 Dehydrohalogenation Hydrogen bonds Generation of nickel(0)—aryne and nickel(II)—biphenyldiyl com- The first pyrazole molybdenum(0) complexes: cis-[Mo(CO),- plexes via in situ dehydrohalogenation of arenes. Molecular (Hdmpz),] crystallizes as a N-H---OC hydrogen-bonded structures of [Ni(2,2’-C,.H4C,H4)(dcepe)] and C,-hexabenzotri- dimer, 120 phenylene, 8 Dendrimer Infrared spectra Diels—Alder reaction of anthracene and N-ethylmaleimide on the Alkynylcarbyne(bipyridine)dicarbonyl(triflouroacetato) complex- carbosilane dendrimer, 96 es—synthesis and detection of reversible association in solu- Density functional calculations tion, 16 Aminosilanolates as precursors of four- and eight-membered Insertion reaction (SiNSiO)-rings, 24 Generation of nickel(0)—aryne and nickel(II)—biphenyldiyl com- Denticity plexes via in situ dehydrohalogenation of arenes. Molecular Synthesis of titanium(IV) ferrocenylaminate complexes, 73 structures of [Ni(2,2’°-Cg>H4CoH4)(dcpe)] and C-hexabenzotri- Diels — Alder phenylene, 8 Diels—Alder reaction of anthracene and N-ethylmaleimide on the lodogermane carbosilane dendrimer, 96 PdCl, and NiCl,-catalyzed hydrogen—halogen exchange for the Dihydrogen compounds convenient preparation of bromo- and iodosilanes and Rhenium pentahydride complexes: characterisation and protona- germanes, 90 tion reactions. Crystal structure of ReH;L'L? (L' = Ph,PO- lodosilane (CH>)2OPPh>; L° = P(OCH3)3, P(OOCH2CH;)3), 103 PdCl, and NiCl,-catalyzed hydrogen—halogen exchange for the 2-(Dimethylphosphinomethy])phenylsilanes convenient preparation of bromo- and iodosilanes and 2-(Dimethylphosphinomethyl)- and 2-(methylthiomethyl)pheny] si- germanes, 90 licon compounds: higher coordination with soft donors, 167 2-(Dimethylphosphinomethyl)phenylsilyl triflate L-Lactide 2-(Dimethylphosphinomethyl)- and 2-(methylthiomethyl)phenyl si- Syntheses of bis- and tetra(trimethylsilyl) substituted lanthanocene licon compounds: higher coordination with soft donors, 167 methyl complexes and their catalyses for polymerizations of Dinuclear half-sandwich methyl methacrylate, e-caprolactone and L-lactide, 42 Syntheses of dinuclear titanium constrained geometry complexes Living polymerizations with polymethylene bridges and their copolymerization proper- Syntheses of bis- and tetra(trimethylsilyl) substituted lanthanocene ties, 53 methyl complexes and their catalyses for polymerizations of methyl methacrylate, e-caprolactone and L-lactide, 42 Ethylene/styrene copolymerization Syntheses of dinuclear titanium constrained geometry complexes Macrocycle with polymethylene bridges and their copolymerization proper- Synthesis and crystal structure of a novel pentanuclear complex of ties, 53 tin (IV) with heterocyclic sulfur and nitrogen donor ligands, 5 Maleimide Ferrocenylaminate ligands Diels—Alder reaction of anthracene and N-ethylmaleimide on the Synthesis of titanium(IV) ferrocenylaminate complexes, 73 carbosilane dendrimer, 96 Subject Index of Volume 667 / Journal of Organometallic Chemistry (2003) 211-214 Metalation Nucleophilic substitution Polychlorinated metallo-siloxanes of iron, molybdenum and Modelling S\2 nucleophilic substitution at silicon by structural tungsten - structure of 1-[dicarbonyl(n°-cyclopentadienyl)fer- correlation with X-ray crystallography and NMR spectroscopy, rio}-1,1,3,3,3-pentachlorodisiloxane, 35 66 Metallo-siloxane Polychlorinated metallo-siloxanes of iron, molybdenum and Oximes tungsten - structure of 1-[dicarbonyl(n°-cyclopentadienyl)fer- Triorganoarsenic(V) compounds with internally functionalized rio}-1,1,3,3,3-pentachlorodisiloxane, 35 oximes: synthetic and spectroscopic aspects of [R3;As(CI)L], Methyl methacrylate {[R3;As(OH)L] and [R3AsL,]: crystal and molecular structure of [Pr;AsOH]* Cl, 61 Syntheses of bis- and tetra(trimethylsilyl) substituted lanthanocene methyl complexes and their catalyses for polymerizations of methyl methacrylate, ¢-caprolactone and L-lactide, 42 Palladium-catalyzed 2-(Methylthiomethyl)phenylsilanes Pd-catalyzed C-arylation of unsaturated compounds with pentava- lent triarylantimony dicarboxylates, 176 2-(Dimethylphosphinomethyl)- and 2-(methylthiomethyl)phenyl si- Palladium(II) acetate licon compounds: higher coordination with soft donors, 167 On the mechanism of the cyclopalladation reaction of benzyl- 2-(Methylthiomethyl)phenylsily! triflate benzylidene-amine with palladium(II) acetate in acetic acid, 192 2-(Dimethylphosphinomethyl)- and 2-(methylthiomethyl)phenyl si- Pendant double bonds licon compounds: higher coordination with soft donors, 167 Reduction-induced double bond coordination and multiple C-H Molybdenum activation in fully-substituted titanocenes bearing a pendant Alkynylcarbyne(bipyridine)dicarbonyl(triflouroacetato) complex- double bond or an eight-membered hydrocarbyl ansa-chain, es—synthesis and detection of reversible association in solu- 154 tion, 16 Pentacoordinate Synthesis and characterization of organotransition metal double Modelling S\2 nucleophilic substitution at silicon by structural u3-RCCo.M (M=Mo, W) cluster complexes containing correlation with X-ray crystallography and NMR spectroscopy, bridged dicyclopentadienyl ligands. Crystal structure of [j13- 66 MeCCo »Mo(CO)g}> [n°-CsH4yC(O) CH>)>, 143 Pentanuclear complex The first pyrazole molybdenum(0) complexes: cis-[Mo(CO),- Synthesis and crystal structure of a novel pentanuclear complex of (Hdmpz)>] crystallizes as a N-—H---OC hydrogen-bonded tin (IV) with heterocyclic sulfur and nitrogen donor ligands, 5 dimer, 120 2-(Phenylhydrazino)pyridine complexes Molybdenum complexes Tetracarbonylmolybdenum complexes of 2-(phenylhydrazino)pyr- Tetracarbonylmolybdenum complexes of 2-(phenylhydrazino)pyridine ligands. Correlations of spectroscopic data with pyridyl idine ligands. Correlations of spectroscopic data with pyridyl substituent effects, 81 substituent effects, 81 Phosphines Synthesis and transition metal chemistry of ‘phosphomide’ ligands: Neodocene methyl a comparison of the reactivity and electronic properties of Syntheses of bis- and tetra(trimethylsilyl) substituted lanthanocene diphenyl-P -perfluoro-octanoyl-phosphine, P-acetyl-diphenyl- methyl complexes and their catalyses for polymerizations of phosphine and P-anisoyl-diphenylphosphine. X-ray crystal methyl methacrylate, ¢-caprolactone and L-lactide, 42 structure of [RhCp*(Ph,PC(O)CH;)C1,], 112 Neutral Ni(II) complexes Phosphites New neutral nickel(II) complexes bearing pyrrole-imine chelate Rhenium pentahydride complexes: characterisation and protona- ligands: synthesis, structure and norbornene polymerization tion reactions. Crystal structure of ReH,L'L? (L' = Ph,PO- behavior, 185 (CH>),OPPh;; L* = P(OCH3)3;, P(OCH2CH;)3), 103 Nickel P—N ligands Generation of nickel(0)—aryne and nickel(I1)—biphenyldiyl com- Synthesis of Ru(II) complexes of the new _ 1-[{(P-diphenyl)-2- plexes via in situ dehydrohalogenation of arenes. Molecular phosphinoethyl]-3,5-dimethylpyrazole ligand and study of their structures of [Ni(2,2’-C,H4C.H4)(dcepe)] and C,-hexabenzotri- reactivity toward terminal alkynes, 126 phenylene, 8 Polymethylene bridge Nitrogen ligands Syntheses of dinuclear titanium constrained geometry complexes Ruthenium complexes with 1|,1’-biisoquinoline as ligand. Synthesis with polymethylene bridges and their copolymerization proper- and hydrogenation activity, 197 ties, 53 NMR Preparations X-ray structures Modelling S\2 nucleophilic substitution at silicon by structural Synthesis of titanium(IV) ferrocenylaminate complexes, 73 correlation with X-ray crystallography and NMR spectroscopy, Pyrazoles 66 The first pyrazole molybdenum(0) complexes: cis-[Mo(CQ),- Triorganoarsenic(V) compounds with internally functionalized (Hdmpz)>] crystallizes as a N-—H---OC hydrogen-bonded oximes: synthetic and spectroscopic aspects of [R3As(CI)L], dimer, 120 [R;As(OH)L] and [R;AsL,]: crystal and molecular structure of [Pr;AsOH]* Cl, 61 Rhenium Norbornene Rhenium pentahydride complexes: characterisation and protona- New neutral nickel(II) complexes bearing pyrrole-imine chelate tion reactions. Crystal structure of ReH;L'L* (L' = Ph,PO- ligands: synthesis, structure and norbornene polymerization (CH>),OPPh;; L* = P(OCH;);. P(OCH»CH;);), 103 behavior, 185 Rhodium Nuclear magnetic resonance Dehydrogenation of cyclohexenes to cyclohexadienes by Tetracarbonylmolybdenum complexes of 2-(phenylhydrazino)pyr- {(PPh;)»Rh]*. The isolation of an intermediate in the dehy- idine ligands. Correlations of spectroscopic data with pyridyl drogenation of cyclohexane to benzene: crystal structure of [(n*- substituent effects, 81 C,Hs)Rh(PPh;)>|[c/oso-CB,, H¢Brg], | 214 Subject Index of Volume 667 / Journal of Organometallic Chemistry (2003) 211-214 Rhodium complexes double bond or an eight-membered hydrocarbyl ansa-chain, Synthesis and transition metal chemistry of ‘phosphomide’ ligands: 154 a comparison of the reactivity and electronic properties of Trialkylarsenic(V) diphenyl-P -perfluoro-octanoyl-phosphine, P-acetyl-diphenyl- Triorganoarsenic(V) compounds with internally functionalized phosphine and P-anisoyl-diphenylphosphine. X-ray crystal oximes: synthetic and spectroscopic aspects of [R3As(CI)L], structure of [RhCp*(Ph,PC(O)CH;)CI,], 112 [R;As(OH)L] and [R;AsL,]: crystal and molecular structure of Ruthenium [Pr;AsOH]* Cl~, 61 Ruthenium complexes with 1,1’-biisoquinoline as ligand. Synthesis Trimethylsilyl substituted samarocene methyl and hydrogenation activity, 197 Syntheses of bis- and tetra(trimethylsilyl) substituted lanthanocene Synthesis of Ru(II) complexes of the new 1-[(P-diphenyl)-2- methyl complexes and their catalyses for polymerizations of phosphinoethy]]-3,5-dimethylpyrazole ligand and study of their methyl methacrylate, e-caprolactone and L-lactide, 42 reactivity toward terminal alkynes, 126 Tungsten Alkynylcarbyne(bipyridine)dicarbonyl(triflouroacetato) complex- Samarocene methyl es—synthesis and detection of reversible association in solu- Syntheses of bis- and tetra(trimethylsilyl) substituted lanthanocene tion, 16 methyl complexes and their catalyses for polymerizations of Synthesis and characterization of organotransition metal double methyl methacrylate, ¢-caprolactone and L-lactide, 42 u3-RCCo»M (M=Mo, W) cluster complexes containing Silicon bridged dicyclopentadienyl ligands. Crystal structure of [p3- Aminosilanolates as precursors of four- and eight-membered MeCCo »Mo(CO)g]> [n°-CsHyC(O) CH3), 143 (SiNSiO)-rings, 24 2-(Dimethylphosphinomethyl)- and 2-(methylthiomethyl)pheny] si- Vinylic polymerization licon compounds: higher coordination with soft donors, 167 New neutral nickel(II) complexes bearing pyrrole-imine chelate Modelling S\2 nucleophilic substitution at silicon by structural ligands: synthesis, structure and norbornene polymerization correlation with X-ray crystallography and NMR spectroscopy, behavior, 185 66 Vinylidenes Polychlorinated metallo-siloxanes of iron, molybdenum and Synthesis of Ru(II) complexes of the new _ 1-[(P-diphenyl)-2- tungsten - structure of 1-[dicarbonyl(n°-cyclopentadieny]l)fer- phosphinoethy]]-3,5-dimethylpyrazole ligand and study of their rio]-1,1,3,3,3-pentachlorodisiloxane, 35 reactivity toward terminal alkynes, 126 Siloxane Diels—Alder reaction of anthracene and N-ethylmaleimide on the X-ray carbosilane dendrimer, 96 Triorganoarsenic(V) compounds with internally functionalized Silylanions oximes: synthetic and spectroscopic aspects of [R3As(CI)L], Reactions of oligosilyl potassium compounds with Group 4 [R;As(OH)L] and [R;AsL,]: crystal and molecular structure of metallocene dichlorides, 149 [Pr;AsOH] “Cl, 61 Silyl transition metal compounds X-ray crystallography Reactions of oligosilyl potassium compounds with Group 4 Reduction-induced double bond coordination and multiple C-H metallocene dichlorides, 149 activation in fully-substituted titanocenes bearing a pendant Si-pentacoordination double bond or an eight-membered hydrocarbyl ansa-chain, 2-(Dimethylphosphinomethyl)- and 2-(methylthiomethyl)phenyl si- 154 licon compounds: higher coordination with soft donors, 167 X-ray diffraction Structural correlation Synthesis and characterization of alkylgermasesquioxanes, 135 Modelling S\2 nucleophilic substitution at silicon by structural X-ray structure correlation with X-ray crystallography and NMR spectroscopy, Dehydrogenation of cyclohexenes to cyclohexadienes by 66 [(PPh;)»Rh]*. The isolation of an intermediate in the dehy- Structure elucidation drogenation of cyclohexane to benzene: crystal structure of [(n7- Aminosilanolates as precursors of four- and eight-membered C.Hs)Rh(PPh;)>][closo-CB,,H¢Bre], 1 (SiNSiO)-rings, 24 2-(Dimethylphosphinomethyl)- and 2-(methylthiomethyl)phenyl si- Structures licon compounds: higher coordination with soft donors, 167 Synthesis and characterization of alkylgermasesquioxanes, 135 Synthesis and characterization of organotransition metal double U3-RCCo»M (M=Mo, W) cluster complexes containing Titanium bridged dicyclopentadienyl ligands. Crystal structure of [p;- Reduction-induced double bond coordination and multiple C—H MeCCo2Mo(CO)s}> [n°-CsHyC(O) CH], 143 activation in fully-substituted titanocenes bearing a pendant X-ray study double bond or an eight-membered hydrocarbyl ansa-chain, Modelling S\2 nucleophilic substitution at silicon by structural 154 correlation with X-ray crystallography and NMR spectroscopy, Titanium(IV) complexes 66 Synthesis of titanium(IV) ferrocenylaminate complexes, 73 Titanocene Zirconocene Reduction-induced double bond coordination and multiple C-H Reactions of oligosilyl potassium compounds with Group 4 activation in fully-substituted titanocenes bearing a pendant metallocene dichlorides, 149