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www.elsevier.nl/locate/jorganchem ELSEVIE4 R Journal of Organometallic Chemistry 599 (2000) 321 299 Author Index of Volume 599 Abd-Elzaher, M.M., 288 Hsu, H.-F., 97 Ozawa, M Akasaka, T., 216 Huang, H., 42 Al-Azab, F., 166 Panda, R., 159 Al-Obaidy, F.N.K., 166 Igau, A., 304 Paolucci, F., 62 Alt, H.G., 261, 275 Iglesias, M., 8 Park, B., 232 Arroyo, M., 170 likura, H., 32 Park, J.T., 49 Ishii, Y., 221 Patel, J., 195 Balakrishna, M.S., 159 Ito, O.. 216 Paz-Sandoval, M.A., 147 Ball, LK., 185 Peregudova, S.M., 87 Bandoh, S., 135 Jang, E.K., 232 Perkins, A.M., 200 Bashilov, V.V., 28, 3 Jawad, J.K., 166 Petrovskii, P.V., 37 Becker, T.M., 308 Jung I 208 Pierre Majoral, J., 304 Beck, W., 238 Jung, J H., 112 Polborn K 238 Bernés, S., 170 Jung I S., 232 Pontorno, L., 298 Birk, U., 247 Prato, M., 62 Brianso, J.L., 170 Kako, M., 216 Buono, G., 304 Kalina, O.G., 28 Butin, K.P Karim, M.M., 261, 275 Qian, M., 143 Kim, C., 123, 208 aiazzo, A Kim, D.H., 232 Rausch, M.D., 107 anty, A.J Kim, J.H., 232 Real, V.M., 178 arano Klaman, A., 159 Retboll, M., 221 eroni, Konishi, T., 216 Richards, R.L., 170 hang, C.-J., 128 Kravchuk, D.N., 3 Rius, J., 170 hang, H.Y., 49 Kuwata, S., 221 Robles J 147 hang, S.-C., 128 Roffia, S., 62 hien, J.C.W., 107 Lazzaroni, R., 298 Rosales-Hoz, M.J., 313 histyakov, A.L., 18 Lee, K., 49 Roth, G., 288 hoi, M.-G., 49 Lee, T.R., 112 Licht, E.H., 261, 275 Sanchez-Cabrera, G., 313 Da Ros, T., 62 Li, R., 143 Sanchez, L., 2 Denisovich, L.1., 87 Liu, S., 74 Santos, A Sasaki, Y Esteruelas, M.A., 178 Maeda, Y., 216 Sawamura Magdesieva, T.V., 3 Seoane, C., 2 Fischer H 288 Maldanis, R.J., 107 Settambolo, R Froneck, T., 288 Mandal, S.K., 308 Shapley, J.R Fujitsuka, M., 216 Marchi, C., 304 Shen, Y., 143 Martin, M., 178 Shim, Y.-B., 232 Garcia-Baez, E.V., 313 Martin, N., 2 Shin, $.C., 232 Geisbauer, A., 238 Mason, M.R., 200 Skelton, B.W., 195 Ginzburg, A.G., 37 Matsuzaka, H., 221 Slanina, Z., 57 Gomez-Lor, B., 8 Mayoral, E., 170 Smith Jr., D.C., 159 Guldi, D.M., 2, 62 McEachin, C., 308 Soheili, S., 247 Gutiérrez, J.A., 147 Miyaji, Y., 135 Sokolov, V.1L., 28, 37 Gvozdev, V., 288 Moriuchi, T., 135 Song, H., 49 Son, S., 123 Hackler, U.E., 32 Nakadaira, Y., 216 Stankevich, L.V., 18 Hammud, J.A., 166 Nakamura, E., 32 Stramm, C., 247 Harrison, P.G., 185 Nishio, M., 221 Siinkel, K., 247 He, R., 143 Nolan, S.P., 159 Sun, S., 74 Herranz, M.A., 2 Novikov, Y.N., 87 Suo, Z., 69 Herrero, J., 178 Hidai, M., 221 Ogio, K.-i., 221 Teuber, R., 247 Hirao, T., 135 Ohama, T., 32 Torr aN 185 Ho, D.M., 308 Oro, L.A., 178 Torrens, H., 170 Hoffman, D.M., 112 Osawa, Ff 57 Tumanskii, B.L., 28 PII: $0022-328X(00)00100-5 olume 599 / Journal of Organometallic Chemistry 599 (2000) 321 Uhlik Wang, Z.-X Yeh Usatov Wei, X., 69 Yin White, A.H., 195 Valh, I 62 Williams, M.T., 308 Zhao, H Vinograc lova, | Woisetschlager, O.I Zhao, X., 5 Vorontsov, E.V Zhou, X.-G., 256 4 Zhou, Z.-Y., 256 Wakahara, T 216 Wang, M., 143 4 www.elsevier.nl/locate/jorganchem ELSEVIER Journal of Organometallic Chemistry 599 (2000) 323-328 Subject Index of Volume 599 Ab initio HF/3-21G method Exohedral mono- and bimetallic hydride complexes of rhodium Endohedral analogs of ferrocene: ab initio theoretical predictions, and iridium with € «o and C.,..: syntheses and electrochemical 18 properties, 87 Alkali-metal fullerides Electron transfer Alkali-metal fullerides MC, (THF), (M = Li, Na, K): a new solu- New n-extended tetrathiafulvalence-containing fulleropyrrolidine tion-phase method for the preparation and characterization dyads endowed with vinyl spacers, 2 with ESR, UV-—NIR and IR spectroscopy, 69 Endohedral clusters Asymmetric catalysis Endohedral analogs of ferrocene: ab initio theoretical predictions New mono- and polyazafulleroids C,.(NR),, (n = 1, 2, 4, 6) derived 18 from a chiral azide containing N- and O-donor groups, and Endohedral metallofullerene reactivity with [RhCK(CO),],, 8 Langmuir—Blodgett films of the endohedral metallofullerene Atom Fe Dy@cC,, at the air—water interface, 42 Endohedral analogs of ferrocene: ab initio theoretical predictions Recent progress in the studies of endohedral metallofullerenes, 74 18 EPR Metal-containing fullerenyl radicals: generation in solution and Carbon-60 EPR study, 28 Triruthenium cluster complexes of C,,, and C,,: carbonyl site ex- ESR spectroscopy change probed via triphenylphosphine ligand derivatives, 97 Alkali-metal fullerides MC, (THF). (M = Li, Na, K): a new solu- Carbon-70 tion-phase method for the preparation and characterization Triruthenium cluster complexes of C,,, and € carbonyl! site ex- with ESR, UV-—NIR and IR spectroscopy, 69 change probed via triphenylphosphine ligand derivatives, 97 n-Extended tetrathiafulvalenes Catalysis New n-extended tetrathiafulvalence-containing fulleropyrrolidine Computational modeling of the elemental catalysis in the Stone dyads endowed with vinyl spacers, 2 Wales fullerene rearrangements, 57 Cluster Ferrocene diphosphine ligand Triruthenium cluster complexes of C,. and € carbony! site A new heterobimetallic palladium—([60}fullerene complex with exchange probed via triphenylphosphine ligand derivatives 97 bidentate bis-1,1'-[P],-ferrocene ligand, 37 Fluorescence Cp ligand New n-extended tetrathiafulvalence-containing fulleropyrrolidine Single-step synthesis of pentaaryl-monohydro[60}fullerenes dyads endowed with vinyl spacers, 2 through fivefold addition of organocopper reagent to C, 27 Fluxional processes Crystal structure Fluxional processes and structural characterization of p,-n~,n~,n°- Fluxional processes and structural characterization of p,-1)°,n°,.n C,,, triosmium cluster complexes, Os,(CO), _ ,(PMe,),,(u.- n.n°.17°-Cy) (2 = 1, 2, 3), 49 Cy triosmium cluster complexes, Os,(CO), _ ,(PMe,), (ps- 1.17°,17°-Cy) (n = 1, 2, 3), 49 Free radical Metal-containing fullerenyl radicals: generation in solution and Cyclic voltammetry New n-extended tetrathiafulvalence-containing fulleropyrrolidine EPR study, 28 dyads endowed with vinyl spacers, 2 [60]F ullerene Cyclopentadiene New mono- and polyazafulleroids C,.(NR),, (n = 1, 2, 4, 6) derived Single-step synthesis of pentaaryl-monohydro[60}fullerenes from a chiral azide containing N- and O-donor groups, and through fivefold addition of organocopper reagent to C, reactivity with [RhCl(CO),],, 8 327 Fullerene A new heterobimetallic palladium—[60)fullerene complex with Donor-—acceptor dyads bidentate bis-1,1'-[P],-ferrocene ligand, 37 New n-extended tetrathiafulvalence-containing fulleropyrrolidine Computational modeling of the elemental catalysis in the Stone dyads endowed with vinyl spacers, 2 Wales fullerene rearrangements, 57 Dynamic NMR Metal-containing fullerenyl radicals: generation in solution and Triruthenium cluster complexes of C,, and C,,: carbonyl site EPR study, 28 exchange probed via triphenylphosphine ligand derivatives, Single-step synthesis of pentaaryl-monohydro[60}fullerenes 97 through fivefold addition of organocopper reagent to C,, 32 Electrochemistry (60]F ullerene A new heterobimetallic palladium—[60}fullerene complex with New n-extended tetrathiafulvalence-containing fulleropyrrolidine bidentate bis-! ,1'-[P],-ferrocene ligand, 37 dyads endowed with vinyl spacers, 2 PIL: $0022-328X(00)00101-7 une 599 ( hemistry 599 (2000) ene complexes Photophysi cs ruthenium clu and Synthes is, electrochemistry I angmuir~— Blodgett deposition and exchar igere Iphosphine photophysics of metal coordinated fullerene— porphyrin dyads 62 Platinum Metal-c« yntaining fullerenyl solution and PR study, 2> 5 ride; complexes Polyazafulleroids syntheses and e New mono and polyazafulleroids C,(NR) d erived from a chiral containing \ Blodget Ss, and reactivity RhCKhCO) Synthesis electrochemistry deposition and photopt sics of porphyrin dyads 62 ofullerenes um-ch emicail Calculauions Endohed ral analogs of fer redictions 18 Rearrangements mputa tional modeling ol W Lilee e f mtamimng AN ind U RhCKCO Bk dgett ; and | Dimet complexes of rhodium and irr idium with ( itheses and electrochemi n and porphyrin er compiexes of ( and j EXC hange probed via trip ylphosphine Sandwich } con iplexes Endohedr al inalogs oO! fterrocet theor retical predictions 1X (28,458 )-4-Azidjoo -1-benzyloxycarb« ylaminocarbonyl) dident DI Vrr I ylidine illeroid New mor 10- and polyazaful (NR) (NR) cleerri) ved n a chiral azide containing \ c ntaining \ gTOU Ips reactivity RhCKCO) RhCKCO) Recent p’ rog in the studies of endohedral met allofullerenes 74 yi-monohyda! Synthesis rganocopper res A lkali-metz al fullerides M(¢ THF). (M=Li, Na, K) a new sol|u tion-phase method for the preparation and characteri zat m with ESR, UV-—NIR and IR spectroscopy oY reagent 4 new he terobimetallic palladiun [60}fullerene complex with synthesis pentaaryl-monohydr bidentate bis-| 1'-{P] errocene ligand, 3 rganocopper Recent progress in th ve studies edral metallofullerenes, 74 Transition met al hydrides Exohedral mono and bimetallic hydride complexes of rhodium -robimetallic 60}fullerene and iridium with ¢ and ¢ syntheses and electrochemi bidentate bis-1,1 rocene ligand, 5 cal p roperties, 87 Phosphine Triosmium carbonyl cluster I uxional processes and str characteriza Fluxional processes and s structural characterization nn-(.nP-M.ne-, ), (u.-n-. tniosmniunl nN c. omp3)l ex4e9 s n7(P N fen) , (( u.-1 tn1os.m iu-m( cluster c> omp3)l, ex4e9s , Os,(CO) Subject Index of Volume 599 / Journal of Organometallic Chemistry 599 (2000) 323-328 Alkenyl ligand terization of (u-n--RCH=CH)(p-R'S)[Fe(CO),}.(u,- Reactions of (p-n--RCH=CH)(p-Cl)Fe(CO), with [(p-EXp- [(u-71--PhCH=CH)Fe(CO),}.(u,-Se), 256 R'E')Fe(CO),|~ (E, I S or Se). Synthesis and charac- terization of (u-n--RCH=CH)(p-R'S)[Fe(CO),].(u,-E) and [(u-1--PhCH=CH)Fe(CO),].(u,-Se), 256 Photoinduced electron-transfer reaction between ( and cyclic Alkyl complexes silicon compounds, 216 Synthesis, X-ray crystallographic, and reactivity studies of rheni Carbosilane um(V) alkyne complexes, 112 Preparation of double-layered dendritic carbosilanes, 123 Alkyne Preparation of ethynylsilane dendrimers, 208 Reactions of cationic dirhodium and diiridium complexes Catalysis [(Cp* M(p-Cl\(u-SPr’),MCp* OTS] (M = Rh, Ir) with termi Alkylaluminophosphonate-catalyzed ring-opening homopolymer nal alkynes. Comparison with the diruthenium system, 221 ization of epichlorohydrin and propylene oxide, 200 Alkyne complexes Chemoselectivity in the rhodium-catalyzed hydroformylation of 4-vinylpyridine: crucial role of phosphine ligand in promot- Synthesis, X-ray crystallographic, and reactivity studies of rheni ing carbonylation instead of hydrogenation, 298 um(V) alkyne complexes, 112 Mechanism of the hydrogenation of 2,5-norbornadiene catalyzed Alkyne(pentacar bonyl)chromium by [Rh(NBD)(PPh,).)BF, in dichloromethane: a kinetic Addition of N-aryl imines to alkyne(pentacarbonyl)chromium and and spectroscopic investigation, 178 tungsten a novel route to alkenyl(amino)carbene com w-Phenylalkyl-substituted zirconocene dichloride complexes as plexes, 288 catalyst precursors for homogeneous ethylene polymeriza- Alkyne(pentacarbony])tungsten tion, 275 Addition of N-aryl imines to alkyne(pentacarbonyl)chromium and Synthesis, characterization and catalytic properties of metalla tungsten a novel route to alkenyl(amino)carbene com cyclic zirconocene complexes, 261 plexes, 288 C coupling Aluminum Kohlenwasserstoffverbriickte Metallkomplexe, XLVIII. Addition Alkylaluminophosphonate-catalyzed ring-opening homopolymer von Bis(ferrocenyl)-1,3-diketonen und von Metalldiketo- ization of epichlorohydrin and propylene oxide, 200 naten an koordinierte, ungesattigte Kohlenwasserstoffe von Aminocyclopentadienyl complexes kationischen Komplexen, 238 Koordinationschemie perhalogenierter Cyclopentadiene und CF bond activation Alkine, XX VI. [1]. Umsetzung von lithiierten Halogency C-F bond activation in polyfluorobenzothiolate compounds mantrenen mit N-Elektrophilen. Molekilstrukturen von Os(III). X-ray structures of [Os(SC.F(F-2)”SC.F.) (OC),Mn{[n°-C.CL,-NH-N-C.Ch] und (OC),Mnfr (PMe,Ph),] [Os(SC,F .).(o-S.C,.F,.(PMe,Ph) and C.H,CKNH,)-1,2], 247 [Os(C,. F .).(0-S,C,F,.4PMe.,Ph).], 170 Azapentadienyl compounds activation Synthesis, characterization and a theoretical investigation of the Synthesis, characterization and catalytic properties of metalla formation of silicon, germanium and tin azapentadiene cyclic zirconocene complexes, 261 compounds from lithium azapentadienyls, 147 moselectivity Azidocyclopentadienyl complexes Chemoselectivity in the rhodium-catalyzed hydroformylation of Koordinationschemie perhalogenierter Cyclopentadiene und 4-vinylpyridine: crucial role of phosphine ligand in promot Alkine, XXVI. [1]. Umsetzung von lithiierten Halogency ing carbonylation instead of hydrogenation, 298 mantrenen mit N-Elektrophilen. Molekilstrukturen von Chiral phosphanes (OC),Mn{[n°-C.Cl,-NH-N-C.Cl,] und (OC),Mnal[n Selective P-N bond cleavage in chiral triquinphosphoranes pro C.H,CWNH,)-1,2], 247 moted by zirconocene complexes, 304 Chromium Bis(diphenylphosph)aimnione Kohlenwasserstoffverbriickte Metallkomplexe, XLVIII. Addition von Bis(ferrocenyl)-1,3-diketonen und von Metalldiketo The reaction of [Ru,(CO),,] with bis(diphenylphosphino)amine naten an koordinierte, ungesattigte Kohlenwasserstoffe von The crystal and molecular structure of [Ru,(CO),,(dppa)] and [Ru,(CO),(dppa),], 313 kationischen Komplexen 238 Bis(ferrocenyl)-| ,3-diketones Synthesis and physical properties of a,@-bis[Co(CO), {p-n Kohlenwasserstoffverbriickte Metallkomplexe, XLVIII. Addition C(R)=C} joligothiophenes > 24 9 von Bis(ferrocenyl)-1,3-diketonen und von Metalldiketo ybalt naten an koordinierte, ungesattigte Kohlenwasserstoffe von Kohlenwasserstoffverbriickte Metallkomplexe, XLVIII. Addition kationischen Komplexen, 238 von Bis(ferrocenyl)-1,3-diketonen und von Metalldiketo- Bis( phosphino )amines naten an koordinierte, ungesattigte Kohlenwasserstoffe von Ruthenium(II) chemistry of phosphorus-based ligands kationischen Komplexen, 238 Ph,PN(R)PPh, (R = Me or Ph) and Ph,PN(Ph)P(E) Ph Complexes (E=S or Se). Solution thermochemical study of ligand Reactions of (p-n°-RCH=CH)\(p-Cl)Fe(CO), with [(p-EXp- substitution reactions in the Cp'RuCkKCOD) (Cp = Cp R'E')Fe(CO),]~ (E, E S or Se). Synthesis and charac- Cp*; COD = cyclooctadiene) system, 159 terization of (u-n°-RCH=CH)(p-R'S)[Fe(CO),].(u,-E) and Bridging-selenium ligand [(u-1°-PhCH=CH)Fe(CO),].(yu,-Se), 256 Reactions of (p-n--RCH=CH)(p-Cl)Fe(CO), with [(u-EXp Conducting polymers R'E')Fe“~CO),]~ (E, I S or Se). Synthesis and charac Synthesis and physical properties of a,@-bis[Co(CO),{p-1 terization of (p-n--RCH=CH)(p-R'S)[Fe(CO),].(u,-E) and C(R)=C} joligothiophenes, 232 [(u-1--PhCH=CH)Fe(CO),].(u,-Se), 256 Crystal structure Brdging-sulfur hgand 4 novel heterobimetallic complex composed of the imide-bridged Reactions of (p-n--RCH=CH)(p-Cl)Fe(CO), with [(p-EXp [3}ferrocenophane and the tridentate palladium(II) com- R'E')Fe“~CO),]~ (E, E S or Se). Synthesis and charac plex, 135 Subject Index of Volume 599 / Journal of Organometallic Chemistry 599 (2000) 323—328 Facial and meridional [N-C-—N intramolecular coordination Ethynylsilane systems: structure of /fac-PtBrMe,{2,6-(pzCH,),C,H Preparation of ethynylsilane dendrimers, 208 1/2C,.H 2,6-(pzCH.,).C,.H 2,6-(bis {(pyrazol-1-yl) [3]Ferrocenophane methyl} phenyl) and mer -PtBr{2,6-(3,5-Me,pzCH,) 4 novel heterobimetallic complex composed of the imide-bridged C,H and an alternative synthetic route to the platinu [3}ferrocenophane and the tridentate palladium(II) com m(IIl) [N-C-N} nel, 195 plex, 135 Kohlenwasserstoffverbriickte Metallkomplexe, XLVIII. Addition Formato complexes von Bis(ferrocenyl)-1,3-diketonen und von Metalldiketo Synthesis and X-ray structures of manganese(l) and rhenium(1) naten an koordinierte, ungesadttigte Kohlenwasserstoffe von formato complexes, fac-(CO),(dppp)M-OC(H)O, 308 kationischen Komplexen, 238 Friedel—Crafts acylation Koordinationschemie perhalogenierter Cyclopentadiene und Intramolecular Friedel-Crafts acylation of acyclic (n*-diene)- Alkine, XXVI. [1]. Umsetzung von lithierten Halogency Fe(CO), complexes, 128 FTIR mantrenen mit trophilen. Molekilstrukturen von FTIR study of thermally induced transformations of trimethyl (OC),Mnf1 ,-N N-C.CL] und (OC),Mnfr silylmethyl acetate in the temperature range 623-813 K C.H,CKNH,)-1! 12s of cationic dirhodium and diiridium complexes Cp* M(u} -Clu-SPr’).MCp* (O TE] J (M = Rh, Ir) with termi Germanium nal alkynes. Comparison with the diruthenium system, 221 Synthesis, characterization and a theoretical investigation of the organosilicon compounds formation of silicon, germanium and tin azapentadiene induced electron-transfer reaction between (¢ compounds from lithium azapentadienyls, 147 silicon compounds, 21¢ oltammetry Half-sandwich complexes resis and physical pr The formation and polymerization behavior of (pentafluoro- C(R )=C} joligothiopher phenyl)-cyclopentadieny! titanium compounds, 107 Heterobimetallic complex Olhigomerization and sim cyclization A novel heterobimetallic complex composed of the imide-bridged methylenecyclopentan talyzed by [3}ferrocenophane and the tridentate palladium(I]) com plexes, 143 plex, 135 yclopentanone Hydroformylation Intramolecular Friedel —( Chemoselectivity in the rhodium-catalyzed hydroformylation of 4- Fe(CO), complexes vinylpyridine: crucial role of phosphine ligand in promot ing carbonylation instead of hydrogenation, 298 Dendrimer Hydrogenation Preparation of double-layered dendritic carbosilanes, 123 Mechanism of the hydrogenation of 2,5-norbornadiene catalyzed Preparation of ethynylsilane dendrimers, 208 by [Rh(NBD)PPh,).]BF, in dichloromethane: a kinetic Diene and spectroscopic investigation, 178 Intramolecular Friedel—Craf acyclic Hydrosilation Fe(CO), complexes Preparation of ethynylsilane dendrimers, 208 Dinuclear complex Hydrosilylation Reactions of cationic dirhodium and diiridium complexes *reparation of double-layered dendritic carbosilanes, 123 [Cp*M(y-Cl\(u-SPr’),.MCp*}OT#] (M = Rh, Ir) with termi nal alkynes. Comparison with the diruthenium system, 221 Insertion reaction Electron-withdrawing Synthesis, X-ray crystallographic, and reactivity studies of rheni- The formation and polymerization behavior of (pentafluoro um(V) alkyne complexes, | 12 phenyl)-cyclopentadienyl titanium compounds, 107 Enthalpy Intramolecular Ruthenium(II) chemistry of phosphorus-based ligands, Ph,PN Intramolecular Friedel-Crafts acylation of acyclic (n*-di- ene)Fe(CO), complexes, 128 (R)PPh, (R = Me or Ph) and Ph,PN(Ph)P(E) Ph, (E=S Intramolecular coordination or Se). Solution thermochemical study of ligand substitu Facial and meridional [N-C-N]~ intramolecular coordination tion reactions in the Cp'RuChCOD) (Cp’'=Cp, Cp systems: structure of fac-PtBrMe,{2,6-(pzCH,).C,H,}:1 COD = cyclooctadiene) system, 159 2C,.H [2,6-(pzCH.,),.C.H,] 2,6-{( p(yrabzoli-1-syl) - Epoxide methyl} phenyl)} and mer -PtBr {2,6-(3,5-Me,pzCH,).- Alkylaluminophosphonate-catalyzed ring-opening homopolymer C.H,}, and an alternative synthetic route to the platinu- ization of epichlorohydrin and propylene oxide, 200 m(II) [N-C-N]~ kernel, 195 Ethylene oligomerization Iridium Oligomerization and simultaneous cyclization of ethylene to Reactions of cationic dirhodium and diiridium complexes methylenecyclopentane catalyzed by zirconocene com [(Cp*M(p-Cl\(p-SPr’),MCp* [OTS] (M = Rh, Ir) with termi- plexes 143 nal alkynes. Comparison with the diruthenium system, 221 Ethylene polymerization Iron -Phenylalkyl-substituted zirconocene dichloride complexes as Intramolecular Friedel-Crafts acylation of acyclic (n*-diene)- catalyst precursors for homogeneous ethylene polymeriza- Fe(CO), complexes, 128 tion, 275 Synthesis, characterization and catalytic properties of metalla- Kohlenwasserstoffverbriickte Metallkomplexe, XLVIII. Addition cyclic zirconocene complexes, 261 von Bis(ferrocenyl)-|,3-diketonen und von Metalldiketo- Ethynyl silane naten an koordinierte, ungesattigte Kohlenwasserstoffe von Preparation of double-layered dendritic carbosilanes, 123 kationischen Komplexen, 238 Subject Index of Volume 599 / Journal of Organometallic Chemistry $99 (2000) 322 3~—3228 Reactions of -n’-RCH#CH \(p-Cl)Fe~CO) with [(n-EXu Opening reaction R'E')Fe(CO),]~ (E, E S or Se). Synthesis and charac Selective P-N bond cleavage in chiral triquinphosphoranes |r e terization of (p-n--RCH=CH)\(p-R 'S)[Fe(CO),}.(u,-E) and moted by zirconocene complexes, 304 I(p-7) PhCH=CH)Fe(CO),}.(u,-Se), 256 Organometallic azapentadienes Kinetics Synthesis, characterization and a theoretical investigation of the Mechanism of the hydrogenation of 2,5-norbornadiene catalyzed formation of silicon germanium and tin azapentadiene by [Rh(NBD)PPh,).]BF, in dichloromethane: a Kinetic compounds from lithium azapentadienyls, 147 and spectroscopic investigation, 178 Organoplatinum Facial and meridional [N-C-N intramolecular coordination Lithium azapentadienyls systems: structure of /fac-PtBrMe,{2,6-(pzCH,).C.H Synthesis, characterization and a theoretical investigation of the 1/2C.H [2,6-(pzCH.).C.H,] 2.6 bis (pyraz42 yl-1-wl) formation of silicon, germanium and tin azapentadiene methyl} phenyl) and = mer-PtBr{2,6-(3,5-Me,pzCH,) compounds from lithium azapentadienyls, 147 C.H and an alternative synthetic route to the piatinu m(I1) [N-C-N] kernel, 195 Manganese Koordinationschemie perhalogemierter Cyclopentadiene und bond activation in polyfluorobenzothiolate comp Alkine, XXVI. [1] Umsetzung von lithiierten Halogency Os(IIl). X-ray structures of [Os(SC,F A F-2) (Se mantrenen mit N- Elektrophilen Molekilstrukturen von (PMe,Ph),] [Os(SC,F .).(0-S,C,.F,(PMe,Ph) (OC),Mn{[n°-C.Cl,-NH-N-C..Cl 4) und (OC),Mnir Os(C, F .).(0-S.C,F,”PMe,Ph).], 170 C.H,CKNH,)-1,2}, 24 Oxidative addition Synthesis and X-ray structures of manganese(I) and rhenium(1) Facial and meridional [N-C-N] intramolecular cox rdination formato complexes, fac (CO),(dppp)M-—OC(H)O, 308 systems structure of fac-PtBrMe 2,6-(pzCH.).C.H Metallacycles 2C,.H [2,6-(pzCH.).C,.H 2,6-(bis {(t pyrazol-1-yl)} Synthesis, characterization and catalytic properties of metallacyclic methyl} phenyl)} and mer -Pt Br {2,6-(3,5-Me,pzCH zirconocene complexes, 261 C.H and an alternative synthetic route to the platinu Metallocene m(II) [N-C-—N] kernel, 195 Selective P—-N bond cleavage in chiral triquinphosphoranes pri Solvent effects on the rate of oxidative addition of me moted by zirconocene complexes, 304 di(4-thiocresol )(2,2’-bipyridyl) platinum(IT) Metallocene complexes w-Phenylalkyl-substituted irconocene dichloride complexes as Palladium catalyst precursors for homogeneous ethylene px Kohlenwasserstoffverbriickte Metallkomplexe, XLVIII. Additior tion, 275 von Bis(ferrocenyl)-1,3-diketonen und von Metalldiketo Metallocenes naten an koordinierte, ungesattigte Kohlenwasserstoffe von The formation and polymerization behavior of (pentafluoro kationischen Komplexen, 238 phenyl)-cyclopentadienyl titanium compounds, 107 Phosphines Methylenecyclopentane Chemoselectivity in the rhodium-catalyzed hydroformylatio Oligomerization and simultaneous cyclization of ethylene to 4-vinylpyridine: crucial role of phosphine ligand u methylenecyclopentane catalyzed by zirconocene com ing carbonylation instead of hydrogenation, 298 plexes 143 Phosphonate MO calculations Alkylaluminophosphonate-catalyzed ring-opening homopolymer Reactions of cationic dirhodium and diuridium < mplexes ization of epichlorohydrin and propylene oxide, 200 [(Cp* M(p-Cl\(u-SPr’), MC p* OTS] (M Rh Ir) with termi Phosphoranes nal alkynes. Comparison with the diruthenium system, 221 Selective P-N bond cleavage in chiral triquinphosphoranes pri Mononuclear moted by zirconocene complexes, 304 Ruthenium(II) chemistry of phosphorus-based ligands, Ph,PN Photoinduced electron transfer (R)PPh, (R = Me or Ph) and Ph,PN(Ph)P(E) Ph, (E = S or Photoinduced electron-transfer reaction between ( and cyclic Se). Solution thermochemical study of ligand substitution silicon compounds, 216 reactions in the Cp’RuClh(COD) (Cp’ = Cp, Cp*; COD inum cyclooctadiene) system, 159 Solvent effects on the rate of oxidative addition of methyl iodide to di(4-thiocresol)(2,,*2 '-bipyridyl) platinum(II), 16¢ N-aryl imines Platinum catalyst Addition of N-aryl imines to alkyne(pentacarbonyl)chromium and Preparation of double-layered dendritic carbosilanes, | 2 tungsten a novel route to alkenyl(amino)carbene com Preparation of ethynylsilane dendrimers, 208 plexes, 288 Polyether N-functionalized cymantrenes Alkylaluminophosphonate-catalyzed ring-opening homopolymer Koordinationschemie perhalogenierter Cyclopentadiene und ization of epichlorohydrin and propylene oxide, 200 Alkine, XXVI. [1]. Umsetzung von lithiierten Halogency Polyfluorobenzothiolate mantrenen mit N- Elektrophilen Molekilstrukturen von C-F bond activation in polyfluorobenzothiolate compounds of (OC),Mn{[n°-C.CL,—NH-N-C.Cl,] und (OC),Mn[n Os(II]). X-ray structures of [Os(SC,F(F-2)(SC,F.).- C.H,CWNH,)-1,2}, 247 (PMe.Ph).], [Os(SC.F.)(o-S,C,F,(PMe,Ph)] and [Os (C.F .).(o-S.C,F,PMe.,Ph).], 170 Olefins Polymerization The formation and polymerization behavior of (pentafluoro Alkylaluminophosphonate-catalyzed ring-opening homopolymer phenyl)-cyclopentadienyl titanium compounds, 107 ization of epichlorohydrin and propylene oxide, 200 Oligothiophenes Polymerizations Synthesis and physical properties of a,@-bis[Co,(CO), {p-n-:n The formation and polymerization behavior of (pentafluoro- C(R)=C} joligothiophenes, 232 phenyl)-cyclopentadienyl titanium compounds, 107 Subject Index of Volume 599 / Journa of Organometallic Chemistry 599 (2000) 3328 Rhenium reactions in the Cp'RuChCOD) (Cp Cp*; COD K ohlenwasserstoffverbriickte Metallkomplexe XLVI Addition cyclooctadiene) system ses 9 von Bis(ferroceny]l)-|! 3-diketonen und von Metalldiketo Thermolysis naten an koordinierte, ungesattigte Kohlenwasserstoffe von C-F bond activation 1 n polyfluorobenzothiolate compounds of kationischen Komplexen, 238 Os(IIl). X-ray structures « f [Os(SC.F,(F-2)(SC,I } - Synthesis anc i X-ray structures of manganese(I) and rhenium(1) (PMe,Ph) [Os(SC,F .).(o-S.A F,PMe,Ph)] and [Os- fT t yrmato complexes, fac-(CO),(dppp)M—OC(H)O, 308 (CF «po S.¢ F,PMe.Ph),], 17 ) Synthesis, X-ray crystallographic and reactivity Studies ol rheni Tin um(V) alkyne comfy 11b9e Synthesis, characterization and a theoretical investigation of the formation ot silicon, germanium and tin azapentadiene compounds from lithium azapentadienyls, 147 Chemoselectivity in the rt :\odium-catalyzed hydroformylation of 4-vinylpyridine: c rucial role of phosphine ligand in promot Titanium ing carbonylation instead of hydrogenation, 298 The formation and polymerization behavior of (pentafluoro- phenyl)-cyclopentadienyl titanium compounds, 107 Mechanism of the hydrogenation of 2,5-norbornadiene catalyzed by [Rh(NBD)(PPh,).|BF, in dichloromethane a kinetic Tridentate podand ligand and spectroscopic investigat ion, 178 4 novel heterobimetallic complex composed of the imide-bridged [3}ferrocenophane and the tridentate palladium(Il) com Reactions ol cationic dirhodium and durdium com plexes [Cp* M(p-Cl)(p-SPr’), M¢ p* OT] (M Rh. Ir) with plex 135 Trimethylsilylacetate terminal alkynes. Comparison with the diruthenium system 71 FTIR study of thermally induced transformations of trimethyl- Ruthenium s1i8l5y lmethyl acetate i nh thtn e temperature range 62 3-813 K Kohlenwasserstoffverbriickte Metallkomplexe XLVIIL. Addition Tungsten von Bis(ferrocenyl)-| ,3-diketonen und von Metalldiketo nkaatteino niasnc hkeono rdKinoimeprtlee,x enu nge2s2a2t tigte Kohlenwasserstoffe von Kohlenwvaosns ersBtios(fffevrerrobcreinyilc)k-t1e ,M3e-dtiakleltoknoemnp leuxned vXoLnV IILM.e tallAddidkiettioo-n naten an koordinierte, ungesattigte Kohlenwasserstoffe von Ruthenium cluster kationischen Komplexen, 2 38 The reaction of [Ru,(CO),.] with bis(diphenylphosphino)amine The crystal and molecular structure of [Ru,(CO) (dppa)] Vinylpyridines and [Ru,(CO),(dppa),]}, 313 Chemoselectivity in the rhodium-catalyzed hydroformylation of Ruthenium(I1) complexes 4-vinylpyridine: crucial role of phosphine ligand in promot Ruthenium(II) chemistry of phosphorus-based ligands ing carbonylation instead of hydrogenation, 298 Ph,.PN(R)PPh, (R = Me or Ph) and Ph,PN(Ph)P(E) Pt (E Solution thermochemical study of ligand X-ray structure substitution reactions in the Cp’RuChCOD) (Cp Cp Synthesis and X-t 4y structures of manganese(I) and rhenium(1) Cp* COD cyclooctadiene) system 159 formato complexes, fac-(CO),(dppp)M-—OC(H)O, 308 Silicon The reaction of [Ru,(CO) with bis(diphenylphosphino)amine Synthesis characterization and a t| heoretical investigation of the The crystal and molecular structure of f [Ru,(CO),,.(dppa)] formation ol silicon, germanium and tin azapentadiene and [Ru,(CO),(dppa).,], 31!I 4 compounds from lithium azapentadienyls, 147 Ylide complexes Solvent effects Synthesis, X-ray crystallographic, and reactivity studies of rheni Solvent effects on the rate of oxidative addition of methyl iodide t um(V) alkyne complexes, 112 di(4-thiocresol)(2,2’-bipyridyl) platinum(II), 166 Synthesis Zirconium Synthesis and X-ray structures of manganese(I) and rhenium(I) w-Phenylalkyl-substituted zirconocene dichloride complexes as formato complexes, fac-(CO),(dppp)M-OC(H)O 308 catalyst precursors for homogeneous ethylene polymeriza- tion 74 Thermal decomposition Selective P-N bond cleavage in chiral triquinphosphoranes pro- FTIR study of thermally induced transformations of trimethyl moted by zirconocene complexes, 304 silyimethyl acetate in the temperature range 62 R13 K Zirconocene complexes 185 Oligomerization and simultaneous cyclization of ethylene to Thermochemistry methylenecyclopentane catalyzec i by zirconocene com- Ruthenium(II) chemistry ol f npih osphorus-based ligands, Ph,PN plexes 143 (R)PPh, (R = Me or Ph) and Ph,PN(Ph)P(E) Ph, (f S or Synthesis, characterization and catalytic properties of metallacyclic Se). Solution thermochemical study of ligand substitution zirconocene complexes, 261

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