Table Of Content

of Or ournal an : hh www.elsevier.nl/locate/jorganchem creme ELSEVIER Journal of Organometallic Chemistry 619 (2001) 331-333 Contents of Volume 619 Regular papers Synthesis of rhodium(III) complexes with the chiral phosphine (S)-Ph,PCH,CHMeCH,OH. Crystal structure of (Sp).S-)-[(n°- C,Me,)RhCI(n?-PPh,CH,CHMeCH,OH-—P,O)]BF,, Oe ee ee en ee ee re es ee ee gee ee Be er Syntheses and ligand properties of 1,3-dit-butyl-2,3-dihydro-1,3-diboroles. Rhodium-(n°-2,3-dihydro-1,3-diborole) and rhodium-(n°-2,3-dihydro-1,3-diborolyl) complexes is. Se: See, SL NG WEIS 5g. ove RW a oT a oe by a ae el de Oca eee ae ee re eae oe Organometallic rhodium (1) complexes with 1-alkylaminopyrazole ligands Sas: SENDS: a. I I, SO I ee a aS Ae a CN ae ae I ee eed SOULS a cee « ees 14 Nature of the metal—ligand bond in trivalent neodymium complexes with neutral m-donor ligands. A theoretical study i: ey Bs GI sida. o> oe ha eee ea ae i ee ee ee ee et Wo ee 0 ee oe ok 24 Preparations and selectivities of magnesium-based mixed cuprates ae: ON Thee, Ga op 5.3% 88a e 4 ke & ee 0a ad Be tee ow ae a Oe ale Wee es Ok aes 3] Aluminium zirconium (+3 and +4) heterometallic hydrido complexes of compositions [(n°-C;H;),Zr(u-H)].(u-H)AICI, and [(n°- C;H,),ZrH(p-H),],Al Fad. GR, Te ee, Fis Te, Be. TO ago ne oe ES OO a 1 Oe Oe he 36 Synthesis and structural characterization of several tris(2-methyl-2-phenylpropyl)tin carboxylates containing germanium Sak Cs as I, Ss BEG Gn eae 6 Rn i RR: POR aS (NR LE le ble “ee Racer Une eer RR OAR a ace we) Sos ee 45 Synthesis of highly ethynylated mono and dinuclear Pt(II) tethers bearing the 4,4’-bis(ethynyl)biphenyl (debp) unit as central core na.¥ . eee, ©. ae ee, Fr; Sees, 4. Ge, FA «cs hie His Fee be ee Sa ee ce ed eee es 49 Benzyl group abstraction from Ti(CH,Ph), by B(C,F,;), and [Ph,C][B(C,F),] to form Ziegler— Natta and carbocationic alkene polymeriza- tion initiators Ee a Perna Fe. | ee ae ee Ree eee se RS ce ey RS Ps ge ane ee a OR ee Re ear ae OS EES 62 Multiply trimethylstannyl substituted ferrocenes synthesis, NMR studies, X-ray structural analysis and electrochemistry N. Lenze, B. Neumann, A. Salmon, A. Stammler, H.-G. Stammler, P. Jutzi......2..2.... .e.ee. ee.e .ee.e .ee e 74 Funktionelle Phosphane: Part XI. Optisch reine B-Aminophosphane und B-Aminophosphinite fiir die komplexkatalysierte Reduktion organischer Carbonylverbindungen. Molekilstrukturen von [(1.R,2R)-Ph,PCH(Ph)CH(Me)NH,Me]JCl, (1R,2S)- Ph,PCH(Ph)CH(Me)NHSO,Me und [{(1.R,2R)-Ph,PCH(Ph)CH(Me)NHMe-kN,kP}Rh(n*-1,5-C,H,,)B|F , ee I Ms ae aa. gu iw 0 aE eek OU SB ee LE RCE eid OO ere ee Foon en ers ae PaaS 8 ed ae 88 Donor-funktionalisierte Alkinyle von Titan(IV), Kupfer(I) und Silber(I); Festkérperstrukturen von [Ti}(C=CCH,NMe,), und {{Ti](C=C’Bu), }C uC=CC=CC,H, W. Frosch, S. Back, H. Miiller, K. Kéhler, A. Driess, B. Schiemenz, G. Huttner, H. Lang....................005. 99 Disilene R*XSi=SiXR* (R*=SitBu,) mit silictumgebundenen H- und Hal-Atomen X: Bildung, Isomerisierung, Reaktionen oe a PCC SS eee. hire ree eo Ce ee ee CeCe 110 Modelling nucleophilic substitution at silicon using hypervalent silicon compounds based on urea ligands A.R. Bassindale, $.J. Giynn, P.G. Taylor, N. Auner, B. Herrechaft ... . 2.0... ce eee tw ee eee 132 The effect of different bithienyl spacers on the linear and non-linear optical properties of organometallic chromophores derived from [Fe,(n°-C;H.)>(CO)>(u-CO)(u-C—CH,)]* [BF,]~. Crystal structure of [Fe,(n°-C;H,)(CO),(p-CO)(u-(E)-C-CH=CH-7-(thieno[3,2- e][1]benzothiophene))]* [BF,]~ R.D.A. Hudson, A.R. Manning, D.F. Nolan, I. Asselberghs, R. Van Boxel, A. Persoons, J.F. Gallagher. ............... 332 Contents of Volume 619/ Journal of Organometallic Chemistry 619 (2001) 331-771 Charge transfer salts of the lanthanides: the crystal structure of [Yb(Tp“*™*),][TCNE]-(THF), ee ee a oe if ended dt ehm icwe ese k a Odo’) ob a A a ee wien wate ele ees SR eee 152 Structural studies of diorganotin(IV) sulphonates The crystal structures of [(n-C,H,),Sn{p-OSO,C,H,(CH,);}>],, and its partially hy- drolyzed product [(n-C,H,).Sn{(p-OH)(p-OSO,C,H.(CH;),)}],, ee NIT eee Pee eee eee So ee eTe e eee ee ee Ae 157 Thioether- and selenoether-carboxylates in palladium chemistry: conclusive proof of hemilabile properties of O—Se ligands M.W. Esterhuysen, R. Brill, H.G. Raubenheimer, C. Esterhuysen, G.J. Kruger... 0... tee ete ee et teens 164 New trisubstituted cyclopentadienyl ligands: synthesis, characterisation and catalytic properties of mono and dinuclear cobalt, rhodium, iron and ruthenium complexes ee eee, ae es, ee, ee ee s,s kab Back Wee wh ee Ree alee OF kote eee eS 179 Selective CO oxidation of heterometallic carbonyl clusters with the oxygen transfer reagent (p-CH,0C,H,),TeO. Crystal structures of (u,-S)FeCoMo(CO).(n°-C;H,COCH,)(PPh,;) and (,-Se)FeCoMo(CO),(n°-C;H,COCH;)(PPh,) AE od OS A re ie eee ee ere re ee Se ee i a aa Or er eee eee ae 194 Synthesis and crystal structure of bis[(4S,5S)-4,5-dihydro-4,5-diphenyl-2-(2’-oxidophenyl-yO)oxazole-yN]copper(II) and its application in the asymmetric Baeyer—Villiger reaction fe we ee Re OR ere rate ee Tk ee LEE eee ee 204 Stabilisation of alkynyl dithiocarboxylates at a ruthenium centre: X-ray crystal structures of [Ru(H)(CO)(S,CC=CPh)(PPh;,),], {[Ru(CO)(CPh=CHPh)(S,CC=CPh)(PPh,),] and [Ru(CO)(C=CMes)(S,CC=CPh)(PPh;),] a en eee Sn So eee y.G ee. BN oon ® > wae: sce Ore eels gee A Sle OB ed ee 209 Synthesis, spectroscopic and structural characterisation of complexes of the new ditelluroether 1,2-bis(methyltelluromethyl)benzene, o-C,H,(CH,TeMe),. X-ray structures of [Mn(CO),Cl{o-C,H,(CH,TeMe),}] and [W(CO),{o-C,H,(CH,TeMe),}] ee he a oe aie ela asi ab oha pie hk hae: e286 kw ae We bAk 66 ado bee wee 218 Synthesis, solution and solid-state NMR spectra of methyl 4,6-O-benzylidene-2,3-bis-O-(organostannylmethyl)-«-D-glucopyranosides: Crystal structure of methyl 4,6-O-benzylidene-2,3-bis-O-[(dimethylphenylstannyl)methyl]-«-D-glucopyranoside S.J. Garden, W.T.A. Harrison, R.A. Howie, i. Rufimo, J.L. Wardell... 0. ce te wc eee ee ee eee eens 226 Direct synthesis of alkyldialkoxysilanes by the reaction of silicon, alcohol and alkene using a high-pressure flow reactor ES ree ee a ee ee ee ere 235 A shortcut hydroformylation route to 7-formyl-5,6-dihydroindolizine from 1-allyl-2-formylpyrrole a gS i ee te Fhe eae eee eos whee weenie sek ese @ ies 241 Transition metal clusters containing carbosilane dendrimers a es a har 9 ke ENS aoe en ele wok Wee Ue ad bee We eg Be ek ee 8 245 Organometallic complexes for second-order non-linear optics: synthesis and molecular quadratic hyperpolarizabilities of n°-monocyclopen- tadienyliron(II) nitrile derivatives with different phosphines. X-ray crystal structure of [FeCp(DPPE)(p-NCC,H,NO,)][PF,]-CH.>Cl, M.H. Garcia, M.P. Robalo, A.R. Dias, M.F.M. Piedade, A. Galvao, W. Wenseleers, E. Goovaerts................... 252 A new class of triazepine—ruthenium(II) complexes: synthesis, crystal structure and NMR spectroscopic properties ee ee, ee ne ce, i Ci CN lS Wee We oetals «3b 4 Wie es & hole 6 ee ee oe wes 265 Insertion of bis-ferrocenylbutadiyne into an osmium hydride bond. The synthesis, structure and electrochemical response of Os,(CO), ,(u-n- Z-FcCC(H)C,Fc)(u-H), es co Rg Ae ts Ea a ee a ew! OS, Beale We Bat OM Wel gta te) Kali: baud we wine te @ eer etetet 271 New routes to diarsenes and arsaphosphenes involving fluorinated arsines M. Boushkhane, H. Gornitzka, J. Escudié, H. Ranaivonjatovo... . 0... ce te eee ewe eee eee eee 275 Synthesis and X-ray crystal structures of ansa-complexes of titanium, zirconium, and hafnium involving methylene-bis(indenyl) ligand A.Y. Agarkov, V.V. Izmer, A.N. Riabov, L.G. Kuz’mina, J.A.K. Howard, I.P. Beletskaya, A.Z. Voskoboynikov........... 280 New catalysts for the alternating copolymerization of 4-tert-butylstyrene/CO A. Bastero, A. Ruiz, J.A. Reina, C. Claver, A.M. Guerrero, F.A. Jalon, B.R. Manzano...................2..000004 287 Phenyl derivatives of mercury functionalised in the 2-position with either a formyl or a vinyl group. Crystal structures of Hg[C,H,(CHO)- 2}Cl and Hg[C,H,(CH=CH,)-2], Pane. Ree, wan. monet, F. Tetome, 6.0. Woeodente, LJ: Wriet.. . 6 ck Heine wo he tee eben e ew be eee 293 Contents of Volume 619/ Journal of Organometallic Chemistry 619 (2001) 331-771 333 Structural and spectroscopic characterization of ruthenium(II) complexes with methyl, formyl, and acetyl groups as model species in multi-step CO, reduction ee a a sg og tp Mere lw MW Atte oe ERR EA 0 Re 6.8 LE Oe Oe ae Ree 299 Synthesis and structure of aminobis(n'-cyclopentadienyl)boranes and related compounds H. Braunschweig, C. von Koblineki, M. Neugebauer, U. Englert, X. Zheng... wtct ewe eee teen nee 305 Note Palladium complex-catalyzed germylation of allylic halides using (germyl)stannanes oR ee ee es Pe ee a ee eee ee ee ee ee ey ee 313 SR ee ee ee ee er es a ee oe ee eyO e ner ee er eee we 319 Fd a ee ee ee ee. Pe ee Pee ee Te ee eee ee Pe ee eG ee Pe 321 ON RE ee re ee ee ee ee ee ee ee ere ae eee ee ee 323 ne SO ED GN oy a:w at, © Wig Ske eset a Me eee W,h ibce BAe eee Rue es KC oo Whee Pe ee! ae ee 325 nC CIR Mr De ee ag Se del we.o rk: Gb ib wn aia) aebade ib oN e eg ere a aaa 16 ak ee ee rete 331